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Footwear - Critical substances potentially present in footwear and footwear components - Lists of critical chemical substances (ISO/TR 16178:2021)

This document defines lists of critical chemical substances potentially present in footwear and footwear
components.
This document describes the critical chemical substances, their potential risks of nocuousness, in which
materials they could be found, and which test method(s) can be used to quantify them.
The test methods listed indicate the state of the art. For some substances, a test method is not available.
This document is applicable to any kind of footwear and footwear components.

Schuhe - Möglicherweise in Schuhen und Schuhbestandteilen vorhandene kritische Substanzen (ISO/TR 16178:2021)

Dieses Dokument legt Listen kritischer chemischer Substanzen fest, die möglicherweise in Schuhen oder Schuhbestandteilen enthalten sind.
Dieses Dokument beschreibt die kritischen chemischen Substanzen, deren potentielles Risiko schädlich zu sein, in welchen Materialien sie enthalten sein könnten, und welche Prüfverfahren zur quantitativen Bestimmung dieser Substanzen angewendet werden können.
Die aufgeführten Prüfverfahren entsprechen dem aktuellen Stand der Technik. Für einige Substanzen gibt es kein Prüfverfahren.
Dieses Dokument ist anwendbar für jede Art von Schuhen und Schuhmaterialien.

Chaussures - Substances critiques potentiellement présentes dans la chaussure et les composants de chaussures - Listes des substances chimiques critiques (ISO/TR 16178:2021)

Le présent document définit des listes de substances chimiques critiques potentiellement présentes dans les chaussures et les composants de chaussures.
Le présent document décrit les substances chimiques critiques, leurs risques potentiels de nocivité, les matériaux dans lesquels on peut les trouver, ainsi que la ou les méthodes d'essai permettant de les quantifier.
Les méthodes d'essai énumérées reflètent l'état de la technique. Pour certaines substances, il n'existe pas de méthode d'essai.
Le présent document s'applique à tout type de chaussure et de composant de chaussure.

Obuvala - Nevarne snovi, ki so lahko prisotne v obuvalih in njihovih sestavnih delih - Seznam kritičnih kemičnih snovi (ISO/TR 16178:2021)

General Information

Status

Published

Public Enquiry End Date

31-Aug-2021

Publication Date

14-Oct-2021

ICS

61.060 - Footwear

Technical Committee

I13 - Imaginarni 13

Current Stage

6060 - National Implementation/Publication (Adopted Project)

Start Date

13-Oct-2021

Due Date

18-Dec-2021

Completion Date

15-Oct-2021

Ref Project

CEN ISO/TR 16178:2021 - Footwear - Critical substances potentially present in footwear and footwear components - Lists of critical chemical substances (ISO/TR 16178:2021)

Relations

Replaces

SIST-TP CEN ISO/TR 16178:2012 - Footwear - Critical substances potentially present in footwear and footwear components (ISO/TR 16178:2012)

Effective Date

13-Oct-2021

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Technical report

TP CEN ISO/TR 16178:2021

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Standards Content (Sample)

SLOVENSKI STANDARD
SIST-TP CEN ISO/TR 16178:2021
01-december-2021
Nadomešča:
SIST-TP CEN ISO/TR 16178:2012
Obuvala - Nevarne snovi, ki so lahko prisotne v obuvalih in njihovih sestavnih
delih - Seznam kritičnih kemičnih snovi (ISO/TR 16178:2021)
Footwear - Critical substances potentially present in footwear and footwear components
- Lists of critical chemical substances (ISO/TR 16178:2021)
Schuhe - Möglicherweise in Schuhen und Schuhbestandteilen vorhandene kritische
Substanzen (ISO/TR 16178:2021)
Chaussures - Substances critiques potentiellement présentes dans la chaussure et les
composants de chaussures - Listes des substances chimiques critiques (ISO/TR
16178:2021)
Ta slovenski standard je istoveten z: CEN ISO/TR 16178:2021
ICS:
61.060 Obuvala Footwear
SIST-TP CEN ISO/TR 16178:2021 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST-TP CEN ISO/TR 16178:2021

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SIST-TP CEN ISO/TR 16178:2021

CEN ISO/TR 16178
TECHNICAL REPORT

RAPPORT TECHNIQUE

October 2021
TECHNISCHER BERICHT
ICS 61.060 Supersedes CEN ISO/TR 16178:2012
English Version

Footwear - Critical substances potentially present in
footwear and footwear components - Lists of critical
chemical substances (ISO/TR 16178:2021)
Chaussures - Substances critiques potentiellement Schuhe - Möglicherweise in Schuhen und
présentes dans la chaussure et les composants de Schuhbestandteilen vorhandene kritische Substanzen
chaussures - Listes des substances chimiques critiques (ISO/TR 16178:2021)
(ISO/TR 16178:2021)

This Technical Report was approved by CEN on 26 July 2021. It has been drawn up by the Technical Committee CEN/TC 309.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.

EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2021 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN ISO/TR 16178:2021 E
worldwide for CEN national Members.

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SIST-TP CEN ISO/TR 16178:2021
CEN ISO/TR 16178:2021 (E)
Contents Page
European foreword . 3

2

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SIST-TP CEN ISO/TR 16178:2021
CEN ISO/TR 16178:2021 (E)
European foreword
This document (CEN ISO/TR 16178:2021) has been prepared by Technical Committee ISO/TC 216
"Footwear" in collaboration with Technical Committee CEN/TC 309 “Footwear” the secretariat of which
is held by UNE.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes CEN ISO/TR 16178:2012.
Any feedback and questions on this document should be directed to the users’ national standards
body/national committee. A complete listing of these bodies can be found on the CEN website.
Endorsement notice
The text of ISO/TR 16178:2021 has been approved by CEN as CEN ISO/TR 16178:2021 without any
modification.

3

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SIST-TP CEN ISO/TR 16178:2021

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SIST-TP CEN ISO/TR 16178:2021
TECHNICAL ISO/TR
REPORT 16178
Third edition
2021-09
Footwear — Critical substances
potentially present in footwear and
footwear components — Lists of
critical chemical substances
Chaussures — Substances critiques potentiellement présentes dans la
chaussure et les composants de chaussures — Listes des substances
chimiques critiques
Reference number
ISO/TR 16178:2021(E)
©
ISO 2021

---------------------- Page: 7 ----------------------
SIST-TP CEN ISO/TR 16178:2021
ISO/TR 16178:2021(E)

COPYRIGHT PROTECTED DOCUMENT
© ISO 2021
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii © ISO 2021 – All rights reserved

---------------------- Page: 8 ----------------------
SIST-TP CEN ISO/TR 16178:2021
ISO/TR 16178:2021(E)

Contents Page
Foreword .vi
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Presence of chemicals in footwear materials . 2
5 Critical substances potentially present in footwear and footwear components .8
5.1 Acrylonitrile . 8
5.1.1 General. 8
5.1.2 Potential risks . 8
5.1.3 Test methods . 8
5.2 Alkylphenols and Alkylphenol ethoxylates (NP, OP, NPEO, OPEO) . 8
5.2.1 General. 8
5.2.2 Potential risks . 9
5.2.3 Test methods . 9
5.3 Aromatic amines .10
5.3.1 General.10
5.3.2 Potential risks .11
5.3.3 Test methods .11
5.4 Benzene .11
5.4.1 General.11
5.4.2 Potential risks .11
5.4.3 Test methods .11
5.5 Biocides .12
5.5.1 Orthophenylphenol .12
5.5.2 2-(thiocyanatomethylthio)-1,3-benzothiazole (TCMTB) .12
5.5.3 2-octylisothiazol-3(2H)-one (OIT) .13
5.5.4 4-Chloro-3-methylphenol (CMK) .13
5.5.5 Triclosan.14
5.6 Bisphenol .15
5.6.1 General.15
5.6.2 Potential risks .15
5.6.3 Test methods .15
5.7 Cadmium – Cd .15
5.8 Chlorinated paraffins .15
5.8.1 General.15
5.8.2 Potential risks .16
5.8.3 Test methods .16
5.9 Chlorobenzenes and chlorotoluenes .16
5.9.1 General.16
5.9.2 Potential risks .17
5.9.3 Test methods .17
5.10 Chromium and Chromium VI .17
5.11 Colophony .18
5.11.1 General.18
5.11.2 Potential risks .18
5.11.3 Test methods .18
5.12 Dimethylformamide .18
5.12.1 General.18
5.12.2 Potential risks .19
5.12.3 Test methods .19
5.13 Dimethylfumarate (DMFu) .19
5.13.1 General.19
5.13.2 Potential risks .19
© ISO 2021 – All rights reserved iii

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SIST-TP CEN ISO/TR 16178:2021
ISO/TR 16178:2021(E)

5.13.3 Test methods .20
5.14 Disperses dyes .20
5.14.1 General.20
5.14.2 Potential risks .21
5.14.3 Test methods .21
5.15 Flame retardants .21
5.15.1 General.21
5.15.2 Potential risks .22
5.15.3 Test methods .22
5.16 Formaldehyde .22
5.16.1 General.22
5.16.2 Potential risks .22
5.16.3 Test methods .23
5.17 Heavy metals .23
5.17.1 General.23
5.17.2 List of heavy metals .23
5.17.3 Potential risks .23
5.17.4 Test methods .25
5.17.5 Special cases .25
5.18 Mercaptobenzothiazole .26
5.18.1 General.26
5.18.2 Potential risks .27
5.18.3 Test methods .27
5.19 N-ethylphenylamine .27
5.19.1 General.27
5.19.2 Potential risks .27
5.19.3 Test methods .27
5.20 N methyl-2-pyrrolidone (NMP) .27
5.20.1 General.27
5.20.2 Potential risks .28
5.20.3 Test methods .28
5.21 N,N-dimethylacetamide .28
5.21.1 General.28
5.21.2 Potential risks .28
5.21.3 Test methods .28
5.22 Nickel – Ni .28
5.23 Nitrosamines.28
5.23.1 General.28
5.23.2 Potential risks .29
5.23.3 Test methods .29
5.24 Organotins compounds .29
5.24.1 General.29
5.24.2 Potential risks .30
5.24.3 Test methods .30
5.25 PAHs (Polycyclic aromatic hydrocarbons) .31
5.25.1 General.31
5.25.2 Potential risks .31
5.25.3 Test methods .32
5.26 Paraphenylene diamine .32
5.26.1 General.32
5.26.2 Potential risks .32
5.26.3 Test methods .32
5.27 Pesticides .32
5.27.1 General.32
5.27.2 Potential risks .32
5.27.3 Test methods .33
5.28 Perfluorinated and polyfluorinated chemicals-PFC .33
5.28.1 Different substances .33
iv © ISO 2021 – All rights reserved

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SIST-TP CEN ISO/TR 16178:2021
ISO/TR 16178:2021(E)

5.28.2 Potential risks .36
5.29 pH .36
5.29.1 General.36
5.29.2 Potential risks .37
5.29.3 Test methods .37
5.30 Phenol .37
5.30.1 General.37
5.30.2 Potential risks .37
5.30.3 Test methods .37
5.31 Phenyl mercury .37
5.31.1 General.37
5.31.2 Potential risks .38
5.31.3 Test methods .38
5.32 Phthalates .38
5.32.1 General.38
5.32.2 Potential risks .40
5.32.3 Test methods .40
5.33 Polychlorophenols .
...

SLOVENSKI STANDARD
kSIST-TP FprCEN ISO/TR 16178:2021
01-september-2021
Obuvala - Nevarne snovi, ki so lahko prisotne v obuvalih in njihovih sestavnih
delih - Seznam kritičnih kemičnih snovi (ISO/PRF TR 16178:2021)
Footwear - Critical substances potentially present in footwear and footwear components
- Lists of critical chemical substances (ISO/PRF TR 16178:2021)
Schuhe - Möglicherweise in Schuhen und Schuhbestandteilen vorhandene kritische
Substanzen (ISO/PRF TR 16178:2021)
Chaussures - Substances critiques potentiellement présentes dans la chaussure et les
composants de chaussures - Listes des substances chimiques critiques (ISO/PRF TR
16178:2021)
Ta slovenski standard je istoveten z: prCEN ISO/TR 16178
ICS:
61.060 Obuvala Footwear
kSIST-TP FprCEN ISO/TR 16178:2021 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
kSIST-TP FprCEN ISO/TR 16178:2021

---------------------- Page: 2 ----------------------
kSIST-TP FprCEN ISO/TR 16178:2021
TECHNICAL ISO/TR
REPORT 16178
Third edition
Footwear — Critical substances
potentially present in footwear and
footwear components — Lists of
critical chemical substances
Chaussures — Substances critiques potentiellement présentes dans la
chaussure et les composants de chaussures — Listes des substances
chimiques critiques
PROOF/ÉPREUVE
Reference number
ISO/TR 16178:2021(E)
©
ISO 2021

---------------------- Page: 3 ----------------------
kSIST-TP FprCEN ISO/TR 16178:2021
ISO/TR 16178:2021(E)

COPYRIGHT PROTECTED DOCUMENT
© ISO 2021
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii PROOF/ÉPREUVE © ISO 2021 – All rights reserved

---------------------- Page: 4 ----------------------
kSIST-TP FprCEN ISO/TR 16178:2021
ISO/TR 16178:2021(E)

Contents Page
Foreword .vi
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Presence of chemicals in footwear materials . 2
5 Critical substances potentially present in footwear and footwear components .8
5.1 Acrylonitrile . 8
5.1.1 General. 8
5.1.2 Potential risks . 8
5.1.3 Test methods . 8
5.2 Alkylphenols and Alkylphenol ethoxylates (NP, OP, NPEO, OPEO) . 8
5.2.1 General. 8
5.2.2 Potential risks . 9
5.2.3 Test methods . 9
5.3 Aromatic amines .10
5.3.1 General.10
5.3.2 Potential risks .11
5.3.3 Test methods .11
5.4 Benzene .11
5.4.1 General.11
5.4.2 Potential risks .11
5.4.3 Test methods .11
5.5 Biocides .12
5.5.1 Orthophenylphenol .12
5.5.2 2-(thiocyanatomethylthio)-1,3-benzothiazole (TCMTB) .12
5.5.3 2-octylisothiazol-3(2H)-one (OIT) .13
5.5.4 4-Chloro-3-methylphenol (CMK) .13
5.5.5 Triclosan.14
5.6 Bisphenol .15
5.6.1 General.15
5.6.2 Potential risks .15
5.6.3 Test methods .15
5.7 Cadmium – Cd .15
5.8 Chlorinated paraffins .15
5.8.1 General.15
5.8.2 Potential risks .16
5.8.3 Test methods .16
5.9 Chlorobenzenes and chlorotoluenes .16
5.9.1 General.16
5.9.2 Potential risks .17
5.9.3 Test methods .17
5.10 Chromium and Chromium VI .17
5.11 Colophony .18
5.11.1 General.18
5.11.2 Potential risks .18
5.11.3 Test methods .18
5.12 Dimethylformamide .18
5.12.1 General.18
5.12.2 Potential risks .19
5.12.3 Test methods .19
5.13 Dimethylfumarate (DMFU) .19
5.13.1 General.19
5.13.2 Potential risks .19
© ISO 2021 – All rights reserved PROOF/ÉPREUVE iii

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kSIST-TP FprCEN ISO/TR 16178:2021
ISO/TR 16178:2021(E)

5.13.3 Test methods .20
5.14 Disperses dyes .20
5.14.1 General.20
5.14.2 Potential risks .21
5.14.3 Test methods .21
5.15 Flame retardants .21
5.15.1 General.21
5.15.2 Potential risks .22
5.15.3 Test methods .22
5.16 Formaldehyde .22
5.16.1 General.22
5.16.2 Potential risks .22
5.16.3 Test methods .23
5.17 Heavy metals .23
5.17.1 General.23
5.17.2 List of heavy metals .23
5.17.3 Potential risks .23
5.17.4 Test methods .25
5.17.5 Special cases .25
5.18 Mercaptobenzothiazole .26
5.18.1 General.26
5.18.2 Potential risks .26
5.18.3 Test methods .27
5.19 N-ethylphenylamine .27
5.19.1 General.27
5.19.2 Potential risks .27
5.19.3 Test methods .27
5.20 N methyl-2-pyrrolidone (NMP) .27
5.20.1 General.27
5.20.2 Potential risks .27
5.20.3 Test methods .28
5.21 N,N-dimethylacetamide .28
5.21.1 General.28
5.21.2 Potential risks .28
5.21.3 Test methods .28
5.22 Nickel – Ni .28
5.23 Nitrosamines.28
5.23.1 General.28
5.23.2 Potential risks .29
5.23.3 Test methods .29
5.24 Organotins compounds .29
5.24.1 General.29
5.24.2 Potential risks .30
5.24.3 Test methods .30
5.25 PAHs (Polycyclic aromatic hydrocarbons) .30
5.25.1 General.30
5.25.2 Potential risks .31
5.25.3 Test methods .31
5.26 Paraphenylene diamine .31
5.26.1 General.31
5.26.2 Potential risks .32
5.26.3 Test methods .32
5.27 Pesticides .32
5.27.1 General.32
5.27.2 Potential risks .32
5.27.3 Test methods .33
5.28 Perfluorinated and polyfluorinated chemicals-PFC .33
5.28.1 Different substances .33
iv PROOF/ÉPREUVE © ISO 2021 – All rights reserved

---------------------- Page: 6 ----------------------
kSIST-TP FprCEN ISO/TR 16178:2021
ISO/TR 16178:2021(E)

5.28.2 Potential risks .36
5.29 pH .36
5.29.1 General.36
5.29.2 Potential risks .36
5.29.3 Test methods .36
5.30 Phenol .36
5.30.1 General.36
5.30.2 Potential risks .37
5.30.3 Test methods .37
5.31 Phenyl mercury .37
5.31.1 General.37
5.31.2 Potential risks .37
5.31.3 Test methods .38
5.32 Phthalates .38
5.32.1 General.38
5.32.2 Potential risks .39
5.32.3 Test methods .39
5.33 Polychlorophenols .40
5.33.1 General.40
5.33.2 Potential risks .41
5.33.3 Test methods .41
5.34 Paratertiary butyl phenol formaldehyde (PTBF) .41
5.34.1 General.41
5.34.2 Potential risks .41
5.34.3 Test methods .42
5.35 Quinoline .42
5.35.1 General.42
5.35.2 Potential risks .42
5.35.3 Test methods .42
5.36 Thiuram and thiocarbamate.42
5.36.1 General.42
5.36.2 Potential risks .43
5.36.3 Test m
...

SIST-TP CEN ISO/TR 16178:2021

Footwear - Critical substances potentially present in footwear and footwear components - Lists of critical chemical substances (ISO/TR 16178:2021)

Footwear - Critical substances potentially present in footwear and footwear components - Lists of critical chemical substances (ISO/TR 16178:2021)

Schuhe - Möglicherweise in Schuhen und Schuhbestandteilen vorhandene kritische Substanzen (ISO/TR 16178:2021)

Chaussures - Substances critiques potentiellement présentes dans la chaussure et les composants de chaussures - Listes des substances chimiques critiques (ISO/TR 16178:2021)