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ASTM D5627-94(2009)

(Test Method)

Standard Test Method for Water Extractable Residue from Particulate Ion-Exchange Resins

Standard Test Method for Water Extractable Residue from Particulate Ion-Exchange Resins

SIGNIFICANCE AND USE
The presence of water extractables in ion-exchange resins can cause fouling of other materials downstream and contamination of process water. The quantity of water extractables is sometimes used as a specification to indicate resin quality, and typical values are 0.01 to 0.1 %.
It is recognized that this test method may not remove all potential sloughage products and does not measure volatile compounds. More extensive extraction and identification of compounds may be needed in specific cases.
SCOPE
1.1 This test method covers the measurement of water soluble extractable residue from particulate ion-exchange resins based on elevated temperature extraction and gravimetric determination of residue.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
30-Apr-2009
ICS
13.060.50 - Examination of water for chemical substances
Technical Committee
D19 - Water
Drafting Committee
D19.08 - Membranes and Ion Exchange Materials
Current Stage
Ref Project

Relations

Replaces
ASTM D5627-94(2004) - Standard Test Method for Water Extractable Residue from Particulate Ion-Exchange Resins
Effective Date
01-May-2009
Replaced By
ASTM D5627-94(2009)e1 - Standard Test Method for Water Extractable Residue from Particulate Ion-Exchange Resins
Effective Date
01-May-2009

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ASTM D5627-94(2009) - Standard Test Method for Water Extractable Residue from Particulate Ion-Exchange ResinsASTM D5627-94(2009) - Standard Test Method for Water Extractable Residue from Particulate Ion-Exchange Resins
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ASTM D5627-94(2009) - Standard Test Method for Water Extractable Residue from Particulate Ion-Exchange Resins
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D5627–94(Reapproved 2009)
Standard Test Method for
Water Extractable Residue from Particulate Ion-Exchange
Resins
This standard is issued under the fixed designation D5627; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope contact time, the concentration of soluble material in the
aqueous phase is measured gravimetrically after filtration.
1.1 This test method covers the measurement of water
soluble extractable residue from particulate ion-exchange res-
5. Significance and Use
ins based on elevated temperature extraction and gravimetric
5.1 The presence of water extractables in ion-exchange
determination of residue.
resins can cause fouling of other materials downstream and
1.2 The values stated in SI units are to be regarded as
contamination of process water. The quantity of water extract-
standard. No other units of measurement are included in this
ables is sometimes used as a specification to indicate resin
standard.
quality, and typical values are 0.01 to 0.1 %.
1.3 This standard does not purport to address all of the
5.2 It is recognized that this test method may not remove all
safety concerns, if any, associated with its use. It is the
potential sloughage products and does not measure volatile
responsibility of the user of this standard to establish appro-
compounds. More extensive extraction and identification of
priate safety and health practices and determine the applica-
compounds may be needed in specific cases.
bility of regulatory limitations prior to use.
6. Interferences
2. Referenced Documents
2 6.1 The hygroscopic nature of some extracted compounds
2.1 ASTM Standards:
can make it difficult to obtain a constant weight. Other
D1129 Terminology Relating to Water
extraction times and temperatures may give results that are not
D1193 Specification for Reagent Water
comparable to these.
D2187 Test Methods for Physical and Chemical Properties
of Particulate Ion-Exchange Resins
7. Apparatus
D2687 Practices for Sampling Particulate Ion-Exchange
7.1 Funnel, 60 mL with coarse frit.
Materials
7.2 Filtration assembly.
D2777 Practice for Determination of Precision and Bias of
7.3 Glass fiber filters, without binder, pre-rinsed with wa-
Applicable Test Methods of Committee D19 on Water
ter.
7.4 Weighing vessel—Platinum, nickel, or aluminum may
3. Terminology
beusedsolongasthereisnoattackbythesampleandconstant
3.1 Definitions:
weight can be achieved.
3.1.1 For definitions of terms used in this test method, refer
7.5 Water bath, for use at 60 6 1°C.
to Terminology D1129.
8. Reagents
4. Summary of Test Method
8.1 Purity of Reagents—Reagent grade chemicals shall be
4.1 A sample of particulate ion exchange material is con-
used in all tests. Unless otherwise indicated, it is intended that
tacted with water at an elevated temperature. After a specified
all reagents shall conform to the specifications of the Commit-
tee onAnalytical Reagents of theAmerican Chemical Society,
This test method is under the jurisdiction of ASTM Committee D19 on Water
and is the direct responsibility of Subcommittee D19.08 on Membranes and Ion
Exchange Materials.
Current edition approved May 1, 2009. Published June 2009. Originally
approved in 1994. Last previous edition approved in 2004 as D5627 – 94 (2004).
DOI: 10.1520/D5627-94R09.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on Gelman Type A/E, Millipore Type AP40, Whatman GF/C, or equivalent, have
the ASTM website. been found suitable for this purpose.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
D5627–94 (2009)
where such specifications are available. Other grades may be 11. Calculation
used, provided it is first ascertained that the reagent is of
11.1 Calculate the water extractable residue, in percent, for
sufficiently high purity to permit its use without lessening the
each of the two sample portions as follows:
accuracy of the determination.
~A 2 B! 3 200
8.2 Purity of Water—Unless otherwise indicated, references
Water Extractable Residue, % wet basis 5
C
to water shall be understood to mean reagent water conforming
to Specification D1193, Type I or lI.
~A 2 B! 3 200
Water Extractable Residue, % dry basis 5
D
9. Sampling
C 3
S D
9.1 Collect the sample in accordance with Practices D2687.
In-service resins are taken after reg
...

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5.1 The incidental conversion of organic material to trihalomethanes and other volatile organohalides during chlorination of water is a possible health hazard and is the object of much research. This test method can be used as a rapid, simple means for determining many volatile organohalides in raw and processed water.
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5.1 The extensive and widespread use of organochlorine pesticides and PCBs has resulted in their presence in all parts of the environment. These compounds are persistent and may have adverse effects on the environment. Thus, there is a need to identify and quantitate these compounds in water samples.
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1.3 Chlordane, toxaphene, and Aroclor products (polychlorinated biphenyls) are multicomponent materials. Precision and bias statements reflect recovery of these materials dosed into water samples. The precision and bias statements may not apply to environmentally altered materials or to samples containing complex mixtures of polychlorinated biphenyls (PCBs) and organochlorine pesticides.  
1.4 For compounds other than those listed in 1.1 or for other sample sources, the analyst must demonstrate the applicability of this test method by collecting precision and bias data on spiked samples (groundwater, tap water) (4) and provide qualitative confirmation of results by gas chromatography/mass spectrometry (GC/MS) (5) or by GC analysis using dissimilar columns.  
1.5 This test method is restricted to use by or under the supervision of analysts experienced in the use of GC and in the interpretation of gas chromatograms. Each analyst must demonstrate the ability to generate acceptable results using the procedure described in Section 13.  
1.6 Analytes that are not separated chromatographically, (analytes that have very similar retention times) cannot be individually identified and measured in the same calibration mixture or water sample unless an alternative technique for identification and quantitation exists (see 13.4).  
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5.1 This test method is used for determination of the carbon content of water from a variety of natural, domestic, and industrial sources. In its most common form, this test method is used to measure organic carbon as a means of monitoring organic pollutants in high purity and drinking water. These measurements are also used in monitoring waste treatment processes.  
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1.1 This practice covers general guidance applicable to certain test methods for the qualitative and quantitative determination of specific organic compounds, or classes of compounds, in water by direct aqueous injection gas chromatography (1, 2, 3, 4).2  
1.2 Volatile organic compounds at aqueous concentrations greater than about 1 mg/L can generally be determined by direct aqueous injection gas chromatography.  
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4.1 Most waters rarely contain more than trace concentrations of cobalt from natural sources. Although trace amounts of cobalt seem to be essential to the nutrition of some animals, large amounts have pronounced toxic effects on both plant and animal life.
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1.1 These test methods cover the determination of dissolved and total recoverable cobalt in water and wastewater 2 by atomic absorption spectrophotometry. Three test methods are included as follows:    
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Standard Test Method for Elements in Water by Direct-Current Plasma Atomic Emission Spectroscopy

SIGNIFICANCE AND USE
5.1 This test method is useful for the determination of element concentrations in many natural waters. It has the capability for the simultaneous determination of up to 15 separate elements. High analysis sensitivity can be achieved for some elements, such as boron and vanadium.
SCOPE
1.1 This test method covers the determination of dissolved and total recoverable elements in water, which includes drinking water, lake water, river water, sea water, snow, and Type II reagent water by direct current plasma atomic emission spectroscopy (DCP).  
1.2 The information on precision and bias may not apply to other waters.  
1.3 This test method is applicable to the 15 elements listed in Annex A1 (Table A1.1) and covers the ranges in Table 1.  
1.4 This test method is not applicable to brines unless the sample matrix can be matched or the sample can be diluted by a factor of 200 up to 500 and still maintain the analyte concentration above the detection limit.  
1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM D3645-15(2023)(Test Method)
Standard Test Methods for Beryllium in Water

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4.1 These test methods are significant because the concentration of beryllium in water must be measured accurately in order to evaluate potential health and environmental effects.
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1.1 These test methods cover the determination of dissolved and total recoverable beryllium in most waters and wastewaters:    
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Sections  
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10 μg/L to 500 μg/L  
7 to 17  
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18 to 26  
1.2 The analyst should direct attention to the precision and bias statements for each test method. It is the user's responsibility to ensure the validity of these test methods for waters of untested matrices.  
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Standard Test Methods for Selenium in Water

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4.1 In most natural waters selenium concentrations seldom exceed 10 μg/L. However, the runoff from certain types of seleniferous soils at various times of the year can produce concentrations as high as several hundred micrograms per litre. Additionally, industrial contamination can be a significant source of selenium in rivers and streams.  
4.2 High concentrations of selenium in drinking water have been suspected of being toxic to animal life. Selenium is a priority pollutant and all public water agencies are required to monitor its concentration.  
4.3 These test methods determine the dominant species of selenium reportedly found in most natural and wastewaters, including selenities, selenates, and organo-selenium compounds.
SCOPE
1.1 These test methods cover the determination of dissolved and total recoverable selenium in most waters and wastewaters. Both test methods utilize atomic absorption procedures, as follows:    
Sections  
Test Method A—Gaseous Hydride AAS2, 3  
7 – 16  
Test Method B—Graphite Furnace AAS  
17 – 26  
1.2 These test methods are applicable to both inorganic and organic forms of dissolved selenium. They are applicable also to particulate forms of the element, provided that they are solubilized in the appropriate acid digestion step. However, certain selenium-containing heavy metallic sediments may not undergo digestion.  
1.3 These test methods are most applicable within the following ranges:    
Test Method A—Gaseous Hydride AAS2, 3  
1 μg/L to 20 μg/L  
Test Method B—Graphite Furnace AAS  
2 μg/L to 100 μg/L
These ranges may be extended (with a corresponding loss in precision) by decreasing the sample size or diluting the original sample, but concentrations much greater than the upper limits are more conveniently determined by flame atomic absorption spectrometry.  
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