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ASTM D801-02(2009)

(Test Method)

Standard Test Methods for Sampling and Testing Dipentene

Standard Test Methods for Sampling and Testing Dipentene

SIGNIFICANCE AND USE
The testing procedures described in these test methods have been in use for many years and emphasize the physical properties rather than the chemical composition of dipentene. These procedures were sufficient when dipentene was used primarily as a solvent. Currently, however, dipentene finds application as a chemical raw material and a knowledge of its chemical composition is therefore important. Test Methods D 6387 describe a capillary gas chromatography method which is suitable for determining both the major and minor components found in dipentene.
SCOPE
1.1 These test methods cover procedures for sampling and testing dipentene and related terpene solvents, consisting chiefly of monocyclic terpene hydrocarbons distilling above the range for turpentine.  
1.2 The procedures given in these test methods appear in the following order:
Section Sampling 4 Detection and Removal of Separated Water 5 Appearance 6 Color 7 Odor 8 Specific Gravity 9 Refractive Index10 Composition11 Flash Point12 Moisture13
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
31-May-2009
ICS
87.060.30 - Solvents
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.34 - Pine Chemicals and Hydrocarbon Resins
Current Stage
Ref Project

Relations

Replaces
ASTM D801-02 - Standard Test Methods for Sampling and Testing Dipentene
Effective Date
01-Jun-2009
Replaced By
ASTM D801-02(2013) - Standard Test Methods for Sampling and Testing Dipentene
Effective Date
01-Jun-2013
Referred By
ASTM E1405-98(2022) - Standard Specification for Laboratory Glass Distillation Flasks
Effective Date
01-Jun-2009
Referred By
ASTM D6387-19 - Standard Test Methods for Composition of Turpentine and Related Terpene Products by Capillary Gas Chromatography
Effective Date
01-Jun-2009

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Standards Content (Sample)


NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D801 − 02 (Reapproved2009)
Standard Test Methods for
Sampling and Testing Dipentene
This standard is issued under the fixed designation D801; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope D6166 Test Method for Color of Pine Chemicals and Re-
lated Products (Instrumental Determination of Gardner
1.1 These test methods cover procedures for sampling and
Color)
testing dipentene and related terpene solvents, consisting
D6387 Test Methods for Composition of Turpentine and
chiefly of monocyclic terpene hydrocarbons distilling above
Related Terpene Products by Capillary Gas Chromatogra-
the range for turpentine.
phy
1.2 Theproceduresgiveninthesetestmethodsappearinthe
E300 Practice for Sampling Industrial Chemicals
following order:
3. Significance and Use
Section
Sampling 4
3.1 The testing procedures described in these test methods
Detection and Removal of Separated Water 5
have been in use for many years and emphasize the physical
Appearance 6
Color 7
properties rather than the chemical composition of dipentene.
Odor 8
These procedures were sufficient when dipentene was used
Specific Gravity 9
Refractive Index 10 primarily as a solvent. Currently, however, dipentene finds
Composition 11
application as a chemical raw material and a knowledge of its
Flash Point 12
chemical composition is therefore important. Test Methods
Moisture 13
D6387 describe a capillary gas chromatography method which
1.3 The values stated in SI units are to be regarded as
is suitable for determining both the major and minor compo-
standard. No other units of measurement are included in this
nents found in dipentene.
standard.
1.4 This standard does not purport to address all of the 4. Sampling
safety concerns, if any, associated with its use. It is the
4.1 Sample the material in accordance with the procedure
responsibility of the user of this standard to establish appro-
described in Guide D268 and Practice E300. If a sample from
priate safety and health practices and determine the applica-
close to the bottom of a tank shows a decided difference in
bility of regulatory limitations prior to use.
colororappearancefromsamplestakenatotherdepths,takean
extra bottom sample and examine it separately from the
2. Referenced Documents
composite sample. In such case the composite sample shall not
2.1 ASTM Standards:
include any portion of such bottom sample.
D268 Guide for Sampling and Testing Volatile Solvents and
5. Detection and Removal of Separated Water
Chemical Intermediates for Use in Paint and Related
Coatings and Material
5.1 Draw a portion of the dipentene by means of a glass or
D890 Test Method for Water in Liquid Pine Chemicals
metal container with a removable stopper or top, or with a
D1209 Test Method for Color of Clear Liquids (Platinum-
thief, from the lowest part of the container, or by opening the
Cobalt Scale)
bottom valve of the level tank car. If water is found to be
present, draw it all out, record the quantity, and deduct it from
the total volume of liquid delivered.
These test methods are under the jurisdiction of ASTM Committee D01 on
Paint and Related Coatings, Materials, and Applications and are the direct
6. Appearance
responsibility of Subcommittee D01.34 on Pine Chemicals and Hydrocarbon
Resins.
6.1 Examine a portion of the sample after agitation to
Current edition approved June 1, 2009. Published June 2009. Originally
determine its clarity and freedom from foreign matter and
approved in 1944. Last previous edition approved in 2002 as D801 – 02. DOI:
10.1520/D0801-02R09. separated water.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on Detailed description of equipment suitable for such sampling is given in
the ASTM website. Pra
...


This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:D801–97 Designation: D 801 – 02 (Reapproved 2009)
Standard Test Methods for
Sampling and Testing Dipentene
This standard is issued under the fixed designation D 801; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 These test methods cover procedures for sampling and testing dipentene and related terpene solvents, consisting chiefly of
monocyclic terpene hydrocarbons distilling above the range for turpentine.
1.2 The procedures given in these test methods appear in the following order:
Section
Sampling 4
Detection and Removal of Separated Water 5
Appearance 6
Color 7
Odor 8
Specific Gravity 9
Refractive Index 10
Composition 11
Flash Point 12
Moisture 13
1.3
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
2. Referenced Documents
2.1 ASTM Standards:
D 268 Guide for Sampling andTestingVolatile Solvents and Chemical Intermediates for Use in Paint and Related Coatings and
MaterialsMaterial
D803Standard Test Methods for Testing Tall Oil
D 890 Test Method for Water in Liquid Naval Stores Test Method for Water in Liquid Naval Stores
D 1209 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)
D3009Standard Test Method for Composition of Turpentine by Gas Chromatography 6166 Test Method for Color of Naval
Stores and Related Products (Instrumental Determination of Gardner Color)
D 6387 Test Methods for Composition of Turpentine and Related Terpene Products by Capillary Gas Chromatography
E 300 Practice for Sampling Industrial Chemicals
3. Significance and Use
3.1Thetestingproceduresdescribedinthesetestmethodshavebeeninuseformanyyearsandemphasizethephysicalproperties
rather than the chemical composition of dipentene. These procedures were sufficient when dipentene was used primarily as a
solvent. Currently, however, dipentene finds application as a chemical raw material and a knowledge of its chemical composition
is therefore important. Gas chromatography is the accepted method for determining the chemical composition of dipentene. An
ASTM test method using an existing ASTM test method using packed column gas chromatography can be used for the major
compounds in dipentene. A capillary GC procedure is currently being written which is suitable for both the major and minor
components.
3.1 The testing procedures described in these test methods have been in use for many years and emphasize the physical
These test methods are under the jurisdiction ofASTM Committee D-1D01 on Paint and Related Coatings, Materials, andApplications and are the direct responsibility
of Subcommittee D01.34 on Naval Stores.
Current edition approved Nov. 10, 1997. Published June 1998. Originally published as D801–44. Last previous edition D801–92.
Current edition approved June 1, 2009. Published June 2009. Originally approved in 1944. Last previous edition approved in 2002 as D 801 – 02.
For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at service@astm.org. For Annual Book ofASTM Standards
, Vol 06.04.volume information, refer to the standard’s Document Summary page on the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
D 801 – 02 (2009)
properties rather than the chemical composition of dipentene.These procedures were sufficient when dipentene was used primarily
as a solvent. Currently, however, dipentene finds application as a chemical raw material and a knowledge of its chemical
composition is therefore important. Test Methods D 6387 describe a capillary gas chromatography method which is suitable for
determining both the major and minor components found in dipentene.
4. Sampling
4.1 Sample the material in accordance with the procedure described in Guide D 268 and Practice E 300. If a sample from close
to the bottom of a tank shows a decided difference in color or appearance from samples taken at other depths, take an extra bottom
sample and examine it separately from the composite sample. In such case the composite sample shall not include
...

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SCOPE
1.1 This test method is for the determination of acetone, methyl acetate, or parachlorobenzotrifluoride (PCBTF), or combination of any of the three, in paints and coatings, by solid phase microextraction (SPME) headspace sampling, and subsequent injection into a gas chromatograph. It has been evaluated for cellulose nitrate, acrylic, and urethane solvent-borne systems. The established working range of this test method is: acetone, 28 to 90 %; methyl acetate, 12 to 22 %; parachlorobenzotrifluoride, 10 to 17 %. There is no reason to believe that it will not work outside these ranges. A minor modification of this test method would make it suitable for the analysis of the same analytes in water-borne coatings (see Note 1).
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1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
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