Gas cylinders - Compatibility of cylinder and valve materials with gas contents - Part 1: Metallic materials (ISO 11114-1:2012)

ISO 11114-1:2012 provides requirements for the selection of safe combinations of metallic cylinder and valve materials and cylinder gas content.
The compatibility data given is related to single gases and to gas mixtures.
Seamless metallic, welded metallic and composite gas cylinders and their valves, used to contain compressed, liquefied and dissolved gases, are considered.
Aspects such as the quality of delivered gas product are not considered.

Gasflaschen - Verträglichkeit von Werkstoffen für Gasflaschen und Ventile mit den in Berührung kommenden Gasen - Teil 1: Metallische Werkstoffe (ISO 11114-1:2012)

Dieser Teil der ISO 11114 enthält Anforderungen für die Auswahl von sicheren Kombinationen von
metallischen Gasflaschen- und Ventilwerkstoffen und den in Berührung kommenden Gasen.
Die Angaben zur Verträglichkeit beziehen sich auf Einzelgase und Gasgemische.
Es sind nahtlose metallische Gasflaschen, geschweißte metallische Gasflaschen und Gasflaschen aus
Verbundwerkstoffen (Composite-Gasflaschen) einschließlich deren Ventile zur Verwendung mit verdichteten,
verflüssigten und gelösten Gasen berücksichtigt.
ANMERKUNG In diesem Teil der ISO 11114 wird der Begriff „Flasche“ für ortsbewegliche Druckgefäße, welche auch
Großflaschen und Druckfässer umfassen, verwendet.
Aspekte wie die Qualität des gelieferten Gasproduktes werden nicht berücksichtigt.

Bouteilles à gaz - Compatibilité des matériaux des bouteilles et des robinets avec les contenus gazeux - Partie 1: Matériaux métalliques (ISO 11114-1:2012)

L'ISO 11114-1:2012 fournit les exigences pour le choix des combinaisons de matériaux sûres pour les bouteilles à gaz métalliques et leur robinet et les gaz contenus dans la bouteille.
Les données de compatibilité indiquées se rapportent aux gaz à l'état pur et aux mélanges de gaz.
L'ISO 11114-1:2012 prend en considération les bouteilles à gaz composites, métalliques soudées, métalliques sans soudure et leurs robinets utilisées pour contenir des gaz comprimés, liquéfiés et dissous.
Elle ne traite pas d'autres aspects tels que la qualité du produit gazeux fourni.

Plinske jeklenke - Združljivost materialov za ventil in jeklenko s plinom - 1. del: Kovinski materiali (ISO 11114-1:2012)

Ta standard določa zahteve za izbiro in oceno združljivosti materialov za kovinske plinske jeklenke in ventile s plinom. Navedeni podatki o združljivosti se nanašajo na enokomponentne pline in mešanice plinov. Obravnavane so brezšivne in varjene plinske jeklenke, ki se uporabljajo za stisnjene, utekočinjene in raztopljene pline.

General Information

Status
Withdrawn
Publication Date
14-Mar-2012
Withdrawal Date
09-Jun-2020
Current Stage
9960 - Withdrawal effective - Withdrawal
Completion Date
10-Jun-2020

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SLOVENSKI STANDARD
01-maj-2012
1DGRPHãþD
SIST EN ISO 11114-1:1999
SIST EN ISO 11114-1:1999/AC:1999
Plinske jeklenke - Združljivost materialov za ventil in jeklenko s plinom - 1. del:
Kovinski materiali (ISO 11114-1:2012)
Gas cylinders - Compatibility of cylinder and valve materials with gas contents - Part 1:
Metallic materials (ISO 11114-1:2012)
Gasflaschen - Verträglichkeit von Werkstoffen für Gasflaschen und Ventile mit den in
Berührung kommenden Gasen - Teil 1: Metallische Werkstoffe (ISO 11114-1:2012)
Bouteilles à gaz - Compatibilité des matériaux des bouteilles et des robinets avec les
contenus gazeux - Partie 1: Matériaux métalliques (ISO 11114-1:2012)
Ta slovenski standard je istoveten z: EN ISO 11114-1:2012
ICS:
23.020.30 7ODþQHSRVRGHSOLQVNH Pressure vessels, gas
MHNOHQNH cylinders
23.060.40 7ODþQLUHJXODWRUML Pressure regulators
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EUROPEAN STANDARD
EN ISO 11114-1
NORME EUROPÉENNE
EUROPÄISCHE NORM
March 2012
ICS 23.020.30 Supersedes EN ISO 11114-1:1997
English Version
Gas cylinders - Compatibility of cylinder and valve materials with
gas contents - Part 1: Metallic materials (ISO 11114-1:2012)
Bouteilles à gaz - Compatibilité des matériaux des Gasflaschen - Verträglichkeit von Werkstoffen für
bouteilles et des robinets avec les contenus gazeux - Partie Gasflaschen und Ventile mit den in Berührung kommenden
1: Matériaux métalliques (ISO 11114-1:2012) Gasen - Teil 1: Metallische Werkstoffe (ISO 11114-1:2012)
This European Standard was approved by CEN on 18 February 2012.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same
status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom.

EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2012 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 11114-1:2012: E
worldwide for CEN national Members.

Contents Page
Foreword .3

Foreword
This document (EN ISO 11114-1:2012) has been prepared by Technical Committee ISO/TC 58 "Gas
cylinders" in collaboration with Technical Committee CEN/TC 23 “Transportable gas cylinders” the secretariat
of which is held by BSI.
This European Standard shall be given the status of a national standard, either by publication of an identical
text or by endorsement, at the latest by September 2012, and conflicting national standards shall be
withdrawn at the latest by September 2012.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN ISO 11114-1:1997.
This European Standard has been submitted for reference into the RID and/or the technical annexes of the
ADR.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech
Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia,
Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain,
Sweden, Switzerland, Turkey and the United Kingdom.
Endorsement notice
The text of ISO 11114-1:2012 has been approved by CEN as a EN ISO 11114-1:2012 without any
modification.
INTERNATIONAL ISO
STANDARD 11114-1
Second edition
2012-03-15
Gas cylinders — Compatibility of cylinder
and valve materials with gas contents —
Part 1:
Metallic materials
Bouteilles à gaz — Compatibilité des matériaux des bouteilles et des
robinets avec les contenus gazeux —
Partie 1: Matériaux métalliques

Reference number
ISO 11114-1:2012(E)
©
ISO 2012
ISO 11114-1:2012(E)
©  ISO 2012
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized in any form or by any means,
electronic or mechanical, including photocopying and microfilm, without permission in writing from either ISO at the address below or
ISO's member body in the country of the requester.
ISO copyright office
Case postale 56  CH-1211 Geneva 20
Tel. + 41 22 749 01 11
Fax + 41 22 749 09 47
E-mail copyright@iso.org
Web www.iso.org
Published in Switzerland
ii © ISO 2012 – All rights reserved

ISO 11114-1:2012(E)
Contents Page
Foreword . iv
Introduction . v
1  Scope . 1
2  Normative references . 1
3  Terms and definitions . 2
4  Materials . 2
4.1  General . 2
4.2  Cylinder materials . 3
4.3  Valve materials . 3
5  Compatibility criteria . 3
5.1  General . 3
5.2  Corrosion . 4
5.3  Hydrogen embrittlement phenomenon . 5
5.4  Generation of dangerous products . 5
5.5  Violent reactions (e.g. ignition) . 5
5.6  Stress corrosion cracking . 5
6  Material compatibility . 5
6.1  Table of compatibility for single gases (see Table 1) . 5
6.2  Compatibility for gas mixtures . 5
6.3  Using Table 1 . 6
Annex A (informative) Gas/materials NQSAB compatibility code . 33
Bibliography . 47

ISO 11114-1:2012(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies
(ISO member bodies). The work of preparing International Standards is normally carried out through ISO
technical committees. Each member body interested in a subject for which a technical committee has been
established has the right to be represented on that committee. International organizations, governmental and
non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the
International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.
The main task of technical committees is to prepare International Standards. Draft International Standards
adopted by the technical committees are circulated to the member bodies for voting. Publication as an
International Standard requires approval by at least 75 % of the member bodies casting a vote.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights.
ISO 11114-1 was prepared by the European Committee for Standardization (CEN) Technical Committee
CEN/TC 23, Transportable gas cylinders, in collaboration with ISO Technical Committee ISO/TC 58, Gas
cylinders, in accordance with the Agreement on technical cooperation between ISO and CEN (Vienna
Agreement).
This second edition cancels and replaces the first edition (ISO 11114-1:1997), which has been technically
revised. The main changes resulting from the revision of this part of ISO 11114 are
 the term “not recommended” has been replaced by “not acceptable”,
 the text has been clarified,
 a requirement for gas mixtures has been introduced.
ISO 11114 consists of the following parts, under the general title Gas cylinders — Compatibility of cylinder and
valve materials with gas contents:
 Part 1: Metallic materials
 Part 2: Non-metallic materials
 Part 3: Autogenous ignition test for non-metallic materials in oxygen atmosphere
 Part 4: Test methods for selecting metallic materials resistant to hydrogen embrittlement
iv © ISO 2012 – All rights reserved

ISO 11114-1:2012(E)
Introduction
Industrial, medical and special gases (e.g. high-purity gases, calibration gases) can be transported or stored
in gas cylinders. An essential requirement of the material from which such gas cylinders and their valves are
manufactured is compatibility with the gas content.
Compatibility of cylinder materials with gas content has been established over many years by practical
application and experience. Existing national and international regulations and standards do not fully cover
this aspect.
This part of ISO 11114 is based on current international experience and knowledge.
Where there is any conflict between this International Standard and any applicable regulation, the regulation
always takes precedence.
This part of ISO 11114 has been written to be in conformity with the UN Recommendations on the Transport
of Dangerous Goods: Model Regulations. When published it will be submitted to the UN Sub Committee of
Experts on the Transport of Dangerous Goods with a request that it be included in the Model Regulations.

INTERNATIONAL STANDARD ISO 11114-1:2012(E)

Gas cylinders — Compatibility of cylinder and valve materials
with gas contents —
Part 1:
Metallic materials
1 Scope
This part of ISO 11114 provides requirements for the selection of safe combinations of metallic cylinder and
valve materials and cylinder gas content.
The compatibility data given is related to single gases and to gas mixtures.
Seamless metallic, welded metallic and composite gas cylinders and their valves, used to contain compressed,
liquefied and dissolved gases, are considered.
NOTE In this part of ISO 11114 the term “cylinder” refers to transportable pressure receptacles, which also include
tubes and pressure drums.
Aspects such as the quality of delivered gas product are not considered.
2 Normative references
The following referenced documents are indispensable for the application of this document. For dated
references, only the edition cited applies. For undated references, the latest edition of the referenced
document (including any amendments) applies.
ISO 9809-1, Gas cylinders — Refillable seamless steel gas cylinders — Design, construction and testing —
Part 1: Quenched and tempered steel cylinders with tensile strength less than
...

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