EN ISO 6978-2:2005

Natural gas - Determination of mercury - Part 2: Sampling of mercury by amalgamation on gold/platinum alloy (ISO 6978-2:2003)

This ISO 6978-2:2003 specifies a method for the determination of total mercury content of pipeline quality natural gas using a sampling method by amalgamation on gold/platinum (Au/Pt) alloy thread. This method is applicable to the sampling of raw natural gas when no condensation is present. At atmospheric pressure, this method is suitable for the determination of mercury content within the range of 0,01 microgram /m3 to 100 micrograms/m3 in natural gas samples. At higher pressures (up to 8 MPa), this sampling method is suitable for the determination of mercury contents within the range of 0,001 microgram/m3 to 1 microgram/m3. The collected mercury is determined by measuring the absorbance or fluorescence of mercury vapour at 253,7 nm.

Erdgas - Bestimmung von Quecksilber - Teil 2: Probenahme von Quecksilber durch Amalgamierung an einer Gold/Platin-Legierung (ISO 6978-2:2003)

Gaz naturel - Détermination de la teneur en mercure - Partie 2: Echantillonnage du mercure par amalgamation sur alliage or/platine (ISO 6978-2:2003)

L'ISO 6978-2:2003 spécifie une méthode de détermination de la teneur totale en mercure dans le gaz naturel de pipeline à l'aide d'une méthode d'échantillonnage par amalgamation sur un fil en alliage or/platine (Au/Pt). Cette méthode est applicable à l'échantillonnage de gaz naturel brut en l'absence de condensation. À pression atmosphérique, cette méthode est appropriée pour la détermination de la teneur en mercure dans des échantillons de gaz naturel allant de 0,01 microgramme/m3 à 100 microgrammes/m3. À des pressions plus élevées (jusqu'à 8 MPa), cette méthode d'échantillonnage est appropriée pour la détermination des teneurs en mercure allant de 0,001 microgramme/m3 à 1 microgramme/m3. Le mercure recueilli est déterminé en mesurant l'absorbance ou la fluorescence de la vapeur de mercure à 253,7 nm.

Zemeljski plin – Določevanje živega srebra – 2. del: Vzorčenje živega srebra z amalgiranjem na zlati/platinasti zlitini (ISO 6978-2:2003)

Ta del standarda ISO 6978 določa metodo za določevanje skupne vsebnosti živega srebra v zemeljskem plinu iz cevovoda z uporabo metode vzorčenja z amalgiranjem na zlati/platinasti (Au/Pt) zlitini. Ta metoda se uporablja za vzorčenje surovega zemeljskega plina ob odsotnosti kondenzacije. Ta metoda je ustrezna za določevanje vsebnosti živega srebra v razponu od 0,01 μg/m3 do 100 μg/m3 v vzorcih zemeljskega plina pri atmosferskem tlaku. Ta metoda je ustrezna za določevanje vsebnosti živega srebra v razponu od 0,001 μg/m3 do 1 μg/m3 v vzorcih zemeljskega plina pri višjem tlaku (do 8 MPa). Pridobljeno živo srebro se določi z merjenjem absorpcije ali fluorescence hlapov živega srebra pri 253,7 nm.
OPOMBA: Standard ISO 6978-1 podaja metodo vzorčenja, ki je ustrezna za določevanje vsebnosti živega srebra v zemeljskem plinu s kemisorpcijo na z jodom impregniranim silikagelom za delovni razpon od 0,1 μg/m3 do 5000 μg/m3 za vzorčenje pri tlaku nad 40 MPa.

General Information

• Status: Published
• Publication Date: 10-May-2005
• ICS: 75.060 - Natural gas
• Technical Committee: CEN/TC 238 - Test gases, test pressures and categories of appliances
• Drafting Committee: CEN/TC 238 - Test gases, test pressures and categories of appliances
• Current Stage: 6060 - Definitive text made available (DAV) - Publishing
• Start Date: 11-May-2005
• Due Date: 16-Dec-2004
• Completion Date: 11-May-2005
• Ref Project: SIST EN ISO 6978-2:2005 - Natural gas - Determination of mercury - Part 2: Sampling of mercury by amalgamation on gold/platinum alloy (ISO 6978-2:2003)

Relations

• Corrected By: EN ISO 6978-2:2005/AC:2016 - Natural gas - Determination of mercury - Part 2: Sampling of mercury by amalgamation on gold/platinum alloy - Technical Corrigendum 2 (ISO 6978-2:2003/Cor 2:2006)
• Effective Date: 13-Jul-2016

Standards Content (Sample)

SLOVENSKI STANDARD
01-julij-2005
=HPHOMVNLSOLQ±'RORþHYDQMHåLYHJDVUHEUD±GHO9]RUþHQMHåLYHJDVUHEUD]
DPDOJLUDQMHPQD]ODWLSODWLQDVWL]OLWLQL,62
Natural gas - Determination of mercury - Part 2: Sampling of mercury by amalgamation
on gold/platinum alloy (ISO 6978-2:2003)
Erdgas - Bestimmung von Quecksilber - Teil 2: Probenahme von Quecksilber durch
Amalgamierung an einer Gold/Platin-Legierung (ISO 6978-2:2003)
Gaz naturel - Détermination de la teneur en mercure - Partie 2: Echantillonnage du
mercure par amalgamation sur alliage or/platine (ISO 6978-2:2003)
Ta slovenski standard je istoveten z: EN ISO 6978-2:2005
ICS:
75.060 Zemeljski plin Natural gas
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EUROPEAN STANDARD
EN ISO 6978-2
NORME EUROPÉENNE
EUROPÄISCHE NORM
May 2005
ICS 75.060
English version
Natural gas - Determination of mercury - Part 2: Sampling of
mercury by amalgamation on gold/platinum alloy (ISO 6978-
2:2003)
Gaz naturel - Détermination de la teneur en mercure - Erdgas - Bestimmung von Quecksilber - Teil 2:
Partie 2: Echantillonnage du mercure par amalgamation sur Probenahme von Quecksilber durch Amalgamierung an
alliage or/platine (ISO 6978-2:2003) einer Gold/Platin-Legierung (ISO 6978-2:2003)
This European Standard was approved by CEN on 17 April 2005.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the Central Secretariat or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the official
versions.
CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,
Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia,
Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: rue de Stassart, 36  B-1050 Brussels
© 2005 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 6978-2:2005: E
worldwide for CEN national Members.

Foreword
The text of ISO 6978-2:2003 has been prepared by Technical Committee ISO/TC 193 "Natural
gas” of the International Organization for Standardization (ISO) and has been taken over as EN
ISO 6978-2:2005 by CMC.
This European Standard shall be given the status of a national standard, either by publication of
an identical text or by endorsement, at the latest by November 2005, and conflicting national
standards shall be withdrawn at the latest by November 2005.

According to the CEN/CENELEC Internal Regulations, the national standards organizations of
the following countries are bound to implement this European Standard: Austria, Belgium,
Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary,
Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.

Endorsement notice
The text of ISO 6978-2:2003 has been approved by CEN as EN ISO 6978-2:2005 without any
modifications.
INTERNATIONAL ISO
STANDARD 6978-2
First edition
2003-10-15
Natural gas — Determination of
mercury —
Part 2:
Sampling of mercury by amalgamation on
gold/platinum alloy
Gaz naturel — Détermination de la teneur en mercure —
Partie 2: Échantillonnage du mercure par amalgamation sur alliage
or/platine
Reference number
ISO 6978-2:2003(E)
©
ISO 2003
ISO 6978-2:2003(E)
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ii © ISO 2003 — All rights reserved

ISO 6978-2:2003(E)
Contents Page
Foreword. iv
Introduction . v
1 Scope. 1
2 Normative references . 1
3 Terms and definitions. 1
4 Principle . 1
5 Apparatus. 2
6 Reagents and materials. 8
7 Preparation of sampling and analytical tubes . 9
7.1 Filling. 9
7.2 Cleaning . 9
7.3 Efficiency testing . 9
8 Sampling . 9
8.1 General. 9
8.2 Conditions for representative sampling. 10
8.3 Sampling procedure at atmospheric pressure (see Figure 1). 10
8.4 Sampling procedure at high pressure (see Figure 4). 11
8.5 Removal of condensate from discarded sampling tubes. 12
9 Mercury determination . 12
9.1 Transfer of mercury to the analytical tube (double amalgamation) . 12
9.2 Transfer of mercury to AAS or AFS instrument. 13
9.3 Calibration. 13
9.4 Blank test . 13
10 Calculation. 13
11 Precision . 16
12 Test report. 16
Bibliography . 17

ISO 6978-2:2003(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies
(ISO member bodies). The work of preparing International Standards is normally carried out through ISO
technical committees. Each member body interested in a subject for which a technical committee has been
established has the right to be represented on that committee. International organizations, governmental and
non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the
International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.
The main task of technical committees is to prepare International Standards. Draft International Standards
adopted by the technical committees are circulated to the member bodies for voting. Publication as an
International Standard requires approval by at least 75 % of the member bodies casting a vote.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights.
ISO 6978-2 was prepared by Technical Committee ISO/TC 193, Natural gas, Subcommittee SC 1, Analysis of
natural gas.
This first edition of ISO 6978-2, together with ISO 6978-1, cancels and replaces ISO 6978:1992, which has
been technically revised.
ISO 6978 consists of the following parts, under the general title Natural gas — Determination of mercury:
 Part 1: Sampling of mercury by chemisorption on iodine
 Part 2: Sampling of mercury by amalgamation on gold/platinum alloy
iv © ISO 2003 — All rights reserved

ISO 6978-2:2003(E)
Introduction
Natural gases may contain considerable amounts of mercury, which are generally present in the elemental
form. Gases with high mercury content have to be purified to avoid the condensation of mercury during
processing and transport as well as to be compliant with the demands of gas sales contracts. Low mercury
concentrations are specified when natural gas is to be liquefied. This is to avoid severe corrosion problems,
for instance in aluminium heat exchangers of liquefaction plants.
Since the presence of hydrocarbons, in particular aromatic hydrocarbons present in low concentrations in
almost every natural gas, interferes in the determination of mercury by atomic absorption spectrometry (AAS)
or atomic fluorescence spectrometry (AFS), mercury cannot be determined directly in natural gas. Therefore,
prior to the analytical determination, mercury has to be collected and separated from aromatic hydrocarbons.
The purpose of the determination of the mercury content can be
 to monitor gas quality,
 to monitor the operation of gas treatment plants for mercury removal.
Several methods for the collection or enrichment of mercury from natural gas have been developed. The
collection of mercury from dry natural gas normally poses no particular problem. However, care should be
taken when sampling mercury from natural gases under nearly condensing conditions (see ISO 6570).
The two parts of ISO 6978 describe the principles of sampling and specify the general requirements for
methods for sampling mercury and for determining total mercury in pipeline quality natural gas. This part of
ISO 6978 specifies a method of sampling mercury by amalgamation on gold/platinum alloy thread whereas
Part 1 specifies a method of sampling mercury by chemisorption on iodine-impregnated silica gel.

INTERNATIONAL STANDARD ISO 6978-2:2003(E)

Natural gas — Determination of mercury —
Part 2:
Sampling of mercury by amalgamation on gold/platinum alloy
WARNING — The use of this part of ISO 6978 may involve hazardous materials, operations and
equipment. This part of ISO 6978 does not purport to address all of the safety problems, associated
with its use. It is the responsibility of the user of this part of ISO 6978 to establish appropriate safety
and health practices and to determine the applicability or regulatory limitations prior to use.
1 Scope
This part of ISO 6978 specifies a method for the determination of total mercury content of pipeline
...