Standard Specification for Uranium Oxides with a <sup>235</sup>U Content of Less Than 5% for Dissolution Prior to Conversion to Nuclear-Grade Uranium Dioxide

SCOPE
1.1 This specification covers uranium trioxide (UO3 ) or U3 O8  powders, or mixtures of the two, that are intended for dissolution into uranyl nitrate solution meeting the requirements of Specification C788 prior to conversion into nuclear grade UO2  powder with a  235 U content of less than 5%. This specification defines the impurity and uranium isotope limits for such urania powders that are to be dissolved prior to processing to nuclear grade UO2  as defined in Specification C753.  
1.2 This specification provides the nuclear industry with a general standard for such uranium oxide powders. It recognizes the diversity of conversion processes and the processes to which such powders are subsequently to be subjected. It is therefore anticipated that it may be necessary to include supplementary specification limits by agreement between the buyer and seller.  
1.3 The scope of this specification does not comprehensively cover all provisions for preventing criticality accidents, for health and safety, or for shipping. Observance of this specification does not relieve the user of the obligation to conform to all international, national, state and local regulations for processing, shipping, or any other way of using urania powders (see 2.2 and 2.3).

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09-Jun-2000
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ASTM C1334-96(2000) - Standard Specification for Uranium Oxides with a <sup>235</sup>U Content of Less Than 5% for Dissolution Prior to Conversion to Nuclear-Grade Uranium Dioxide
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: C 1334 – 96 (Reapproved 2000)
Standard Specification for
Uranium Oxides with a U Content of Less Than 5 % for
Dissolution Prior to Conversion to Nuclear-Grade Uranium
Dioxide
This standard is issued under the fixed designation C 1334; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope C 799 Test Methods for Chemical, Mass Spectrometric,
Spectrochemical, Nuclear, and Radiochemical Analysis of
1.1 This specification covers uranium trioxide (UO)or
Nuclear-Grade Uranyl Nitrate Solutions
U O powders, or mixtures of the two, that are intended for
3 8
C 859 Terminology Relating to Nuclear Materials
dissolution into uranyl nitrate solution meeting the require-
C 996 Specification for Uranium Hexafluoride Enriched to
ments of Specification C 788 prior to conversion into nuclear
Less Than 5 % U
grade UO powder with a U content of less than 5 %. This
C 1233 Practice for Determining Equivalent Boron Con-
specification defines the impurity and uranium isotope limits
tents of Nuclear Materials
for such urania powders that are to be dissolved prior to
E 11 Specification for Wire-Cloth Sieves for Testing Pur-
processing to nuclear grade UO as defined in Specification
poses
C 753.
E 105 Practice for Probability Sampling of Materials
1.2 This specification provides the nuclear industry with a
2.2 ANSI Standard:
generalstandardforsuchuraniumoxidepowders.Itrecognizes
ASME NQA-1 Quality Assurance Program, Requirements
the diversity of conversion processes and the processes to
for Nuclear Facilities
which such powders are subsequently to be subjected. It is
2.3 U.S. Government Document:
therefore anticipated that it may be necessary to include
Federal Regulations Title 10, (Energy) Part 50, Domestic
supplementary specification limits by agreement between the
Licensing of Production and Utilization Facilities
buyer and seller.
1.3 The scope of this specification does not comprehen-
3. Terminology
sively cover all provisions for preventing criticality accidents,
3.1 Definition of Term Specific to This Standard:
for health and safety, or for shipping. Observance of this
3.1.1 Terms shall be defined in accordance with Terminol-
specification does not relieve the user of the obligation to
ogy C 859, except for the following:
conform to all international, national, state and local regula-
3.1.2 Commercial Grade Uranium Oxide, n—uranium tri-
tionsforprocessing,shipping,oranyotherwayofusingurania
oxide (UO ), U O , or a mixture of the two, made from
3 3 8
powders (see 2.2 and 2.3).
unirradiated uranium. It is recognized some contamination
2. Referenced Documents with reprocessed uranium may occur during routine process-
ing; this is acceptable provided that the specification for
2.1 ASTM Standards:
Commercial Grade Uranium Oxide as set forth in 4.1 is met.
C 696 Test Methods for Chemical, Mass Spectrometric, and
Spectrochemical Analysis of Nuclear-Grade Uranium Di-
4. Isotopic Content
oxide Powders and Pellets
4.1 For Commercial Grade Uranium Oxide with an isotopic
C 753 Specification for Nuclear-Grade, Sinterable Uranium
content of U between that of natural uranium and 5 %, the
Dioxide Powder
isotopic limits of Specification C 996 shall apply. The specific
C 788 Specification for Nuclear-Grade Uranyl Nitrate So-
isotopic measurements required by Specification C 996 may be
lution
1 3
This specification is under the jurisdiction of ASTM Committee C26 on Annual Book of ASTM Standards, Vol 14.02.
Nuclear Fuel Cycle and is the direct responsibility of Subcommittee C26.02 on Fuel Available from American National Standards Institute, 11 West 42nd St., 13th
and Fertile Material Specifications. Floor, New York, NY 10036.
Current edition approved April 10, 1996. Published May 1996. Available from the Superintendent of Documents, U.S. Government Printing
Annual Book of ASTM Standards, Vol 12.01. Office, Washington, DC 20402.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
C 1334
waived, provided that the seller can demonstrate compliance buyer and seller. Packing or agglomeration during shipping, or
through, for instance, the seller’s quality assurance records. both, may be a concern.
4.2 For commercial uranium oxides not having an assay in 5.8 Dissolvability—At the buyer’s request, a dissolvability
the range set forth in 4.1, the isotopic requirements shall be as test shall be performed by a procedure and to a specification as
agreed upon between the buyer and seller. mutually agreed upon between buyer and seller. The test
parameters(suchastime,temperature,nitricacidmolarity)and
5. Physical and Chemical Requirements
characteristics to be measured (such as dissolution rate, in-
solubles, foam generation) shall be defined by agreement
5.1 Uranium Content—The uranium content shall be deter-
between the buyer and seller.
mined using methods described in Test Methods C 696 and
C 799, or as agreed upon between the buyer and seller. Based
6. Lot Requirements
on the oxygen-to-uranium ratio, the minimum total uranium
6.1 A lot is defined as a quantity of Commercial Grade
content shall also be agreed upon between the buyer and seller.
Uranium Oxide powder that is uniform in isotopic, chemical,
5.2 Impurity Content—The impurity content shall not ex-
and flowability characteristics.
ceed the individual element limit specified in Table 1 on a
6.2 The identity of a lot shall be retained throughout.
uranium weight basis. The summation of the contribution of
6.3 Apowder lot shall form the basis for defining sampling
each of the impurity elements listed inTable 1 shall not exceed
plans used to establish conformance to this specification.
1000 µg/gU. The impurity content shall be determined using
6.4 Sampling plans shall be mutually agreed upon by the
methods described in Test Methods C 696 or as agreed upon
buyer and seller. A suggested sampling procedure is given in
between the buyer and seller.
Annex A1.
5.3 Equivalent Boron Content—The total equivalent
...

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