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ASTM

ASTM D5394-97

(Specification)

Standard Specification for Reclaimed 1,1,1-Trichloroethane

Standard Specification for Reclaimed 1,1,1-Trichloroethane

SCOPE
1.1 This specification defines Type I (high quality reclaimed 1,1,1-trichloroethane, approximating MIL Specification), Type II (good quality reclaimed solvent), Type III (minimal acceptable reclaimed solvent).
1.2 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For a specific hazards statement see Section 4.
1.3 1,1,1-trichloroethane is also commercially known as methyl chloroform.

General Information

Status
Historical
Publication Date
09-May-1997
ICS
71.080.20 - Halogenated hydrocarbons
Technical Committee
D26 - Halogenated Organic Solvents and Fire Extinguishing Agents
Drafting Committee
D26.02 - Vapor Degreasing
Current Stage
Ref Project

Relations

Replaced By
ASTM D5394-02 - Standard Specification for Reclaimed 1,1,1-Trichloroethane
Effective Date
10-Dec-2002

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ASTM D5394-97 - Standard Specification for Reclaimed 1,1,1-TrichloroethaneASTM D5394-97 - Standard Specification for Reclaimed 1,1,1-Trichloroethane
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ASTM D5394-97 - Standard Specification for Reclaimed 1,1,1-Trichloroethane
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NOTICE: This standard has either been superseded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
Designation: D 5394 – 97
Standard Specification for
Reclaimed 1,1,1-Trichloroethane
This standard is issued under the fixed designation D 5394; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
TABLE 1 Properties, Type I
1. Scope
Property Specification Test Method
1.1 This specification defines Type I (high quality reclaimed
Appearance Free of turbidity and D 3741
1,1,1-trichloroethane, approximating MIL Specification), Type
suspended matter
II (good quality reclaimed solvent), Type III (minimal accept-
1,1,1-trichloroethane, weight %, 92 D 3742
able reclaimed solvent).
min
Nonvolatile residue, weight 0.0040 D 2109
1.2 This standard does not purport to address all of the
%, max
safety concerns, if any, associated with its use. It is the
Color, Pt-Co, max 25 D 2108
responsibility of the user of this standard to establish appro-
Water, weight %, max 0.015 D 3401
Acid acceptance as NaOH, weight 0.20 D 2942
priate safety and health practices and determine the applica-
%, min
bility of regulatory limitations prior to use. For a specific
A
Aluminum scratch test Passes D 2943
hazards statement see Section 4.
Acidity as HCl, weight %, max 0.001 D 2989
Alkalinity as NaOH, weight %, max 0.020 D 2106
1.3 1,1,1-trichloroethane also is known commercially as
Halide as Cl, weight %, max 0.0005 D 2988
methyl chloroform.
A
Distill 100 mL solvent, collect 50 mL distillate, and conduct scratch test on
distillate and portion remaining in distillation flask.
2. Referenced Documents
2.1 ASTM Standards:
D 2106 Test Method for the Determination of Amine Acid
STP-310A Handbook of Vapor Degreasing
2 4
Acceptance (Alkalinity) of Halogenated Organic Solvents
STP-403A Cold Cleaning with Halogenated Solvents
D 2108 Test Method for Color of Halogenated Organic
3. Properties
Solvents and Their Admixtures (Platinum-Cobalt Scale)
D 2109 Test Methods for Nonvolatile Matter in Haloge- 3.1 Reclaimed 1,1,1-trichloroethane, Type I, shall conform
nated Organic Solvents and Their Admixtures to the requirements of Table 1.
D 2942 Test Method for Total Acid Acceptance of Haloge- 3.2 Reclaimed 1,1,1-trichloroethane, Type II, shall conform
nated Organic Solvents (Nonreflux Method) to the requirements of Table 2. See STP-310A.
D 2943 Test Method for Aluminum Scratch of 1,1,1- 3.3 Reclaimed 1,1,1-trichloroethane, Type III, shall con-
Trichloroethane form to the requirements of Table 3. See STP-403A.
D 2988 Test Method for Water-Soluble Halide Ion in Halo- 3.4 This specification does not address the possibility of
genated Organic Solvents and Their Admixtures product flash points due to the presence of flammable constitu-
D 2989 Test Method for Acidity-Alkalinity of Halogenated
ents. However, flash point must be determined for proper
Organic Solvents and Their Admixtures labeling and shipment. The Tag closed-cup procedure is
D 3401 Test Methods for Water in Halogenated Organic
recommended.
Solvents and Their Admixtures 3.5 Specific gravity for these grades typically will be
D 3741 Test Method for Appearance of Admixtures Con-
between 1.25 and 1.37.
taining Halogenated Organic Solvents
2 4. Hazards
D 3742 Test Method for 1,1,1-Trichloroethane Content
D 3844 Practice for Labeling Halogenated Hydrocarbon 4.1 Due to the possible presence of low level foreign
Solvent Containers contaminants in reclaimed 1,1,1-trichloroethane, the user is
2.2 Other Documents: cautioned to use due care in determining the effects of these
contaminants.
4.2 1,1,1
...

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