ASTM D4360-11(2019)

Standard Specification for Methyl <emph type="bdit">n</emph>-Amyl Ketone

ABSTRACT
This certification of coating conformance form provides procurement information concerning products being furnished in accordance with a specific coating specification and additional requirements contained in the purchase order. The certification form is divided into four headings: General Type and Description(I), Buyer Information(II), Seller Information (III), and Certification (IV). The first heading consists of the following information: generic type, manufacturer's designation, specification number, formula number, component number, component identification, and color. The second heading consists purchase order number, release number, part number, item number, and stock number. The third heading consists of seller's representative, batch number, lot number, date of manufacture, and date of certification expiration. The last heading is a paragraph describing the certification.
SCOPE
1.1 This specification covers methyl n-amyl ketone (98 % grade) for use in paint, varnish, lacquer, and related products.  
1.2 For specific hazard information and guidance, see the supplier's Material Safety Data Sheet for materials listed in this specification.  
1.3 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

• Status: Published
• Publication Date: 31-Mar-2019
• ICS: 71.080.80 - Aldehydes and ketones
• Technical Committee: D01 - Paint and Related Coatings, Materials, and Applications
• Drafting Committee: D01.35 - Solvents, Plasticizers, and Chemical Intermediates

Relations

• Replaces: ASTM D4360-11 - Standard Specification for Methyl <span class="italic">n</span>-Amyl Ketone
• Effective Date: 01-Apr-2019
• Refers: ASTM D1613-06(2012) - Standard Test Method for Acidity in Volatile Solvents and Chemical Intermediates Used in Paint, Varnish, Lacquer, and Related Products
• Effective Date: 01-Jun-2012
• Refers: ASTM D1078-11 - Standard Test Method for Distillation Range of Volatile Organic Liquids
• Effective Date: 15-Nov-2011
• Refers: ASTM D5386-10 - Standard Test Method for Color of Liquids Using Tristimulus Colorimetry
• Effective Date: 01-Jan-2010
• Refers: ASTM D3893-03(2009) - Standard Test Method for Purity of Methyl Amyl Ketone and Methyl Isoamyl Ketone by Gas Chromatography
• Effective Date: 01-Dec-2009
• Refers: ASTM E29-08 - Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
• Effective Date: 01-Oct-2008
• Refers: ASTM D1364-02(2007) - Standard Test Method for Water in Volatile Solvents (Karl Fischer Reagent Titration Method)
• Effective Date: 01-Jun-2007
• Refers: ASTM D268-01(2007) - Standard Guide for Sampling and Testing Volatile Solvents and Chemical Intermediates for Use in Paint and Related Coatings and Material
• Effective Date: 01-Jun-2007
• Refers: ASTM E29-06b - Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
• Effective Date: 15-Nov-2006
• Refers: ASTM E29-06a - Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
• Effective Date: 15-Sep-2006
• Refers: ASTM E29-06 - Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
• Effective Date: 01-May-2006
• Refers: ASTM D1613-06 - Standard Test Method for Acidity in Volatile Solvents and Chemical Intermediates Used in Paint, Varnish, Lacquer, and Related Products
• Effective Date: 01-Apr-2006
• Refers: ASTM D5386-05 - Standard Test Method for Color of Liquids Using Tristimulus Colorimetry
• Effective Date: 15-Oct-2005
• Refers: ASTM D1078-05 - Standard Test Method for Distillation Range of Volatile Organic Liquids
• Effective Date: 15-May-2005
• Refers: ASTM D1209-05 - Standard Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)
• Effective Date: 15-May-2005

Overview

ASTM D4360-11(2019) - Standard Specification for Methyl n-Amyl Ketone sets forth quality and testing requirements for methyl n-amyl ketone (98% grade), a specialized solvent used in coatings such as paints, varnishes, lacquers, and related products. Developed by ASTM International, this standard ensures uniformity and safety, guiding manufacturers, suppliers, and end-users toward consistent product quality aligned with internationally recognized practices.

Methyl n-amyl ketone (sometimes referenced as MAK or 2-heptanone) is valued in industrial applications for its strong solvency, compatibility with diverse resins, and contribution to optimal flow and leveling characteristics in formulated coatings.

Key Topics

• Scope and Coverage

  • Specifies methyl n-amyl ketone for use in paint, varnish, lacquer, and related industries.
  • Establishes minimum purity of 98% and strict limits for water content, color, acidity, and boiling point.

• Quality and Purity Requirements

  • Apparent specific gravity, color (Pt-Co scale), distillation range, water content, acidity as acetic acid, and purity levels are precisely defined.
  • Testing must conform to referenced ASTM methods, including D4052 (density), D1209 (color), D1078 (distillation), D1364 (water), D1613 (acidity), and D3893 (purity).

• Sampling and Conformance

  • Sampling procedures are governed by ASTM Practice E300, ensuring representative and reliable assessments.
  • Clearly defined rounding rules (in accordance with ASTM E29) for determining compliance with limits.

• Packaging and Handling

  • Packaging sizes are subject to agreement between purchaser and supplier and must meet applicable carrier regulations or Federal Specification PPP-C-2020 when required.

• Safety Guidance

  • Users are directed to consult the supplier's Material Safety Data Sheet for detailed hazard information and safe handling practices.

Applications

Methyl n-amyl ketone, conforming to ASTM D4360-11(2019), is extensively used in:

• Paint and Coating Formulations

  • Enhances the spreadability and finish quality of paints, varnishes, and lacquers.
  • Ensures compatibility with various binders and pigments.

• Industrial and Automotive Finishes

  • Facilitates fast drying and optimal film formation for durable coatings.

• Cleaning and Degreasing Solutions

  • Used as an effective industrial solvent for removal of grease and contaminants.

Organizations, formulators, and suppliers benefit from ASTM D4360 compliance by ensuring product consistency, regulatory adherence, and confidence in performance across multiple application sectors. Proper specification and certification streamline procurement and quality assurance processes.

Related Standards

Key referenced and related ASTM standards include:

• ASTM D268 - Guide for Sampling and Testing Volatile Solvents and Chemical Intermediates for Use in Paint and Related Coatings and Material.
• ASTM D1078 - Test Method for Distillation Range of Volatile Organic Liquids.
• ASTM D1209/D5386 - Methods for Measuring Color of Liquids.
• ASTM D1364 - Test Method for Water Content in Volatile Solvents.
• ASTM D1613 - Test Method for Acidity in Volatile Solvents and Chemical Intermediates.
• ASTM D3893 - Test Method for Purity of Methyl Amyl Ketone and Methyl Isoamyl Ketone by Gas Chromatography.
• ASTM E29 - Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications.
• ASTM E300 - Practice for Sampling Industrial Chemicals.
• Federal Specification PPP-C-2020 - Requirements for Packaging Chemicals.

By referencing ASTM D4360-11(2019), stakeholders ensure rigorous standards for methyl n-amyl ketone in coatings and chemicals industries, facilitating global trade and compliance with international quality expectations.

Standards Content (Sample)

This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D4360 −11 (Reapproved 2019)
Standard Specification for
Methyl n-Amyl Ketone
This standard is issued under the fixed designation D4360; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope D3893 Test Method for Purity of Methyl Amyl Ketone and
Methyl Isoamyl Ketone by Gas Chromatography
1.1 This specification covers methyl n-amyl ketone (98 %
D4052 Test Method for Density, Relative Density, and API
grade) for use in paint, varnish, lacquer, and related products.
Gravity of Liquids by Digital Density Meter
1.2 For specific hazard information and guidance, see the
D5386 Test Method for Color of Liquids Using Tristimulus
supplier’sMaterialSafetyDataSheetformaterialslistedinthis
Colorimetry
specification.
E29 Practice for Using Significant Digits in Test Data to
Determine Conformance with Specifications
1.3 The following applies to all specified limits in this
standard: for purposes of determining conformance with this E300 Practice for Sampling Industrial Chemicals
standard, an observed value or a calculated value shall be 2.2 Federal Specification:
rounded off “to the nearest unit” in the last right-hand digit PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging
of
used in expressing the specification limit, in accordance with
the rounding-off method of Practice E29.
3. Properties
1.4 This international standard was developed in accor-
3.1 Methyl n-amyl ketone shall conform to the following
dance with internationally recognized principles on standard-
requirements:
ization established in the Decision on Principles for the
Development of International Standards, Guides and Recom- Apparent specific gravity
20/20 °C 0.815–0.818
mendations issued by the World Trade Organization Technical
or or
Barriers to Trade (TBT) Committee.
25/25 °C 0.812–0.815
Color, Pt-Co scale, max (Note 1) 10
Distillation, 760 mm Hg, °C
2. Referenced Documents
Initial boiling point, min 147
Dry point, max 153.5
2.1 ASTM Standards:
Water, max, weight % 0.1
D268 Guide for Sampling and Testing Volatile Solvents and
Acidity, as acetic acid, max, weight % 0.02
Chemical Intermediates for Use in Paint and Related
Purity, min, weight % 98
Coatings and Material
NOTE 1—Instrumental Pt-Co color determined by Test Method D5386
D1078 Test Method for Distillation Range of Volatile Or-
has been shown to have no statistically significant difference from Pt-Co
ganic Liquids
color determined by Test Method D1209. However, it is not known
D1209 Test Method for Color of Clear Liquids (Platinum- whether methyl n-amyl ketone was part of the sample set included in the
interlaboratory study.
Cobalt Scale)
D1364 Test Method for Water in Volatile Solvents (Karl
4. Sampling
Fischer Reagent Titration Method)
4.1 The material shall be sampled in accordance with
D1613 Test Method for Acidity in Volatile Solvents and
Practice E300.
Chemical Intermediates Used in Paint, Varnish, Lacquer,
and Related Products
5. Test Methods
5.1 The
...