Standard Test Method for Determination of Gaseous and Particulate Polycyclic Aromatic Hydrocarbons in Ambient Air (Collection on Sorbent-Backed Filters with Gas Chromatographic/Mass Spectrometric Analysis)

SIGNIFICANCE AND USE
5.1 Polycyclic aromatic hydrocarbons (PAH) as defined by this test method are compounds made up of two or more fused aromatic rings.  
5.2 Several PAH are considered to be probable human carcinogens.  
5.3 PAH are emitted in the atmosphere primarily through wood or fossil fuel combustion.  
5.4 Two- and three-ring PAH are typically present in urban air at concentrations ranging from 10 to several hundred nanograms per cubic metre (ng/m3); those with four or more rings are usually found at concentrations of a few ng/m3 or lower.  
5.5 PAH span a broad spectrum of vapor pressures (for example, from 1.1 × 10–2 kPa for naphthalene to 2 × 10–13 kPa for coronene at 25 °C). Table 1 lists some PAH that are frequently found in ambient air. Those with vapor pressures above about 10–8 kPa will be present in the ambient air substantially distributed between the gas and particulate phases. This test method will permit the collection of both phases. However, particulate-phase PAH will tend to be lost from the particulate filter during sampling due to desorption and volatilization. (A) Many of these compounds sublime.  
5.5.1 The distribution between phases depends on ambient temperature, humidity, types and concentrations of PAH and particulate matter, and residence time in the air. PAH, especially those having vapor pressures above 10–8 kPa, may vaporize from particulate filters during sampling. Consequently, a back-up vapor trap must be used for efficient sampling.  
5.6 Separate analyses of the filter and vapor trap will not reflect the original atmospheric phase distributions and should be discouraged.
SCOPE
1.1 This test method2 specifies sampling, cleanup, and analysis procedures for the determination of polycyclic aromatic hydrocarbons (PAH) in ambient air.  
1.2 This test method is designed to collect both gas-phase and particulate-phase PAH and to determine them collectively.  
1.3 This test method is a high-volume sampling (100 to 250 L/min) method capable of detecting PAH at sub-nanograms per cubic metre (ng/m3) concentrations with sampling volumes up to 350 m3 of air.  
1.4 This test method has been validated for sampling periods up to 24 h.  
1.5 Precision and bias under normal conditions can be expected to be ±35 to 50 %.  
1.6 This test method describes a sampling and analysis procedure for PAH that involves collection from air on a combination fine-particle filter and sorbent trap and subsequent analysis by gas chromatography/mass spectrometry (GC/MS).  
1.7 The range of this test method is approximately 0.05 to 1000 ng/m3 of air sampled.  
1.8 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. See also Section 8 for additional safety precautions.  
1.10 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

Status
Published
Publication Date
28-Feb-2021
Current Stage
Ref Project

Relations

Buy Standard

Standard
ASTM D6209-21 - Standard Test Method for Determination of Gaseous and Particulate Polycyclic Aromatic Hydrocarbons in Ambient Air (Collection on Sorbent-Backed Filters with Gas Chromatographic/Mass Spectrometric Analysis)
English language
14 pages
sale 15% off
Preview
sale 15% off
Preview
Standard
REDLINE ASTM D6209-21 - Standard Test Method for Determination of Gaseous and Particulate Polycyclic Aromatic Hydrocarbons in Ambient Air (Collection on Sorbent-Backed Filters with Gas Chromatographic/Mass Spectrometric Analysis)
English language
14 pages
sale 15% off
Preview
sale 15% off
Preview

Standards Content (Sample)

This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D6209 − 21
Standard Test Method for
Determination of Gaseous and Particulate Polycyclic
Aromatic Hydrocarbons in Ambient Air (Collection on
Sorbent-Backed Filters with Gas Chromatographic/Mass
1
Spectrometric Analysis)
This standard is issued under the fixed designation D6209; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope priate safety, health, and environmental practices and deter-
2 mine the applicability of regulatory limitations prior to use.
1.1 This test method specifies sampling, cleanup, and
See also Section 8 for additional safety precautions.
analysis procedures for the determination of polycyclic aro-
1.10 This international standard was developed in accor-
matic hydrocarbons (PAH) in ambient air.
dance with internationally recognized principles on standard-
1.2 This test method is designed to collect both gas-phase
ization established in the Decision on Principles for the
and particulate-phase PAH and to determine them collectively.
Development of International Standards, Guides and Recom-
mendations issued by the World Trade Organization Technical
1.3 This test method is a high-volume sampling (100 to 250
L/min)methodcapableofdetectingPAHatsub-nanogramsper Barriers to Trade (TBT) Committee.
3
cubic metre (ng/m ) concentrations with sampling volumes up
3 2. Referenced Documents
to 350 m of air.
3
2.1 ASTM Standards:
1.4 This test method has been validated for sampling
D1356Terminology Relating to Sampling and Analysis of
periods up to 24 h.
Atmospheres
1.5 Precision and bias under normal conditions can be
D1357Practice for Planning the Sampling of the Ambient
expected to be 635 to 50%.
Atmosphere
D3631Test Methods for Measuring Surface Atmospheric
1.6 This test method describes a sampling and analysis
Pressure
procedure for PAH that involves collection from air on a
D4840Guide for Sample Chain-of-Custody Procedures
combinationfine-particlefilterandsorbenttrapandsubsequent
E1Specification for ASTM Liquid-in-Glass Thermometers
analysis by gas chromatography/mass spectrometry (GC/MS).
E2251Specification for Liquid-in-Glass ASTM Thermom-
1.7 The range of this test method is approximately 0.05 to
eters with Low-Hazard Precision Liquids
3
1000 ng/m of air sampled.
3. Terminology
1.8 The values stated in SI units are to be regarded as
standard. No other units of measurement are included in this
3.1 Definitions—For definitions of terms used in this test
standard.
method, refer to Terminology D1356.
1.9 This standard does not purport to address all of the
3.2 Definitions of Terms Specific to This Standard:
safety concerns, if any, associated with its use. It is the
3.2.1 sampling effıciency (SE), n—ability of the sampler to
responsibility of the user of this standard to establish appro-
trap and retain PAH; the percent SE is the percentage of the
analyte of interest collected and retained by the sampling
medium when it is introduced into the air sampler and the
1
This test method is under the jurisdiction of ASTM Committee D22 on Air sampler is operated under normal conditions for a period of
Quality and is the direct responsibility of Subcommittee D22.03 on Ambient
time equal to or greater than that required for the intended use.
Atmospheres and Source Emissions.
3.2.2 dynamic retention effıciency, n—ability of the sam-
Current edition approved March 1, 2021. Published April 2022. Originally
approved in 1997. Last previous edition approved in 2013 as D6209–13. DOI:
pling medium to retain a given PAH that has been added to the
10.1520/D6209-21.
2
This test method is based on U.S. Environmental ProtectionAgency Compen-
3
dium Method TO-13A, Compendium of Methods for the Determination of Toxic For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Organic Compounds in Ambient Air, Second Edition, Report No. EPA/625/R-96/ contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
010b, January 1999, available from the National Technical Information Service, Standards volume information, refer to the standard’s Document Summary page on
5285 Port Royal Rd., Springfield, VA 22161, Order No. PB90-11989/AS. the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D6209 − 21
TABLE 1 Formulae and Physical Properties of Selective PAH
Vapor
Melting
Boiling
Compound CAS Regist
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D6209 − 13 D6209 − 21
Standard Test Method for
Determination of Gaseous and Particulate Polycyclic
Aromatic Hydrocarbons in Ambient Air (Collection on
Sorbent-Backed Filters with Gas Chromatographic/Mass
1
Spectrometric Analysis)
This standard is issued under the fixed designation D6209; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
2
1.1 This test method specifies sampling, cleanup, and analysis procedures for the determination of polycyclic aromatic
hydrocarbons (PAH) in ambient air.
1.2 This test method is designed to collect both gas-phase and particulate-phase PAH and to determine them collectively.
1.3 This test method is a high-volume sampling (100 to 250 L/min) method capable of detecting PAH at sub-nanograms per cubic
3 3
) concentrations with sampling volumes up to 350 m of air.
metre (ng/m
1.4 This test method has been validated for sampling periods up to 24 h.
1.5 Precision and bias under normal conditions can be expected to be 635 to 50 %.
1.6 This test method describes a sampling and analysis procedure for PAH that involves collection from air on a combination
fine-particle filter and sorbent trap and subsequent analysis by gas chromatography/mass spectrometry (GC/MS).
3
1.7 The range of this test method is approximately 0.05 to 1000 ng/m of air sampled.
1.8 The values stated in SI units shall are to be regarded as standard. No other units of measurement are included in this standard.
1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety safety, health, and healthenvironmental practices and determine the
applicability of regulatory limitations prior to use. See also Section 8 for additional safety precautions.
1.10 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
1
This test method is under the jurisdiction of ASTM Committee D22 on Air Quality and is the direct responsibility of Subcommittee D22.03 on Ambient Atmospheres
and Source Emissions.
Current edition approved April 1, 2013March 1, 2021. Published April 2013April 2022. Originally approved in 1997. Last previous edition approved in 20122013 as
D6209 – 98 (2012).D6209 – 13. DOI: 10.1520/D6209-13.10.1520/D6209-21.
2
This test method is based on U. S. U.S. Environmental Protection Agency CompendumCompendium Method TO-13,TO-13A, Compendium of Methods for the
Determination of Toxic Organic Compounds in Ambient Air, Second Edition, Report No. EPA/600-4-89/018, June 1988,EPA/625/R-96/010b, January 1999, available from
the National Technical Information Service, 5285 Port Royal Rd., Springfield, VA 22161, Order No. PB90-11989/AS.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D6209 − 21
2. Referenced Documents
3
2.1 ASTM Standards:
D1356 Terminology Relating to Sampling and Analysis of Atmospheres
D1357 Practice for Planning the Sampling of the Ambient Atmosphere
D3631 Test Methods for Measuring Surface Atmospheric Pressure
D4840 Guide for Sample Chain-of-Custody Procedures
E1 Specification for ASTM Liquid-in-Glass Thermometers
E2251 Specification for Liquid-in-Glass ASTM Thermometers with Low-Hazard Precision Liquids
3. Terminology
3.1 Definitions—For definitions of terms used in this test method, refer to Terminology D1356.
3.2 Definitions of Terms Specific to This Standard:
3.2.1 sampling effıciency (SE), n—ability of the sampler to trap and retain PAH. ThePAH; the percent SE is the percentage of the
analyte of interest collected and retained by the sampling medium when it is introduced into the air sampler and the sampler is
operated under normal conditions for a period of time equal to or greater than that required for the intended use.
3.2.2 dynamic retention effıciency, n—ability of the sampling medium to retain a given PAH that has been added to the sorbent
trap in a spiking solution when air is drawn through the
...

Questions, Comments and Discussion

Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.