Standard Test Method for Determination of the Susceptibility of Metallic Materials to Hydrogen Gas Embrittlement (HGE)

SIGNIFICANCE AND USE
This test method will provide a guide for the choice of metallic materials for applications in high pressure hydrogen gas.
The value of the PHe/PH2 ratio will be a relative indication of the severity of degradation of the mechanical properties to be expected in hydrogen.
SCOPE
1.1 This test method covers the quantitative determination of the susceptibility of metallic materials to hydrogen embrittlement, when exposed to high pressure gaseous hydrogen.
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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Historical
Publication Date
31-Mar-2006
Current Stage
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ASTM F1459-06 - Standard Test Method for Determination of the Susceptibility of Metallic Materials to Hydrogen Gas Embrittlement (HGE)
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
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Designation:F1459–06
Standard Test Method for
Determination of the Susceptibility of Metallic Materials to
1
Hydrogen Gas Embrittlement (HGE)
This standard is issued under the fixed designation F1459; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 4. Significance and Use
1.1 This test method covers the quantitative determination 4.1 This test method will provide a guide for the choice of
of the susceptibility of metallic materials to hydrogen em- metallic materials for applications in high pressure hydrogen
brittlement, when exposed to high pressure gaseous hydrogen. gas.
1.2 The values stated in SI units are to be regarded as the 4.2 The value of the P /P ratio will be a relative
He H2
standard. The values given in parentheses are for information indication of the severity of degradation of the mechanical
only. properties to be expected in hydrogen.
1.3 This standard does not purport to address all of the
5. Apparatus
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appro- 5.1 A basic test system shall consist of the following items:
5.1.1 Test Cell, consists of two flanges as shown schemati-
priate safety and health practices and determine the applica-
bility of regulatory limitations prior to use. cally in Fig. 1.
5.1.1.1 The test cell shall befabricated from materials such
2. Referenced Documents
as 316 stainless steel in the annealed condition that are not
2.1 ASTM Standards: susceptible to HGE (3, 4).
E384 Test Method for Microindentation Hardness of Mate- 5.1.1.2 The seals shall be elastomer O-rings for helium
rials testing and hydrogen testing at rates of 10 bar/min (145
psig/min) or higher. For hydrogen tests at a lower rate, indium
3. Summary of Test Method
O-rings shall be used.
3.1 Athin disk metallic specimen is subjected to an increas- 5.1.1.3 An evaluation port (Item 1 in Fig. 1) on the lower
ing gas pressure at constant rate until failure (bursting or
flangeisusedtocheckgaspurityandadjustpressurizationrate.
cracking of the disk). The embrittlement of the material can be 5.1.2 The test cell is pressurized with hydrogen or helium
evaluated by comparing the rupture pressures of identical disk
throughapneumaticsystem.Fig.2schematicallyillustratesthe
specimens in hydrogen (P ) and in a reference inert gas such pneumatic system.
H2
2
as helium (P ) (1, 2).
5.1.2.1 The pressurization rate shall be adjustable in the
He
3.2 The ratio P /P can be used to evaluate the suscepti- system.Athrottle valve is used to adjust the pressurization rate
He H2
bility of the metallic material to gaseous hydrogen embrittle-
in Fig. 2.
ment. The ratio is dependent on the pressurization rate.Aratio
6. Gases
of 1 or less indicates the material is not susceptible to hydrogen
embrittlement.Aratio greater than 1 indicates that the material 6.1 Helium, purity 99.995 minimum, 6000-psig (41 400-
is susceptible to hydrogen embrittlement and the susceptibility kPa) or higher pressure source.
increases as the ratio increases. 6.2 Hydrogen, purity 99.995 minimum, 6000-psig (41 400-
kPa) or higher pressure source.
1
This test method is under the jurisdiction of ASTM Committee F07 on
7. Specimen Preparation
Aerospace and Aircraft and is the direct responsibility of Subcommittee F07.04 on
7.1 Fifteen (15) specimens with identical dimensions and
Hydrogen Embrittlement.
Current edition approved April 1, 2006. Published May 2006. Originally
temper conditions shall be prepared for each test program. Six
´1
approved in 1993. Last previous edition approved in 1998 as F1459 – 93 (1998) .
(6) specimens are to be tested in helium and nine (9) specimens
DOI: 10.1520/F1459-06.
2
The boldface numbers in parentheses refer to the list of references at the end of
this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
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F1459–06
1
7.3 The disk specimen shall have a flatness of less than ⁄10
1
mm ( ⁄254 in.) deflection.
7.4 The surface of the disk specimen shall be free of oxides.
The surface roughness Ra shall be 0.001 mm (40 µin.) or less.
7.5 The disk specimen shall be prepared by a method that
does not alter mechanical properties of the material at the edge
of the specimen. Microhardness testing should be conducted
per Test Method E384 at the outer edge of the specimen
(outside the tested area) to ensure it is as a means of confirming
that the mechanical properties were not altered.
7.6 The specimens shall be cleaned, free of grease
...

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