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ASTM D5702-02

(Practice)

Standard Practice for Field Sampling of Coating Films for Analysis for Heavy Metals

Standard Practice for Field Sampling of Coating Films for Analysis for Heavy Metals

SCOPE
1.1 This practice covers a method to control the removal of samples of coating films from substrates for subsequent laboratory analysis for heavy metal content on a mass basis. This technique can be used in the field, the fabricating shop, or laboratory.
1.2 The values stated in SI units are to be regarded as the standard. The values in parentheses are for information only.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard information, see Section 5, Note 1 and Note 3.

General Information

Status
Historical
Publication Date
09-Jan-2002
ICS
13.040.01 - Air quality in general
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.46 - Industrial Protective Coatings
Current Stage
Ref Project

Relations

Replaces
ASTM D5702-95 - Standard Practice for Field Sampling of Coating Films for Analysis for Heavy Metals
Effective Date
10-Jan-2002
Replaced By
ASTM D5702-07 - Standard Practice for Field Sampling of Coating Films for Analysis for Heavy Metals
Effective Date
01-Jul-2007
Referred By
ASTM D5065-17(2021) - Standard Guide for Assessing the Condition of Aged Coatings on Steel Surfaces
Effective Date
10-Jan-2002
Referred By
ASTM D6206-09(2021) - Standard Practice for Sampling of Coating Films
Effective Date
10-Jan-2002

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ASTM D5702-02 - Standard Practice for Field Sampling of Coating Films for Analysis for Heavy MetalsASTM D5702-02 - Standard Practice for Field Sampling of Coating Films for Analysis for Heavy Metals
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ASTM D5702-02 - Standard Practice for Field Sampling of Coating Films for Analysis for Heavy Metals
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D5702–02
Standard Practice for
Field Sampling of Coating Films for Analysis for Heavy
1
Metals
This standard is issued under the fixed designation D 5702; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope The number and location of samples to be removed must also
be determined to characterize properly the extent of the
1.1 This practice covers a method to control the removal of
presence of hazardous materials, if any, on a structure.
samples of coating films from substrates for subsequent labo-
ratory analysis for heavy metal content on a mass basis. This
4. Materials and Equipment
technique can be used in the field, the fabricating shop, or
4.1 Sample Collection Container—A clean plastic bag or
laboratory.
rigid container comprised of a material such as polyethylene
1.2 The values stated in SI units are to be regarded as the
that will not contaminate the sample.
standard. The values in parentheses are for information only.
4.2 Straight Edge or Ruler.
1.3 This standard does not purport to address all of the
4.3 Knife or Chisel, cleaned and sharpened, for removing
safety concerns, if any, associated with its use. It is the
paint samples.
responsibility of the user of this standard to establish appro-
4.4 Dry Film Thickness Gage, for measuring total coating
priate safety and health practices and determine the applica-
thickness.
bility of regulatory limitations prior to use. For specific hazard
information, see Section 5, Note 1 and Note 3.
5. Procedure
2. Referenced Documents 5.1 Select a sufficient number of areas for coating removal
that properly characterize the coatings on the structure.
2.1 ASTM Standards:
5.1.1 Selection may be based on painting history, knowl-
D 1186 Test Methods for Nondestructive Measurement of
edge of previously applied coatings, prior touch-up and re-
Dry Film Thickness of Nonmagnetic Coatings Applied to
2 painting programs, and other such factors.
a Ferrous Base
5.1.2 Select areas that properly characterize the range of
D 1400 Test Method for Nondestructive Measurement of
thickness found. Dry film thickness can be measured in
DryFilmThicknessofNonconductiveCoatingsAppliedto
2 accordance with Test Methods D 1186, D 1400, or D 4138.
a Nonferrous Metal Base
5.1.3 Remove a minimum of three samples.
D 4138 Test Methods for Measurement of Dry Film Thick-
3 5.2 At each sample site, clean the surface of dirt, dust, or
ness of Protective Coating Systems by Destructive Means
debris.
3. Significance and Use
NOTE 1—Hazardous materials can be present in surface debris and
3.1 Prior to beginning a project that involves the removal, chalk which may be removed during cleaning. Thus, consideration should
be given to collecting this surface debris and chalk for analysis.
cutting, grinding, or burning of paint, it is necessary to
determine if the coating contains hazardous materials, such as
5.3 At each sample site, use a knife and straight edge to
lead, as certain requirements for worker and environmental
scribe the perimeter of a square through the coating film to the
protection may need to be imposed. The presence and quantity
substrate. The square should be of sufficient size to give a one
of hazardous materials in a paint can be determined through
gram sample.
laboratory analysis; however, since the analysis is based on the
3
NOTE 2—Paint with a density of 1.5 g/cm and 250 microns (10 mils)
weight of the specimen, the removal of the sample must be
thick will generate one gram of sample in a square that is 5 cm (2 in.) on
properly controlled to improve the reliability of the test results.
a side assuming 100 percent of the material is collected. Paint density
3
normally ranges from 1.1 to 2.5 g/cm . Adjust the sample size based on
density, thickness and collection efficiency.
1
This practice is under the jurisdiction of ASTM Committee D01 on Paint and
Related Coatings, Materials, and Applications and is the direct responsibility of 5.4 Remove essentially all of the coating within the square
Subcommittee D01.46 on Industrial Protective Coatings.
down to the substrate by scraping, by making closely-spaced
Current edition approved Jan. 10, 2002. Published March 2002. Originally
parallel scribes to disbond ribbons of the coating, or other
published as D 5702 – 95. Last previous edition D 5702 – 95.
2
controlled means that permit collection of all of the film
Annual Book of ASTM Standards, Vol 06.01.
3
Annual Book of ASTM Standards, Vol 06.02.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

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Standard Practice for Field Sampling of Coating Films for Analysis for Heavy Metals

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3.1 Prior to beginning a project that involves the removal, cutting, grinding, or burning of paint, it is necessary to determine if the coating contains hazardous metals, such as lead. If it does, certain requirements for worker and environmental protection may need to be imposed. The presence and quantity of hazardous metals in a paint can be determined through laboratory analysis. Proper sampling protocol is needed to assure the laboratory results represent the actual amount of heavy metal in the coating. The number and location of samples to be removed must also be determined to characterize properly the extent of the presence of hazardous materials, if any, on a structure.
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6.1 Manufacturers increasingly are being asked or required to demonstrate that vapor-phase emissions of chemicals of concern from their products under normal use conditions comply with various voluntary or regulatory acceptance criteria. This process typically requires manufacturers to have their products periodically tested for VOC emissions by independent laboratories using designated reference test methods (for example, Test Method D6007, ISO 16000-9, and ISO 16000-10). To ensure continuing compliance, manufacturers may opt to, or be required to, implement screening tests at the production level.  
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5.1 Studies of indoor air problems are often iterative in nature. A thorough engineering evaluation of a building (1-4)3 is sometimes sufficient to identify likely causes of indoor air problems. When these investigations and subsequent remedial measures are not sufficient to solve a problem, more intensive investigations may be necessary.  
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5.1 Effects of Air Change—Air change often accounts for a significant portion of the heating or air-conditioning load of a building. It also affects the moisture and contaminant balances in the building. Moisture-laden air passing through the building envelope can permit condensation and cause material degradation. An appropriate level of ventilation is required in all buildings; one should consult ASHRAE Standard 62 to determine the ventilation requirements of a building.  
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5.6.4 Unattended sample collection,  
5.6.5 Analysis of samples from multiple sites with one analytical system,  
5.6.6 Collection of replicate samples for ...
SCOPE
1.1 This test method2 presents a procedure for sampling and determination of non-methane organic compounds (NMOC) in ambient, indoor, or workplace atmospheres.  
1.2 This test method describes the collection of integrated whole air samples in silanized or other passivated stainless steel canisters, and their subsequent laboratory analysis.  
1.2.1 This test method describes a procedure for sampling in canisters at final pressures above atmospheric pressure (pressurized sampling).  
1.3 This test method employs a cryogenic trapping procedure for concentration of the NMOC prior to analysis.  
1.4 This test method describes the determination of the NMOC by the flame ionization detection (FID), without the use of gas chromatographic columns and other procedures necessary for species separation.  
1.5 The range of this test method is from 20 ppb C to 10 000 ppb C (1, 2).3  
1.6 This test method has a larger uncertainty for some halogenated or oxygenated hydrocarbons than for simple hydrocarbons or aromatic compounds. This is especially true if there are high concentrations of chlorocarbons or chlorofluorocarbons present.  
1.7 The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units that are provided for information only and are not considered standard.  
1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.9 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Techn...

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ASTM
ASTM D5702-18(2022)(Practice)
Standard Practice for Field Sampling of Coating Films for Analysis for Heavy Metals

SIGNIFICANCE AND USE
3.1 Prior to beginning a project that involves the removal, cutting, grinding, or burning of paint, it is necessary to determine if the coating contains hazardous metals, such as lead. If it does, certain requirements for worker and environmental protection may need to be imposed. The presence and quantity of hazardous metals in a paint can be determined through laboratory analysis. Proper sampling protocol is needed to assure the laboratory results represent the actual amount of heavy metal in the coating. The number and location of samples to be removed must also be determined to characterize properly the extent of the presence of hazardous materials, if any, on a structure.
SCOPE
1.1 This practice covers a method to control the removal of samples of coating films from substrates for subsequent laboratory analysis for heavy metal content on a mass basis. This technique can be used in the field, the fabricating shop, or laboratory.  
1.2 The values stated in SI units are to be regarded as the standard. The values in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard information, see Section 5, Note 1, and Note 3.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM D5954-22a(Test Method)
Standard Test Method for Mercury Sampling and Measurement in Gaseous Fuels by Atomic Absorption Spectroscopy

SIGNIFICANCE AND USE
5.1 This test method can be used to measure the level of mercury in any gaseous fuel (as defined by Terminology D4150) for purposes such as determining compliance with regulations, studying the effect of various abatement procedures on mercury emissions, checking the validity of direct instrumental measurements, and verifying that mercury concentrations are below those required for gaseous fuel processing and operations.  
5.2 Adsorption of the mercury on gold-coated sorbent can remove interferences associated with the direct measurement of mercury in the presence of high concentrations of organic compounds. It preconcentrates the mercury before analysis, thereby offering measurement of ultra-low average concentrations in a gas stream over a long time span. It avoids the cumbersome use of liquid spargers with on-site sampling and eliminates contamination problems associated with the use of potassium permanganate solutions.5,6,7
SCOPE
1.1 This test method covers the determination of total mercury in gaseous fuels at concentrations down to 0.5 ng/m3. It includes separate procedures for both sampling and atomic absorption spectrophotometric determination of mercury. This procedure detects both inorganic and organic forms of mercury.  
1.2 Units—The values stated in SI units are to be regarded as the standard.  
1.3 Warning—Mercury has been designated by many regulatory agencies as a hazardous material that can cause serious medical issues. Mercury, or its vapor, has been demonstrated to be hazardous to health and corrosive to materials. Caution should be taken when handling mercury and mercury containing products. See the applicable product Safety Data Sheet (SDS) for additional information. Users should be aware that selling mercury or mercury containing products, or both, into your state or country may be prohibited by law.  
1.4 This standard does not purport to address all of the safety concerns associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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