ASTM D901-91(1997)
(Test Method)Standard Test Methods for Askarels (Withdrawn 2004)
Standard Test Methods for Askarels (Withdrawn 2004)
SCOPE
1.1 These methods cover procedures for testing askarels that are used in transformers and certain other electrical apparatus as an insulating and cooling medium. These methods are generally suitable for specification acceptance, factory control, reference testing, and research. The procedures appear in the following sections: Test MethodASTM Designation of Test MethodChemical Tests:Neutralization NumberD664, D974Water ContentD1533Scavenger ContentD1701Chrlorine Compounds, HydrolyzableD1820, D2441Chlorides, InorganicD1821Thermal StabilityD1936Electrical Tests:Dielectric Breakdown VoltageD877Dissipation Factor and Relative PermittivityD924Specific ResistanceD1169Physical Tests:ViscosityD88, D455Fire PointD92Pour PointD97SamplingD923Refractive IndexD1218Visual ExaminationD1702Specific GravityD1810Coefficient of Thermal ExpansionD1903ColorD2129Polychlorinated Biphenyls in Environmental MaterialsD3304Polychlorinated Biphenyls in MineralInsulating Oils by Gas ChromatographyD4059
For askarels having a Saybolt Universal viscosity of over 110 s at 100oF, modifications of certain test procedures are necessary.
1.2 As a precaution, insulating systems incorporating askarels and cellulose or other organic materials should be purged to remove any traces of flammable gases by bubbling dry nitrogen through the askarel and flushing the gas space with dry nitrogen before any work is performed on the apparatus.
1.3 Current governmental regulations prohibit the manufacture and sale of polychlorinated biphenyls (PCBs). This method serves as a reference for all askarels, PCB and non-PCB.
Note 1--Various materials have been used successfully in taking, storing, and testing samples of askarels. Until experience has developed a strong preference, materials referred to in these methods will be understood to be approved but not specified.
Note 2--Methods for handling and disposal of askarels and askarel-impregnated materials are given in a recent ANSI Committee C-107 Guide, Guidelines for Handling and Disposal of Capacitor and Transformer-Grade Askarels Containing Polychlorinated Biphenyls.
Note 3--For specifications for askarels, see Specifications D2233 and D2283.
1.4 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in 1.2.
General Information
Standards Content (Sample)
NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
Designation: D 901 – 91 (Reapproved 1997)
Standard Test Methods for
Askarels
This standard is issued under the fixed designation D 901; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope 1.3 Current governmental regulations prohibit the manufac-
ture and sale of polychlorinated biphenyls (PCBs). This
1.1 These test methods cover procedures for testing askarels
method serves as a reference for all askarels, PCB and
that are used in transformers and certain other electrical
non-PCB.
apparatus as an insulating and cooling medium. These methods
are generally suitable for specification acceptance, factory
NOTE 1—Various materials have been used successfully in taking,
control, reference testing, and research. The procedures appear
storing, and testing samples of askarels. Until experience has developed a
strong preference, materials referred to in these methods will be under-
in the following sections:
stood to be approved but not specified.
ASTM Designation of
NOTE 2—Methods for handling and disposal of askarels and askarel-
Test Method Test Method
Chemical Tests: impregnated materials are given in a recent ANSI Committee C-107
Neutralization Number D 664, D974
Guide, Guidelines for Handling and Disposal of Capacitor and
Water Content D 1533
Transformer-Grade Askarels Containing Polychlorinated Biphenyls.
Scavenger Content D 1701
NOTE 3—For specifications for askarels, see Specifications D 2233 and
Chlorine Compounds, Hydrolyzable D 1820, D2441
D 2283.
Chlorides, Inorganic D 1821
Thermal Stability D 1936
1.4 This standard does not purport to address all of the
Electrical Tests:
safety concerns, if any, associated with its use. It is the
Dielectric Break- D 877
down Voltage
responsibility of the user of this standard to establish appro-
Dissipation Factor and Relative Per- D 924
priate safety and health practices and determine the applica-
mittivity
bility of regulatory limitations prior to use. Specific precau-
Specific Resistance D 1169
Physical Tests: tionary statements are given in 1.2.
Viscosity D 88, D455
Fire Point D 92
2. Referenced Documents
Pour Point D 97
Sampling D 923 2.1 ASTM Standards:
Refractive Index D 1218 3
D 88 Test Method for Saybolt Viscosity
Visual Examination D 1702
D 92 Test Method for Flash and Fire Points by Cleveland
Specific Gravity D 1810
Coefficient of Thermal Expansion D 1903 Open Cup
Color D 2129
D 97 Test Method for Pour Point of Petroleum Products
Polychlorinated Biphenyls in Envi- D 3304
D 445 Test Method for Kinematic Viscosity of Transparent
ronmental Materials
Polychlorinated Biphenyls in Mineral D 4059
and Opaque Liquids (and the Calculation of Dynamic
Insulating Oils by Gas Chroma- 4
Viscosity)
tography
D 664 Test Method for Acid Number of Petroleum Products
For askarels having a Saybolt Universal viscosity of over
by Potentiometric Titration
110 s at 100°F, modifications of certain test procedures are
D 877 Test Method for Dielectric Breakdown Voltage of
necessary.
Insulating Liquids Using Disk Electrodes
1.2 As a precaution, insulating systems incorporating
D 923 Test Methods for Sampling Electrical Insulating
askarels and cellulose or other organic materials should be
Liquids
purged to remove any traces of flammable gases by bubbling
D 924 Test Method for Dissipation Factor (or Power Factor)
dry nitrogen through the askarel and flushing the gas space
and Relative Permittivity (Dielectric Constant) of Electri-
with dry nitrogen before any work is performed on the
cal Insulating Liquids
apparatus.
1 2
These methods are under the jurisdiction of ASTM Committee D-27 on Available from the American National Standards Institute, 11 West 42nd Street,
Electrical Insulating Liquids and Gasesand are the direct responsibility of Subcom- 13th Floor, New York, NY 10036.
mittee D27.02on Synthetics. Annual Book of ASTM Standards, Vol 04.04.
Current edition approved Aug. 15, 1991. Published November 1991. Originally Annual Book of ASTM Standards, Vol 05.01.
published as D 901 – 46 T. Last previous edition D 901 – 86. Annual Book of ASTM Standards, Vol 10.03.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
D 901
D 974 Test Method for Acid and Base Number by Color- 5.2 Since askarel is not subject to deterioration by oxida-
Indicator Titration tion, small changes in the neutralization value of used askarels
D 1169 Test Method for Specific Resistance (Resistivity) of may indicate the solution of basic or acidic materials from the
Electrical Insulating Liquids various solid materials in contact with the askarel or the
D 1218 Test Method for Refractive Index and Refractive deterioration of such soluble materials to form basic or acidic
Dispersion of Hydrocarbon Liquids materials. A large change in acidity may indicate decomposi-
D 1533 Test Method for Water in Insulating Liquids (Karl tion of the askarel by an electric arc.
Fischer Reaction Method)
6. Procedure
D 1701 Test Methods for Scavenger Content of Askarels
6.1 Determine the neutralization number in accordance with
D 1702 Method for Visual Examination of Used Chlori-
nated Aromatic Hydrocarbons (Askarels) in the Field Test Method D 974. Neutralization number may also be deter-
mined in accordance with Test Method D 664 if it is desired to
D 1810 Test Method for Specific Gravity of Askarels
D 1820 Test Method for Hydrolyzable Chlorine Com- use an electrometric titration method.
pounds in Chlorinated Aromatic Hydrocarbons (Askarels)
5 WATER CONTENT
D 1821 Test Method for Inorganic Chlorides in Askarels
D 1903 Test Method for Coefficient of Thermal Expansion
7. Definition
of Electrical Insulating Liquids of Petroleum Origin, and
7.1 water content of an askarel—that amount of water,
Askarels
expressed in parts per million, by weight which is present in
D 1936 Test Method for Thermal Stability of Chlorinated
the liquid.
Aromatic Hydrocarbons (Askarels)
D 2129 Test Method for Color of Water White Electrical
8. Significance and Use
Insulating Liquids
8.1 The test is significant in that it will show the presence of
D 2233 Specification for Chlorinated Aromatic Hydrocar-
water which may not be evident from electrical tests.
bons (Askarels) for Capacitors
8.2 Changes in water content of an askarel in service may be
D 2283 Specification for Chlorinated Aromatic Hydrocar-
5 indicative of undesirable operating conditions requiring cor-
bons (Askarels) for Transformers
rection.
D 2441 Test Method for Hydrolyzable Chlorine Com-
pounds in Chlorinated Aromatic Hydrocarbons (Askarels)
9. Procedure
by Refluxing
9.1 Determine the water content of askarel in accordance
D 2864 Terminology Relating to Electrical Insulating Liq-
with Test Methods D 1533.
uids and Gases
D 3304 Method for Analysis of Environmental Materials
SCAVENGER CONTENT
for Polychlorinated Biphenyls
D 4059 Test Method for Analysis of Polychlorinated Biphe- 10. Description of Term Specific to This Standard
nyls in Insulating Liquids by Gas Chromatography
10.1 scavenger—askarels are decomposed by an electric arc
with the evolution of HCl gas. A scavenger is or may be added
3. Terminology Definitions
to the askarel which reacts chemically with HCl gas to form a
3.1 For definitions of terms not defined in these methods, nonvolatile reaction product, serving a useful function in
see Terminology D 2864. improved preservation of the arced apparatus.
CHEMICAL TEST METHODS
11. Significance and Use
11.1 Measurement of scavenger content indicates the
NEUTRALIZATION NUMBER
amount of protection available against arc-formed gases and
permits estimation of the amount of make-up additive required.
4. Definitions
12. Procedure
4.1 total acid number—the number of milligrams of potas-
sium hydroxide (KOH) required to react with1gof askarel
12.1 Determine the scavenger content of askarels in accor-
when tested as prescribed.
dance with Test Methods D 1701.
4.2 strong base number—the number of milligrams of KOH
CHLORINE COMPOUNDS,HYDROLYZABLE
equivalent to the acid required to react with1gof askarel when
tested as prescribed.
13. Scope
13.1 This method provides a quantitative measure of the
5. Significance and Use
stability of the askarel to hydrolysis under prescribed test
5.1 In the inspection of unused askarels, the neutralization
methods.
value is of importance as a quality index of purity.
14. Significance and Use
14.1 Unstable compounds, if present in amounts beyond the
Discontinued, see 1990 Annual Book of ASTM Standards, Vol 10.03. acceptable limit, may be deleterious to askarel-filled apparatus.
NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
D 901
15. Procedure 24. Referee Tests
15.1 Determine the hydrolyzable chlorine compounds as 24.1 For referee tests, make breakdowns in an atmosphere
parts per million of chloride ion in accordance with Test having a relative humidity not exceeding 55 %. At higher
Method D 1820. Where service conditions require the detec- humidities, the dielectric breakdown voltage of the test
tion of certain chlorine addition compounds that do not respond samples may be materially lowered by the absorption of
fully to the temperature used in Test Method D 1820, Test atmosphere moisture.
Method D 2441 may be used.
DISSIPATION FACTOR AND PERMITTIVITY
CHLORIDES,INORGANIC
25. Definition
16. Significance and Use
25.1 For definitions of dissipation and relative permittivity
16.1 In the presence of water, chlorides can ionize. Their refer to Definitions D 2864.
corrosive action can then be detrimental to the life of the
26. Significance and Use
apparatus in which the askarel is used.
26.1 The dissipation factor of an askarel is essentially
17. Procedure
proportional to the energy dissipated as heat in the askarel,
other factors remaining constant. In many types of electrical
17.1 Determine the inorganic chlorides in accordance with
equipment, it is necessary or highly desirable to keep the heat
Test Method D 1821.
loss in the dielectric to a minimum. Since askarel is not subject
to oxidation, an increased dissipation factor value may be
THERMAL STABILITY
attributed to the presence of dissolved polar contaminants in
the askarel.
18. Description of Term Specific to This Standard
26.2 The relative permittivity of an askarel is a measure of
18.1 thermal stability of chlorinate aromatic hydrocarbon
its relative ability to store electrostatic energy. It is of consid-
materials—their resistance to thermal decomposition which
erable importance in the design of certain electrical apparatus
results in the liberation of chloride ions.
and may also be useful as an indication of the composition and
purity of the askarel.
19. Significance and Use
19.1 Adequate thermal stability is required for satisfactory
27. Procedure
use of these materials as dielectric fluids.
27.1 Determine the dissipation factor and relative permit-
tivity of askarels in accordance with Test Method D 924,
20. Procedure
observing the precaution that in cells used for testing askarels,
20.1 Determine the thermal stability of the askarel as parts
phenolic insulation should not be used at any point where it
per million of reactive chlorine in accordance with Test
comes in contact with the liquid.
Method D 1936.
SPECIFIC RESISTANCE
ELECTRICAL TEST METHODS
28. Definition
DIELECTRIC BREAKDOWN VOLTAGE
28.1 specific resistance (resistivity)—the ratio of the d-c
potential gradient in volts per centimetre paralleling the current
21. Definitions
flow within the specimen, to the current density in amperes per
21.1 Refer to Definitions D 2864.
square centimetre at a given instant of time and under
prescribed conditions. This is numerically equal to the resis-
22. Significance and Use
tance between opposite faces of a centimetre cube of the liquid.
The units are ohm-centimetres.
22.1 The dielectric breakdown voltage of an askarel is of
importance as a measure of its ability to withstand electrical
29. Significance and Use
stress without failure. It may also indicate the presence of
contaminating materials, such as water, conducting solid par-
29.1 The resistivity of a liquid is a measure of its electrical
ticles, dissolved contaminants, or the decomposition products insulating properties under conditions comparable to those of
resulting from an electric arc. A high dielectric breakdown
the test. High resistivity reflects low content of free ions and
voltage, however, is not a certain indication of the absence of ion-forming particles, and normally indicates a low concentra-
all contaminants.
tion of conductive contaminants.
23. Procedure 30. Procedure
23.1 Except as stated in Section 24, determine the dielectric 30.1 Determine the specific resistance (resistivity) of elec-
breakdown voltage of askarels in accordance with Test Method trical insulating liquids in accordance with Test Method
D 877. D 1169.
NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
D 901
PHYSICAL TEST METHODS being seriously impeded. The pour point of a capacitor askarel
is also of importance in the design of certain types of capacitors
VISCOSITY
for low-temperature applications.
31. Description of Term Specific to This Standard
39. Procedure
31.1 viscosity of an askarel—its resistance to uniformly
39.1 Determine the pour point in accordance with Test
continuous flow, without turbulence, inertia, or other forces,
Method D 97.
and is usually determined by measuring the time of flow of a
SAMPLING
given quantity of the liquid under controlled conditions.
Viscosity of askarels varies with temperature, and for that
40. Description of Term Specific to This Standard
reason is always designated at a specified temperature.
40.1 sampling—the obtaining of an adequate portion that is
32. Significance and Use representative of an entire quantity or of a particular cross
section of material. In some cases the detection of contami-
32.1 Viscosity is a controlling factor in the dissipation of
nants that are not ordinarily dispersed uniformly in an askarel,
heat by convection in insulating and cooling liquids. This is
su
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