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ASTM D5983-97(2002)

(Specification)

Standard Specification for Methyl Tertiary-Butyl Ether (MTBE) for Downstream Blending for Use in Automotive Spark-Ignition Engine Fuel

Standard Specification for Methyl <I>Tertiary</I>-Butyl Ether (MTBE) for Downstream Blending for Use in Automotive Spark-Ignition Engine Fuel

SCOPE
1.1 This specification covers requirements for fuel grade methyl tertiary-butyl ether utilized in commerce, terminal blending, or downstream blending with fuels for spark-ignition engines. Other MTBE grades may be available for blending that are not covered by this specification.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.

General Information

Status
Historical
Publication Date
09-Dec-2002
ICS
75.160.20 - Liquid fuels
Technical Committee
D02 - Petroleum Products, Liquid Fuels, and Lubricants
Drafting Committee
D02.A0.02 - Oxygenated Fuels and Components
Current Stage
Ref Project

Relations

Replaces
ASTM D5983-97 - Standard Specification for Methyl <I>Tertiary</I>-Butyl Ether (MTBE) for Downstream Blending for Use in Automotive Spark-Ignition Engine Fuel
Effective Date
10-Dec-2002
Replaced By
ASTM D5983-06 - Standard Specification for Methyl Tertiary-Butyl Ether (MTBE) for Downstream Blending for Use in Automotive Spark-Ignition Engine Fuel
Effective Date
01-May-2006
Referred By
ASTM D8235-21 - Standard Specification for Ethyl Tertiary-Butyl Ether (ETBE) for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
Effective Date
10-Dec-2002
Referred By
ASTM D6227-18(2023) - Standard Specification for Unleaded Aviation Gasoline Containing a Non-hydrocarbon Component
Effective Date
10-Dec-2002
Referred By
ASTM D8076-21b - Standard Specification for 100 Research Octane Number Test Fuel for Automotive Spark-Ignition Engines
Effective Date
10-Dec-2002

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ASTM D5983-97(2002) - Standard Specification for Methyl <I>Tertiary</I>-Butyl Ether (MTBE) for Downstream Blending for Use in Automotive Spark-Ignition Engine FuelASTM D5983-97(2002) - Standard Specification for Methyl <I>Tertiary</I>-Butyl Ether (MTBE) for Downstream Blending for Use in Automotive Spark-Ignition Engine Fuel
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ASTM D5983-97(2002) - Standard Specification for Methyl <I>Tertiary</I>-Butyl Ether (MTBE) for Downstream Blending for Use in Automotive Spark-Ignition Engine Fuel
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Standards Content (Sample)


NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
An American National Standard
Designation: D 5983 – 97 (Repproved 2002)
Standard Specification for
Methyl Tertiary-Butyl Ether (MTBE) for Downstream
Blending for Use in Automotive Spark-Ignition Engine Fuel
This standard is issued under the fixed designation D 5983; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope E 203 TestMethodforWaterUsingVolumetricKarlFischer
Titration
1.1 This specification covers requirements for fuel grade
E 300 Practice for Sampling Industrial Chemicals
methyl tertiary-butyl ether utilized in commerce, terminal
E 1064 Test Method for Water in Organic Liquids by
blending, or downstream blending with fuels for spark-ignition
Coulometric Karl Fischer Titration
engines. Other MTBE grades may be available for blending
that are not covered by this specification.
3. Terminology
1.2 The values stated in SI units are to be regarded as the
3.1 Definitions:
standard. The values given in parentheses are for information
3.1.1 methanol, n—the chemical compound CH OH.
only.
3.1.2 methyl tertiary-butyl ether (MTBE), n—the chemical
2. Referenced Documents compound (CH ) COCH [C H O].
3 3 3 5 12
3.1.3 oxygenate, n—an oxygen-containing ashless, organic
2.1 ASTM Standards:
compound, such as an alcohol or ether, which may be used as
D 130 Test Method for Detection of Copper Corrosion from
a fuel or fuel supplement.
Petroleum Products by the Copper Strip Tarnish Test
D 156 Test Method for Saybolt Color of Petroleum Prod-
4. Performance Requirements
ucts (Saybolt Chromometer Method)
4.1 Methyl tertiary-butyl ether utilized in commerce, termi-
D 381 Test Method for Gum Content in Fuels by Jet
2 nal blending, or downstream blending with fuels for ground
Evaporation
vehicles equipped with spark-ignition engines shall conform to
D 1298 Test Method for Density, Relative Density (Specific
the requirements of Table 1.
Gravity), or API Gravity of Crude Petroleum and Liquid
Petroleum Products by Hydrometer Method
NOTE 1—Individual applications may require a more restrictive sulfur
D 4045 Test Method for Sulfur in Petroleum Products by limit. These requirements are to be negotiated between buyer and seller.
Hydrogenolysis and Rateometric Colorimetry
5. Workmanship
D 4052 Test Method for Density and Relative Density of
5.1 The MTBE shall be visually free of undissolved water,
Liquids by Digital Density Meter
sediment, and suspended matter. It shall be clear and bright at
D 4057 Practice for Manual Sampling of Petroleum and
the ambient temperature or 21°C (70°F), whichever is higher.
Petroleum Products
5.2 The specification defines only a basic purity for this
D 4176 Test Method for Free Water and Particulate Con-
product. The product shall be free of any adulterant or
tamination in Distillate Fuels (Visual Inspection Proce-
contaminant that may render the material unacceptable for its
dures)
commonly used applications.
D 4953 Test Method for Vapor Pressure of Gasoline and
Gasoline-Oxygenate Blends (Dry Method)
6. Sampling
D 5441 TestMethodforAnalysisofMethyltert-ButylEther
6.1 Samples may be obtained by an appropriate procedure
(MTBE) by Gas Chromatography
of Practice D 4057 or Practice E 300. Do not use soldered
metal containers although they are specified in 11.3 of Practice
This specification is under the jurisdiction of ASTM Committee D02 on
E 300, because the soldering flux in the containers may
Petroleum Products and Lubricants and is the direct responsibility of Subcommittee
contaminate the sample. Some soldered cans, such as those
D02.A0 on Gasoline and Oxygenated Fuels.
conforming to the requirements of 7.1 of Practice D 4057 are
Current edition approved Dec. 10, 2002. Published March 2003. Originally
approved in 1996. Last previous edition approved in 1997 as D 5983 – 97.
Annual Book of ASTM Standards, Vol 05.01.
3 5
Annual Book of ASTM Standards, Vol 05.02. Annual Book of ASTM Standards, Vol 15.05.
4 6
Annual Book of ASTM Standards, Vol 05.04. Discontinued. See 2000 Annual Book of ASTM Standards, Vol 15.05.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
D 5983 – 97 (Repproved 2002)
TABLE 1 Performance Requirements
7.2 Appearance—Test Method D 4176, Procedure 1.
Property Limits
7.3 Sulfur—Test Method D 4045 (see Note 2).
Appearance Clear and bright
7.4 Solvent-Washed Gum Content—Test Method D 381,
Color, Saybolt, min + 5
air-jet apparatus.
Sulfur, mg/kg, max 300
Solvent-washed gum content, mg/100 mL, max 5.0
7.5 MTBE, mass %—Test Method D 5441.
Copper strip corrosion, max 1
MTBE, mass %, min 95.0 7.6 Methanol, mass %—Test Method D 5441.
Methanol, mass% , max 0.5
7.7 API Gravity at 15.6°C (60°F)—Practice D 1298.
Vapor pressure, kPa (psi), max 62 (9.0)
Water, mass %, max 0.10
7.8 Density at 15°C—Practice D 1298 or Test Method
API gravity at 15.6°C (60°F) or density at 15°C, Report
D 4052.
kg/l
7.9 Copper Strip Corrosion—Test Method D 130,3hat
50°C (122°F).
acceptable, but because they cannot readily be distinguished
7.10 Water Content—Test Methods E 203 or E 1064.
fromcanswhichdonotmeetthisspecification,theuseofmetal
7.11 Vapor Pressure—Test Method D 4953.
containers is to be avoided.
6.2 Sample Size—Aminimum of about 2 Lor 2 U.S. quarts 7.12 Color, Saybolt—Test Method D 156.
is recommended.
NOTE 2—Test Method D 4045 may require dilution of the sample with
6.3 Lot Size—A lot shall normally consist of the amount
a sulfur-free diluent.
contained in a tanker compartment or other bulk container in
which it is delivered. If this definition does not apply, the
8. Keywords
definition of a lot must be agreed upon between the supplier
8.1 automotive spark-ignition engine fuel; blending; corro-
and purchaser.
sion; impurities; methanol; methyl tertiary-butyl ether; oxy-
7. Test Methods
genate; water content
7.1 The scope of some of the test methods specified below
donotincludeMTBE.Theprecisionofthosetestmethodsmay
differ from the reported precisions when testing MTBE.
APPENDIX
(Nonmandatory Information)
X1. SIGNIFICANCE OFASTM SPECIFICATION FOR MTBE FOR DOWNSTREAM BLENDING FOR USE INAUTOMOTI
...

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ASTM D2699-24a(Test Method)
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SCOPE
1.1 This test method covers an analytical scheme using the gas chromatography/mass spectrometry (GC-MS) to determine the hydrocarbon types present in middle distillates 170 °C to 365 °C boiling range, 5 % to 95 % by volume as determined by Test Method D86, including biodiesel blends with up to 20 % by volume of fatty acid methyl ester (FAME). The detailed hydrocarbon composition, total aromatic hydrocarbon and polycyclic aromatic hydrocarbon contents can be determined. The hydrocarbon types include: paraffins, noncondensed cycloparaffins, condensed dicycloparaffins, condensed tricycloparaffins, alkylbenzenes, indans or tetralins, or both, CnH2n-10 (indenes, etc.), naphthalenes, CnH2n-14 (acenaphthenes, etc.), CnH2n-16 (acenaphthylenes, etc.), and tricyclic aromatics. The content of FAME in biodiesel blends can also be determined by GC.  
1.2 The values stated in acceptable SI units are to be regarded as the standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM D7566-24a(Specification)
Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons

SCOPE
1.1 This specification covers the manufacture of aviation turbine fuel that consists of conventional and synthetic blending components.  
1.2 See Appendix X2 for an expanded description of the procedure for the production and blending of synthetic blend components.  
1.3 This specification applies only at the point of batch origination, as follows:  
1.3.1 Aviation turbine fuel manufactured, certified, and released to all the requirements of Table 1 of this specification (D7566), meets the requirements of Specification D1655 and shall be regarded as Specification D1655 turbine fuel. Duplicate testing is not necessary; the same data may be used for both D7566 and D1655 compliance. Once the fuel is released to this specification (D7566) the unique requirements of this specification are no longer applicable: any recertification shall be done in accordance with Table 1 of Specification D1655.  
1.3.2 Any location at which blending of synthetic blending components specified in Annex A1 (FT SPK), Annex A2 (HEFA SPK), Annex A3 (SIP), Annex A4 synthesized paraffinic kerosine plus aromatics (SPK/A), Annex A5 (ATJ), Annex A6 catalytic hydrothermolysis jet (CHJ), Annex A7 (HC-HEFA SPK), or Annex A8 (ATJ-SKA) with D1655 fuel (which may on the whole or in part have originated as D7566 fuel) or with conventional blending components takes place shall be considered batch origination in which case all of the requirements of Table 1 of this specification (D7566) apply and shall be evaluated. Short form conformance test programs commonly used to ensure transportation quality are not sufficient. The fuel shall be regarded as D1655 turbine fuel after certification and release as described in 1.3.1.  
1.3.3 Once a fuel is redesignated as D1655 aviation turbine fuel, it can be handled in the same fashion as the equivalent refined D1655 aviation turbine fuel.  
1.4 This specification defines the minimum property requirements for aviation turbine fuel that contain synthesized hydrocarbons and lists acceptable additives for use in civil operated engines and aircrafts. Specification D7566 is directed at civil applications, and maintained as such, but may be adopted for military, government, or other specialized uses.  
1.5 This specification can be used as a standard in describing the quality of aviation turbine fuel from production to the aircraft. However, this specification does not define the quality assurance testing and procedures necessary to ensure that fuel in the distribution system continues to comply with this specification after batch certification. Such procedures are defined elsewhere, for example in ICAO 9977, EI/JIG Standard 1530, JIG 1, JIG 2, API 1543, API 1595, and ATA-103, and IATA Guidance Material for Sustainable Aviation Fuel Management.  
1.6 This specification does not include all fuels satisfactory for aviation turbine engines. Certain equipment or conditions of use may permit a wider, or require a narrower, range of characteristics than is shown by this specification.  
1.7 While aviation turbine fuels defined by Table 1 of this specification can be used in applications other than aviation turbine engines, requirements for such other applications have not been considered in the development of this specification.  
1.8 Synthetic blending components and blends of synthetic blending components with conventional petroleum-derived fuels in this specification have been evaluated and approved in accordance with the principles established in Practice D4054.  
1.9 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.10 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.11 This internati...

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ASTM
ASTM D5623-24(Test Method)
Standard Test Method for Sulfur Compounds in Light Petroleum Liquids by Gas Chromatography and Sulfur Selective Detection

SIGNIFICANCE AND USE
5.1 Gas chromatography with sulfur selective detection provides a rapid means to identify and quantify sulfur compounds in various petroleum feeds and products. Often these materials contain varying amounts and types of sulfur compounds. Many sulfur compounds are odorous, corrosive to equipment, and inhibit or destroy catalysts employed in downstream processing. The ability to speciate sulfur compounds in various petroleum liquids is useful in controlling sulfur compounds in finished products and is frequently more important than knowledge of the total sulfur content alone.
SCOPE
1.1 This test method covers the determination of volatile sulfur-containing compounds in light petroleum liquids. This test method is applicable to distillates, gasoline motor fuels (including those containing oxygenates) and other petroleum liquids with a final boiling point of approximately 230 °C (450 °F) or lower at atmospheric pressure. The applicable concentration range will vary to some extent depending on the nature of the sample and the instrumentation used; however, in most cases, the test method is applicable to the determination of individual sulfur species at levels of 0.1 mg/kg to 100 mg/kg.  
1.2 The test method does not purport to identify all individual sulfur components. Detector response to sulfur is linear and essentially equimolar for all sulfur compounds within the scope (1.1) of this test method; thus both unidentified and known individual compounds are determined. However, many sulfur compounds, for example, hydrogen sulfide and mercaptans, are reactive and their concentration in samples may change during sampling and analysis. Coincidently, the total sulfur content of samples is estimated from the sum of the individual compounds determined; however, this test method is not the preferred method for determination of total sulfur.  
1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM D910-24(Specification)
Standard Specification for Leaded Aviation Gasolines

ABSTRACT
This specification covers purchases of aviation gasoline under contract and is intended primarily for use by purchasing agencies. This specification does not include all gasoline satisfactory for reciprocating aviation engines, but rather, defines the following specific types of aviation gasoline for civil use: Grade 80; Grade 91; Grade 100; and Grade 100LL. The gasoline shall adhere to octane rating requirements specified for individual grades, as follows: lean mixture knock value (motor octane number and aviation lean rating); rich mixture knock value (octane and performance number); tetraethyl lead content; color; and dye content (blue, yellow, red, and orange). Conversely, the gasoline shall meet the following requirements specified for all grades: density; distillation (initial and final boiling points, fuel evaporated, evaporated temperatures); recovery, residue, and loss volume; vapor pressure; freezing point; sulfur content; net heat of combustion; copper strip corrosion; oxidation stability (potential gum and lead precipitate); volume change during water reaction; and electrical conductivity.
SCOPE
1.1 This specification covers formulating specifications for purchases of aviation gasoline under contract and is intended primarily for use by purchasing agencies.  
1.2 This specification defines specific types of aviation gasolines for civil use. It does not include all gasolines satisfactory for reciprocating aviation engines. Certain equipment or conditions of use may permit a wider, or require a narrower, range of characteristics than is shown by this specification.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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