ASTM G217-16
(Guide)Standard Guide for Corrosion Monitoring in Laboratories and Plants with Coupled Multielectrode Array Sensor Method
Standard Guide for Corrosion Monitoring in Laboratories and Plants with Coupled Multielectrode Array Sensor Method
SIGNIFICANCE AND USE
4.1 Guide G96 describes a linear-polarization method and an electrical resistance method for online monitoring of corrosion in plant equipment without the need to enter the system physically to withdraw coupons. These two online monitoring techniques are useful in systems in which process upsets or other problems can create corrosive conditions. An early warning of corrosive attack can permit remedial action before significant damage occurs to process equipment. The two methods described in Guide G96 are suitable for uniform corrosion, but may not be sensitive enough for non-uniform corrosion, especially localized corrosion. This guide describes a new method for monitoring non-uniform corrosion, especially localized corrosion.
4.2 The CMAS technique measures the net anodic current or net cathodic current from each of the individual electrodes (Iaex or Icex in Fig. 1), which is the characteristic of non-uniform corrosion such as localized corrosion and uneven general corrosion. Therefore, the CMAS technique can be used to estimate the rate of uneven general corrosion and localized corrosion (see Section 5).
Note 1: The upper section shows the electron flows from the corroding area to the less corroding areas inside a metal when localized corrosion takes place; the lower section shows the electron flows after the anodic and cathodic areas are separated into individual small electrodes and coupled through an external circuit that measures the anodic current (Iaex) and cathodic current (Icex) through each of the individual electrodes (4).
4.3 Unlike uniform corrosion, the rate of non-uniform corrosion, especially localized corrosion, can vary significantly from one area to another area of the same metal exposed to the same environment. Allowance shall be made for such variations when the measured non-uniform corrosion rate is used to estimate the penetration of the actual metal structure or the actual wall of process equipment. This variability is less critical ...
SCOPE
1.1 This guide outlines the procedure for conducting corrosion monitoring in laboratories and plants by use of the coupled multielectrode array sensor (CMAS) technique.
1.2 For plant applications, this technique can be used to assess the instantaneous non-uniform corrosion rate, including localized corrosion rate, on a continuous basis, without removal of the monitoring probes, from the plant.
1.3 For laboratory applications, this technique can be used to study the effects of various testing conditions and inhibitors on non-uniform corrosion, including pitting corrosion and crevice corrosion.
1.4 Units—The values stated in SI units are to be regarded as the standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
General Information
Standards Content (Sample)
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Designation: G217 − 16
Standard Guide for
Corrosion Monitoring in Laboratories and Plants with
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Coupled Multielectrode Array Sensor Method
This standard is issued under the fixed designation G217; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope tance of Stainless Steels and Related Alloys by Use of
Ferric Chloride Solution
1.1 This guide outlines the procedure for conducting corro-
G96 Guide for Online Monitoring of Corrosion in Plant
sionmonitoringinlaboratoriesandplantsbyuseofthecoupled
Equipment (Electrical and Electrochemical Methods)
multielectrode array sensor (CMAS) technique.
G102 Practice for Calculation of Corrosion Rates and Re-
1.2 For plant applications, this technique can be used to
lated Information from Electrochemical Measurements
assess the instantaneous non-uniform corrosion rate, including
G193 Terminology and Acronyms Relating to Corrosion
localized corrosion rate, on a continuous basis, without re-
G199 Guide for Electrochemical Noise Measurement
moval of the monitoring probes, from the plant.
3. Terminology
1.3 For laboratory applications, this technique can be used
to study the effects of various testing conditions and inhibitors
3.1 Definitions—The terminology used herein, if not spe-
on non-uniform corrosion, including pitting corrosion and
cifically defined otherwise, shall be in accordance with Termi-
crevice corrosion.
nology G193. Definitions provided herein and not given in
Terminology G193 are limited only to this guide.
1.4 Units—The values stated in SI units are to be regarded
as the standard. No other units of measurement are included in
3.2 Definitions of Terms Specific to This Standard:
this standard.
3.2.1 coupled multielectrode array sensor, CMAS,
1.5 This standard does not purport to address all of the n—device with multiple working electrodes that are coupled
through an external circuit such that all the electrodes operate
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appro- at the same electrode potential to simulate the electrochemical
behavior of a single-piece metal.
priate safety and health practices and determine the applica-
bility of regulatory limitations prior to use.
3.2.2 non-uniform corrosion, n—corrosion that occurs at
various rates across the metal surface, with some locations
2. Referenced Documents
exhibiting higher anodic rates while others have higher ca-
2
2.1 ASTM Standards: thodic rates, thereby requiring that the electron transfer occurs
G1 Practice for Preparing, Cleaning, and Evaluating Corro- between these sites within the metal.
sion Test Specimens 3.2.2.1 Discussion—Non-uniform corrosion includes both
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G4 Guide for Conducting Corrosion Tests in Field Applica- localized corrosion and uneven general corrosion (1). Non-
tions uniform corrosion also includes the type of general corrosion
G16 Guide for Applying Statistics to Analysis of Corrosion that produces even surfaces at the end of a large time interval,
Data but uneven surfaces during small time intervals.
G46 Guide for Examination and Evaluation of Pitting Cor-
3.2.3 uneven general corrosion, n—corrosion that occurs
rosion
overthewholeexposedsurfaceoralargeareaatdifferentrates.
G48 Test Methods for Pitting and Crevice Corrosion Resis-
3.2.3.1 Discussion—In this guide, general corrosion is fur-
ther divided into even general corrosion, or uniform corrosion,
which is defined as the corrosion that proceeds at exactly the
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This guide is under the jurisdiction ofASTM Committee G01 on Corrosion of
same rate over the surface of a material (see Terminology
Metals and is the direct responsibility of Subcommittee G01.11 on Electrochemical
G193) and uneven general corrosion. Uneven general corro-
Measurements in Corrosion Testing.
Current edition approved Nov. 1, 2016. Published November 2016. DOI:
sion is defined as the general corrosion that produces uneven
10.1520/G0217-16.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
3
Standards volume information, refer to the standard’s Document Summary page on The boldface numbers in parentheses refer to a list of references at the end of
the ASTM website. this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
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G217 − 16
surfaceorwave-likesurfaceonametalthathasanevensurface a new method for monitoring non-uniform corrosion, espe-
before the
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