SIST-TS CEN ISO/TS 16189:2014

Footwear - Critical substances potentially present in footwear and footwear components - Test method to quantitatively determine dimethylformamide in footwear materials (ISO/TS 16189:2013)

This Technical Specification specifies a method to determine the amounts of dimethylformamide (DMFo) in footwear and footwear components containing polyurethane (PU) coated material.

Schuhe - Möglicherweise in Schuhen und Schuhbestandteilen vorhandene kritische Substanzen - Prüfverfahren zur quantitativen Bestimmung von Dimethylformamid in Schuhwerkstoffen (ISO/TS 16189:2013)

Diese Technische Spezifikation legt ein Verfahren zur quantitativen Bestimmung von Dimethyl-formamid (DMFo) in Schuhen und Schuhbestandteilen fest, die mit Polyurethan (PU) beschichtetes Material enthalten.
ANMERKUNG   In der Schuhindustrie ist für diesen Prozess, bei dem PU eingespritzt wird (RIM-Verfahren), die Verwendung von DMFo nicht erforderlich. DMFo kann für das mit PU beschichtete Material verwendet werden.

Chaussures - Substances critiques potentiellement présentes dans la chaussure et les composants de chaussure - Méthodes d'essai pour déterminer quantitativement le diméthylformamide dans les matériaux de chaussure (ISO/TS 16189:2013)

L'ISO/TS 16189:2013 spécifie une méthode pour déterminer la quantité de diméthylformamide (DMF) dans les chaussures et les composants de chaussures contenant un matériau enduit de polyuréthane (PU).

Obutev - Kritične snovi, ki so lahko v obutvi in delih obutve - Preskusna metoda za kvantitativno ugotavljanje dimetilformamida v obutvenih materialih (ISO/TS 16189:2013)

Ta tehnična specifikacija določa metodo za ugotavljanje količine dimetilformamida (DMF) v obutvenih materialih, ki vsebujejo material, prevlečen s poliuretanom (PU).

General Information

• Status: Withdrawn
• Publication Date: 11-Dec-2013
• Withdrawal Date: 19-Dec-2021
• ICS: 61.060 - Footwear
• Technical Committee: I13 - Imaginarni 13
• Current Stage: 9900 - Withdrawal (Adopted Project)
• Start Date: 15-Dec-2021
• Due Date: 07-Jan-2022
• Completion Date: 20-Dec-2021
• Ref Project: CEN ISO/TS 16189:2013 - Footwear - Critical substances potentially present in footwear and footwear components - Test method to quantitatively determine dimethylformamide in footwear materials (ISO/TS 16189:2013)

Relations

• Replaced By: SIST EN ISO 16189:2022 - Footwear - Critical substances potentially present in footwear and footwear components - Test method to quantitatively determine dimethylformamide in footwear materials (ISO 16189:2021)
• Effective Date: 15-Dec-2021

Standards Content (Sample)

SLOVENSKI STANDARD
SIST-TS CEN ISO/TS 16189:2014
01-januar-2014
2EXWHY.ULWLþQHVQRYLNLVRODKNRYREXWYLLQGHOLKREXWYH3UHVNXVQDPHWRGD]D
NYDQWLWDWLYQRXJRWDYOMDQMHGLPHWLOIRUPDPLGDYREXWYHQLKPDWHULDOLK,6276

Footwear - Critical substances potentially present in footwear and footwear components -
Test method to quantitatively determine dimethylformamide in footwear materials
(ISO/TS 16189:2013)
Schuhe - Möglicherweise in Schuhen und Schuhbestandteilen vorhandene kritische
Substanzen - Prüfverfahren zur quantitativen Bestimmung von Dimethylformamid in
Schuhwerkstoffen (ISO/TS 16189:2013)
Chaussures - Substances critiques potentiellement présentes dans la chaussure et les
composants de chaussure - Méthodes d'essai pour déterminer quantitativement le
diméthylformamide dans les matériaux de chaussure (ISO/TS 16189:2013)
Ta slovenski standard je istoveten z: CEN ISO/TS 16189:2013
ICS:
61.060 Obuvala Footwear
SIST-TS CEN ISO/TS 16189:2014 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST-TS CEN ISO/TS 16189:2014

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SIST-TS CEN ISO/TS 16189:2014


TECHNICAL SPECIFICATION
CEN ISO/TS 16189

SPÉCIFICATION TECHNIQUE

TECHNISCHE SPEZIFIKATION
July 2013
ICS 61.060
English Version
Footwear - Critical substances potentially present in footwear
and footwear components - Test method to quantitatively
determine dimethylformamide in footwear materials (ISO/TS
16189:2013)
Chaussures - Substances critiques potentiellement Schuhe - Möglicherweise in Schuhen und
présentes dans la chaussure et les composants de Schuhbestandteilen vorhandene kritische Substanzen -
chaussure - Méthodes d'essai pour déterminer Prüfverfahren zur quantitativen Bestimmung von
quantitativement le diméthylformamide dans les matériaux Dimethylformamid in Schuhwerkstoffen (ISO/TS
de chaussure (ISO/TS 16189:2013) 16189:2013)
This Technical Specification (CEN/TS) was approved by CEN on 15 July 2013 for provisional application.

The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to submit their
comments, particularly on the question whether the CEN/TS can be converted into a European Standard.

CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS available
promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in parallel to the CEN/TS)
until the final decision about the possible conversion of the CEN/TS into an EN is reached.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2013 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN ISO/TS 16189:2013: E
worldwide for CEN national Members.

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SIST-TS CEN ISO/TS 16189:2014
CEN ISO/TS 16189:2013 (E)
Contents
Page
Foreword .3

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SIST-TS CEN ISO/TS 16189:2014
CEN ISO/TS 16189:2013 (E)
Foreword
This document (CEN ISO/TS 16189:2013) has been prepared by Technical Committee CEN/TC 309
“Footwear", the secretariat of which is held by AENOR, in collaboration with Technical Committee ISO/TC 216
"Footwear".
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria, Croatia, Cyprus,
Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany,
Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom.
Endorsement notice
The text of ISO/TS 16189:2013 has been approved by CEN as CEN ISO/TS 16189:2013 without any
modification.

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SIST-TS CEN ISO/TS 16189:2014
TECHNICAL ISO/TS
SPECIFICATION 16189
First edition
2013-07-15
Footwear — Critical substances
potentially present in footwear
and footwear components — Test
method to quantitatively determine
dimethylformamide in footwear
materials
Chaussures — Substances critiques potentiellement présentes dans
la chaussure et les composants de chaussure — Méthodes d’essai
pour déterminer quantitativement le diméthylformamide dans les
matériaux de chaussure
Reference number
ISO/TS 16189:2013(E)
©
ISO 2013

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SIST-TS CEN ISO/TS 16189:2014
ISO/TS 16189:2013(E)

COPYRIGHT PROTECTED DOCUMENT
© ISO 2013
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form
or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior
written permission. Permission can be requested from either ISO at the address below or ISO’s member body in the country of
the requester.
ISO copyright office
Case postale 56 • CH-1211 Geneva 20
Tel. + 41 22 749 01 11
Fax + 41 22 749 09 47
E-mail [e-mail]
Web www.iso.org
Published in Switzerland
ii © ISO 2013 – All rights reserved

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SIST-TS CEN ISO/TS 16189:2014
ISO/TS 16189:2013(E)

Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Method principle . 1
4 Reagents and solvents . 1
4.1 Reagents. 1
4.2 Stock solutions . 1
5 Equipment . 2
6 Preparation of sample . 2
6.1 Sampling . 2
6.2 Extraction . 2
7 Determination with GC-MS . 3
7.1 Calibration standard . 3
7.2 Examples of instrumental method . 3
8 Quantification . 3
8.1 Calibration curve . 3
9 Performance of the method . 4
10 Test report . 4
Annex A (informative) Suggested parameters for GC-MS determination of DMFo .5
Bibliography . 6
© ISO 2013 – All rights reserved iii

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