ASTM G189-07
(Guide)Standard Guide for Laboratory Simulation of Corrosion Under Insulation
Standard Guide for Laboratory Simulation of Corrosion Under Insulation
SCOPE
1.1 This guide covers the simulation of corrosion under insulation (CUI), including both general and localized attack, on insulated specimens cut from pipe sections exposed to a corrosive environment usually at elevated temperature. It describes a CUI exposure apparatus (hereinafter referred to as a CUI-Cell), preparation of specimens, simulation procedures for isothermal or cyclic temperature, or both, and wet/dry conditions, which are parameters that need to be monitored during the simulation and the classification of simulation type.
1.2 The application of this guide is broad and can incorporate a range of materials, environments and conditions that are beyond the scope of a single test method. The apparatus and procedures contained herein are principally directed at establishing acceptable procedures for CUI simulation for the purposes of evaluating the corrosivity of CUI environments on carbon and low alloy pipe steels, and may possibly be applicable to other materials as well. However, the same or similar procedures can also be utilized for the evaluation of (1) CUI on other metals or alloys, (2) anti-corrosive treatments on metal surfaces, and (3) the potential contribution of thermal insulation and its constituents on CUI. The only requirements are that they can be machined, formed or incorporated into the CUI-Cell pipe configuration as described herein.
1.3 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
General Information
Standards Content (Sample)
NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: G189 − 07
StandardGuide for
Laboratory Simulation of Corrosion Under Insulation
This standard is issued under the fixed designation G189; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope priate safety and health practices and determine the applica-
bility of regulatory limitations prior to use.
1.1 This guide covers the simulation of corrosion under
insulation (CUI), including both general and localized attack,
2. Referenced Documents
on insulated specimens cut from pipe sections exposed to a
2.1 ASTM Standards:
corrosive environment usually at elevated temperature. It
A106/A106MSpecification for Seamless Carbon Steel Pipe
describes a CUI exposure apparatus (hereinafter referred to as
for High-Temperature Service
a CUI-Cell), preparation of specimens, simulation procedures
C552Specification for Cellular Glass Thermal Insulation
for isothermal or cyclic temperature, or both, and wet/dry
C871Test Methods for ChemicalAnalysis of Thermal Insu-
conditions, which are parameters that need to be monitored
lationMaterialsforLeachableChloride,Fluoride,Silicate,
during the simulation and the classification of simulation type.
and Sodium Ions
1.2 The application of this guide is broad and can incorpo-
D1193Specification for Reagent Water
rate a range of materials, environments and conditions that are
G1Practice for Preparing, Cleaning, and Evaluating Corro-
beyond the scope of a single test method. The apparatus and
sion Test Specimens
procedures contained herein are principally directed at estab-
G3Practice for Conventions Applicable to Electrochemical
lishing acceptable procedures for CUI simulation for the
Measurements in Corrosion Testing
purposes of evaluating the corrosivity of CUI environments on
G5Reference Test Method for Making Potentiostatic and
carbon and low alloy pipe steels, and may possibly be
Potentiodynamic Anodic Polarization Measurements
applicable to other materials as well. However, the same or
G15Terminology Relating to Corrosion and CorrosionTest-
similarprocedurescanalsobeutilizedfortheevaluationof (1)
ing (Withdrawn 2010)
CUI on other metals or alloys, (2) anti-corrosive treatments on
G31PracticeforLaboratoryImmersionCorrosionTestingof
metal surfaces, and (3) the potential contribution of thermal
Metals
insulation and its constituents on CUI. The only requirements
G46Guide for Examination and Evaluation of Pitting Cor-
are that they can be machined, formed or incorporated into the
rosion
CUI-Cell pipe configuration as described herein.
G59Test Method for Conducting Potentiodynamic Polariza-
tion Resistance Measurements
1.3 The values stated in inch-pound units are to be regarded
G102Practice for Calculation of Corrosion Rates and Re-
as standard. The values given in parentheses are mathematical
lated Information from Electrochemical Measurements
conversions to SI units that are provided for information only
and are not considered standard.
3. Terminology
1.4 This standard does not purport to address all of the
3.1 The terminology used herein, if not specifically defined
safety concerns, if any, associated with its use. It is the
otherwise, shall be construed to be in accordance with Termi-
responsibility of the user of this standard to establish appro-
nology G15.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
This guide is under the jurisdiction ofASTM Committee G01 on Corrosion of contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Metals and is the direct responsibility of Subcommittee G01.11 on Electrochemical Standards volume information, refer to the standard’s Document Summary page on
Measurements in Corrosion Testing. the ASTM website.
Current edition approved Feb. 15, 2007. Published March 2007. DOI: 10.1520/ The last approved version of this historical standard is referenced on
G0189-07. www.astm.org.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
G189 − 07
NOTE 1—The actual CUI corrosion rates can be in excess of the those obtain in conventional laboratory immersion exposures.
FIG. 1 Comparison of Actual Plant CUI Corrosion Rates Measurements (Open Data Points Shown is for Plant CUI) with Laboratory Cor-
rosion Data Obtained in Open and Closed Systems
3.2 Definitions of Terms Specific to This Standard: or cyclic temperature and under wet or wet/dry conditions
3.2.1 corrosion under insulation (CUI)—the corrosion of simulating desired conditions in service. Comparison of the
steel or other materials under thermal insulation due to the measured corrosion rates from exposures conducted with
presence of water, oxygen and/or other corrodants. various surface treatments on steel and/or with various insula-
tive materials with corrosion rates obtained with bare steel
3.2.2 control condition—an exposure condition using a
underthecontrolconditionprovidesthebasisforassessmentof
pre-selected environment without the inclusion of inhibitors,
protection efficiency. A value of protection efficiency of less
protective treatments, or additives to the thermal insulation or
than1.0indicatesreductionintheseverityofcorrosionrelative
exposureenvironment.Itisselectedtoprovidebaselinedatato
to the control condition whereas a value greater than 1.0
which data from other exposure conditions can be compared.
indicates an increase in the severity of corrosion relative to the
3.2.3 protection ratio—ratio of the corrosion rate with the
control condition.
surfacetreatmentorparticularinsulativematerial,orboth,with
that obtained for the control condition.
5. Significance and Use
5.1 The corrosion observed on steel and other materials
4. Summary of Guide
underthermalinsulationisofgreatconcernformanyindustries
4.1 The CUI-Cell consists of three to six ring specimens
including chemical processing, petroleum refining and electric
separated by non-conductive spacers and held together by two
power generation. In most cases, insulation is utilized on
blind flanged pipe sections, one on each end. Thermal insula-
piping and vessels to maintain the temperatures of the operat-
tion is placed around one-half of the evaluation section of the
ing systems for process stabilization and energy conservation.
cellandsealedprovidinganannularspacetoretainacorrosive
However,thesesituationscanalsoprovidetheprerequisitesfor
environment. The other half of the insulation is put in place to
theoccurrenceofgeneralorlocalizedcorrosion,orboth,andin
have proper heat transfer conditions as a typical insulated pipe
stainless steels, stress corrosion cracking. For example, com-
sectionwithinternalheating.Provisionsaregivenhereintouse
bined with elevated temperatures, CUI can sometimes result in
the specimens as corrosion coupons or electrodes in two
aqueous corrosion rates for steel that are greater than those
separateelectrochemicalcells.OnehalfoftheCUI-Cellcanbe
foundinconventionalimmersiontestsconductedineitheropen
used to perform a CUI simulation under the control condition
or closed systems (see Fig. 1). This figure shows actual CUI
while the other can be used to evaluate inhibitors, protective
data determined in the field compared with the corrosion data
coatings or insulative materials.
from fully immersed corrosion coupons tests.
4.2 Corrosion measurements can be made using either mass
loss data (Procedure A) or electrochemical dynamic polariza-
Ashbaugh, W. G., “Corrosion of Metals Under Insulation,” Process Industries
tion resistance methods (Procedure B), or both. This apparatus
Corrosion, Ed. B. J. Moniz andW. I. Pollock,ASTM STP880,West Conshohoken,
canbeusedtoconductlaboratoryevaluationsunderisothermal PA, 1986.
G189 − 07
5.2 This guide provides a technical basis for laboratory 6. Apparatus
simulation of many of the manifestations of CUI. This is an
6.1 TheCUI-Cell cansimulatetheseverityandmodalityof
area where there has been a need for better simulation
corrosion that has been described to occur under thermal
techniques, but until recently, has eluded many investigators.
4,6
insulation. Initiallythiscellwasdevelopedfortheevaluation
Much of the available experimental data is based on field and
of various surface treatments to be applied on the external
inplantmeasurementsofremainingwallthickness.Laboratory
surface of pipe to remediate CUI problems. However,
studies have generally been limited to simple immersion tests
subsequently, this same apparatus has been used successfully
for the corrosivity of leachants from thermal insulation on
to evaluate the influence of various types of thermal insulation
corrosion coupons using techniques similar to those given in
on CUI. In the cell, corrosion is intended to occur on the outer
Practice G31. The field and inplant tests give an indication of
surface of ring specimens machined from a selected material.
corrosion after the fact and can not be easily utilized for
Fig. 2 shows a schematic representation of the CUI-Cell. The
experimental purposes. The use of coupons in laboratory
components of the cell include the following:
immersion tests can give a general indication of corrosion
6.1.1 Blind Flange Sections—TheCUI-Cellconsistsoftwo,
tendencies. However, in some cases, these procedures are
nominal two-inch diameter pipe sections [that is, two-inch
useful in ranking insulative materials in terms of their tenden-
cies to leach corrosive species. However, this immersion nominal diameter pipe material with a thickness of 0.187 in.
techniquedoesnotalwayspresentanaccuraterepresentationof (4.75 mm) as shown in Specification A106/A106M, Grade B,
the actual CUI tendencies experienced in the service due to or alternative material to match that being evaluated by this
differences in exposure geometry, temperature, cyclic simulation]; one for each end of the cell. Each end includes a
temperatures, or wet/dry conditions in the plant and field
bolted flange pair consisting of a weldneck, threaded or lap
environments. joint flange and a blind flange and attached pipe section. Pipe
clampsorothersuitabledevicescanbeusedtoholdtheflanged
5.3 One of the special aspects of the apparatus and meth-
endsandtheringspecimenstogether.Anydeviceisacceptable
odologies contained herein are their capabilities to accommo-
that provide adequate sealing force between the various sec-
dateseveralaspectscriticaltosuccessfulsimulationoftheCUI
tions of the CUI-Cell.
exposure condition. These are: (1) an idealized annular geom-
etry between piping and surrounding thermal insulation, (2) 6.1.2 Ring Specimens—The CUI-Cell consists of six ring
internal heating to produce a hot-wall surface on which CUI specimens that are separated by nonporous, nonconductive
can be quantified, (3) introduction of ionic solutions into the spacers (see Section 7 for more detailed information). The
annular cavity between the piping and thermal insulation, (4) evaluation portion, which includes alternate ring specimens of
control of the temperature to produce either isothermal or
theintendedmaterialandnonconductiverings,isheldtogether
cyclictemperatureconditions,and (5)controlofthedeliveryof by two blind flanged pipe sections on both ends. The two sets
the control or solution to produce wet or wet-dry conditions.
of three ring specimens and spacers should be separated by an
Other simpler methods can be used to run corrosion evalua-
extra thick, nonconductive ring spacer (dam) at the center of
tions on specimens immersed in various solutions and
the CUI-cell.This allows for separate corrosion measurements
leachants from thermal insulation. In some cases, these proce-
to be made on each set of specimens. For electrochemical
dures may be acceptable for evaluation of the contribution of
measurements, each ring specimen should contain an attach-
various factors on corrosion. However, they do not provide
mentscrewforconnectionofelectricalleadstothepotentiostat
accommodation of the above mentioned factors that may be
(Fig. 2). The connections should be made outside of the area
needed for CUI simulation.
exposed to the corrosive environment. The nonconductive
spacers should be made from a machinable, temperature
5.4 With the CUI-Cell, the pipe material, insulation and
resistant, non-conductive material. Machinable polytetrafluo-
environmentcanbeselectedforthedesiredsimulationneeded.
roethylene (PTFE) resins with high melting points are suitable
Therefore, no single standard exposure condition can be
in most cases for use up to about 400 to 450°F (200 to 230°C).
defined. The guide is designed to assist in the laboratory
simulation of (1) the influence of different insulation materials
onCUIthat,insomecases,maycontainmaterialsoradditives,
or both, that can accelerate corrosion, (2) the effect of applied 5
Abayarathna, D.,Ashbaugh, W. G., Kane, R. D., McGowan, N., and Heimann,
or otherwise incorporated inhibitors or protective coatings on
B., “Measurement of Corrosion Under Insulation and Effectiveness of Protective
Coatings,” Corrosion/97, Paper No. 266, NACE International, Houston, Texas,
reducing the extent and severity of CUI. This guide provides
March 1997.
information on CUI in a relatively short time (approximately
Ullrich, O.A., MTI Technical Report No. 7, “Investigation of anApproach for
72 h) as well as providing a means of assessing variation of
Detection of Corrosion Under Insulation,” MTI Project 12, Phase II, Materials
corrosion rate with time and environmental conditions. Technology Institute of the Chemical Process Industries, March 1982.
G189 − 07
NOTE1—TheelectricalconnectionstothespecimensandcontactofthethermocouplemustbemadeoutsideofthewettedportionoftheCUI-Cell(see
Figs. 3 and 4 for more details).
FIG. 2 Schematic of CUI-Cell
6.1.3 Internal Heater and Temperature Controller—The selected based on those materials used in the particular
temperature on the outer surface of the ring specimens is condition(s) of interest. The control condition should use a
achieved via an immersion heater (nominally 0.625 in. (1.6 water resistant molded foam glass thermal insulation in accor-
cm) in diameter) having 400 W located on the inside of the dance with Specification C552 with low concentration of
pipe section mounted through the center of one of the blind chlorides (<40 ppm) and other leachable compounds. For the
flanges using an NPT connection. The temperature of the simulations involving specific surface treatments, solutions or
evaluation section of the
...
Questions, Comments and Discussion
Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.