iTeh StandardsiTeh Standards
EURUSD
Your shopping cart is empty.
ASTM

ASTM D79-86(1999)

(Specification)

Standard Specification for Zinc Oxide Pigments

Standard Specification for Zinc Oxide Pigments

SCOPE
1.1 This specification covers the pigments commercially known as "zinc white" or zinc oxide. The pigments may be purchased in the dry form or as a paste in oil.  Note-Zinc oxides are used in many industries. For additional information, see Specification D4295 and Test Methods D4315 for descriptions of zinc oxide use in rubber compounding.

General Information

Status
Historical
Publication Date
09-May-1999
ICS
87.060.10 - Pigments and extenders
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.31 - Pigment Specifications
Current Stage
Ref Project

Relations

Replaced By
ASTM D79-86(2004) - Standard Specification for Zinc Oxide Pigments
Effective Date
01-Nov-2004
Referred By
ASTM D4302-14(2021) - Standard Specification for Artists’ Oil, Resin-Oil, and Alkyd Paints
Effective Date
10-May-1999

Buy Standard

ASTM D79-86(1999) - Standard Specification for Zinc Oxide PigmentsASTM D79-86(1999) - Standard Specification for Zinc Oxide Pigments
PreviousNext
Technical specification
ASTM D79-86(1999) - Standard Specification for Zinc Oxide Pigments
English language
2 pages
sale 15% off
Preview
sale 15% off
Preview

Standards Content (Sample)


NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
American Association State
Designation: D 79 – 86 (Reapproved 1999) Highway and Transportation Officials Standard
AASHTO No.: M124
Standard Specification for
Zinc Oxide Pigments
This standard is issued under the fixed designation D 79; the number immediately following the designation indicates the year of original
adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A superscript
epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope mildew protection, ultraviolet absorption, hiding power, and
neutralization of acids formed upon oxidation of the paint film.
1.1 This specification covers the pigments commercially
known as “zinc white” or zinc oxide. The pigments may be
4. Composition and Properties
purchased in the dry form or as a paste in oil.
4.1 Dry Pigment, French Process—In the manufacture of
NOTE 1—Zinc oxides are used in many industries. For additional
French process zinc oxide, metallic zinc is vaporized, either in
information, see Specification D 4295 and Test Methods D 4315 for
a boiler or a refining column, and the resulting vapor is burned
descriptions of zinc oxide use in rubber compounding.
in a controlled manner in an orifice. The fine particles of zinc
oxide are cooled enough to agglomerate and are collected by a
2. Referenced Documents
system of fabric bags. French process oxide shall conform to
2.1 ASTM Standards:
the properties listed in Table 1.
D 185 Test Methods for Coarse Particles in Pigments,
4.2 Dry Pigment, American Process— In the manufacture
Pastes, and Paints
of American process zinc oxide, zinc ore is reduced in the
D 280 Test Methods for Hygroscopic Moisture (and Other
2 presence of a carbonaceous fuel. The resulting vapor is burned
Matter Volatile Under the Test Conditions) in Pigments
in a combustion chamber, and the fine particles of zinc oxide
D 281 Test Method for Oil Absorption of Pigments by
3 are cooled enough to agglomerate and are collected by a
Spatula Rub-Out
system of fabric bags. American process oxide shall conform to
D 332 Test Method for Relative Tinting Strength of White
3 the properties listed in Table 1.
Pigments by Visual Observation
4.3 Paste in Oil—The paste shall be made by thoroughly
D 1483 Test Method for Oil Absorption of Pigments by
3 grinding the specified pigment with linseed oil. As received it
Gardner-Coleman Method
shall not be caked in the container and shall break up readily in
D 2745 Test Method for Relative Tinting Strength of White
oil to form a smooth paint of brushing consistency. The paste
Pigments by Reflectance Measurements
shall conform to the following requirements:
D 3280 Test Methods for Analysis of White Zinc Pigments
Pigment, % 80 to 86
D 4295 Classification for Rubber Compounding
Linseed oil, % 14 to 20
Materials—Zinc Oxide
Moisture and other volatile matter, max, % 0.5
Coarse particles and skins (total residue retained on a 1.5
D 4315 Test Methods for Rubber Compounding Material—
4 No. 325 (45-μm) sieve), max, % of the dry pigment
Zinc Oxide
E 20 Practice for Particle Size Analysis of Particulate Sub- 4.4 In such physical properties as are specified by the
stances in the Range of 0.2 to 75 μm by Optical Micros-
purchaser, the pigment shall satisfactorily match a reference
copy sample mutually agreed upon by the purchaser and the seller.
The most frequently specified properties are oil absorption,
3. Significance and Use
tinting strength, and particle shape. Appropriate test methods
3.1 Zinc oxide functions as both a chemical and a pigment.
are listed in Section 6. In the event that either an acicular type
It is used in a variety of applications including rubber, paint,
or a nodular (spherical) type of zinc oxide is desired, the
reprography, glass, chemicals, etc. In paint, it contributes to
particl
...

Questions, Comments and Discussion

Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.

This May Also Interest You

ASTM
ASTM D6131-17(2023)(Test Method)
Standard Test Method for Evaluating the Relative Tint Undertone of Titanium Dioxide Pigments

SIGNIFICANCE AND USE
5.1 This test method allows the user to make a determination of the blueness or yellowness of the tint undertone of titanium dioxide pigments, versus a reference pigment agreed upon by the parties to the test. This is an important measure of tone, since it gives both a measure of effective particle size, and quick approximation of the blue/yellow undertone that can be expected when a coating containing the titanium dioxide is tinted.  
5.2 Such matters as the vehicle for preparing the dispersions and the mechanical method of preparing the dispersion are left to the user. However, variation in these practices will lead to increased variance in the results, so users ought to fix these parameters, in-so-far as is possible, within any one laboratory. This will lead to reduced uncertainty of the results within that laboratory, and it is seldom that interlaboratory comparisons of this test result is needed.  
5.3 Each user must decide whether the loss of accuracy in his measurements due to variation of these parameters is negligibly small for the purpose for which the data are obtained.
SCOPE
1.1 This test method is intended to be used to determine the tint undertone (blue or yellow) of titanium dioxide pigments. This relates to the effective particle size of the pigment  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    2 pages
    English language
    sale 15% off
ASTM
ASTM D6580-17(2023)(Test Method)
Standard Test Method for The Determination of Metallic Zinc Content in Both Zinc Dust Pigment and in Cured Films of Zinc-Rich Coatings

SIGNIFICANCE AND USE
4.1 This test method is useful for determining the amount of metallic zinc in zinc dust pigment, and also in dried films of both inorganic and organic zinc-rich coatings. Test Methods D521 is an appropriate method for analyzing zinc dust, but has shortcomings when applied to samples of cured coatings.
SCOPE
1.1 This test method covers the determination by differential scanning calorimetry of the metallic zinc content of both zinc-dust pigment, and of dried films of zinc-rich coatings. This test method is applicable to both inorganic and organic zinc-rich coatings.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    3 pages
    English language
    sale 15% off
ASTM
ASTM D2745-00(2023)(Test Method)
Standard Test Method for Relative Tinting Strength of White Pigments by Reflectance Measurements

SIGNIFICANCE AND USE
4.1 Tinting strength is one of the most important properties of a white pigment. This test method provides a means of testing this property for quality control.  
4.2 This test method is a referee method, and the vehicle for preparing the dispersion and the black for tinting are suggested, but others may be used provided both the purchaser and the seller agree to the changes.  
4.3 The results obtained with a muller do not necessarily agree with industrial situations where different dispersing conditions exist. However, dispersing with a muller is a fast, relatively inexpensive way of testing tinting strength for routine quality control.
SCOPE
1.1 This test method describes the procedure for determining the relative tinting strength of white pigments by reflectance measurements of black tints.  
1.2 This test method is applicable only for comparing the test pigment with a reference standard of the same type and grade.  
Note 1: Test Method D332 describes a procedure for visual assessment of blue-tinted samples.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    3 pages
    English language
    sale 15% off
ASTM
ASTM D126-87(2023)(Test Method)
Standard Test Methods for Analysis of Yellow, Orange, and Green Pigments Containing Lead Chromate and Chromium Oxide Green

SIGNIFICANCE AND USE
4.1 These test methods are for analysis designed as an aid in quality of yellow, orange, and green pigments containing lead chromate and chromium oxide green. Some sections may be applicable to analysis of these pigments when extracted from whole paints.
SCOPE
1.1 These test methods cover procedures for the chemical analysis of yellow, orange, and green pigments containing lead chromate and chromium oxide green.  
1.2 The analytical procedures appear in the following order:    
Sections  
Chrome  Yellow, Chrome Orange, and Molybdate Orange  
Organic Colors and Lakes  
7  
Moisture and Other Volatile Matter  
8  
Matter Soluble in Water  
9  
Lead Chromate  
10 and 11  
Total Lead  
12  
Sulfate  
13 and 14  
Carbon Dioxide  
15  
Molybdenum  
16 and 17  
Extenders  
18 – 22  
Calculation of Substances Other than Insoluble Lead
Compounds  
23 and 24  
Pure  Chrome Green and Reduced Chrome Green  
Organic Colors and Lakes  
25  
Moisture and Other Volatile Matter  
26  
Matter Soluble in Water  
27  
Iron Blue  
28  
Lead Chromate  
29 and 30  
Barium Sulfate and Insoluble Siliceous Material  
31  
Total Lead  
32  
Sulfate  
33  
Calcium Oxide Soluble in Acid  
34 and 35  
Extenders  
36  
Calculation of Insoluble Lead Compounds  
37  
Chromium Oxide Green  
Organic Colors and Lakes  
38  
Moisture and Other Volatile Matter  
39  
Matter Soluble in Water  
40  
Total Chromium as Chromium Oxide  
41  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Note 3.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    8 pages
    English language
    sale 15% off
ASTM
ASTM D210-05(2023)(Specification)
Standard Specification for Bone Black Pigment

ABSTRACT
This specification covers bone black, ivory black, or drop black pigment. The pigment may be in dry form or in aqueous dispersion. Dry pigment shall be made by the calcinations of bones, unmixed with any other substance. Dry pigment shall compose of ash, ash insoluble in acids, and coarse particles. Pigment in aqueous dispersion shall be made by grinding the pigment with water, dispersing agent, biocide, fungicide, pH stabilizer, and defoamer. ASTM test methods shall be conducted for coarse particles, pigment and linseed oil in paste in oil, and mass color and tinting strength.
SCOPE
1.1 This specification covers the pigment commercially known as bone black, ivory black, or drop black. The pigment may be purchased in the dry form or as an aqueous dispersion.  
1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Technical specification
    2 pages
    English language
    sale 15% off
ASTM
ASTM D209-81(2023)(Specification)
Standard Specification for Lampblack Pigment

ABSTRACT
This specification covers the pigment commercially known as lampblack, which may be purchased in the dry form or as a paste in oil. The dry pigment shall be made by burning oils or tars. It shall conform to chemical compositions of ash, acetone extract, moisture and other volatile matter, and coarse particles. The paste in oil, on the other hand, shall be made by thoroughly grinding the specified pigment with linseed oil. It shall conform to chemical compositions of pigment, linseed oil, moisture and other volatile matter, and coarse particles and skins. Both forms of the pigment shall also be sampled, and tested appropriately for mass color and character, and tinting strength.
SCOPE
1.1 This specification covers the pigment commercially known as lampblack. The pigment may be purchased in the dry form or as a paste in oil.  
1.2 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Technical specification
    2 pages
    English language
    sale 15% off
ASTM
ASTM D279-02(2023)(Test Method)
Standard Test Methods for Bleeding of Pigments

SIGNIFICANCE AND USE
4.1 Test Method A determines the amount of color produced when the pigment is in direct contact with a selected solvent such as toluene. It is useful as a rapid, easily conducted test of the general bleeding characteristics of pigments.  
4.2 Test Method B determines the amount of color migration into a white film applied over a base coat containing the pigment. It may give a more practical evaluation of whether a pigment will meet specific requirements for bleed resistance.  
4.3 Both Test Method A and Test Method B measure the extent of bleed.
SCOPE
1.1 These test methods cover procedures for determining the bleeding characteristics of dry pigments by direct solvent extraction of the pigment and by overstriping a film with a white coating and observing for the color migration from the base coat containing the pigment.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    2 pages
    English language
    sale 15% off
ASTM
ASTM D263-05(2023)(Specification)
Standard Specification for Chrome Oxide Green Pigment

ABSTRACT
This specification establishes the properties and requirements for the dry pigment commercially known as chrome oxide green. The pigment shall consist of practically pure chromium sesqui-oxide without any admixture. Specimens shall be sampled and tested adequately, and shall conform to the following composition requirements: total chromium; total water-soluble matter; moisture and other volatile matter; coarse particles (total residue retained on a No. 325 sieve); and organic colors or lakes. The pigments shall adhere to mass color, tint character, and tinting strength requirements as well.
SCOPE
1.1 This specification covers the dry pigment commercially known as chrome oxide green.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Technical specification
    2 pages
    English language
    sale 15% off
ASTM
ASTM D50-90(2023)(Test Method)
Standard Test Methods for Chemical Analysis of Yellow, Orange, Red, and Brown Pigments Containing Iron and Manganese

SIGNIFICANCE AND USE
3.1 These test methods compile in one place, recommended procedures for analyzing inorganic colored pigments. These pigments are used extensively in paints, and for this reason their compositions are important to the formulators and user.
SCOPE
1.1 These test methods cover procedures for the chemical analysis of yellow, orange, red, and brown pigments containing iron and manganese. The test methods apply specifically to the following pigments: synthetic hydrated yellow iron oxide, yellow ocher, red and brown iron oxides, raw and burnt umber, raw and burnt sienna, and venetian red.  
1.2 The analytical procedures appear in the following order:    
ASTM  
Method  
Refer-  
Dry Pigments
Sections  
ences  
Moisture and Other Volatile Matter  
6  
D280  
Loss on Ignition  
7  
Coarse Particles  
8  
D185  
Matter Soluble in Water  
9  
D1208  
Organic Coloring Matter  
10  
Iron Oxide  
11 and 12  
Calcium Compounds (Reported as CaO)  
13 and 14  
Sulfates Soluble in Hydrochloric Acid  
15 and 16  
Lead Chromate (in Ochers)  
17  
Calcium Carbonate (in Venetian Red)  
18  
C25  
Manganese (in Siennas and Umbers)  
19 and 20  
Pigment Pastes in Oil  
Pigment Content  
21  
D1208  
Moisture and Other Volatile Matter  
22  
D1208  
Nonvolatile Matter in Vehicle  
23  
Moisture by Distillation  
24  
D1208  
Coarse Particles and Skins  
25  
D185  
Consistency (Stormer)  
26  
D562  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to us.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    5 pages
    English language
    sale 15% off
ASTM
ASTM D185-07(2023)(Test Method)
Standard Test Methods for Coarse Particles in Pigments

SIGNIFICANCE AND USE
3.1 In production of paints, smoothness of the paint film is of paramount importance. Agglomerates or coarse particles larger than 45 μm are difficult to disperse and may prevent obtaining a smooth film. These test methods are a valuable quality control test for grading raw materials.
SCOPE
1.1 These test methods cover the determination of the amount of coarse particles in dry pigments.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    2 pages
    English language
    sale 15% off