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ASTM D788-06

(Classification)

Standard Classification System for Poly(Methyl Methacrylate) (PMMA) Molding and Extrusion Compounds

Standard Classification System for Poly(Methyl Methacrylate) (PMMA) Molding and Extrusion Compounds

ABSTRACT
The purpose of this classification system is to provide a method of adequately identifying poly(methyl methacrylate) (PMMA) molding and extrusion compounds. These compounds are polymers based on methyl methacrylate, and at least 70 % of the polymer shall be polymerized from methyl methacrylate. Poly(methyl methacrylate) molding and extrusion compounds are classified into groups in accordance with their composition. These groups are subdivided into classes and grades: class 1, 2, 3, and 4; grade 1 - materials used where special ultraviolet transmission, filtering, or stabilization characteristics are not required, grade 2 - materials used for those specialized applications in which the greatest amount of transmission of UV light is required, and grade 3 - materials (transparent UV stabilized or transparent UV absorbing) used when either special resistance to slight color change over long exposure times or high-intensity UV radiation is required, or when the material is required to filter out ultraviolet light. The plastics composition shall be uniform and shall conform to the requirements specified.
SCOPE
1.1 The purpose of this classification system is to provide a method of adequately identifying PMMA materials using a system consistent with that of Classification System D 4000. It further provides a means for specifying these materials by the use of a simple line callout designation.
1.2 This classification system covers poly(methyl methacrylate) molding and extrusion compounds. These compounds are polymers based on methyl methacrylate, and at least 70 % of the polymer shall be polymerized from methyl methacrylate.
1.3 The properties in this classification system are those required to identify the compositions covered. There may be other requirements necessary to identify particular characteristics important to specific applications. These shall be described by using the suffixes as given in Section 5.
1.4 Acrylic molding and extrusion compounds are used frequently in applications where extreme clarity and the ability to retain that clarity and color under severe weathering and other environmental exposures are of primary significance. While the test specimen properties of this document may be used to evaluate nonvirgin materials, the user should take precautions to ensure that parts made from these materials meet the desired end-use requirements. Accordingly, this specification allows for the use of those acrylic plastic materials that can be recycled, reconstituted, and regrounded provided the following:
1.4.1 The requirements as stated in this specification are met,
1.4.2 The material has not been modified in any way to alter its conformance to food contact regulations or similar requirements, and
1.4.3 The requirements of the particular end-use application are met.
1.5 This classification system and subsequent line callout (specification) are not intended for the selection of materials, but only as a means to call out plastic materials to be used for the manufacture of parts. The selection of these materials is to be made by personnel with expertise in the plastics field in which the environment, inherent properties of the materials, performance of the parts, part design, manufacturing process, and economics are considered. Note 1 - This classification system is similar to ISO 8257-1:1987 in title only. The technical content is significantly different.
1.6 The values stated in SI units are to be regarded as standard.
This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
31-Aug-2006
ICS
83.140.99 - Other rubber and plastics products
Technical Committee
D20 - Plastics
Drafting Committee
D20.15 - Thermoplastic Materials
Current Stage
Ref Project

Relations

Replaces
ASTM D788-05 - Standard Classification System for Poly(Methyl Methacrylate) (PMMA) Molding and Extrusion Compounds
Effective Date
01-Sep-2006
Replaced By
ASTM D788-11 - Standard Classification System for Poly(Methyl Methacrylate) (PMMA) Molding and Extrusion Compounds
Effective Date
01-Dec-2011
Referred By
ASTM D4000-23 - Standard Classification System for Specifying Plastic Materials
Effective Date
01-Sep-2006
Referred By
ASTM D955-21 - Standard Test Method of Measuring Shrinkage from Mold Dimensions of Thermoplastics
Effective Date
01-Sep-2006
Referred By
ASTM F3087-15 - Standard Specification for Acrylic Molding Resins for Medical Implant Applications
Effective Date
01-Sep-2006

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ASTM D788-06 - Standard Classification System for Poly(Methyl Methacrylate) (PMMA) Molding and Extrusion CompoundsASTM D788-06 - Standard Classification System for Poly(Methyl Methacrylate) (PMMA) Molding and Extrusion Compounds
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ASTM D788-06 - Standard Classification System for Poly(Methyl Methacrylate) (PMMA) Molding and Extrusion Compounds
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D788 – 06
Standard Classification System for
Poly(Methyl Methacrylate) (PMMA) Molding and Extrusion
1
Compounds
This standard is issued under the fixed designation D788; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope* but only as a means to call out plastic materials to be used for
the manufacture of parts. The selection of these materials is to
1.1 The purpose of this classification system is to provide a
be made by personnel with expertise in the plastics field in
method of adequately identifying PMMA materials using a
which the environment, inherent properties of the materials,
system consistent with that of Classification System D4000.It
performance of the parts, part design, manufacturing process,
further provides a means for specifying these materials by the
and economics are considered.
use of a simple line callout designation.
1.2 Thisclassificationsystemcoverspoly(methylmethacry-
NOTE 1—This classification system is similar to ISO 8257-1:1987 in
late) molding and extrusion compounds. These compounds are
title only. The technical content is significantly different.
polymers based on methyl methacrylate, and at least 70 % of
1.6 The values stated in SI units are to be regarded as
the polymer shall be polymerized from methyl methacrylate.
standard.
1.3 The properties in this classification system are those
1.7 This standard does not purport to address all of the
required to identify the compositions covered. There may be
safety concerns, if any, associated with its use. It is the
other requirements necessary to identify particular character-
responsibility of the user of this standard to establish appro-
istics important to specific applications. These shall be de-
priate safety and health practices and determine the applica-
scribed by using the suffixes as given in Section 5.
bility of regulatory limitations prior to use.
1.4 Acrylic molding and extrusion compounds are used
frequently in applications where extreme clarity and the ability 2. Referenced Documents
to retain that clarity and color under severe weathering and 2
2.1 ASTM Standards:
other environmental exposures are of primary significance.
D149 Test Method for Dielectric Breakdown Voltage and
While the test specimen properties of this document may be
Dielectric Strength of Solid Electrical Insulating Materials
used to evaluate nonvirgin materials, the user should take
at Commercial Power Frequencies
precautionstoensurethatpartsmadefromthesematerialsmeet
D150 Test Methods for AC Loss Characteristics and Per-
the desired end-use requirements. Accordingly, this specifica-
mittivity (Dielectric Constant) of Solid Electrical Insula-
tionallowsfortheuseofthoseacrylicplasticmaterialsthatcan
tion
be recycled, reconstituted, and regrounded provided the fol-
D257 Test Methods for DC Resistance or Conductance of
lowing:
Insulating Materials
1.4.1 The requirements as stated in this specification are
D618 Practice for Conditioning Plastics for Testing
met,
D883 Terminology Relating to Plastics
1.4.2 The material has not been modified in any way to alter
D1003 Test Method for Haze and Luminous Transmittance
its conformance to food contact regulations or similar require-
of Transparent Plastics
ments, and
D1238 Test Method for Melt Flow Rates of Thermoplastics
1.4.3 The requirements of the particular end-use application
by Extrusion Plastometer
are met.
D1600 Terminology for Abbreviated Terms Relating to
1.5 This classification system and subsequent line callout
Plastics
(specification) are not intended for the selection of materials,
D3641 Practice for Injection Molding Test Specimens of
Thermoplastic Molding and Extrusion Materials
1
ThisclassificationsystemisunderthejurisdictionofASTMCommitteeD20on
Plastics and is the direct responsibility of Subcommittee D20.15 on Thermoplastic
2
Materials. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved Sept. 1, 2006. Published September 2006. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
approved in 1944. Last previous edition approved in 2005 as D788 - 05. DOI: Standards volume information, refer to the standard’s Document Summary page on
10.1520/D0788-06. the ASTM website.
*A Summary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
D788 – 06
TABLE
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ASTM D2659-16(2023)(Test Method)
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SIGNIFICANCE AND USE
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SCOPE
1.1 This test method covers the determination of mechanical properties of blown thermoplastic containers, whether blown commercially or in the laboratory, loaded under columnar crush conditions at a constant rate of compressive deflection.
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ASTM D2561-17(2023)(Test Method)
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5.1 When properly used, these procedures serve to isolate such factors as material, blow-molding conditions, post-treatment, and so forth, on the stress-crack resistance of the container.  
5.2 Environmental stress cracking of blow-molded containers is governed by many factors. Since variance of any of these factors can change the environmental stress-crack resistance of the container, the test results are representative only of a given test performed under defined conditions in the laboratory. The reproducibility of results between laboratories on containers made on more than one machine from more than one mold has not been established.  
5.3 Results can be used for estimating the shelf life of blow-molded containers in terms of their resistance to environmental stress cracking provided this is done against a rigorous background of practical field experience and reproducible test data.
SCOPE
1.1 Under certain conditions of stress, and in the presence of environments such as soaps, wetting agents, oils, or detergents, blow-molded polyethylene containers exhibit mechanical failure by cracking at stresses appreciably below those that would cause cracking in the absence of these environments.  
1.2 This test method measures the environmental stress crack resistance of blow-molded containers, which is the summation of the influence of container design, resin, blow-molding conditions, post treatment, or other factors that can affect this property. Three procedures are provided as follows:  
1.2.1 Procedure A, Stress-Crack Resistance of Containers to Potential Stress-cracking Liquids—This procedure is particularly useful for determining the effect of container design on stress-crack resistance or the stress-crack resistance of a proposed container that contains a liquid product.  
1.2.2 Procedure B, Stress-Crack Resistance of a Specific Container to Polyoxyethylated Nonylphenol (CAS 68412-54-4), a Stress-Cracking Agent—The conditions of test described in this procedure are designed for testing containers made from Class 3 polyethylene Specification D4976. Therefore, this procedure is recommended for containers made from Class 3 polyethylene only. This procedure is particularly useful for determining the effect of resin on the stress-crack resistance of the container.  
1.2.3 Procedure C, Controlled Elevated Pressure Stress-Crack Resistance of a Specific Container to Polyoxyethylated Nonylphenol (CAS 68412-54-4), a Stress-Cracking Agent—The internal pressure is controlled at a constant elevated level.
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1.3 These procedures are not designed to test the propensity for environmental stress cracking in the neck of containers, such as when the neck is subjected to a controlled strain by inserting a plug.  
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Note 2: There is no known ISO equivalent to this standard.  
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ASTM D2463-23(Test Method)
Standard Test Method for Drop Impact Resistance of Blow-Molded Thermoplastic Containers

SIGNIFICANCE AND USE
5.1 These procedures provide a means to assess the drop impact resistance of the group or lot of blown containers from which the test specimens were selected.  
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5.4 Before proceeding with this test method, reference the specification of the material being tested. Any test specimen preparation, conditioning, dimensions, or testing parameters, or combination thereof, covered in the materials specification shall take precedence over those mentioned in this test method. If there are no material specifications, then the default conditions apply.
SCOPE
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ABSTRACT
This specification covers requirements and methods of test for the material, dimensions, and workmanship, and the properties of extruded, compression molded, and injection molded PAEK sheet, plate, rod, and tubular bar manufactured from PAEK. The type of PAEK extruded, compression molded, and injection molded product may be categorized by type, grade and class depending on resin and filler compositions. Every type of PAEK shape may be categorized into one of several grades as follows: Grade 1 (general purpose) which is extruded, compression molded or injection molded product made using only 100% virgin PAEK resin and Grade 2 (recycle grade) which is extruded, compression molded or injection molded product made using any amount up to 100% of recycled thermoplastic PAEK. The type, class and grade is further differentiated based on dimensional stability. Different tests shall be conducted in order to determine the following properties of PAEK: tensile stress at break, elongation at break, tensile modulus, dimensional stability, lengthwise camber and widthwise bow, squareness, flexural modulus, and Izod impact.
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ASTM D7258-23(Specification)
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ABSTRACT
This specification establishes the physical and performance requirements for round and rectangular cross-section polymeric piles in axial and lateral load-bearing applications including, by not limited to, marine, waterfront, and corrosive environments. It does not apply to individual polymeric pile products, sheet piles, and other mechanically connected polymeric pile products using inter-locking systems. Covered here are six types of polymeric piles that are fabricated from materials that may be virgin, recycled, or both, as long as the finished product meets all of the criteria specified herein. These types are: Type I, polymeric only; Type II, polymeric with reinforcement in the form of chopped, milled or continuous fiber or mineral; Type III, polymeric with reinforcement in the form of metallic bars, cages, or shapes; Type IV, polymeric with reinforcement in the form of non-metallic bars or cages; Type V, polymeric composite tube with a concrete core; and Type VI, any other polymeric piling meeting the requirements stated herein and not otherwise described by Types I through V. The polymeric tiles shall adhere to specified physical attributes such as size, cross-sectional shape, length, straightness, placement of reinforcement, and surface conditions. The performance requirements which pile specimens shall conform to include creep rupture, serviceability, flexural properties, shear strength, bearing strength, design flexural stiffness, energy absorption, compressive strength, combined stresses, dimensional stability (thermal expansion), hygrothermal cycling, and flame spread index.
SCOPE
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1.2 This specification is only applicable to individual polymeric pile products. Sheet pile and other mechanically connected polymeric pile products using inter-locking systems, are not part of this specification.  
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ASTM D7486-22(Test Method)
Standard Test Method for Measurement of Fines and Dust Particles on Plastic Pellets by Wet Analysis

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5.1 Molding and extruding plastic pellets require dust free, dry pellets to prevent processing problems. Plastic producers try to remove the dust and streamers with dust removal systems prior to packaging and loading. How to accurately measure dust and streamer content in plastic pellets is an important quality control issue.  
5.2 Particle size analysis is used to determine a percentage of particle size distribution from a representative sample of the whole. In terms of size analysis concerning plastic pellets, sieving is used to determine the dust content in the range of 500 to 2000 micron. Test Method D1921, Test Method B, is used to determine this type of particle sizing.  
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5.4 The wet analysis provides accurate quantification of small to large amounts of fines, negating static effects, and eliminating detrimental effects of mechanical agitation. A wet analysis must be employed to accurately quantify lower PPM dust levels in plastic pellets.
SCOPE
1.1 This test method measures the amount of fine particles adhered on plastic pellets or granules in which they are commonly produced and supplied. The lower limit of this test method is restricted only by the porosity of the filter disc used to capture the particle size being quantified.  
1.2 The wet analysis technique allows for separation and collection of statically charged particles by liquid wash and filtration methods. This must be performed under standard laboratory conditions.  
1.3 The values stated in SI units are to be regarded as standard.  
1.4 This test method describes an essential practice to check the quality of plastics once the production cycle is terminated and to evaluate the performance of pellet cleaning systems or of the special pneumatic conveying systems for the distinct size fractions below 500 micron only.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
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ASTM D1562-22(Specification)
Standard Classification System and Basis for Specification for Cellulose Acetate Propionate Molding and Extrusion Compounds (CAP)

SCOPE
1.1 This classification system covers requirements for plasticized cellulose acetate propionate thermoplastic compounds suitable for injection molding and extrusion. These compounds have a propionyl content less than 48 % and an acetyl content less than 3 % and can contain dyes and pigments. Cellulosic plastic materials, being thermoplastic, are reprocessable and recyclable. This classification system allows for the use of those cellulosic materials, provided that all specific requirements of this classification system are met.  
1.2 The properties included in this classification system are those required to identify the compositions covered. Other requirements necessary to identify particular characteristics important to specialized applications are specified by using the suffixes as given in Section 5.  
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ASTM D5336-22(Specification)
Standard Classification System and Basis for Specification for Polyphthalamide (PPA) Injection Molding Materials

ABSTRACT
This specification covers the classification, testing, and requirements of polyphthalamide (PPA) materials, both virgin and recycled, suitable for injection molding. This specification is intended to be a means of calling out plastics materials used in the fabrication of end items or parts, and not for the selection of materials. The materials are classified into groups according to crystallinity, and are further subdivided into classes and grades as specified. Materials shall be sampled, prepared, and conditioned appropriately for testing, for which specimens shall conform to specified values of the following requirements: inherent viscosity; melting temperature; glass transition; tensile strength; flexural strength and modulus; Izod impact strength; deflection temperature; and moisture.
SCOPE
1.1 This classification system covers polyphthalamide (PPA) materials suitable for injection molding.  
1.2 The properties included in this classification system are those required to identify the compositions covered. Other requirements necessary to identify particular characteristics important to specialized applications are to be specified by using suffixes as given in Section 5.  
1.3 This classification system allows for the use of recycled materials provided that all specification requirements are met.  
1.4 This classification system is intended to be a means of calling out plastics materials used in the fabrication of end items or parts. It is not intended for the selection of materials. Material selection can be made by those having expertise in the plastics field only after careful consideration of the design and the performance required of the part, the environment to which it will be exposed, the fabrication process to be employed, the costs involved, and the inherent properties of the material other than those covered by this classification system.  
1.5 The values stated in SI units are to be regarded as the standard (see IEEE/ASTM SI-10). The values given in parentheses are for information only.  
1.6 The following precautionary caveat pertains only to the test methods portion, Section 11, of this classification system: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in 11.7.1.
Note 1: There is no known ISO equivalent to this standard. ISO 16396-1/-2 for polyamides may also be used to describe and classify these PPA materials, but the technical content is significantly different.
Note 2: ASTM Standard D6779 on polyamide materials also includes PPA materials in its coverage of various polyamide chemistries. This standard gives additional information for classification and specification for PPA compositions classified as Group 10 (PA6T/66), Group 12 (PA6T/6I/66) and Group 13 (PA6T/6I) in ASTM Standard D6779 and includes provisions for other PPA compositions to utilize the classification presented.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM D3294-22(Specification)
Standard Specification for Polytetrafluoroethylene (PTFE) Resin Molded Sheet and Molded Basic Shapes

ABSTRACT
This specification establishes the requirements and test methods for the material, dimensions, and workmanship, and the physical and electrical properties of molded sheet manufactured from polytetrafluoroethylene (PTFE) resin molding materials and molded basic shapes made from resin molding and extrusion materials. The sheet or molded basic shape shall be made from unpigmented PTFE and shall be free from foreign matters. Each of the samples shall undergo visual and dimensional inspection to verify their compliance with the standard requirements. The specimens shall conform to the following physical and electrical property requirements: tensile strength; elongation; dielectric strength; specific gravity; porosity; and melting point. Examination for internal defects shall also be conducted to ensure that the specimens are free from microscopic cracks, voids, inclusions, and other surface defects that might affect the serviceability of the materials.
SCOPE
1.1 This specification establishes requirements and methods of test for the material, dimensions, and workmanship, and the physical and electrical properties of molded sheet in minimum thicknesses of 0.794 mm (1/32 in.) manufactured from PTFE resin molding materials defined in Specification D4894.  
1.2 This specification also establishes requirements for molded basic shapes made from molding materials. This specification is for products 300 mm (12 in.) or less in a dimension parallel to and 12.7 mm (0.5 in.) or greater in the dimension perpendicular to the direction of the applied molding pressure.  
1.3 The values stated in SI units are to be regarded as the standard.  
1.4 The following precautionary caveat pertains only to the test method portion, Section 7, of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Special attention is called to 13.2, 13.3, 13.6, 13.8, and A1.  
Note 1: There is no known ISO equivalent to this standard.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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