Imaging materials — Wet-processed silver-gelatin type black-and-white photographic reflection prints — Specifications for dark storage

ISO 18929:2012 establishes the specifications for silver-gelatin photographic reflection prints intended for dark storage. It covers silver-gelatin print types of all weights. ISO 18929:2012 applies to wet-processed black-and-white silver-gelatin photographic prints, including those that have been chemically treated (with a gold, selenium, sulfur, or other chemical treatment bath) to improve the permanence of the silver image. It also applies to silver-gelatin prints processed by a monobath, which includes thiosulfate as a fixing agent followed by a conventional wash.

Matériaux pour l'image — Tirages photographiques par réflexion par traitement humide gélatinoargentique de type noir et blanc — Spécifications pour le stockage dans l'obscurité

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Published
Publication Date
29-Mar-2012
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9093 - International Standard confirmed
Completion Date
01-Dec-2022
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INTERNATIONAL ISO
STANDARD 18929
Second edition
2012-04-01
Imaging materials — Wet-processed
silver-gelatin type black-and-white
photographic reflection prints —
Specifications for dark storage
Matériaux pour l’image — Tirages photographiques par réflexion
par traitement humide gélatinoargentique de type noir et blanc —
Spécifications pour le stockage dans l’obscurité
Reference number
ISO 18929:2012(E)
©
ISO 2012

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ISO 18929:2012(E)
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© ISO 2012
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Published in Switzerland
ii © ISO 2012 – All rights reserved

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ISO 18929:2012(E)
Contents Page
Foreword .iv
Introduction . v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Safety and operational precautions . 2
4.1 Hazard warnings . 2
4.2 Hazard information code system . 2
4.3 Safety precautions . 3
5 Requirements for physical stability of prints . 3
5.1 Wedge brittleness . 3
5.2 Tensile energy absorption (see Annex C) . 3
5.3 Resin cracking of RC papers (see Annex D) . 3
6 Requirements for processed image stability (see Annex E) . 3
6.1 Residual thiosulfate concentration . 3
6.2 Residual silver concentration . 4
6.3 Yellowing limit (see Annex G) . 4
7 LE designation . 4
8 Test methods . 4
8.1 Wedge brittleness . 4
8.2 Tensile energy absorption . 5
8.3 Yellowing . 6
8.4 Residual silver compound test using cyanogen iodide (CNI) extraction . 6
8.5 Residual silver compound test by use of sulfuric acid/nitric acid extraction . 7
8.6 Resin cracking . 8
Annex A (informative) Stabilization treatments to prevent silver oxidation . 11
Annex B (informative) Potential silver-image discolouration of RC prints under display conditions .12
Annex C (informative) Tensile energy absorption .13
Annex D (informative) Environmental resin-cracking .14
Annex E (informative) Effects of residual thiosulfate and silver in processed prints .15
Annex F (informative) Degradation of silver images due to extraneous oxidation .17
Annex G (informative) Discolouration of black-and-white photographic prints .18
Annex H (informative) Densitometric versus spectrophotometric measurement of yellowing .20
Bibliography .21
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ISO 18929:2012(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies
(ISO member bodies). The work of preparing International Standards is normally carried out through ISO
technical committees. Each member body interested in a subject for which a technical committee has been
established has the right to be represented on that committee. International organizations, governmental and
non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International
Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.
The main task of technical committees is to prepare International Standards. Draft International Standards
adopted by the technical committees are circulated to the member bodies for voting. Publication as an
International Standard requires approval by at least 75 % of the member bodies casting a vote.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights.
ISO 18929 was prepared by Technical Committee ISO/TC 42, Photography.
This second edition cancels and replaces the first edition (ISO 18929:2003), which has been technically revised.
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ISO 18929:2012(E)
Introduction
Black-and-white silver-gelatin fibre-base papers have been important imaging materials for well over 100 years.
Reflection prints, made with such papers, have become increasingly important pictorial and documentary
records that are housed in many libraries, archives, museums, universities and other public and private
institutions. Although the intrinsic stability of properly processed and stored silver-gelatin prints is very good,
there are internal and external factors that can cause degradation of such prints during storage and shorten
their useful life. This International Standard provides specifications for tests that evaluate the stability of black-
and-white silver-gelatin prints under prescribed storage conditions. It does not cover tests for the possible
harmful effects of extended exposure to light.
Black-and-white prints are laminates, whose main components are a paper base, a white opaque intermediate
layer, an image layer, and a protective layer. Paper has been used as a support for prints since about 1840. The
history of its evolution into a very stable, high alpha-cellulose type fibre-base in the 1920s and to a polyethylene
resin-coated (RC) paper base in the 1960s has been covered extensively in the literature (see References [11],
[12], [13], [14] and [15]).
The intermediate, white opaque layer can be of two types. For fibre paper, since the 1880s it has been a gelatin
layer containing white barium sulfate pigment (baryta layer) and other additives that enhance the paper’s
reflectivity, hardness, holdout, adhesion and surface characteristics (glossy, matte, textured). The second
type came into use in the 1960s with the introduction of an RC base. This has a paper core coated on both
sides with water-impermeable extruded polyethylene layers. The top layer contains white titanium dioxide
pigment that provides higher reflectivity than barium sulfate; the bottom layer is transparent and formulated to
counteract the curl induced by the emulsion, which is coated on top of the pigmented layer.
Prints on fibre paper have the advantage of having demonstrated long-term stability from years of practical
experience in both dark storage and in reasonable display conditions. Proper processing and cleanliness or
lack of contamination are important. Diluted toning solutions have been used successfully to enhance stability
(see Annex A).
Prints on an RC paper base offer the advantages of higher wet strength, reduction in washing and drying times,
lower consumption of processing chemicals, better dimensional stability, lower curl, and freedom from cockle and
other effects of differential shrinkage. As with fibre-base materials, toning has been used successfully to enhance
stability. However, they can suffer from stability-related problems such as light-induced image discolouration,
silver mirroring, yellowing and cracking of the polyethylene layer (see References [16], [17], [18] and [19]).
This International Standard only applies to prints in dark storage since an applicable test for light-induced image
deterioration has not been agreed upon. One reason for this has been that different brands of RC papers, or
papers manufactured at different periods, have exhibited widely varying stability characteristics. It has been
very difficult to reconcile all of the observed differences in behaviour in a relatively simple standardized test
(see Annex B).
The image layer of most black-and-white prints is a gelatin coating containing a dispersion of light-sensitive
silver halide crystals that are selectively converted into metallic silver grains by an image-forming exposure and
chemical processing. Gelatin is a natural polymer that has been the preferred binder for photographic materials
since the 1880s because it has proven to be the best protective colloid for the precipitation, growth and
controlled suspension of silver crystals and for the formation of a dry, flexible image layer during a subsequent
coating operation. Gelatin also can be hardened to reduce its swelling and susceptibility to physical damage,
without blocking the absorption and desorption of aqueous processing solutions required for image formation
and removal or stabilization of chemical by-products (see References [20] and [21]).
Converting the metallic silver to a complex or pre-oxidized form of silver will improve image stability. Many toner
solutions have been designed to accomplish this, such as selenium, sepia, gold, brown and poly-toners. For
example, in the case of sepia toner treatment, the silver is converted from oxidizable metallic silver to a stable
silver sulfide.
The storage stability and useful life of reflection black-and-white prints depends on their physical and chemical
properties, as well as on the conditions under which they are stored. For many years, the term “archival
medium” was used to designate a recording material that can be expected to retain information forever so that
it can be retrieved without significant loss when properly stored. However, there is no such material and it is a
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ISO 18929:2012(E)
term no longer employed for material or systems specifications of International Standards. Another reason for
abandonment of the term is the multiplicity of meanings that it acquired over the years, ranging from “preserving
information forever” to “temporary storage of actively used information”. The unambiguous term used in this
International Standard is “life expectancy” (LE), defined as the length of time that information is predicted to be
retrievable in a system after storage. For example, a designation of LE-100 indicates that the information can
be retrieved without significant loss after at least 100 years. Reflection prints are classified according to their
LE designation in this International Standard.
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INTERNATIONAL STANDARD ISO 18929:2012(E)
Imaging materials — Wet-processed silver-gelatin type black-
and-white photographic reflection prints — Specifications for
dark storage
1 Scope
This International Standard establishes the specifications for silver-gelatin photographic reflection prints
intended for dark storage. It covers silver-gelatin print types of all weights.
This International Standard applies to wet-processed black-and-white silver-gelatin photographic prints,
including those that have been chemically treated (with a gold, selenium, sulfur, or other chemical treatment
bath) to improve the permanence of the silver image. It also applies to silver-gelatin prints processed by a
monobath, which includes thiosulfate as a fixing agent followed by a conventional wash.
This International Standard is not applicable to instant black-and-white photographic prints, stabilization-
processed black-and-white prints (those where the undeveloped silver halide has been chemically converted
and not removed), or thermally processed black-and-white prints. It does not apply to colour or dye-based
photographic prints, nor to prints that have been processed by a monobath using other than a thiosulfate-type
fixing solution, or prints where the silver salts are rendered more soluble by means other than thiosulfate.
Laminated and adhesive mounted reflection prints, prints on poly (ethylene terephthalate) support, and prints
that have been displayed are also excluded from this International Standard.
2 Normative references
The following referenced documents are indispensable for the application of this document. For dated
references, only the edition cited applies. For undated references, the latest edition of the referenced document
(including any amendments) applies.
ISO 5-3, Photography and graphic technology — Density measurements — Part 3: Spectral conditions
ISO 5-4, Photography and graphic technology — Density measurements — Part 4: Geometric conditions for
reflection density
ISO 18907, Imaging materials — Photographic films and papers — Wedge test for brittleness
ISO 18917, Photography — Determination of residual thiosulfate and other related chemicals in processed
photographic materials — Methods using iodine-amylose, methylene blue and silver sulfide
TAPPI T494 om, Tensile breaking properties of paper and paperboard (using constant rate of elongation apparatus)
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
3.1
archival medium
material that can be expected to preserve images forever, so that such images can be retrieved without
significant loss when properly stored
NOTE As no such material exists, this is a deprecated term and as such is not to be used in International Standards
for imaging materials or system specifications.
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ISO 18929:2012(E)
3.2
emulsion
image or image-forming layer(s) of silver halide photographic films, papers, and plates
3.3
life expectancy
LE
rating for the life expectancy of recording materials and associated retrieval systems
NOTE 1 The number following the LE symbol is a prediction of the minimum life expectancy in years for which
information can be retrieved without significant loss when stored in the conditions defined in the relevant standards. For
example, LE-100 indicates that the information can be retrieved after at least 100 years storage.
NOTE 2 The actual useful life of black-and-white paper is very dependent upon the existing storage conditions (see
ISO 18902 and ISO 18920).
3.4
reflection print support
white, opaque support for the image-forming and auxiliary layers of a photographic print, intended for viewing
by reflected light
3.5
treated silver image
silver image that has been given a specific treatment, either during or after processing, to modify colour or
increase stability
4 Safety and operational precautions
4.1 Hazard warnings
Some of the chemicals specified in the test procedures are caustic, toxic, or otherwise hazardous. Safe
laboratory practice for the handling of chemicals requires the use of safety glasses or goggles, and in some
cases other protective apparel, such as rubber gloves, face masks and aprons. Specific danger notices are
given in the text and footnotes for particularly dangerous materials, but normal precautions are required during
the performance of any chemical procedure at all times.
The first time that a hazardous material is noted in the procedures, the hazard will be indicated by the word
“DANGER” followed by a symbol consisting of angle brackets “〈 〉” containing a letter that designates the specific
hazard. A double bracket “〈〈 〉〉” will be used for particularly perilous situations. In subsequent statements involving
handling of these hazardous materials, only the hazard symbol consisting of the brackets and letter(s) will be
displayed. Furthermore, for a given material, the hazard symbols will be used only once in a single paragraph.
Hazard warning symbols will not be used for common organic solvents when used in quantities of less than
1 litre, unless they are particularly hazardous.
Detailed warnings for handling chemicals and their diluted solutions are beyond the scope of this
International Standard.
Employers shall provide training and health and safety information in conformance with legal requirements.
The hazard code system used in this International Standard is intended to provide information to the users and
is not meant for compliance with any legal requirements for labelling, as these vary from country to country.
It is strongly recommended that anyone using these chemicals obtains pertinent information from the
manufacturer about the hazards, handling, use and disposal of these chemicals.
4.2 Hazard information code system
〈B〉 Harmful if inhaled. Avoid breathing dust, vapour, mist or gas. Use only with adequate ventilation.
〈C〉 Harmful if contact occurs. Avoid contact with eyes, skin or clothing. Wash thoroughly after handling.
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ISO 18929:2012(E)
〈F〉 Will burn. Keep away from heat, sparks and open flame. Use with adequate ventilation.
〈O〉 Oxidizer. Contact with other material may cause fire. Do not store near combustible materials.
〈S〉 Harmful if swallowed. Wash thoroughly after handling. If swallowed, obtain medical attention immediately.
〈〈S〉〉 May be fatal if swallowed. If swallowed, obtain medical attention immediately.
4.3 Safety precautions
4.3.1 All pipette operations shall be performed with a pipette bulb or plunger pipette. Failure to observe this
warning notice can result in cyanide poisoning. This is a critical safety warning.
4.3.2 Digestion procedures shall be performed in an exhaust hood. Hydrogen cyanide or other toxic substances
can be evolved.
4.3.3 Safety glasses shall be worn for all laboratory work.
4.3.4 Cyanogen iodide (CNI) may be detoxified by treatment with sodium hypochlorite.
5 Requirements for physical stability of prints
5.1 Wedge brittleness
Unincubated RC paper shall not show a paper crack value greater than 12 mm when tested as described
in 8.1.4. Incubated RC paper shall not show an increase in the paper crack value greater than 14 mm when
incubated as described in 8.1.2 and tested as described in 8.1.4.
The test is not run on unincubated fibre paper. Incubated fibre paper shall not show a crack value greater than
14 mm when incubated as described in 8.1.2 and tested as described in 8.1.4.
5.2 Tensile energy absorption (see Annex C)
Fibre paper and RC paper shall not show a decrease in tensile energy absorption (TEA) greater than 50 %
when incubated as described in 8.2.2 and tested as described in 8.2.4.
5.3 Resin cracking of RC papers (see Annex D)
After 30 days, processed RC papers shall not show any evidence of resin cracking when tested as
described in 8.6.5.
6 Requirements for processed image stability (see Annex E)
6.1 Residual thiosulfate concentration
Prints shall be fixed in solutions containing either sodium thiosulfate (hypo) or ammonium thiosulfate. After
2
processing, fibre-base and RC-base black-and-white prints shall not contain more than 0,014 g/m of residual
2−
thiosulfate [calculated as thiosulfate ions (SO ) when measured by the iodine amylose method in ISO 18917].
23
2
NOTE 1 The concentration of thiosulfate is expressed in grams per square metre (g/m ), which conforms to SI units.
2 2
NOTE 2 0,010 g/m = 1 µg/cm .
NOTE 3 A very low concentration of thiosulfate due to excessive washing may cause the silver image to be more
susceptible to oxidative attack. These concentrations may be below the detection limit of ISO 18917.
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ISO 18929:2012(E)
Three methods for measuring residual thiosulfate levels are described in ISO 18917, i.e. the iodine amylose,
methylene blue, and silver sulfide densitometric test methods. All of them are considered sufficiently reliable
2
to determine thiosulfate concentrations at the 0,014 g/m level, but only the iodine amylose method has been
found to give reliable results with all types of fibre-base and RC prints. Therefore, it is the only method chosen
for this International Standard.
The iodine amylose method measures only the concentration of thiosulfate ions. It can be run up to two weeks
after processing, but the analysis shall be carried out with eluent obtained from a minimum density area of the
processed print. It is only in such areas that the thiosulfate concentration does not change appreciably over a
two-week period.
The methylene blue method shall not be used because it fails to detect residual thiosulfate in RC-base prints
whose unexposed emulsion layers contain a considerable amount of developing agent in order to provide very
rapid development during processing.
While the silver sulfide method does detect residual thiosulfate in RC-base prints, it also measures the
concentration of polythionate decomposition products and other residual chemicals. Moreover, it also has been
shown to give exaggeratedly high thiosulfate values with some RC prints (see Reference [22]).
Hypo-eliminating agents containing strongly oxidizing substances, such as peroxides or hypochlorites, shall
not be used because they contain peroxides that attack the silver image (see Annexes E and F). However,
the use of hypo-clearing solutions (such as a 2 % solution of sodium sulfite containing a wetting agent) does
facilitate the washing of thiosulfate ions from the fibre prints without chemically altering the thiosulfate. They
should not be used for RC prints.
6.2 Residual silver concentration
2
The processed print shall not contain more than 0,025 g/m of silver when tested in accordance with 8.4.3 or
8.5.3 using the atomic absorption technique.
6.3 Yellowing limit (see Annex G)
The status A blue density of minimum density areas shall not increase by more than 0,08 units on the front
(emulsion) surface or the back surface of the prints after incubation under conditions specified in 8.3.2 and
testing as described in 8.3.3.
7 LE designation
Prints that meet all the specifications set forth in this International Standard shall have an LE rating of 100.
8 Test methods
8.1 Wedge brittleness
8.1.1 Preparation of specimens
Paper samples shall be exposed and processed to yield maximum density. Specimens shall be cut in an
atmosphere of (23 ± 2) °C and (50 ± 5) % RH. The cutter shall be of a precision type and shall provide specimen
edges that are smooth and free of nicks. Specimens shall be 300 mm long by 15 mm to 16 mm wide.
A set of 10 specimens shall be prepared for the original measurements and another set of 10 specimens for
incubation as described in 8.1.2. The operator in handling the specimens, both in their preparation and testing,
shall wear moisture-impermeable dust- and powder-free gloves.
NOTE Latex gloves can cause hypersensitivity in some individuals.
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ISO 18929:2012(E)
8.1.2 Incubation
One set of 10 specimens shall be freely suspended for 30 days in a forced-air oven maintained at (80 ± 2) °C
and (50 ± 2) % RH. The short-term fluctuation in relative humidity shall not exceed ± 5 % RH.
8.1.3 Conditioning of specimens
Specimens shall be conditioned at (23 ± 1) °C and (20 ± 2) % RH before measurements. Fibre papers shall be
conditioned for at least 1 day and RC papers for at least 7 days prior to measurement. The specimens shall be
conditioned in racks that permit free circulation of air around the specimens.
8.1.4 Measurement
Specimens shall be tested at (23 ± 1) °C and (20 ± 2) % RH, as described in ISO 18907, using wedge apparatus
with a 74 mm opening.
8.1.5 Reporting
Specimens shall be evaluated for either paper cracks or paper breaks, depending on which occurs at the wider
wedge opening. Specimens which pass through the narrowest point of the wedge (1,5 mm) without failure shall
be arbitrarily assigned a value of 1,0 mm, to permit averaging with those specimens which show failure caused
by paper cracks or paper breaks.
The average of 10 specimens shall be calculated for both unincubated and incubated specimens. Samples
shall meet the criteria given in 5.1.
NOTE Paper cracks may be evident by white paper fibres showing through the emulsion layer processed to
maximum density.
8.2 Tensile energy absorption
8.2.1 Preparation of specimens
Paper specimens shall be prepared as described in 8.1.1. A set of 20 specimens shall be prepared for the
original measurements and another set of 20 specimens for incubation as described in 8.2.2.
8.2.2 Incubation
One set of 20 specimens shall be hung freely in a controlled forced-air oven maintained at (80 ± 2) °C and
(50 ± 2) % RH for 30 days. The set-point accuracy for the RH shall be as described in 8.1.2.
8.2.3 Conditioning
Specimens shall be conditioned as in 8.1.3.
8.2.4 Measurement
Specimens shall be tested at (23 ± 1) °C and (50 ± 2) % RH for tensile energy absorption (TEA) as described
in TAPPI T494 om.
8.2.5 Reporting
The average TEA of 20 specimens shall be calculated for both unincubated and incubated specimens. Samples
shall meet the specification given in 5.2.
Attention shall be given to the sections of TAPPI T494 om which pertain to the discarding of tensile measurements.
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ISO 18929:2012(E)
8.3 Yellowing
8.3.1 Preparation of specimens
Two minimum density specimens shall be prepared for each sample and conditioned as outlined in 8.1.3. The
2
area of each specimen shall be at least 90 cm . To prevent contamination by fingerprints, the operator shall
wear gloves during the preparation and testing of the specimens.
8.3.2 Incubation
Both specimens shall be freely suspended for 14 days in a forced-air oven maintained at (80 ± 2) °C and
(50 ± 2) % RH. The short-term fluctuation in the test chamber shall not exceed ± 5 % RH.
8.3.3 Measurement
The status A blue reflection density of both specimens, backed by a black material, shall be measured before
and after incubation (see Annex H). The spectral characteristics of the densitometer shall conform to ISO 5-3,
and its geometry to ISO 5-4. Four measurements shall be made of the front and of the back surfaces of the two
specimens, making a total of 16 measurements.
8.3.4 Reporting
The average of eight measurements shall be calculated for the front (emulsion) surface and the back surface,
before and after incubation. The sample shall meet the density criteria specified in 6.3.
8.4 Residual silver compound test using cyanogen iodide (CNI) extraction
8.4.1 General
NOTE 1 For additional information, refer to Referenc
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