ASTM B75M-99(2005)

Standard Specification for Seamless Copper Tube [Metric]

ABSTRACT
This specification establishes the requirements for seamless round, rectangular, and square copper tube (UNS Nos. C10100, C10200, C10300, C10800, C12000, and C12200) suitable for general engineering applications. The material of manufacture shall be billets, cast bars, or tube. The tube shall be manufactured by hot- and cold-working processes, shall be cold drawn to the finished size and wall thickness, and shall be supplied in cold-drawn or annealed temper condition. The material shall conform to the chemical composition requirements prescribed for copper, phosphorus, and arsenic, as determined by chemical analysis, and to the mechanical property requirements including tensile strength, yield strength, Rockwell hardness, and straightening. Requirements for grain size, electrical mass resistivity, and dimensions are specified. The following test methods are detailed: grain size, electrical resistivity, tensile and yield strength, and hardness tests, expansion test for round table, microscopical examination, test for hydrogen embrittlement, and nondestructive tests such as electromagnetic (eddy-current), hydrostatic, and pneumatic pressure tests.
SCOPE
1.1 This specification establishes the requirements for seamless round, rectangular, and square copper tube suitable for general engineering applications.
1.1.1 Tubes made from any of the following Copper UNS No. designations shall be supplied unless otherwise specified in the contract or purchase order:Copper UNS No.Type of CopperC10100Oxygen-free electronicC10200Oxygen-free without residual deoxidantsC10300Oxygen-free, extra low phosphorusC10800Oxygen-free, low phosphorusC12000Phosphorus deoxidized, low residual phosphorusC12200Phosphorus deoxidized, high residual phosphorus
1.2 The values stated in SI units are the standard.
1.3 This specification is the companion to inch-pound Specification B 75.
The following hazard statement pertains only to the test method described in Sections , , and of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

• Status: Historical
• Publication Date: 28-Feb-2005
• ICS: 77.150.30 - Copper products
• Technical Committee: B05 - Copper and Copper Alloys
• Drafting Committee: B05.04 - Pipe and Tube

Relations

• Replaces: ASTM B75M-99 - Standard Specification for Seamless Copper Tube [Metric]
• Effective Date: 01-Mar-2005

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: B75M – 99 (Reapproved 2005)
Standard Specification for
Seamless Copper Tube (Metric)
This standard is issued under the fixed designation B75M; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope* B170 Specification for Oxygen-Free Electrolytic Copper—
2 Refinery Shapes
1.1 This specification establishes the requirements for
B193 Test Method for Resistivity of Electrical Conductor
seamless round, rectangular, and square copper tube suitable
Materials
for general engineering applications.
B251M Specification for General Requirements for
1.1.1 Tubes made from any of the following Copper UNS
Wrought Seamless Copper and Copper-Alloy Tube (Met-
No.designationsshallbesuppliedunlessotherwisespecifiedin
ric)
the contract or purchase order:
B577 Test Methods for Detection of Cuprous Oxide (Hy-
Copper UNS No. Type of Copper
drogen Embrittlement Susceptibility) in Copper
C10100 Oxygen-free electronic
B601 Classification for Temper Designations for Copper
C10200 Oxygen-free without residual deoxidants
and Copper Alloys—Wrought and Cast
C10300 Oxygen-free, extra low phosphorus
E3 Guide for Preparation of Metallographic Specimens
C10800 Oxygen-free, low phosphorus
C12000 Phosphorus deoxidized, low residual phosphorus
E8M Test Methods for Tension Testing of Metallic Materi-
C12200 Phosphorus deoxidized, high residual phosphorus
als [Metric]
1.2 The values stated in SI units are the standard.
E18 Test Methods for Rockwell Hardness of Metallic Ma-
1.3 This specification is the companion to inch-pound
terials
Specification B75.
E53 TestMethodforDeterminationofCopperinUnalloyed
1.4 The following hazard statement pertains only to the test
Copper by Gravimetry
method described in Sections 20.5.2.1, 21.2.9, and 21.2.10 of
E62 Test Methods for Chemical Analysis of Copper and
thisspecification: This standard does not purport to address all
Copper Alloys (Photometric Methods)
of the safety concerns, if any, associated with its use. It is the E112 Test Methods for Determining Average Grain Size
responsibility of the user of this standard to establish appro-
E243 Practice for Electromagnetic (Eddy-Current) Exami-
priate safety and health practices and determine the applica- nation of Copper and Copper-Alloy Tubes
bility of regulatory limitations prior to use.
E255 Practice for Sampling Copper and Copper Alloys for
the Determination of Chemical Composition
2. Referenced Documents
E527 Practice for Numbering Metals and Alloys in the
2.1 ASTM Standards:
Unified Numbering System (UNS)
B75 Specification for Seamless Copper Tube
3. Terminology, Specific
B153 Test Method for Expansion (Pin Test) of Copper and
Copper-Alloy Pipe and Tubing 3.1 Definitions of Terms Specific to This Standard:
3.1.1 capable of—the test need not be performed by the
producer of the material. However, should subsequent testing
ThisspecificationisunderthejurisdictionofASTMCommitteeB05onCopper
bythepurchaserestablishthatthematerialdoesnotmeetthese
and CopperAlloys and is the direct responsibility of Subcommittee B05.04 on Pipe
and Tube. requirements, the material shall be subject to rejection.
Current edition approved March 1, 2005. Published March 2005. Originally
3.1.2 unaided eye, n—visual inspection without the use of
approved in 1984. Last previous edition approved in 1999 as B75M–99. DOI:
special equipment or ehancement excepting the use of correc-
10.1520/B0075M-99R05.
tive lenses.
For ASME Boiler and Pressure Vessel Code applications refer to related
Specification SB-75 in Section II of that Code.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on Withdrawn. The last approved version of this historical standard is referenced
the ASTM website. on www.astm.org.
*A Summary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
B75M – 99 (2005)
4. Ordering Information 4.2.4 Pneumatic test,
4.2.5 Certification, and
4.1 Include the following information in orders for prod-
4.2.6 Test report.
ucts.
4.1.1 ASTM designation and year of issue (for example,
5. Material and Manufacture
B75M–99),
TABLE 1 Chemical Requirements
Composition, %
Element Copper UNS No.
A
C10100 C10200 C10300 C10800 C12000 C12200 C14200
B
Copper , min 99.99 99.95 . . 99.90 99.9 99.40
B
Copper + . . 99.95 99.95 . . .
phosphorus, min
Phosphorus . . 0.001–0.005 0.005–0.012 0.004–0.012 0.015–0.040 0.015–0.040
Arsenic . . . . . . 0.15–0.50
A
Refer to Table 1, Chemical Requirements, Grade 1, of Specification B170 for impurity limits for Copper UNS No. C10100.
B
Refer to Table 1, Chemical Requirements, Grade 2, of Specification B170 for impurity limits for Copper UNS No. C10200.
4.1.2 Copper UNS No. (for example, C10100), 5.1 Material—The material of manufacture shall be billets,
TABLE 2 Mechanical Property Requirements of Drawn-Temper and Annealed-Temper Tube
Outside Diameter,
Yield
Temper Designation Rockwell Hardness
or Major Average Tensile
A
Strength,
Distance Between Wall Thickness, mm Grain Strength,
min,
Outside Parallel Size, mm MPa
Standard Former Scale Hardness
MPa
Surfaces, mm
B C
H55 light-drawn all all 30T 30 to 60 250–325 205
C
H58 drawn (general purpose) all all 30T 30 min 250 min 205
B C
H80 hard-drawn up to 102 0.508 to 6.35, incl 30T 55 min 310 min 275
D E
O60 soft anneal all 0.381 to 0.889 15T 60 max 0.040 min 205 min 62
D E
0.889 and over F 50 max 0.040 min 205 min 62
D E
O50 light anneal all 0.381 to 0.889 15T 65 max 0.040 max 205 min 62
D E
0.889 and over F 55 max 0.040 max 205 min 62
A
Yield strength to be determined at 0.5 % extension under load.
B
Light-drawn and hard-drawn tempers are normally available in round tubes only.
C
Rockwell hardness values shall apply only to tubes having a wall thickness of 0.508 mm or over, to round tubes having an inside diameter of 8.0 mm or over, and to
rectangular including square tubes having an inside major distance between parallel surfaces of 5.0 mm or over. Rockwell hardness tests shall be made on the inside
surface of the tube. When suitable equipment is not available for determining the specified Rockwell hardness, other Rockwell scales and values shall be specified subject
to agreement between purchaser and supplier.
D
Rockwell hardness values shall apply only to tubes having a wall thickness of 0.40 mm or over, to round tubes having an inside diameter of 8.0 or over, and to
rectangular including square tubes having an inside major distance between parallel surfaces of 5.0 mm or over. For all other tube no Rockwell values shall apply. Rockwell
hardness tests shall be made on the inside surface of the tube. When suitable equipment is not available for determining the specified Rockwell hardness, other Rockwell
scales and values shall be specified subject to agreement between purchaser and supplier.
E
Light-straightening operation shall be permitted.
4.1.3 Temper (Section 7), cast bars, or tube of Copper UNS No. C10100, C10200,
4.1.4 Dimensions; diameter or distance between parallel C10300, C10800, C12000, or C12200, and shall be of such
surfaces, and wall thickness (Section 14), soundness as to be suitable for processing into the tubular
4.1.5 How furnished; coils or straight lengths, products described.
4.1.6 Number of pieces or footage; each size and type, 5.2 Manufacture—The tube shall be manufactured by such
4.1.7 Total weight, hot-andcold-workingprocessesastoproduceahomogeneous,
4.1.8 When product is purchased for ASME Boiler and uniform wrought structure in the finished product. It shall be
Pressure Vessel Code application, and cold drawn to the finished size and wall thickness. When
4.1.9 When product is purchased for agencies of the U.S. cold-drawn temper is required, the final drawing operation
Government. shall be such as to meet the specified temper. When annealed
4.2 The following options are available and shall be speci- temperisrequired,thetubeshallbeannealedsubsequenttothe
fied at the time of placing the order, when required: final cold draw.
4.2.1 Electrical mass resistivity test,
4.2.2 Hydrogen embrittlement test,
4.2.3 Hydrostatic test, Refer to Practice E527 for explanation of Unified Numbering System (UNS).
B75M – 99 (2005)
6. Chemical Composition (a) Tubes having a wall thickness of 0.508 mm and over,
(b) Round tubes having an inside diameter of 8.0 mm and
6.1 The material shall conform to the requirements inTable
over,
1 for the specified Copper UNS No. designation.
(c) Rectangular and square tubes having major distances
6.1.1 Thesespecificationlimitsdonotprecludethepresence
between parallel surfaces of 5 mm and over.
of other elements. When included in the contract or purchase
10.2.1.2 The Rockwell Hardness values for tube in the O60
order,andagreeduponbythemanufacturerorsupplierandthe
and O50 temper shall apply only to the following:
purchaser, limits shall be established and analysis required for
(a) Tubes having a wall thickness of 0.40 mm and over;
unnamed elements.
(b) Round tubes having an inside diameter of 8 mm and
over;
7. Temper
(c) Rectangular and square tubes having inside major dis-
7.1 The requirements and size availability of tube in the
tances between parallel surfaces of 5 mm and over.
cold-drawn tempers H55, H58, and H80, as defined in Classi-
10.3 Straightening—It shall not be prohibited to use light
fication B601, are specified in Table 2.
straightening for tube in the O60 and O50 temper.
7.1.1 Rectangular, including square, tube shall normally be
supplied only in H58 temper. When requested by the manu-
11. Performance Requirements
facturer or supplier, and upon agreement with the purchaser,
11.1 Expansion Test for Round Tube—Whenspecifiedinthe
tube shall be supplied in H55 or H58 temper.
contract or purchase order, annealed tubes shall be capable of
7.1.1.1 For any combination of diameter and wall thickness
withstanding an expansion of the outside diameter of 40% for
not listed under H80 temper, the requirements specified for
tube 19.0 mm and under and 30% for tube over 19.0 mm.The
H58 temper shall apply.
tube shall show no cracking or rupture visible to the unaided
7.2 The requirements and size availability of tube in the
eye.
annealed tempers O50 and O60, as defined in Classification
B601, are specified in Table 2.
12. Microscopical Examination
NOTE 1—The purchaser shall confer with the manufacturer or supplier
12.1 TubesfurnishedinCopperUNSNo.C10100,C10200,
for the availability of product in a specific temper.
NOTE 2—Refer to Appendix X1 for recommended applications based
C10300, and C12000 shall be essentially free of cuprous oxide
on temper.
as determined by Procedure A of Test Methods B577.
8. Grain Size Requirements
13. Hydrogen Embrittlement
8.1 Tube in the annealed temper shall conform to the grain
13.1 Whenspecifiedinthecontractorpurchaseorder,tubes
size specified in Table 2.
produced in all designated copper material shall be capable of
conforming to the requirements of Procedure B of Test
9. Physical Property Requirements
Methods B577.
9.1 Electrical Resistivity—Whenspecifiedinthecontractor
purchase order, tube ordered for electrical conductor applica-
14. Purchases for U.S. Government Agencies
tion produced from Copper UNS No. C10100, C10200,
14.1 When the contract or purchase order stipulates the
C10300, or C12000 shall have an electrical mass resistivity,
purchase is for an agency of the U.S. Government, the tubes
V·g/m , not to exceed the following limit for the specified
furnished shall conform to the conditions specified in the
copper and temper when tested in accordance with Test
Supplementary Requirements of Specification B251M.
Method B193:
Copper UNS No.
Temper
15. Nondestructive Test
C10100 C10200 C10300 C12000
15.1 The tubes shall be tested in the drawn tempers or as
O60, O50 0.151 76 0.153 28 0.156 14 0.170 31
drawn before the final-annealed temper unless otherwise
H55, H58, H80 0.156 14 0.157 37 0.159 40 0.174 18
agreed upon between the manufacturer and the purchaser.
NOTE 3—Refer toAppendix X2 for the InternationalAnnealed Copper
15.2 Electromagnetic (Eddy-Current) Test:
Standard (IACS) electrical conductivity equivalents.
15.2.1 Each tube up to and including 79 mm in outside
10. Mechanical Property Requirements
diameter shall be subjected to test.
15.2.2 WhentestedinaccordancewithPracticeE243,tubes
10.1 Tensile and Yield Strength:
10.1.1 The tube shall conform to the requirements of Table which do not actuate the signaling device of the testing unit
shall be considered as conforming to the requirements of the
2 for the specified temper and wall thickness.
10.1.2 For any combination of diameter and wall thickness test.
not listed under H80, the requirements for H58 shall apply. 15.3 Hydrostatic Pressure Test—When specified in the
10.2 Rockwell Hardness: contract or purchase order, each tube shall be capable of
10.2.1 The tube shall conform to the requirements of Table withstanding an internal hydrostatic pressure sufficient to
2 for the specified temper and wall thickness. produce a fiber stress of 41 MPa without leakage. The tube
10.2.1.1 TheRockwellHardnessvaluesfortubeintheH55, need not be subjected to a pressure gage reading over 6.9 MPa
H58, and H80 temper shall apply only to the following: unless specifically stipulated in the contract or purchase order.
B75M – 99 (2005)
A
Each test portion shall be taken from a separate tube.
15.4 Pneumatic Pressure Test—When specified in the con-
18.2 Chemical Composition:
tract or purchase order, each tube shall be capable of with-
18.2.1 The composite sample shall be taken in approximate
standing an internal air pressure of 400 kPa, minimum, for 5 s
equalweightsfromeachportionpieceselectedin18.1.2andin
without leakage.
accordance with Practice E255. The minimum weight of the
16. Dimensions, Mass, and Permissible Variations composite shall be 150 g.
18.2.2 The manufacturer shall have the option of sampling
16.1 Thedimensionsandtolerancesforproductfurnishedto
at the time the castings are poured or taken from the semifin-
this specification shall be as specified in the following tables
ished product. The number of samples taken during the course
and related sections of
...