Standard Test Method for Spectral Responsivity Measurements of Photovoltaic Devices

SIGNIFICANCE AND USE
5.1 The spectral responsivity of a photovoltaic device is necessary for computing spectral mismatch parameter (see Test Method E973). Spectral mismatch is used in Test Method E948 to measure the performance of photovoltaic cells in simulated sunlight, in Test Methods E1036 to measure the performance of photovoltaic modules and arrays, in Test Method E1125 to calibrate photovoltaic primary reference cells using a tabular spectrum, and in Test Method E1362 to calibrate photovoltaic secondary reference cells. The spectral mismatch parameter can be computed using absolute or relative spectral responsivity data.  
5.2 This test method measures the differential spectral responsivity of a photovoltaic device. The procedure requires the use of white-light bias to enable the user to evaluate the dependence of the differential spectral responsivity on the intensity of light reaching the device. When such dependence exists, the overall spectral responsivity should be equivalent to the differential spectral responsivity at a light bias level somewhere between zero and the intended operating conditions of the device. Depending on the linearity response of the DUT over the intensity range up to the intended operating conditions, it may not be necessary to set up a very high light bias level.  
5.3 The spectral responsivity of a photovoltaic device is useful for understanding device performance and material characteristics.  
5.4 The procedure described herein is appropriate for use in either research and development applications or in product quality control by manufacturers.  
5.5 The reference photodetector’s calibration must be traceable to SI units through a National Institute of Standards and Technology (NIST) spectral responsivity scale or other relevant radiometric scale.3 ,4 The calibration mode of the photodetector (irradiance or power) will affect the procedures used and the kinds of measurements that can be performed.  
5.6 This test method does not address issues...
SCOPE
1.1 This test method is to be used to determine either the absolute or relative spectral responsivity response of a single-junction photovoltaic device.  
1.2 Because quantum efficiency is directly related to spectral responsivity, this test method may be used to determine the quantum efficiency of a single-junction photovoltaic device (see 10.10).  
1.3 This test method requires the use of a bias light.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: E1021 − 15 An American National Standard
Standard Test Method for
Spectral Responsivity Measurements of Photovoltaic
1
Devices
This standard is issued under the fixed designation E1021; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope E948Test Method for Electrical Performance of Photovol-
taic Cells Using Reference Cells Under Simulated Sun-
1.1 This test method is to be used to determine either the
light
absolute or relative spectral responsivity response of a single-
E973Test Method for Determination of the Spectral Mis-
junction photovoltaic device.
match Parameter Between a Photovoltaic Device and a
1.2 Because quantum efficiency is directly related to spec-
Photovoltaic Reference Cell
tralresponsivity,thistestmethodmaybeusedtodeterminethe
E1036Test Methods for Electrical Performance of Noncon-
quantum efficiency of a single-junction photovoltaic device
centrator Terrestrial Photovoltaic Modules and Arrays
(see 10.10).
Using Reference Cells
E1125 Test Method for Calibration of Primary Non-
1.3 This test method requires the use of a bias light.
ConcentratorTerrestrial Photovoltaic Reference Cells Us-
1.4 The values stated in SI units are to be regarded as
ing a Tabular Spectrum
standard. No other units of measurement are included in this
E1362Test Methods for Calibration of Non-Concentrator
standard.
Photovoltaic Non-Primary Reference Cells
1.5 This standard does not purport to address all of the
E2236Test Methods for Measurement of Electrical Perfor-
safety concerns, if any, associated with its use. It is the
mance and Spectral Response of Nonconcentrator Multi-
responsibility of the user of this standard to establish appro-
junction Photovoltaic Cells and Modules
priate safety, health, and environmental practices and deter-
G173TablesforReferenceSolarSpectralIrradiances:Direct
mine the applicability of regulatory limitations prior to use.
Normal and Hemispherical on 37° Tilted Surface
1.6 This international standard was developed in accor-
dance with internationally recognized principles on standard-
3. Terminology
ization established in the Decision on Principles for the
3.1 Definitions—Definitions of terms used in this test
Development of International Standards, Guides and Recom-
method may be found in Terminology E772.
mendations issued by the World Trade Organization Technical
3.2 Definitions of Terms Specific to This Standard:
Barriers to Trade (TBT) Committee.
3.2.1 chopper, n—a rotating blade or other device used to
modulate a light source.
2. Referenced Documents
2
3.2.2 device under test (DUT), n—aphotovoltaicdevicethat
2.1 ASTM Standards:
is subjected to a spectral responsivity measurement.
E691Practice for Conducting an Interlaboratory Study to
Determine the Precision of a Test Method
3.2.3 irradiance mode calibration, n—a calibration method
E772Terminology of Solar Energy Conversion
in which the reference photodetector measures the irradiance
E927Specification for Solar Simulation for Photovoltaic
produced by the monochromatic beam.
Testing
3.2.4 monitor photodetector, n—a photodetector incorpo-
rated into the optical system to monitor the amount of light
reaching the device under test, enabling adjustments to be
1
This test method is under the jurisdiction of ASTM Committee E44 on Solar,
made to accommodate varying light intensity.
GeothermalandOtherAlternativeEnergySourcesandisthedirectresponsibilityof
Subcommittee E44.09 on Photovoltaic Electric Power Conversion.
3.2.5 monochromatic beam, n—choppedlightfromamono-
Current edition approved Feb. 1, 2015. Published April 2015. Originally
chromatic source reaching the reference photodetector or
approved in 1993. Last previous edition approved in 2012 as E1021–12. DOI:
device under test.
10.1520/E1021-15.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
3.2.6 monochromator, n—an optical device that allows a
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
selected wavelength of light to pass while blocking other
Standardsvolume information, refer to the standard’s Document Summary page on
the ASTM website. wavelengths.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
E1021 − 15
3.2.7 power mode calibration, n—a calibration method in φ—power of the monochromatic beam or irradiance of the
–2
which the reference photodetector measures the power in the monochromatic beam, W or W·m ,
–19
monochromatic beam. q—elementary charge, 1.602176565×10 C,
Q—ex
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: E1021 − 12 E1021 − 15
Standard Test Method for
Spectral Responsivity Measurements of Photovoltaic
1
Devices
This standard is issued under the fixed designation E1021; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This test method is to be used to determine either the absolute or relative spectral responsivity response of a single-junction
photovoltaic device.
1.2 Because quantum efficiency is directly related to spectral responsivity, this test method may be used to determine the
quantum efficiency of a single-junction photovoltaic device (see 10.10).
1.3 This test method requires the use of a bias light.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
2. Referenced Documents
2
2.1 ASTM Standards:
E691 Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
E772 Terminology of Solar Energy Conversion
E927 Specification for Solar Simulation for Photovoltaic Testing
E948 Test Method for Electrical Performance of Photovoltaic Cells Using Reference Cells Under Simulated Sunlight
E973 Test Method for Determination of the Spectral Mismatch Parameter Between a Photovoltaic Device and a Photovoltaic
Reference Cell
E1036 Test Methods for Electrical Performance of Nonconcentrator Terrestrial Photovoltaic Modules and Arrays Using
Reference Cells
E1125 Test Method for Calibration of Primary Non-Concentrator Terrestrial Photovoltaic Reference Cells Using a Tabular
Spectrum
E1362 Test Method for Calibration of Non-Concentrator Photovoltaic Secondary Reference Cells
E2236 Test Methods for Measurement of Electrical Performance and Spectral Response of Nonconcentrator Multijunction
Photovoltaic Cells and Modules
G173 Tables for Reference Solar Spectral Irradiances: Direct Normal and Hemispherical on 37° Tilted Surface
3. Terminology
3.1 Definitions—Definitions of terms used in this test method may be found in Terminology E772.
3.2 Definitions of Terms Specific to This Standard:
3.2.1 chopper, n—a rotating blade or other device used to modulate a light source.
3.2.2 device under test (DUT), n—a photovoltaic device that is subjected to a spectral responsivity measurement.
3.2.3 irradiance mode calibration, n—a calibration method in which the reference photodetector measures the irradiance
produced by the monochromatic beam.
1
This test method is under the jurisdiction of ASTM Committee E44 on Solar, Geothermal and Other Alternative Energy Sources and is the direct responsibility of
Subcommittee E44.09 on Photovoltaic Electric Power Conversion.
Current edition approved March 1, 2012Feb. 1, 2015. Published April 2012April 2015. Originally approved in 1993. Last previous edition approved in 20062012 as
E1021 – 06.E1021 – 12. DOI: 10.1520/E1021-12.10.1520/E1021-15.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
E1021 − 15
3.2.4 monitor photodetector, n—a photodetector incorporated into the optical system to monitor the amount of light reaching
the device under test, enabling adjustments to be made to accommodate varying light intensity.
3.2.5 monochromatic beam, n—chopped light from a monochromatic source reaching the reference photodetector or device
under test.
3.2.6 monochromator, n—an optical device that allows a selected wavelength of light to pass while blocking other wavelengths.
3.2.7 power mode calibration, n—a calibration method in which the reference photodetector measures the power in the
monochromatic beam.
3.2.8 reference photodetector, n—a photodetector calibrated photodetector with a known spectral responsivity over a
wavelength range and used to
...

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