ASTM D1614-09
(Test Method)Standard Test Method for Alkalinity in Acetone
Standard Test Method for Alkalinity in Acetone
SIGNIFICANCE AND USE
This test method provides a measurement of alkalinity in acetone. The results of this measurement can be used for specification acceptance.
SCOPE
1.1 This test method covers the determination in acetone of alkalinity calculated as ammonia (NH3).
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E 29.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 For specific hazard information and guidance, consult the supplier's Material Safety Data Sheet.
1.5 This standard does not purport to address the safety concerns, if any, associated with its use. It is the responsibility of whoever uses this standard to consult and establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 7.
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Designation: D1614 − 09
Standard Test Method for
1
Alkalinity in Acetone
This standard is issued under the fixed designation D1614; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope* 4. Significance and Use
1.1 This test method covers the determination in acetone of 4.1 This test method provides a measurement of alkalinity
alkalinity calculated as ammonia (NH ).
in acetone. The results of this measurement can be used for
3
specification acceptance.
1.2 The following applies to all specified limits in this
standard; for purposes of determining conformance with this
5. Apparatus
standard, an observed value or a calculated value shall be
5.1 Buret, 10-mL, graduated in 0.05-mL subdivisions.
rounded off “to the nearest unit” in the last right-hand digit
used in expressing the specification limit, in accordance with 5.2 Erlenmeyer Flask, 250-mL capacity.
the rounding-off method of Practice E29.
6. Reagents and Materials
1.3 The values stated in SI units are to be regarded as
6.1 Purity of Reagents—Reagent grade chemicals shall be
standard. No other units of measurement are included in this
used in all tests. Unless otherwise indicated, it is intended that
standard.
all reagents shall conform to the specifications of the Commit-
1.4 For specific hazard information and guidance, consult
tee onAnalytical Reagents of theAmerican Chemical Society,
the supplier’s Material Safety Data Sheet.
3
where such specifications are available. Other grades may be
1.5 This standard does not purport to address the safety
used, provided it is first ascertained that the reagent is of
concerns, if any, associated with its use. It is the responsibility
sufficiently high purity to permit its use without lessening the
of whoever uses this standard to consult and establish appro-
accuracy of the determination.
priate safety and health practices and determine the applica-
6.2 Purity of Water—Unless otherwise indicated, references
bility of regulatory limitations prior to use. Specific hazard
to water shall be understood to mean reagent water conforming
statements are given in Section 7.
to Type IV or higher purity of Specification D1193.
2. Referenced Documents
6.3 Methyl Red Indicator Solution (1 g/L)—Dissolve 0.1 g
2
2.1 ASTM Standards:
of methyl red in 100 mL of methanol, ethanol, or isopropanol.
D1193 Specification for Reagent Water
Prepare a fresh solution at least once a month as needed.
E29 Practice for Using Significant Digits in Test Data to
6.4 Sodium Hydroxide, Standard Solution (0.05 N)—
Determine Conformance with Specifications
Prepare and standardize a 0.05 N sodium hydroxide (NaOH)
E200 Practice for Preparation, Standardization, and Storage
solution (Note 1) in accordance with Sections 12 to 17 of
of Standard and Reagent Solutions for ChemicalAnalysis
Practice E200.
3. Summary of Test Method
NOTE 1—Alternatively, potassium hydroxide (KOH) solution may be
used.
3.1 The specimen is added to water previously neutralized
tothemethylredendpoint.Ifalkalinityisdetected,itistitrated
6.5 Sulfuric Acid, Standard Solution (0.05 N)—Prepare and
with 0.05 N H SO and reported as weight percent of NH .
standardize a 0.05 N sulfuric acid (H SO ) solution.
2 4 3
2 4
7. Hazards
1
This test method is under the jurisdiction of ASTM Committee D01 on Paint
and Related Coatings, Materials, andApplications and is the direct responsibility of
7.1 Acetone is a highly flammable liquid.
Subcommittee D01.35 on Solvents, Plasticizers, and Chemical Intermediates.
Current edition approved June 1, 2009. Published June 2009. Originally
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approved in 1958. Last previous edition approved in 2008 as D1614 – 08. DOI: Reagent Chemicals, American Chemical Society Specifications, American
10.1520/D1614-09. Chemical Society, Washington, DC. For suggestions on the testing of reagents not
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or listed by the American Chemical Society, see Analar Standards for Laboratory
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Chemicals, BDH Ltd., Poole, Dorset, U.K., and the United States Pharmacopeia
Standards volume information, refer to the standard’s Document Summary page on and National Formulary, U.S. Pharmacopeial Convention, Inc. (USPC), Rockville,
the ASTM website. MD.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
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This document is not anASTM standard and is intended only to provide the user of anASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:D1614–08 Designation: D 1614 – 09
Standard Test Method for
1
Alkalinity in Acetone
This standard is issued under the fixed designation D 1614; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope*
1.1 This test method covers the determination in acetone of alkalinity calculated as ammonia (NH ).
3
1.2 For specific hazard information and guidance, consult the supplier’s Material Safety Data Sheet.
1.3The1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this
standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in
expressing the specification limit, in accordance with the rounding-off method of Practice E 29.
1.4The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 For specific hazard information and guidance, consult the supplier’s Material Safety Data Sheet.
1.5 This standard does not purport to address the safety concerns, if any, associated with its use. It is the responsibility of
whoever uses this standard to consult and establish appropriate safety and health practices and determine the applicability of
regulatory limitations prior to use. Specific hazard statements are given in Section 7.
2. Referenced Documents
2
2.1 ASTM Standards:
D 1193 Specification for Reagent Water
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
E 200 Practice for Preparation, Standardization, and Storage of Standard and Reagent Solutions for Chemical Analysis
3. Summary of Test Method
3.1 The specimen is added to water previously neutralized to the methyl red end point. If alkalinity is detected, it is titrated with
0.05 N H SO and reported as weight percent of NH .
2 4 3
4. Significance and Use
4.1 This test method provides a measurement of alkalinity in acetone. The results of this measurement can be used for
specification acceptance.
5. Apparatus
5.1 Buret, 10-mL, graduated in 0.05-mL subdivisions.
5.2 Erlenmeyer Flask, 250-mL capacity.
6. Reagents and Materials
6.1 Purity of Reagents—Reagent grade chemicals shall be used in all tests. Unless otherwise indicated, it is intended that all
reagents shall conform to the specifications of the Committee on Analytical Reagents of the American Chemical Society, where
3
such specifications are available. Other grades may be used, provided it is first ascertained that the reagent is of sufficiently high
purity to permit its use without lessening the accuracy of the determination.
1
This test method is under the jurisdiction of ASTM Committee D01 on Paint and Related Coatings, Materials, and Applications and is the direct responsibility of
Subcommittee D01.35 on Solvents, Plasticizers, and Chemical Intermediates .
Current edition approved Nov.June 1, 2008.2009. Published November 2008.June 2009. Originally approved in 1958. Last previous edition approved in 20032008 as
D 1614 – 038.
2
For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
3
Reagent Chemicals, American Chemical Society Specifications , American Chemical Society, Washington, DC. For suggestions on the testing of reagents not listed by
the American Chemical Society, see Analar Standards for Laboratory Chemicals, BDH Ltd., Poole, Dorset, U.K., and the United States Pharmacopeia and National
Formulary, U.S. Pharmacopeial Convention, Inc. (USPC), Rockville, MD.
*A Summary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
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D1614–09
6.2 Purity of Water—Unless otherwise indicated, references to water shall be understood to mean reagent water conforming to
Type IV or higher purity of Specification D 1193.
6.3 Methyl Red Indi
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