D26 - Halogenated Organic Solvents and Fire Extinguishing Agents
The promotion of knowledge pertaining to virgin and reclaimed halogenated organic solvents, and fire extinguishing agents, including formulation of specifications, practices, definitions and methods of test. Committee activities and standards will include the preparation of precautionary and preventive statements and suggested treatments relating to health, welfare or well-being of workers and the public, relative to the use of halogenated organic solvents and fire extinguishing agents based on currently accepted industry procedures. Standards peculiar to electrical insulating liquids, paint thinners and non-halogenated components of admixtures normally are excluded from the scope of the Committee D26. The work of the Committee will be coordinated with other ASTM Committees and other organizations having mutual interests.
Halogenated Organic Solvents and Fire Extinguishing Agents
The promotion of knowledge pertaining to virgin and reclaimed halogenated organic solvents, and fire extinguishing agents, including formulation of specifications, practices, definitions and methods of test. Committee activities and standards will include the preparation of precautionary and preventive statements and suggested treatments relating to health, welfare or well-being of workers and the public, relative to the use of halogenated organic solvents and fire extinguishing agents based on currently accepted industry procedures. Standards peculiar to electrical insulating liquids, paint thinners and non-halogenated components of admixtures normally are excluded from the scope of the Committee D26. The work of the Committee will be coordinated with other ASTM Committees and other organizations having mutual interests.
General Information
SCOPE
1.1 This specification covers requirements for iodotrifluoromethane (CF3I, CAS No. 2314-97-8) as an agent for fire suppression. This specification is not intended for large-scale commercial usage.
1.2 This specification does not address fire-fighting equipment or hardware that uses CF3I or the conditions of using such equipment (for example, portable extinguishers, fixed fire suppression systems, explosion inerting systems, and so forth).
1.3 This specification does not address the storage or transportation of CF3I. The storage, handling, and transportation issues may be addressed in future ASTM specifications.
1.4 CF3I has been found to be a cardiac sensitizer with a no observed adverse effect level (NOAEL) of 0.2 %. Therefore, sampling and other procedures should be performed only in areas with effective mechanical ventilation. Long-term exposures should be avoided pending the development of appropriate exposure standards.
1.5 Units—The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in non-conformance with the standard.
1.6 The following precautionary statement pertains only to the test method portion of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification9 pagesEnglish language
ABSTRACT
This specification covers reclaimed methylene chloride used in various industries for noncritical applications. Tests for specific gravity, acidity, water content, appearance, color, nonvolatile residue, chloride content, assay, and 1,1,1-trichloroethane content shall be performed and shall conform to the requirements specified.
SCOPE
1.1 This specification covers the grade of methylene chloride typically needed in various industries for noncritical applications, such as in paint stripping formulations. It may be used as a reference document by purchasers or by persons establishing in-house methylene chloride recovery programs.
1.2 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification2 pagesEnglish language
ABSTRACT
This specification covers solvents based on stabilized normal-propyl bromide (nPB) for use in vapor degreasing. The standard also includes a separate specification for technicalgraden-propyl bromide. Blends and azeotropic mixtures of stabilized nPB for vapor-degreasing shall be blended from nPB meeting the specification for technical-grade nPB. Vapor-degreasing solvents based on stabilized normalpropyl bromide shall conform to the requirements of different properties such as boiling point, acidity, water content, appearance, color, free halogen, nonvolatile residue, acid acceptance, and aluminum corrosion at reflux. Blends and azeotropic mixtures of stabilized nPB with other materials for use in vapor degreasing shall be prepared from technical-grade nPB which shall conform also to requirements of different properties such as: specific gravity, boiling point, acidity, water content, appearance, color, free halogen, nonvolatile residue, normal-propyl bromide content, and iso-propyl bromide content.
SCOPE
1.1 This standard covers solvents based on stabilized normal-propyl bromide (nPB) for use in vapor degreasing. The standard also includes a separate specification for technical-grade n-propyl bromide.
1.2 Blends and azeotropic mixtures of stabilized nPB for vapor-degreasing shall be blended from nPB meeting the specification for technical-grade nPB.
Note 1: Guide D3844, Practice D4276, and MNL22 provide additional important information on vapor degreasing and solvent properties.
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification2 pagesEnglish language
ABSTRACT
This specification covers dry cleaning-grade perchloroethylene suitable for use in the dry cleaning industry. Materials shall be tested and the individual grades shall conform to specified values of appearance, water content, residual odor, specific gravity, non-volatile residue content, boiling point, dry point, acid acceptance, and copper corrosion.
SCOPE
1.1 This specification covers drycleaning-grade perchloroethylene suitable for use in the drycleaning industry.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
Note 1: Guide D3844 provides additional important information on proper labeling.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification2 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This practice describes the symptoms and causes of an acid degreaser as well as methods for correcting the problem.
4.2 This practice is intended as a reference for use by persons responsible for the operation or maintenance of vapor degreasers or stills.4
4.3 This practice is not intended to cover every possible situation.
SCOPE
1.1 This practice covers the procedures required for recognizing and handling an acid vapor degreaser or still.
1.2 If the degreaser(s) is equipped with a still, follow the procedure in this practice for all of the equipment.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard3 pagesEnglish language
ABSTRACT
This specification covers technical grade ethylene dichloride. Technical grade ethylene dichloride shall conform to the requirements prescribed. The color, ethylene dichloride content, specific gravity, acidity, and water content shall be tested to meet the requirements prescribed.
SCOPE
1.1 This specification covers technical grade ethylene dichloride.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification2 pagesEnglish language
SIGNIFICANCE AND USE
4.1 Solvents that have been depleted in stabilizer content can become acidic. Acids can cause corrosion to process and storage equipment used for halogenated solvents.
4.2 Halogenated organic solvents may contain amine type (alkaline, aqueous extractable) acid accepting additives, neutral type (typically epoxide) acid accepting additives or both. This test method can determine the combined acid acceptance from both types of stabilizers. In addition, if the amine acid acceptance is determined by a separate procedure (see Test Methods D2106), the amount of neutral acid accepting stabilizers in a solvent can be calculated from the difference between combined and amine acid acceptance values.
4.3 This test method may be used by producers and users to verify that a product is complying with acid acceptance product specifications or by users to monitor the acid accepting ability of a solvent in use.
SCOPE
1.1 This test method covers the determination of the total acid acceptance including amine and neutral type (alpha epoxide) stabilizers in halogenated organic solvents.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 7.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard3 pagesEnglish language
ABSTRACT
This specification covers the requirements for Halon 1301, or halogenated hydrocarbon compound Bromotrifluoromethane (CF3Br) as a fire-fighting medium. The fire-fighting equipment or hardware that employs Halon 1301, the conditions of employing such equipment (for example, handhelds, fixed installations, etc.), and the storage or transportation of Halon 1301, are not addressed in this specification. The material shall be tested for purity, methanol impurity, acidity, water content, halogen ion content, nonvolatile residue, suspended matter and sediment, and fixed or nonabsorbable gases in the vapor phase.
SCOPE
1.1 This specification covers the requirements for Halon 1301 as a fire-fighting medium.
1.2 This specification does not address the fire-fighting equipment or hardware that employs Halon 1301 or the conditions of employing such equipment (for example, handhelds, fixed installations, etc.).
1.3 This specification does not address the storage or transportation of Halon 1301. Storage, handling, and transportation issues are addressed in Practice D5631.
1.4 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are not necessarily exact equivalents; therefore, to ensure conformance with the standard, each system shall be used independently of the other, and values from the two systems shall not be combined.
1.5 The following safety hazards caveat pertains only to the test methods portion, Section 6, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in 4.5.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification5 pagesEnglish language
ABSTRACT
This specification covers the requirements for 1,1,1,2,3,3,3-Heptafluoropropane (HFC-227ea) for use as a fire-fighting medium. However, this specification does not include the fire-fighting equipment or hardware that employs HFC-227ea, the conditions for employing such equipment, nor the storage or transportation of HFC-227ea. Material covered by this specification is of two types: Type I (mixtures of HFC-227ea and nitrogen) and Type II (HFC-227ea). Tests for purity, acidity, water content, fluoride ion content, suspended matter and sediment, nonvolatile residue, and fixed gases in the vapor phase shall be performed and shall conform to the requirements specified.
SCOPE
1.1 This specification covers requirements for HFC-227ea as a fire-fighting medium.
1.2 This specification does not address the fire-fighting equipment or hardware that employs HFC-227ea or the conditions of employing such equipment (for example, handhelds, fixed installations, etc.).
1.3 This specification does not address the storage or transportation of HFC-227ea. Storage, handling, and transportation issues may be addressed in future ASTM specifications.
1.4 The values stated in both inch-pound and SI units are to be regarded separately as the standard. The values given in parentheses are for information only.
1.5 The following safety hazards caveat pertains only to the test methods portion, Section 5, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Note 1.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification5 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This test method is useful for the determination of the amount of acid acceptance contributed by amines or bases as compared to other acid-accepting compounds.
SCOPE
1.1 These test methods, where applicable, cover the determination of the acid acceptance of halogenated organic solvents due to the presence therein of an organic amine titratable by standard acid. These test methods are suitable for samples of 0.001 to 0.02 weight percent (10 ppm to 200 ppm) alkalinity as NaOH. Two test methods are covered as follows:
1.1.1 Test Method A—pH Method, and
1.1.2 Test Method B—Indicator Method.
1.1.3 Test Method C—GC Method.
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard4 pagesEnglish language
ABSTRACT
This specification covers vapor-degreasing grade methylene chloride. Vapor-degreasing grade methylene chloride shall be subjected to different tests so as to determine properties such as specific gravity, distillation range at initial boiling point, distillation range at dry point, acidity, water content, appearance, color, nonvolatile residue, and acid acceptance.
SCOPE
1.1 This specification covers vapor-degreasing grade methylene chloride.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
Note 1: Guide D3844, Practice D4276, and MNL22 provide additional important information on vapor degreasing and solvent properties.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification2 pagesEnglish language
SIGNIFICANCE AND USE
3.1 Nonvolatile matter in solvents can adversely affect their cleaning properties. These test methods can be used to control soil contamination in the boiling solvent, which if allowed to become too high, can decrease the stability of the solvent.
3.2 These test methods can be used to establish manufacturing and purchasing specifications.
SCOPE
1.1 These test methods cover the determination of nonvolatile matter in halogenated organic solvents and admixtures.
1.2 Five test methods are covered, as follows:
1.2.1 Test Method A—For halogenated organic solvents or admixtures having less than 50 ppm nonvolatile matter; or where precision better than ±10 ppm is required.
1.2.2 Test Method B—For halogenated organic solvents or admixtures having more than 50 ppm nonvolatile matter or where precision of ±0.001 % (10 ppm) is satisfactory.
1.2.3 Test Method C—For low-boiling halogenated organic solvents or their admixtures (for example, methylene chloride, trichlorotrifluoroethane) that may superheat and cause bumping while evaporating to dryness with steam. A precision of greater than ±10 ppm can be attained.
1.2.4 Test Method D—For rapid measurement of nonvolatile matter in halogenated organic solvents and their admixtures and where precision better than ±10 ppm is required.
1.2.5 Test Method E—For halogenated organic solvents or admixtures and where precision better than ±10 ppm is required.
1.3 The values stated in SI units are to be regarded as standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard4 pagesEnglish language
SIGNIFICANCE AND USE
3.1 This test method provides an analysis in weight percent of the normal-propyl bromide concentration of virgin, formulated, or reclaimed normal-propyl bromide: compounds that co-elute with normal-propyl bromide or normal-heptane (internal standard) may interfere with this test method.
SCOPE
1.1 This test method provides a basis for the determination of the normal-propyl bromide (weight %) in the presence of stabilizers and impurities, in virgin or reclaimed normal-propyl bromide (nPB). The application range is from 50 wt % to 100 wt %.
1.2 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard2 pagesEnglish language
SIGNIFICANCE AND USE
3.1 The pH of halogenated solvents varies according to the nature of stabilizers in the particular solvent. Solvents with alkaline stabilizers (amine-types) generally have pHs in the 7 to 11 range, whereas solvents containing neutral stabilizers (epoxide-types) generally have pHs in the 5 to 7 range.
3.2 Virgin and reclaimed solvents should have pHs within these ranges, dependent upon the claimed method of stabilization. These values should be within the accepted limits as proposed by the producers of the original virgin solvent.
3.3 A lowering of pH from the above values, on receipt or use, is cause for concern. In this event, solvents having epoxide stabilizers should be tested for acid acceptance; solvent having alkaline stabilizers should be tested for alkalinity.
SCOPE
1.1 This test method covers the measurement of the pH of water extractions of halogenated organic solvents and admixtures thereof. This test method is applicable for the determination of the pH of water extractions of virgin, reclaimed, or used solvents.
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard2 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This test method can be used to establish manufacturing and purchasing specifications. It can also be used to determine the condition of solvents in use.
SCOPE
1.1 This test method covers the determination of acidity in halogenated organic solvents and admixtures thereof. The alkalinity may be determined utilizing Test Methods D2106, by substituting the end point measured at pH 7 by bromothymol blue or pH meter.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 7.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard3 pagesEnglish language
ABSTRACT
This practice covers the standard procedure for determining impurities, stabilizers, and assays of halogenated organic solvents and their admixtures by gas chromatography. It is not the intent of this practice to provide a specific method of gas chromatography, but rather it defines what is required for a user to demonstrate that a method to be used is valid. The use of this practice allows the user to use the most effective technology and demonstrate that the method in use complies with a standard practice and is valid for the analytes involved.
SCOPE
1.1 This practice covers the determination of impurities, stabilizers and assay of halogenated organic solvents and their admixtures by gas chromatography.
1.2 It is not the intent of this practice to provide a specific method of gas chromatography. The intent of this practice is to define what is required for a user to demonstrate that a method to be used is valid. The reason for this approach, as opposed to stating a method, is that gas chromatography is such a dynamic field that methods are often obsolete by the time they are validated. The use of this practice allows the user to use most effective technology and demonstrate that the method in use complies with a standard practice and is valid for the analysis of halogenated organic solvents and their admixtures.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard3 pagesEnglish language
SIGNIFICANCE AND USE
4.1 High water concentrations can have a detrimental effect on many uses of halogenated solvents.
4.1.1 Water can cause corrosion and spotting when solvents are used for metal cleaning.
4.1.2 Water can reduce the shelf life of aerosol formulations.
4.1.3 Water can inhibit desired reactions when solvents are used in formulations.
SCOPE
1.1 These test methods describe the use of the Karl Fischer (KF) titration for determination of water in halogenated organic solvents and mixtures thereof. Water concentrations from 2 ppm to 1000 ppm can be determined in these solvents. Two test methods are covered as follows:
1.1.1 Test Method A, Water Determination Using a Coulometric KF Titrator—The coulometric test method is known for its high degree of sensitivity (typically 2O) and should be the test method of choice if water concentrations are typically below 50 ppm or if only small amounts of sample are available for water determinations. This test method requires the use of equipment specifically designed for coulometric titrations.
1.1.2 Test Method B, Water Determination Using a Volumetric KF Titrator—The volumetric test method is a more traditional approach to KF water determinations. Although titrators are specifically designed for KF volumetric determinations, many automatic titrators on the market can be adapted to perform KF titrations.
1.2 Either of these test methods can be used to determine typical water concentrations (15 ppm to 500 ppm) found in halogenated solvents.
1.3 These test methods recommend the use of commercially available Karl Fischer titrators and reagents.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific precautionary statements, see Sections 11 and 15.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard5 pagesEnglish language
ABSTRACT
This specification covers the grades of trichloroethylene typically needed in various industries for noncritical applications such as in metal cleaning formulations. It may also be used as a reference document by purchasers or persons establishing in-house trichloroethylene recovery programs. The specimens are classified into three types: Type I – generally recognized for use in precision applications; Type II – for use in less-demanding precision applications; and Type III – may not be suitable for all applications. The three types of reclaimed trichloroethylene shall meet the specific gravity, nonvolatile residue, water content, assay percentage, 1,1,1 trichloroethane content, color in platinum-cobalt scale, appearance, acid acceptance, and acidity requirements.
SCOPE
1.1 This specification covers the grades of trichloroethylene2 typically needed in various industries for noncritical applications such as in metal cleaning formulations. It may be used as a reference document by purchasers or persons establishing in-house trichloroethylene recovery programs.
1.2 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification2 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This test method is to be used as a guide in selecting or eliminating certain grades of perchloroethylene used for drycleaning fabrics or degreasing metal parts.
SCOPE
1.1 This test method covers the evaluation of the corrosiveness to copper metal by perchloroethylene.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard3 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This practice provides requirements for the handling, transportation, and storage of HFC Blend B encountered in distribution through both commercial and military channels. It is intended to ensure that HFC Blend B is handled, transported, and stored in such a way that its physical property virtues are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, water, and air.
SCOPE
1.1 This practice covers guidance and direction to suppliers, reclaimers, purchasers, and users in the handling, transportation, and storage of HFC Blend B.
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard6 pagesEnglish language
- Standard6 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This practice provides requirements for the handling, transportation, and storage of IG-55 encountered in distribution through both commercial and military channels. It is intended to ensure that IG-55 is handled, transported, and stored in such a way that its physical property virtues are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, and water.
SCOPE
1.1 This practice covers guidance and direction to suppliers, purchasers, and users in the handling, transportation, and storage of IG-55.
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard3 pagesEnglish language
- Standard3 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This practice provides requirements for the handling, transportation, and storage of HCFC Blend B encountered in distribution through both commercial and military channels. It is intended to ensure that HCFC Blend B is handled, transported, and stored in such a way that its physical property virtues are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, water, and air.
SCOPE
1.1 This practice covers guidance and direction to suppliers, reclaimers, purchasers, and users in the handling, transportation, and storage of HCFC Blend B.
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard4 pagesEnglish language
- Standard4 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This practice provides requirements for the handling, transportation, and storage of IG-541 encountered in distribution through both commercial and military channels. It is intended to ensure that IG-541 is handled, transported, and stored in such a way that its physical property virtues are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, and water.
SCOPE
1.1 This practice covers guidance and direction to suppliers, purchasers, and users in the handling, transportation, and storage of IG-541.
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard4 pagesEnglish language
- Standard4 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This practice provides requirements for the handling, transportation, and storage of Halon 1301 encountered in distribution through both commercial and military channels. It is intended to ensure that Halon 1301 is handled, transported, and stored in such a way that its physical property values are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, water, and air.
SCOPE
1.1 This practice covers guidance and direction to suppliers, recyclers, reclaimers, purchasers, and users in the handling, transportation, and storage of Halon 1301.
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and to determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard4 pagesEnglish language
- Standard4 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This practice provides requirements for the handling, transportation, and storage of 2-BTP encountered in distribution through both commercial and military channels. It is intended to ensure that 2-BTP is handled, transported, and stored in such a way that its physical property virtues are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, water, and air.
SCOPE
1.1 This practice covers guidance and direction to suppliers, reclaimers, purchasers, and users in the handling, transportation, and storage of 2-Bromo-3,3,3-Trifluoro-1-Propene (“2-BTP”).
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard3 pagesEnglish language
- Standard3 pagesEnglish language
ABSTRACT
This specification covers requirements for HCFC Blend B as a fire-fighting medium. The fill density of HCFC Blend B within a container should not exceed that needed to achieve complete filling of the container at the maximum envisaged storage temperature. Properties like HCFC-123 purity, HCFC-123 content, argon content, tetrafluoromethane content, acidity, water content, nonvolatile residue content, and suspended matter or sediment content shall be determined by subjecting HCFC Blend B to various tests.
SCOPE
1.1 This specification covers requirements for HCFC Blend B as a fire-fighting medium.
1.2 This specification does not address the fire-fighting equipment or hardware that employs HCFC Blend B or the conditions of employing such equipment (for example, handhelds, fixed installations, etc.).
1.3 This specification does not address the storage or transportation of HCFC Blend B. Storage, handling, and transportation issues are addressed in Practice D7123.
1.4 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.5 The following safety hazards caveat pertains only to the test methods portion, Section 6, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in 4.5.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification3 pagesEnglish language
- Technical specification3 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This practice provides requirements for the handling, transportation, and storage of HFC-236fa encountered in distribution through both commercial and military channels. It is intended to ensure that HFC-236fa is handled, transported, and stored in such a way its physical properties are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, water, and air.
SCOPE
1.1 This practice covers guidance and direction to suppliers, purchasers, and users in the handling, transportation, and storage of HFC-236fa.
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard4 pagesEnglish language
- Standard4 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This practice provides requirements for the handling, transportation, and storage of HFC-23 encountered in distribution through both commercial and military channels. It is intended to ensure that HFC-23 is handled, transported, and stored in such a way its physical property values are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, water, and air.
SCOPE
1.1 This practice covers guidance and direction to suppliers, purchasers, and users in the handling, transportation, and storage of HFC-23.
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard3 pagesEnglish language
- Standard3 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This practice provides requirements for the handling, transportation, and storage of HFC-227ea encountered in distribution through both commercial and military channels. It is intended to ensure that HFC-227ea is handled, transported, and stored in such a way that its physical property virtues are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, water, and air.
SCOPE
1.1 This practice covers guidance and direction to suppliers, reclaimers, purchasers, and users in the handling, transportation, and storage of HFC-227ea.
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard4 pagesEnglish language
- Standard4 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This practice provides requirements for the handling, transportation, and storage of HFC-125 encountered in distribution through both commercial and military channels. It is intended to insure that HFC-125 is handled, transported, and stored in such a way its physical properties are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, water, and air.
SCOPE
1.1 This practice covers guidance and direction to suppliers, purchasers, and users in the handling, transportation, and storage of HFC-125, pentafluoroethane (C2HF5).
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
FIG. 1 Effect of Temperature on Storage Cylinder Pressure (HFC-125 Mixed with Nitrogen)
Note 1: Applicable to a container fill density of 57.5 lb/ft3 only.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard3 pagesEnglish language
- Standard3 pagesEnglish language
SCOPE
1.1 This specification covers requirements for HFC Blend B as a fire-fighting medium.
1.2 This specification does not address the fire-fighting equipment or hardware that employs HFC Blend B or the conditions of employing such equipment (for example, handhelds, fixed installations, etc.).
1.3 This specification does not address the storage or transportation of HFC Blend B. Storage, handling, and transportation issues are addressed in Practice D7326.
1.4 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard
1.5 The following safety hazards caveat pertains only to the test methods portion, Section 6, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 4.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification3 pagesEnglish language
- Technical specification3 pagesEnglish language
ABSTRACT
This specification covers the requirements for HFC- 236fa HFC-236fa, 1,1,1,3,3,3-hexafluoropropane, (CF3CH 2CF3) as a fire-fighting medium. The materials are classified into two types: type I - mixtures of HFC-236fa and nitrogen, and type II - HFC-236fa. The purity, acidity, water content, non-volatile residue, fixed gases in the vapour phase, and suspended matter or sediment shall be tested to meet the requirements prescribed.
SCOPE
1.1 This specification covers the requirements for HFC-236fa as a fire-fighting medium.
1.2 This specification does not address the fire-fighting equipment or hardware that employs HFC-236fa or the conditions of employing such equipment (for example, hand-helds, fixed installations, and so forth).
1.3 This specification does not address the storage or transportation of HFC-236fa. Storage, handling, and transportation issues are addressed in Practice D6427.
1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.
1.5 The following safety hazards caveat pertains to the test methods portion, Section 6, of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. A specific warning statement is given in 4.3.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification3 pagesEnglish language
- Technical specification3 pagesEnglish language
ABSTRACT
This specification covers the requirements for HFC-125 (pentafluoroethane, C2HF5) as a fire-fighting medium. It does not however address the fire-fighting equipment or hardware that employs HFC-125, the conditions of employing such equipment like hand helds, fixed installations, etc., or the storage and transportation of HFC-125. Samples of HFC-125 taken in the liquid phase shall be taken from filled containers in accordance to a specific method and shall be tested for quality conformance using gas chromatography, sodium hydroxide titration, and Karl Fischer methods. HFC-125 shall conform to the purity, acidity, water content, nonvolatile residue, presence of fixed gases in the vapor phase, and suspended matter or sediment requirements when tested by the appropriate test methods.
SCOPE
1.1 This specification covers the requirements for HFC-125 as a fire-fighting medium.
1.2 This specification does not address the fire-fighting equipment or hardware that employs HFC-125 or the conditions of employing such equipment, for example, hand helds, fixed installations, etc.
1.3 This specification does not address the storage or transportation of HFC-125. Storage, handling, and transportation issues are addressed in Practice D6268.
1.4 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are not necessarily exact equivalents; therefore, to ensure conformance with the standard, each system shall be used independently of the other, and values from the two systems shall not be combined.
1.5 The following safety hazards caveat pertains to the test methods portion, Section 6, of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in 4.3.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification3 pagesEnglish language
- Technical specification3 pagesEnglish language
ABSTRACT
This specification covers the requirements for Halon 1211 as a fire-fighting medium. There are a number of limitations to this specification, such as the fire-fighting equipment or hardware that require the use of Halon 1211 and the storage or transportation of Halon 1211. Due to these limitations in this specification, storage, handling, and transportation issues may be addressed in future ASTM standards.
SCOPE
1.1 This specification covers the requirements for Halon 1211 as a fire-fighting medium.
1.2 This specification does not address the fire-fighting equipment or hardware that employs Halon 1211 or the conditions of employing such equipment (for example, handhelds, fixed installations, etc.).
1.3 This specification does not address the storage or transportation of Halon 1211. Storage, handling, and transportation issues are addressed in Practice D7815.
1.4 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are not necessarily exact equivalents; therefore, to ensure conformance with the standard, each system shall be used independently of the other, and values from the two systems shall not be combined.
1.5 The following safety hazards caveat pertains only to the test methods portion, Section 6, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 4.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification4 pagesEnglish language
- Technical specification4 pagesEnglish language
ABSTRACT
This specification applies to 2-Bromo-3, 3,3-Trifluoro-1-Propene (“2-BTP”) as a fire-fighting medium. It does not address the fire-fighting equipment or hardware that employs 2-BTP or the conditions of employing such equipment (for example, handhelds, fixed installations, etc.). The storage or transportation of 2-BTP is also not covered.
SCOPE
1.1 This specification covers requirements for 2-Bromo-3,3,3-Trifluoro-1-Propene (“2-BTP”) as a fire-fighting medium.
1.2 This specification does not address the fire-fighting equipment or hardware that employs 2-BTP or the conditions of employing such equipment (for example, handhelds, fixed installations, etc.).
1.3 This specification does not address the storage or transportation of 2-BTP. Storage, handling, and transportation issues are addressed in Practice D8061.
1.4 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.5 The following safety hazards caveat pertains only to the test methods portion, Section 6, of this specification:
1.5.1 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 4.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification2 pagesEnglish language
- Technical specification2 pagesEnglish language
ABSTRACT
This specification covers the test methods and requirements for HFC-23 (trifluoromethane, CHF3) as a fire fighting medium. This specification, however, does not address the fire fighting equipment or hardware that employs HFC-23 or the conditions of employing such equipment (for example, handshields, fixed installations, etc.). It also does not address the storage or transportation of HFC-23. When analyzed by appropriate test methods, sampled specimens shall conform to requirements as to purity, acidity, water content, nonvolatile residue, and suspended matter or sediment.
SCOPE
1.1 This specification covers the requirements for HFC-23 as a fire fighting medium.
1.2 This specification does not address the fire fighting equipment or hardware that employs HFC-23 or the conditions of employing such equipment (for example: handshields, fixed installations, etc.).
1.3 This specification does not address the storage or transportation of HFC-23 Storage handling, and transportation issues are addressed in Practice D6127.
1.4 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are not necessarily exact equivalents; therefore, to ensure conformance with the standard, each system shall be used independently of the other, and values from the two systems shall not be combined.
1.5 The following safety hazards caveat pertains to the test methods portion, Section 6, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification3 pagesEnglish language
- Technical specification3 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This practice provides requirements for the handling, transportation, and storage of Halon 1211 encountered in distribution through both commercial and military channels. It is intended to ensure that Halon 1211 is handled, transported, and stored in such a way that its physical property values are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, water, and air.
SCOPE
1.1 This practice covers guidance and direction to suppliers, recyclers, reclaimers, purchasers, and users in the handling, transportation, and storage of Halon 1211.
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard4 pagesEnglish language
- Standard4 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This practice provides requirements for the handling, transportation, and storage of IG-100 encountered in distribution through both commercial and military channels. It is intended to ensure that IG-100 is handled, transported, and stored in such a way that its physical property virtues are not degraded. Transport may be by various means, such as, but not limited to, highway, rail and water.
SCOPE
1.1 This practice covers guidance and direction to suppliers, purchasers, and users in the handling, transportation, and storage of IG-100 (nitrogen).
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard3 pagesEnglish language
- Standard3 pagesEnglish language
ABSTRACT
This specification covers the requirements for trichloromethane chloroform intended for use as fluorocarbon feedstock. The fluorocarbon feedstock grade chloroform shall have a clear appearance, free of sediments and suspended matters. Tests shall be conducted to determine conformance to the following properties: water content, non-volatile residue content, color in the platinum-cobalt scale, free halogen content, acidity as HCl, dichloroethane content, carbon tetrachloride content, methylene chloride content, dichloroethylene content, and wt% of the assay. Products shall be packaged and labeled in accordance with DOT regulations, state and local regulations, and OSHA regulations.
SCOPE
1.1 This specification specifies chloroform (trichloromethane) that is suitable for use as feedstock for fluorocarbons.
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification2 pagesEnglish language
ABSTRACT
This specification establishes the requirements for three grades of 1,1,2-trichloro 1,2,2-trifluoroethane solvent, as follows: Type I, electronic or ultra-clean grade; Type II, standard or vapour-degreasing grade; and Type IIA, general purpose grade packaged in a pressurized container. Each grade shall adhere to individually specified values of the following chemical and physical properties: boiling point at standard barometric pressure; chemical purity; moisture content; chloride ions content; specific aqueous conductance; acid number; and residue content.
SCOPE
1.1 This specification establishes the requirements for three grades of trichlorotrifluoroethane solvent:
1.1.1 Type I electronic or ultra-clean grade,
1.1.2 Type II standard or vapor-degreasing grade, and
1.1.3 Type IIA general purpose, packaged in a pressurized container grade.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification2 pagesEnglish language
SIGNIFICANCE AND USE
4.1 The density or specific gravity of a pure chlorinated solvent at a given temperature is constant. Density or specific gravity can be used in identification of materials, the assay of binary mixtures, and as an indication of purity of a given solvent.
SCOPE
1.1 These test methods cover the determination of the specific gravity of halogenated organic solvents and solvent admixtures. They define suitable apparatus and procedures and furnish details underlying the interpretation of test data and the selection of numerical limits for agreement among interested persons and agencies.
1.2 Three methods are covered as follows:
1.2.1 Method A, specific gravity by means of a hydrometer.
1.2.2 Method B, specific gravity and density by means of a pycnometer.
Note 1: In referee problems, Method B may be used.
1.2.3 Method C, specific gravity and density by means of an electronic densitometer.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard5 pagesEnglish language
SIGNIFICANCE AND USE
5.1 This guide is to be used by anyone developing cleaning requirements for specifications for manufacturing, maintenance, or overhaul. This guide has been designed to be application specific for each cleaning task and to assure the design engineer that the process selected by the industrial or manufacturing engineer will be compatible with both the part material and the subsequent process(es). This guide allows the industrial or manufacturing engineer to customize the selection of the cleaning product based on the materials of the part being cleaned; the cleanliness required for the subsequent process(es); and the environmental, cost, and health and safety concerns.
SCOPE
1.1 This guide is intended to assist design engineers, manufacturing/industrial engineers, and production managers in selecting the best fit cleaning agent and process. This guide takes into account environmental pollution prevention factors in a selection process.
1.2 This guide is not to be considered as a database of acceptable materials. It will guide the engineers and managers through the cleaning material selection process, calling for engineers to customize their selection based on the cleaning requirements for the cleaning tasks at hand. If a part can be cleaned, and kept clean, it can be cycled through several process steps that have cleaning requirements. This eliminates extra cleaning process steps during the total process. A total life cycle cost analysis or performance/cost of ownership study is recommended to compare the methods available.
1.3 This guide is for general industry manufacturing, equipment maintenance and remanufacturing operations, and to some extent precision cleaning of mechanical parts and assemblies. It is not intended to be used for optical, medical, or electronics applications, nor is it intended for dry-cleaning or super-critical fluid cleaning.
1.4 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are not necessarily exact equivalents; therefore, to ensure conformance with the standard, each system shall be used independently of the other and values from the two systems shall not be combined.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Guide7 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This practice is intended for use by employers in developing their own specific operation standards for solvent vapor degreasing operations.
4.2 Certain vapor degreasing operations are subject to the requirements of the National Emission Standards for Halogenated Solvent Cleaning (Halogenated Solvent Cleaner NESHAP) as found in 40 CFR Part 63, Subpart T. The determination of the applicability of these, or any additional requirements is the responsibility of the user.
4.3 This practice is not intended to address all of the requirements contained in the Halogenated Solvent Cleaner NESHAP. Development and implementation of training programs, recordkeeping, and other additional requirements of the NESHAP are the responsibility of the user.
SCOPE
1.1 This practice recommends work practices for conventional vapor degreasing operations utilizing any solvent or solvent blend that has been categorized as nonflammable.
1.2 This practice is not intended for use in vapor degreasing operations utilizing flammable (low flash point) solvents or in vapor degreasing operations utilizing enclosed (sealed, airtight) equipment. For these non-applicable operations, users should consult the solvent or equipment supplier for additional information.
1.3 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard6 pagesEnglish language
ABSTRACT
This specification covers the three grades of 1,1,2- trichloro 1,2,2 trifluoroethane typically needed in various industries. This may be a reference for 1,1,2-trichloro 1,2,2- trifluoroethane recovery programs. The three classifications are as follows: Type I - generally recognized for use in precision applications; Type II - used for less demanding precision applications; and Type III - general-purpose technical grade. Materials shall be tested and the individual grades shall conform to specified values of specific gravity, chloride content, acid number, non-volatile residue content, water content, 1,1,2-trichloro 1,2,2- trifluoroethane content, 1,1,1- trichloroethane content, color, and appearance.
SCOPE
1.1 This specification covers the three grades of 1,1,2-trichloro 1,2,2-trifluoroethane2 typically needed in various industries. It may be used as a reference document by purchasers or by persons establishing in-house, 1,1,2-trichloro 1,2,2-trifluoroethane recovery programs.
1.2 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification2 pagesEnglish language
SIGNIFICANCE AND USE
3.1 This test method allows for the determination of ionizable contaminants (expressed in terms of ppb of HCl) in trichlorotrifluoroethane via measurement of specific aqueous conductance.
3.2 This test method can be used for establishing manufacturing and purchasing specifications.
SCOPE
1.1 This test method covers the determination of aqueous conductivity due to ionizable contaminants extracted from trichlorotrifluoroethane. The value of 1.9 μS/cm as maximum specific aqueous conductance corresponds to 0.1 ppm of chloride ion (100 ppb). It was calculated by putting the solvent specification of 0.1 ppm chloride into the equation of the subject method to find C2 − C1 equals 19.08. The specific conductance due to contaminants from the solvent was then calculated as follows:
1.2 The above is exclusive of the background specific conductance of the water used in the analysis.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3.1 Exception—Values are stated in inch-pound units in Fig. 1.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to consult and establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 6.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard4 pagesEnglish language
SIGNIFICANCE AND USE
5.1 This test method gives valid comparisons of the evaporation rates of the subject materials. These comparisons are required for the determination of the suitability of a proposed material for specific cleaning applications.
SCOPE
1.1 This test method covers the measurement of the relative evaporation time of halogenated organic solvents and their admixtures. This test method is not applicable in the presence of excessive drafts or high-velocity air currents.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard2 pagesEnglish language
SIGNIFICANCE AND USE
3.1 These test methods are used to establish manufacturing and purchasing specifications. These test methods will provide a means of determining the condition of the solvent in use. A high water soluble chloride level may indicate the start of solvent decomposition.
SCOPE
1.1 Test Methods 1, 2, and 3—These test methods cover the determination of water-extractable halide ion in halogenated organic solvents and their admixtures. Fluoride ion is not measured due to the solubility of silver fluoride.
1.2 Test Method 4—This test method covers the determination of chloride ion in halogenated organic solvents and their admixtures.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 6.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard3 pagesEnglish language
SIGNIFICANCE AND USE
4.1 Free halogens will react with any residual moisture in a solvent to form acid. These acids can cause corrosion to process and storage equipment used for halogenated solvents.
4.2 The presence of free halogens in halogenated solvents is often an indication that the stabilizers in the solvent system are breaking down.
4.3 This test method provides a means of detecting the presence of free halogens in halogenated solvents and their admixtures.
SCOPE
1.1 This test method covers the evaluation of free halogens in halogenated organic solvents and their admixtures.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard2 pagesEnglish language
SIGNIFICANCE AND USE
2.1 These test methods are useful for determining the appearance of halogenated hydrocarbons and their admixtures.
SCOPE
1.1 These test methods cover the visual determination of the physical appearance of admixtures containing halogenated hydrocarbons. These test methods are qualitative test methods.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard2 pagesEnglish language
ABSTRACT
This specification covers technical grade methylene chloride. Technical grade methylene chloride shall conform to the requirements prescribed. Tests shall be performed to determine the property requirements of the material in accordance to the following test methods: appearance; color; specific gravity; distillating range; nonvolatile residue; acidity; water; and free halogens.
SCOPE
1.1 This specification covers technical grade methylene chloride.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
Note 1: See Guide D3844, Practice D4276, and STP 403A2 for additional important information on solvent handling and solvent properties.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Technical specification2 pagesEnglish language
Frequently Asked Questions
D26 is a Technical Committee within ASTM International. It is named "Halogenated Organic Solvents and Fire Extinguishing Agents" and is responsible for: The promotion of knowledge pertaining to virgin and reclaimed halogenated organic solvents, and fire extinguishing agents, including formulation of specifications, practices, definitions and methods of test. Committee activities and standards will include the preparation of precautionary and preventive statements and suggested treatments relating to health, welfare or well-being of workers and the public, relative to the use of halogenated organic solvents and fire extinguishing agents based on currently accepted industry procedures. Standards peculiar to electrical insulating liquids, paint thinners and non-halogenated components of admixtures normally are excluded from the scope of the Committee D26. The work of the Committee will be coordinated with other ASTM Committees and other organizations having mutual interests. This committee has published 326 standards.
D26 develops ASTM standards in the area of Information technology. The scope of work includes: The promotion of knowledge pertaining to virgin and reclaimed halogenated organic solvents, and fire extinguishing agents, including formulation of specifications, practices, definitions and methods of test. Committee activities and standards will include the preparation of precautionary and preventive statements and suggested treatments relating to health, welfare or well-being of workers and the public, relative to the use of halogenated organic solvents and fire extinguishing agents based on currently accepted industry procedures. Standards peculiar to electrical insulating liquids, paint thinners and non-halogenated components of admixtures normally are excluded from the scope of the Committee D26. The work of the Committee will be coordinated with other ASTM Committees and other organizations having mutual interests. Currently, there are 326 published standards from this technical committee.
ASTM is a standardization organization that develops and publishes standards to support industry, commerce, and regulatory requirements.
A Technical Committee (TC) in ASTM is a group of experts responsible for developing international standards in a specific technical area. TCs are composed of national member body delegates and work through consensus to create standards that meet global industry needs. Each TC may have subcommittees (SCs) and working groups (WGs) for specialized topics.