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ASTM D5373-13

(Test Method)

Standard Test Methods for Determination of Carbon, Hydrogen and Nitrogen in Analysis Samples of Coal and Carbon in Analysis Samples of Coal and Coke

Standard Test Methods for Determination of Carbon, Hydrogen and Nitrogen in Analysis Samples of Coal and Carbon in Analysis Samples of Coal and Coke

SIGNIFICANCE AND USE
4.1 Carbon and hydrogen values can be used to determine the amount of oxygen (air) required in combustion processes and for calculation of the efficiency of combustion processes.  
4.2 Carbon and hydrogen determinations can be used in calculations including material balance, reactivity and yields of products relevant to coal conversion processes such as gasification and liquefaction.  
4.3 Carbon and nitrogen values can be used in material balance calculations employed for emission accounting purposes.Note 2—The bulk composition of coal changes at a rate that varies from coal to coal during storage. As a result using coal for calibration can yield incorrect estimates of carbon, and hydrogen content in particular.
SCOPE
1.1 Test Method A covers the determination of carbon in the range of 54.9 % to 84.7 %, hydrogen in the range of 3.25 % to 5.10 %, and nitrogen in the range of 0.57 % to 1.80 % in the analysis samples (7.1) of coal.  
1.1.1 Test Method B covers the determination of carbon in analysis samples of coal in the range of 58.0 % to 84.2 %, and carbon in analysis samples of coke in the range of 86.3 % to 95.2 %.Note 1—The coals included in the interlaboratory study employed to derive the precision statement for this standard cover ASTM rank lignite A to low volatile bituminous. Additional information concerning the composition of these coals appears in Annex A5. The cokes used in the interlaboratory study employed to derive the precision statement for coke included an equal number of met cokes and pet cokes.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
14-Oct-2013
ICS
75.160.10 - Solid fuels
Technical Committee
D05 - Coal and Coke
Drafting Committee
D05.21 - Methods of Analysis
Current Stage
Ref Project

Relations

Replaces
ASTM D5373-08 - Standard Test Methods for Instrumental Determination of Carbon, Hydrogen, and Nitrogen in Laboratory Samples of Coal
Effective Date
15-Oct-2013
Replaced By
ASTM D5373-14 - Standard Test Methods for Determination of Carbon, Hydrogen and Nitrogen in Analysis Samples of Coal and Carbon in Analysis Samples of Coal and Coke
Effective Date
01-Mar-2014
Referred By
ASTM D6316-17 - Standard Test Method for Determination of Total, Combustible and Carbonate Carbon in Solid Residues from Coal and Coke
Effective Date
15-Oct-2013
Referred By
ASTM E2779-10(2017) - Standard Test Method for Determining Particulate Matter Emissions from Pellet Heaters
Effective Date
15-Oct-2013
Referred By
ASTM D3176-15 - Standard Practice for Ultimate Analysis of Coal and Coke
Effective Date
15-Oct-2013

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REDLINE ASTM D5373-13 - Standard Test Methods for Determination of Carbon, Hydrogen and Nitrogen in Analysis Samples of Coal and Carbon in Analysis Samples of Coal and CokeREDLINE ASTM D5373-13 - Standard Test Methods for Determination of Carbon, Hydrogen and Nitrogen in Analysis Samples of Coal and Carbon in Analysis Samples of Coal and Coke
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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D5373 − 13
StandardTest Methods for
Determination of Carbon, Hydrogen and Nitrogen in
Analysis Samples of Coal and Carbon in Analysis Samples
1
of Coal and Coke
This standard is issued under the fixed designation D5373; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope D3180 Practice for Calculating Coal and Coke Analyses
from As-Determined to Different Bases
1.1 Test MethodAcovers the determination of carbon in the
D5865 Test Method for Gross Calorific Value of Coal and
range of 54.9 % to 84.7 %, hydrogen in the range of 3.25 % to
Coke
5.10 %, and nitrogen in the range of 0.57 % to 1.80 % in the
D7582 Test Methods for Proximate Analysis of Coal and
analysis samples (7.1) of coal.
Coke by Macro Thermogravimetric Analysis
1.1.1 Test Method B covers the determination of carbon in
2.2 ISO Standard:
analysis samples of coal in the range of 58.0 % to 84.2 %, and
ISO 5725-6 Accuracy (Trueness and Precision) of Measure-
carbon in analysis samples of coke in the range of 86.3 % to
ment Methods and Results Part 6: Use in Practice of
95.2 %.
3
Accuracy Values
NOTE 1—The coals included in the interlaboratory study employed to
derive the precision statement for this standard cover ASTM rank lignite
A to low volatile bituminous. Additional information concerning the 3. Summary of Test Methods
composition of these coals appears in Annex A5. The cokes used in the
3.1 In MethodA, carbon, hydrogen and nitrogen in coal are
interlaboratory study employed to derive the precision statement for coke
determined concurrently in a single instrumental procedure
included an equal number of met cokes and pet cokes.
using a furnace operating at temperatures in the range of 900
1.2 The values stated in SI units are to be regarded as
°C to 1050°C. The quantitative conversion of the carbon,
standard. No other units of measurement are included in this
hydrogen and nitrogen into their corresponding gases (CO ,
2
standard.
H O, and NO ) occurs during combustion of the sample at an
2 x
1.3 This standard does not purport to address all of the
elevated temperature in an atmosphere of oxygen. Combustion
safety concerns, if any, associated with its use. It is the
products which can interfere with the subsequent gas analysis
responsibility of the user of this standard to establish appro-
are removed. Oxides of nitrogen (NO ) are reduced to N
x 2
priate safety and health practices and determine the applica-
before detection.The carbon dioxide, water vapor and elemen-
bility of regulatory limitations prior to use.
tal nitrogen in the gas stream are determined by appropriate
instrumental detection procedures.
2. Referenced Documents
3.2 In Method B, carbon in coal and coke is determined by
2
2.1 ASTM Standards:
combusting the sample in a 1350°C furnace. The HOinthe
2
D346/D346M Practice for Collection and Preparation of
combustion gases is removed and CO is determined by
2
Coke Samples for Laboratory Analysis
infrared absorption.
D2013 Practice for Preparing Coal Samples for Analysis
D3173 Test Method for Moisture in the Analysis Sample of
4. Significance and Use
Coal and Coke
4.1 Carbon and hydrogen values can be used to determine
D3176 Practice for Ultimate Analysis of Coal and Coke
the amount of oxygen (air) required in combustion processes
and for calculation of the efficiency of combustion processes.
1
ThesetestmethodsareunderthejurisdictionofASTMCommitteeD05onCoal
4.2 Carbon and hydrogen determinations can be used in
and Coke and are the direct responsibility of Subcommittee D05.21 on Methods of
Analysis.
calculationsincludingmaterialbalance,reactivityandyieldsof
Current edition approved Oct. 15, 2013. Published November 2013. Originally
products relevant to coal conversion processes such as gasifi-
approved in 1993. Last previous edition approved in 2008 as D5373 – 08. DOI:
cation and liquefaction.
10.1520/D5373-13.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
3
Standards volume information, refer to the standard’s Document Summary page on Available fromAmerican National Standards Institute (ANSI), 25 W. 43rd St.,
the ASTM website. 4th Floor, New York, NY 10036, http://www.ansi.org.
Copyright ©ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA19428-2959. United States
1

---------------------- Page: 1 ----------------------
D5373 − 13
4.3 Carbon and nitrogen values can be used in material sufficiently high purity to permit its use without lessening the
balance calculations employed for
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D5373 − 08 D5373 − 13
Standard Test Methods for
Instrumental Determination of Carbon, Hydrogen,Hydrogen
and Nitrogen in LaboratoryAnalysis Samples of Coal and
1
Carbon in Analysis Samples of Coal and Coke
This standard is issued under the fixed designation D5373; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This test methodTest Method A covers the instrumental the determination of carbon in the range of 54.9 % m/m to 84.7 %
m/m, 84.7 %, hydrogen in the range of 3.25 % m/m to 5.10 % m/m, 5.10 %, and nitrogen in the range of 0.57 % m/m to 1.80 %
m/m in the analysis samplesamples (7.1) of coal.
1.1.1 Test Method B covers the determination of carbon in analysis samples of coal in the range of 58.0 % to 84.2 %, and carbon
in analysis samples of coke in the range of 86.3 % to 95.2 %.
NOTE 1—The coals included in the interlaboratory study employed to derive the precision statement for this standard cover ASTM rank lignite A to
low volatile bituminous. Additional information concerning the composition of these coals appears in Annex A5. The cokes used in the interlaboratory
study employed to derive the precision statement for coke included an equal number of met cokes and pet cokes.
1.2 The values stated in SI units shall are to be regarded as the standard. No other units of measurement are included in this
standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
2. Referenced Documents
2
2.1 ASTM Standards:
D346/D346M Practice for Collection and Preparation of Coke Samples for Laboratory Analysis
D2013 Practice for Preparing Coal Samples for Analysis
D3173 Test Method for Moisture in the Analysis Sample of Coal and Coke
D3176 Practice for Ultimate Analysis of Coal and Coke
D3180 Practice for Calculating Coal and Coke Analyses from As-Determined to Different Bases
D5142D5865 Test Methods for Proximate Analysis of the Analysis Sample of Method for Gross Calorific Value of Coal and
Coke by Instrumental Procedures (Withdrawn 2010)
D5865D7582 Test Method for Gross Calorific Value Methods for Proximate Analysis of Coal and Coke by Macro
Thermogravimetric Analysis
2.2 ISO Standard:
ISO 5725-6 Accuracy (Trueness and Precision) of Measurement Methods and Results Part 6: Use in Practice of Accuracy
3
Values
3. Summary of Test Methods
3.1 Carbon, In Method A, carbon, hydrogen and nitrogen in coal are determined concurrently in a single instrumental procedure.
procedure using a furnace operating at temperatures in the range of 900 °C to 1050°C. The quantitative conversion of the carbon,
hydrogen and nitrogen into their corresponding gases (CO , H O, and NO ) occurs during combustion of the sample at an elevated
2 2 x
temperature in an atmosphere of oxygen. Combustion products which can interfere with the subsequent gas analysis are removed.
1
These test methods are under the jurisdiction of ASTM Committee D05 on Coal and Coke and are the direct responsibility of Subcommittee D05.21 on Methods of
Analysis.
Current edition approved Feb. 1, 2008Oct. 15, 2013. Published February 2008 November 2013. Originally approved in 1993. Last previous edition approved in 20072008
as D5373 – 02 (2007).D5373 – 08. DOI: 10.1520/D5373-08.10.1520/D5373-13.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
3
Available from American National Standards Institute (ANSI), 25 W. 43rd St., 4th Floor, New York, NY 10036, http://www.ansi.org.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D5373 − 13
Oxides of nitrogen (NO ) are reduced to N before detection. The carbon dioxide, water vapourvapor and elemental nitrogen in
x 2
the gas stream are determined by appropriate instrumental detection procedures.
3.2 In Method B, carbon in coal and coke is determined by combusting the sample in a 1350°
...

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ASTM
ASTM D6349-21(Test Method)
Standard Test Method for Determination of Major and Minor Elements in Coal, Coke, and Solid Residues from Combustion of Coal and Coke by Inductively Coupled Plasma—Atomic Emission Spectrometry

SIGNIFICANCE AND USE
5.1 A compositional analysis of coal and coke and their associated combustion residues are often useful in assessing their quality. Knowledge of the elemental composition of the associated residues is also useful in predicting the elemental enrichment/depletion compositional behavior of ashes and slags in comparison to the mass fraction in the parent coal. Utilization of the ash by-products and hazardous potential may also depend on the chemical composition and leachability of the inorganic constituents of the coal ash.  
5.2 The chemical composition of laboratory-prepared ash may not exactly represent the composition of mineral matter in coal or the composition of fly ash and slag resulting from commerical-scale burning of the coal.
SCOPE
1.1 This test method covers a procedure for the analysis of the commonly determined major and minor elements in coal, coke, and solid residues from combustion of coal and coke. These residues may be laboratory ash, bottom ash, fly ash, flue gas desulfurization sludge, and other combustion process residues.
Note 1: There are two interlaboratory studies associated with this test method. The first was conducted in 1997 ( RR:D05-1035)2 and the second was conducted in 2007 ( RR:D05-1032).3 Sulfur trioxide was only included in the 2007 study, and that study only included combustion residues derived from ash and no combustion residues derived from coke.  
1.2 Units—The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM D167/D167M-21a(Test Method)
Standard Test Method for Apparent and True Specific Gravity and Porosity of Lump Coke

SIGNIFICANCE AND USE
4.1 Apparent and true specific gravity, as determined by this test method, are influenced by the type of coals carbonized and the operating and preparational conditions of that carbonization, that is, charge bulk density, heating rate, and pulverization level. In turn, these properties directly influence the performance in processes using coke.
SCOPE
1.1 This test method covers the determination of apparent specific gravity (Sections 5 to 9) and true specific gravity (Sections 10 to 14) of lump coke larger than 25 mm [1 in.] size and calculating porosity (Section 15) from the specific gravity data.  
1.2 Units—The values stated in either SI units or non-SI units are to be regarded separately as standard. The values stated in each system are not necessarily exact equivalents; therefore, to ensure conformance with the standard, each system shall be used independently of the other, and values from the two systems shall not be combined.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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