Standard Test Method for Spectral Responsivity Measurements of Photovoltaic Devices

SIGNIFICANCE AND USE
The spectral responsivity of a photovoltaic device is necessary for computing spectral mismatch parameter (see Test Method E973). Spectral mismatch is used in Test Method E948 to measure the performance of photovoltaic cells in simulated sunlight, in Test Methods E1036 to measure the performance of photovoltaic modules and arrays, in Test Method E1125 to calibrate photovoltaic primary reference cells using a tabular spectrum, and in Test Method E1362 to calibrate photovoltaic secondary reference cells. The spectral mismatch parameter can be computed using absolute or relative spectral responsivity data.
This test method measures the differential spectral responsivity of a photovoltaic device. The procedure requires the use of white-light bias to enable the user to evaluate the dependence of the differential spectral responsivity on the intensity of light reaching the device. When such dependence exists, the overall spectral responsivity should be equivalent to the differential spectral responsivity at a light bias level somewhere between zero and the intended operating conditions of the device.
The spectral responsivity of a photovoltaic device is useful for understanding device performance and material characteristics.
The procedure described herein is appropriate for use in either research and development applications or in product quality control by manufacturers.
The reference photodetector’s calibration must be traceable to SI units through a National Institute of Standards and Technology (NIST) spectral responsivity scale or other relevant radiometric scale. , The calibration mode of the photodetector (irradiance or power) will affect the procedures used and the kinds of measurements that can be performed.
This test method does not address issues of sample stability.
Using results obtained by this test method and additional measurements including reflectance versus wavelength, one can compute the internal quantum efficiency of a device. These measu...
SCOPE
1.1 This test method is to be used to determine either the absolute or relative spectral responsivity response of a single-junction photovoltaic device.  
1.2 Because quantum efficiency is directly related to spectral responsivity, this test method may be used to determine the quantum efficiency of a single-junction photovoltaic device (see 10.10).
1.3 This test method requires the use of a bias light.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: E1021 − 12
StandardTest Method for
Spectral Responsivity Measurements of Photovoltaic
1
Devices
This standard is issued under the fixed designation E1021; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope E1036Test Methods for Electrical Performance of Noncon-
centrator Terrestrial Photovoltaic Modules and Arrays
1.1 This test method is to be used to determine either the
Using Reference Cells
absolute or relative spectral responsivity response of a single-
E1125 Test Method for Calibration of Primary Non-
junction photovoltaic device.
ConcentratorTerrestrial Photovoltaic Reference Cells Us-
1.2 Because quantum efficiency is directly related to spec-
ing a Tabular Spectrum
tralresponsivity,thistestmethodmaybeusedtodeterminethe
E1362Test Method for Calibration of Non-Concentrator
quantum efficiency of a single-junction photovoltaic device
Photovoltaic Secondary Reference Cells
(see 10.10).
E2236Test Methods for Measurement of Electrical Perfor-
mance and Spectral Response of Nonconcentrator Multi-
1.3 This test method requires the use of a bias light.
junction Photovoltaic Cells and Modules
1.4 The values stated in SI units are to be regarded as
G173TablesforReferenceSolarSpectralIrradiances:Direct
standard. No other units of measurement are included in this
Normal and Hemispherical on 37° Tilted Surface
standard.
1.5 This standard does not purport to address all of the
3. Terminology
safety concerns, if any, associated with its use. It is the
3.1 Definitions—Definitions of terms used in this test
responsibility of the user of this standard to establish appro-
method may be found in Terminology E772.
priate safety and health practices and determine the applica-
3.2 Definitions of Terms Specific to This Standard:
bility of regulatory limitations prior to use.
3.2.1 chopper, n—a rotating blade or other device used to
modulate a light source.
2. Referenced Documents
2
3.2.2 device under test (DUT), n—aphotovoltaicdevicethat
2.1 ASTM Standards:
is subjected to a spectral responsivity measurement.
E691Practice for Conducting an Interlaboratory Study to
Determine the Precision of a Test Method
3.2.3 irradiance mode calibration, n—a calibration method
E772Terminology of Solar Energy Conversion
in which the reference photodetector measures the irradiance
E927Specification for Solar Simulation for Photovoltaic
produced by the monochromatic beam.
Testing
3.2.4 monitor photodetector, n—a photodetector incorpo-
E948Test Method for Electrical Performance of Photovol-
rated into the optical system to monitor the amount of light
taic Cells Using Reference Cells Under Simulated Sun-
reaching the device under test, enabling adjustments to be
light
made to accommodate varying light intensity.
E973Test Method for Determination of the Spectral Mis-
3.2.5 monochromatic beam, n—choppedlightfromamono-
match Parameter Between a Photovoltaic Device and a
Photovoltaic Reference Cell chromatic source reaching the reference photodetector or
device under test.
3.2.6 monochromator, n—an optical device that allows a
1
This test method is under the jurisdiction of ASTM Committee E44 on Solar,
selected wavelength of light to pass while blocking other
GeothermalandOtherAlternativeEnergySourcesandisthedirectresponsibilityof
wavelengths.
Subcommittee E44.09 on Photovoltaic Electric Power Conversion.
Current edition approved March 1, 2012. Published April 2012. Originally
3.2.7 power mode calibration, n—a calibration method in
approved in 1993. Last previous edition approved in 2006 as E1021–06. DOI:
which the reference photodetector measures the power in the
10.1520/E1021-12.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or monochromatic beam.
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
3.2.8 reference photodetector, n—a photodetector used to
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. quantify the amount of light in monochromatic beam.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
E1021 − 12
3.2.9 spectral bandwidth, n—the range of wavelengths in a R —relative spectral responsivity for power mode,
pr
monochromatic light source, determined as the difference dimensionless,
–1 2 –1
between its half-maximum-intensity wavelengths. SR—spectral responsivity, A·W or A·m ·W .
3.3.2 Symbolic quantities that are functions of wavelength
3.3 Symbols:
appear as X(λ).
3.3.1 The following symbols and uni
...

This document is not anASTM standard and is intended only to provide the user of anASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:E1021–06 Designation:E1021–12
Standard Test Method for
Spectral Responsivity Measurements of Photovoltaic
1
Devices
This standard is issued under the fixed designation E1021; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1This test method is to be used to determine either the absolute or relative spectral responsivity response of a single-junction
photovoltaic device. This test method requires the use of a bias light.
1.2
1.1 Thistestmethodistobeusedtodetermineeithertheabsoluteorrelativespectralresponsivityresponseofasingle-junction
photovoltaic device.
1.2 Because quantum efficiency is directly related to spectral responsivity, this test method may be used to determine the
quantum efficiency of a single-junction photovoltaic device (see 10.10).
1.3 This test method requires the use of a bias light.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
2. Referenced Documents
2
2.1 ASTM Standards:
E691 Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
E772 Terminology of Solar Energy Conversion
E927 Specification for Solar Simulation for Photovoltaic Testing
E948 Test Method for Electrical Performance of Photovoltaic Cells Using Reference Cells Under Simulated Sunlight
E973 Test Method for Determination of the Spectral Mismatch Parameter Between a Photovoltaic Device and a Photovoltaic
Reference Cell
E1036 Test Methods for Electrical Performance of Nonconcentrator Terrestrial Photovoltaic Modules and Arrays Using
Reference Cells
E1125 Test Method for Calibration of Primary Non-Concentrator Terrestrial Photovoltaic Reference Cells Using a Tabular
Spectrum E1328Terminology Relating to Photovoltaic Solar Energy Conversion
E1362 Test Method for Calibration of Non-Concentrator Photovoltaic Secondary Reference Cells
E2236 Test Methods for Measurement of Electrical Performance and Spectral Response of Nonconcentrator Multijunction
Photovoltaic Cells and Modules
G173 Tables for Reference Solar Spectral Irradiances: Direct Normal and Hemispherical on 37 Tilted Surface
3. Terminology
3.1 Definitions—Definitions of terms used in this test method may be found in Terminology E772and in Terminology E1328.
3.2 Definitions of Terms Specific to This Standard:
3.2.1 chopper, n—a rotating blade or other device used to modulate a light source.
3.2.2 device under test (DUT), n—a photovoltaic device that is subjected to a spectral responsivity measurement.
1
This test method is under the jurisdiction of ASTM Committee E44 on Solar, Geothermal and Other Alternative Energy Sources and is the direct responsibility of
Subcommittee E44.09 on Photovoltaic Electric Power Conversion.
Current edition approved Nov. 1, 2006. Published January 2007. Originally approved in 1993. Last previous edition approved in 2001 as E1021–95 (2001). DOI:
10.1520/E1021-06.
Current edition approved March 1, 2012. Published April 2012. Originally approved in 1993. Last previous edition approved in 2006 as E1021–06. DOI:
10.1520/E1021-12.
2
ForreferencedASTMstandards,visittheASTMwebsite,www.astm.org,orcontactASTMCustomerServiceatservice@astm.org.For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
E1021–12
3.2.3 irradiance mode calibration, n—a calibration method in which the reference photodetector measures the irradiance
produced by the monochromatic beam.
3.2.4 monitor photodetector, n—a photodetector incorporated into the optical system to monitor the amount of light reaching
the device under test, enabling adjustments to be made to accommodate varying light intensity.
3.2.5 monochromatic beam, n—chopped light from a monochromatic source reaching the reference photodetector or device
under test.
3.2.6 monochromator, n—anop
...

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