Standard Practice for Operating Open Flame Carbon Arc Light Apparatus for Exposure of Nonmetallic Materials

SCOPE
1.1 This practice covers the basic principles and operating procedures for using open flame carbon-arc light and water apparatus intended to reproduce the weathering effects that occur when materials are exposed to sunlight (either direct or through window glass) and moisture as rain or dew in actual use. This practice is limited to the procedures for obtaining, measuring, and controlling conditions of exposure. A number of exposure procedures are listed in an appendix; however, this practice does not specify the exposure conditions best suited for the material to be tested.
Note 1--Practice G151 describes performance criteria for all exposure devices that use laboratory light sources. This practice replaces Practice G23, which describes very specific designs for devices used for carbon-arc exposures. The apparatus described in Practice G23 is covered by this practice.
1.2 Test specimens are exposed to filtered open flame carbon arc light under controlled environmental conditions. Different filters are described.
1.3 Specimen preparation and evaluation of the results are covered in methods or specifications for specific materials. General guidance is given in Practice G151 and ISO 4892-1. More specific information about methods for determining the change in properties after exposure and reporting these results is described in ISO 4582.
1.4 The values stated in SI units are to be regarded as the standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
1.5.1 Should any ozone be generated from the operation of the light source, it shall be carried away from the test specimens and operating personnel by an exhaust system.
1.6 This practice is technically similar to ISO 4892-4.

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NOTICE: This standard has either been superseded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
Designation: G 152 – 00
Standard Practice for
Operating Open Flame Carbon Arc Light Apparatus for
Exposure of Nonmetallic Materials
This standard is issued under the fixed designation G 152; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope D 3980 Practice for Interlaboratory Testing of Paint and
Related Materials
1.1 This practice covers the basic principles and operating
E 691 Practice for Conducting an Interlaboratory Study to
procedures for using open flame carbon-arc light and water
Determine the Precision of a Test Method
apparatus intended to reproduce the weathering effects that
G 23 Practice for Operating Light—Exposure Apparatus
occur when materials are exposed to sunlight (either direct or
(Carbon-Arc Type) With and Without Water for Exposure
through window glass) and moisture as rain or dew in actual
of Nonmetallic Materials
use. This practice is limited to the procedures for obtaining,
G 113 Terminology Relating to Natural and Artificial
measuring, and controlling conditions of exposure. A number
Weathering Tests of Nonmetallic Materials
of exposure procedures are listed in an appendix; however, this
G 151 Practice for Exposing Nonmetallic Materials in Ac-
practice does not specify the exposure conditions best suited
celerated Test Devices That Use Laboratory Light
for the material to be tested.
Sources
NOTE 1—Practice G 151 describes performance criteria for all exposure
2.2 CIE Standard:
devices that use laboratory light sources. This practice replaces Practice
CIE-Publ. No. 85: Recommendations for the Integrated
G 23, which describes very specific designs for devices used for carbon-
Irradiance and the Spectral Distribution of Simulated
arc exposures. The apparatus described in Practice G 23 is covered by this
Solar Radiation for Testing Purposes
practice.
2.3 ISO Standards:
1.2 Test specimens are exposed to filtered open flame
ISO 4582, Plastics—Determination of the Changes of
carbon arc light under controlled environmental conditions.
Colour and Variations in Properties After Exposure to
Different filters are described.
Daylight Under Glass, Natural Weathering or Artificial
1.3 Specimen preparation and evaluation of the results are
Light
covered in methods or specifications for specific materials.
ISO 4892-1, Plastics—Methods of Exposure to Laboratory
General guidance is given in Practice G 151 and ISO 4892-1.
Light Sources, Part 1, General Guidance
More specific information about methods for determining the
ISO 4892-4, Plastics—Methods of Exposure to Laboratory
change in properties after exposure and reporting these results
Light Sources, Part 4, Open-Flame Carbon Arc Lamp
is described in ISO 4582.
1.4 The values stated in SI units are to be regarded as the
3. Terminology
standard.
3.1 Definitions—The definitions given in Terminology
1.5 This standard does not purport to address all of the
G 113 are applicable to this practice.
safety concerns, if any, associated with its use. It is the
3.1.1 As used in this practice, the term sunlight is identical
responsibility of the user of this standard to establish appro-
to the terms daylight and solar irradiance, global as they are
priate safety and health practices and determine the applica-
defined in Terminology G 113.
bility of regulatory limitations prior to use.
1.5.1 Should any ozone be generated from the operation of
4. Summary of Practice
the light source, it shall be carried away from the test
4.1 Specimens are exposed to repetitive cycles of light and
specimens and operating personnel by an exhaust system.
moisture under controlled environmental conditions.
1.6 This practice is technically similar to ISO 4892-4.
4.1.1 Moisture usually is produced by spraying the test
2. Referenced Documents
2.1 ASTM Standards:
Discontinued 1998; see 1998 Annual Book of ASTM Standards, Vol 06.01.
Annual Book of ASTM Standards, Vol 14.02.
Annual Book of ASTM Standards, Vol 14.04.
This practice is under the jurisdiction of ASTM Committee G3 on Weathering
and Durability and is the direct responsibility of Subcommittee G03.03 on Available from Secretary, U.S. National Committee, CIE, National Institute of
Simulated and Controlled Exposure Tests. Standards and Technology, Gaithersburg, MD 20899.
Current edition approved March 10, 2000. Published May 2000. Originally Available from American National Standards Institute, 11 W. 42nd St., 13th
published as G 152 – 97. Last previous edition G 152 – 98. Floor, New York, NY 10036.
Copyright © ASTM, 100 Barr Harbor Drive, West Conshohocken, PA 19428-2959, United States.
G 152
specimen with demineralized/deionized water or by condensa- distribution of the open flame carbon arc to make it match
tion of water vapor onto the specimen. daylight in the long wavelength UV or the visible light regions
4.2 The exposure condition may be varied by selection of: of the spectrum.
4.2.1 Light source filter, 6.1.3 The following factors can affect the spectral power
4.2.2 The type of moisture exposure, distribution of open flame carbon arc light sources:
4.2.3 The timing of the light and moisture exposure, 6.1.3.1 Differences in the composition and thickness of
4.2.4 The temperature of light exposure, and filters can have large effects on the amount of short wavelength
4.2.5 The timing of a light/dark cycle. UV radiation transmitted.
4.3 Comparison of results obtained from specimens exposed 6.1.3.2 Aging of filters can result in changes in filter
in same model of apparatus should not be made unless transmission. The aging properties of filters can be influenced
reproducibility has been established among devices for the by the composition. Aging of filters can result in a significant
material to be tested. reduction in the short wavelength UV emission of a burner.
4.4 Comparison of results obtained from specimens exposed 6.1.3.3 Accumulation of dirt or other residue on filters can
in different models of apparatus should not be made unless affect filter transmission.
correlation has been established among devices for the material 6.1.3.4 Differences in the composition of the metallic salts
to be tested. used in he carbon rods can affect the spectral power distribu-
tion.
5. Significance and Use
6.1.4 Spectral Irradiance:
5.1 The use of this apparatus is intended to induce property
6.1.4.1 Spectral Irradiance of Open Flame Carbon Arc with
changes associated with the end use conditions, including the Daylight Filters—Daylight filters are used to reduce the short
effects of sunlight, moisture, and heat. These exposures may
wavelength UV irradiance of the open flame carbon arc in an
include a means to introduce moisture to the test specimen. attempt to provide simulation of the short wavelength UV
Exposures are not intended to simulate the deterioration caused
region of daylight. Although these filters are specified in many
by localized weather phenomena, such as atmospheric pollu- tests because of historical precedent, they transmit significant
tion, biological attack, and saltwater exposure. Alternatively,
radiant energy below 300 nm (the typical cut-on wavelength
the exposure may simulate the effects of sunlight through for terrestrial sunlight) and may result in aging processes not
window glass. Typically, these exposures would include mois-
occurring outdoors. The data in Table 1 is representative of the
ture in the form of humidity.
spectral irradiance received by a test specimen mounted in the
5.2 Cautions—Refer to Practice G 151 for full cautionary
specimen plane of an open flame carbon arc equipped with
guidance applicable to all laboratory weathering devices.
daylight filters.
Variation in results may be expected when operating conditions
6.1.4.2 Spectral Irradiance of Open Flame Carbon Arc With
are varied within the accepted limits of this practice. No
Window Glass Filters—Window glass filters use a heat resis-
reference, therefore, shall be made to results from the use of
tant glass to filter the open flame carbon arc in a simulation of
this practice unless accompanied by a report detailing the
sunlight filtered through single strength window glass. The
specific operating conditions in conformance with Section 10.
data in Table 2 is representative of the spectral irradiance
It is recommended that a similar material of known perfor-
received by a test specimen mounted in the specimen plane of
mance, a control, be exposed simultaneously with the test
an open flame carbon arc equipped with window glass filters.
specimen to provide a standard for comparative purposes. It is
NOTE 2—The most commonly used type of daylight filters are made
recommended that at least three replicates of each material
from Potash-Lithia glass and are commonly known as Corex D filters.
evaluated be exposed in each test to allow for statistical
6.2 Test Chamber—The design of the test chamber may
evaluation of results.
vary, but it should be constructed from corrosion resistant
6. Apparatus material, and in addition to the radiation source, may provide
for means of controlling temperature and relative humidity.
6.1 Laboratory Light Source—Open flame carbon arc light
When required, provision shall be made for the spraying of
sources typically use three or four pairs of carbon rods, which
water on the test specimen or for the formation of condensate
contain a mixture of rare-earth metal salts and have a metal
on the exposed face of the specimen.
coating such as copper on the surface. An electric current is
6.2.1 The radiant source(s) shall be located with respect to
passed between the carbon rods which burn and give off
the specimens such that the irradiance at the specimen face
ultraviolet, visible, and infrared radiation. The carbon rod pairs
complies with the requirements in Practice G 151.
are burned in sequence, with one pair burning at any one time.
6.3 Instrument Calibration—To ensure standardization and
Use carbon rods recommended by the device manufacturer.
accuracy, the instruments associated with the exposure appa-
6.1.1 Filter Types—Radiation emitted by the open flame
ratus, for example, timers, thermometers, wet bulb sensors, dry
carbon arc contains significant levels of very short wavelength
UV (less than 260 nm) and must be filtered. Two types of glass
filters are commonly used. Other filters may be used by mutual
Fischer, R., Ketola, W., Murray, W., “Inherent Variability in Accelerated
agreement by the interested parties as long as the filter type is
Weathering Devices,” Progress in Organic Coatings, Vol 19 (1991), pp. 165–179.
reported in conformance with the report section in Practice
Ketola, W., Robbins, J. S., “UV Transmission of Single Strength Window
G 151.
Glass,” Symposium on Accelerated and Outdoor Durability Testing of Organic
6.1.2 None of these fibers changes the spectral power Materials, ASTM STP 1202, ASTM, 1993.
G 152
TABLE 1 Relative Spectral Power Distribution Specification for TABLE 2 Typical Relative Spectral Power Distribution for Open
Open Flame Carbon Arc With Daylight Filters Flame Carbon Arc With Window Glass Filters (Representative
Data)
Ultraviolet Wavelength region
Irradiance as a Percentage of Total Irradiance from 300 to 400 nm
Ultraviolet Wavelength Region
Irradiance as a Percentage of Total Irradiance from 300 to 400 nm
Open Flame Carbon Arc
A,B C
Bandpass (nm) with Daylight Filters Sunlight
Open Flame Carbon Arc Estimated Window Glass
A B
250–279 0–4.0 % 0 %
Bandpass (nm) with Window Glass Filters Filtered Sunlight
280–290 0–1.8 % 0 %
250–270 0 % 0 %
291–300 0.1–1.3 % 0 %
271–290 0 % 0 %
301–320 2.4–5.4 % 5.6 %
291–300 0 % 0 %
321–340 6.8–10.4 % 18.5 %
301–320 2.1 % 0.1–1.5 %
341–360 9.4–14.8 % 21.7 %
321–340 8.1 % 9.4–14.8 %
361–380 21.6–27.6 % 26.6 %
341–360 13.2 % 23.2–23.5 %
381–400 44.6–56.6 % 27.6 %
361–380 27.3 % 29.6–32.5 %
381–400 49.3 % 30.9–34.5 %
Ultraviolet and Visible Wavelength region
D
Irradiance as a Percentage of Total Irradiance from 300 to 800 nm
Ultraviolet and Visible Wavelength Region Irradiance as a Percentage of Total
C
Irradiance from 300 to 800 nm
C
Open Flame Carbon Arc
Irradiance as a Percentage of Total Irradiance from 300 to 800 nm
A,B E
Bandpass (nm) with Daylight Filters Sunlight
300–400 22.7–34.1 % 11 %
Open Flame Carbon Arc Estimated Window Glass
E D
401–700 51.1–67.3 % 72 %
Bandpass (nm) with Window Glass Filters Filtered Sunlight
A 300–400 22.7–34.1 % 9.0–11.1 %
Carbon Arc Data—Open flame carbons arcs emit significant short wavelength
401–700 51.1–67.3 % 71.3–73.1 %
UV radiation between 250 and 280 nm. The intensity of this short wavelength UV
7 *Data from 701 to 800 nm is not shown
radiation varies with age and initial transmission of the filters used and the
composition of the carbon rods. Composition of the carbon rods may vary between
A
production lots and between manufacturers.
Carbon Arc Data—This data are for a typical spectral power distribution for an
B
Carbon Arc Data—The ranges given are based on spectral power distribution
open flame carbons arc with window glass filters. Not enough spectral data is
measurements made for open flame carbon arcs devices operating with carbon
available for meaningful analysis to develop a specification. Subcommittee G03.03
rods from different sources and with filters from different lots and varying ages. The
is working to collect sufficient data in order to develop a specification.
B
ranges are based on the three sigma limits from the averages of these SPD
Sunlight Data—The sunlight data is for global irradiance on a horizontal surface
measurements.
with an air mass of 1.2, column ozone 0.294 atm cm, 30 % relative humidity,
C
Sunlight Data—The sunlight data is for global irradiance on a horizontal
altitude 2100 m (atmospheric pressure of 787.8 mb), and an aerosol represented
surface with an air mass of 1.2, column ozone 0.294 atm cm, 30 % relative
by an optical thickness of 0.081 at 300 nm and 0.62 at 400 nm. The range is
humidity, altitude 2100 m (atmospheric pressure of 787.8 mb), and an aerosol
determined by multiplying solar irradiance by the upper and lower limits for
represented by an optical thickness of 0.081 at 300 nm and 0.62 at 400 nm.
transmission of single strength window glass samples used for studies conducted
D
Data from 701 to 800 nm is not shown.
by Subcommittee G03.02.
E
C
Sunlight Data—The sunlight data is from Table 4 of CIE Publication No. 85,
Sunlight Data—The sunlight data is from Table 4 of CIE Publication No. 85,
global solar irradiance on a horizontal surface with an air mass of 1.0, column
...

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