Standard Classification for E-CTFE-Fluoroplastic Molding, Extrusion, and Coating Materials

SCOPE
1.1 This classification covers melt processible molding, extrusion, and coating materials of ethylene-chlorotrifluoroethylene (E-CTFE) fluoroplastics. The resin is a copolymer of ethylene and chlorotrifluoroethylene containing approximately 80 weight % of chlorotrifluoroethylene.
1.2 The values stated in SI units, as detailed in IEEE/ASTM SI 10, are to be regarded as the standard.
1.3 The following precautionary statement pertains only to the test methods portion, Section 11 of this specification.This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
Note 1--Although this specification and ISO 12086-1 (1995) and ISO 12086-2 (1995) differ in approach or detail, data obtained using either are technically equivalent.

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09-Dec-2000
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D 3275 – 00
Standard Classification for
E-CTFE-Fluoroplastic Molding, Extrusion, and Coating
1
Materials
This standard is issued under the fixed designation D 3275; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope * D 1708 Test Method for Tensile Properties of Plastics By
3
Use of Microtensile Specimens
1.1 This classification covers melt processible molding,
D 2863 Test Method for Measuring the Minimum Oxygen
extrusion, and coating materials of ethylene-
Concentration to Support Candle-Like Combustion of
chlorotrifluoroethylene (E-CTFE) fluoroplastics. The resin is a
4
Plastics (Oxygen Index)
copolymer of ethylene and chlorotrifluoroethylene containing
4
D 3892 Practice for Packaging/Packing of Plastics
approximately 80 weight % of chlorotrifluoroethylene.
D 4000 Classification System for Specifying Plastic Mate-
1.2 The values stated in SI units, as detailed in IEEE/ASTM
4
rials
SI 10, are to be regarded as the standard.
D 4591 Test Method for Determining Temperatures and
1.3 The following precautionary statement pertains only to
Heats of Transitions of Fluoropolymer by Differential
the test methods portion, Section 11 of this specification. This
5
Scanning Calorimetry
standard does not purport to address all of the safety concerns,
IEEE/ASTM SI 10 Standard for the Use of the Interna-
if any, associated with its use. It is the responsibility of the user
6
tional System of Units (SI): The Modern Metric System
of this standard to establish appropriate safety and health
practices and determine the applicability of regulatory limita-
3. Terminology
tions prior to use.
3.1 Definitions: Definitions of terms used in this specifica-
NOTE 1—Although this specification and ISO 12086-1 (1995) and ISO
tion shall be in accordance with Terminology D 883.
12086-2 (1995) differ in approach or detail, data obtained using either are
3.1.1 lot, n—one production run or a uniform blend of two
technically equivalent.
or more production runs.
3.2 Abbreviations:Abbreviations are in accordance with
2. Referenced Documents
Terminology D 1600.
2.1 ASTM Standards:
D 150 Test Methods for A-C Loss Characteristics and
4. Classification
Permittivity (Dielectric Constant) of Solid Electrical Insu-
4.1 ECTFE materials are classified into groups according to
2
lating Materials
their physical appearance. The groups are further divided into
3
D 618 Practice for Conditioning Plastics for Testing
classes based on melt flow rate. These classes are subdivided
3
D 638 Test Method for Tensile Properties of Plastics
into grades as shown in the Table E-CTFE.
D 792 Test Methods for Specific Gravity (Relative Density)
An example of a material of this classification system is
3
and Density of Plastics by Displacement
given as follows: ECTFE 01 1 1
3
D 883 Terminology Relating to Plastics
D 1238 Test Method for Melt Flow Rates ofThermoplastics
where:
3
by Extrusion Plastometer
01 = ECTFE powder
D 1600 Terminology for Abbreviated Terms Relating to
1 = low melt flow
3
Plastics
2 = properties in accordance with Table E-CTFE (Grade
1)
1
This specification is under the jurisdiction of ASTM Committee D20 on
Plastics and is the direct responsibility of Subcommittee D20.15 on Thermoplastic
Materials (Section 20.15.12).
Current edition approved Dec. 10, 2000. Published March 2001. Originally
4
published as D 3275 – 73. Last previous edition D 3275 – 97. Annual Book of ASTM Standards, Vol 08.02.
2 5
Annual Book of ASTM Standards, Vol 10.01. Annual Book of ASTM Standards, Vol 08.03.
3 6
Annual Book of ASTM Standards, Vol 08.01. Annual Book of ASTM Standards, Vol 14.02.
*A Summary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

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D 3275
TABLE E–CTFE
D,E
Group Class Description Grade Melt Flow Specific Tensile Elongation, Melting Oxygen Dielectric Dissipation
A B C,D F G H I
Rate, Gravity, Strength, min, % Point, °C, Index, Constant, Factor,
6 6
g/10 min 23/23°C min, MPa min min, % max, 10 Hz max, 10 Hz
01 powder 1 Low melt flow 1 0.05–1.50 1.65–1.71 40 200 240 60 2.6 0.015
rate
2 Medium melt 1 1.51–6.0 1.65–1.71 40 200 240 60 2.6 0.015
flow rate
3 High melt 1 6.1–25 1.65–1.71 40 200 240 60 2.6 0.015
flow rate
0 Other 0
02 pellet 1 Low melt flow 1 0.05–1.50 1.65–1.71 40 200 240 60 2.6 0.015
rate
2 Medium melt 1 1.51–6.0 1.65–1.71 40 200 240 60 2.6 0.015
flow rate
3 High melt 1 6.1–25 1.65–1.71 40 200
...

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