Standard Classification System and Basis for Specification for Polyamide-Imide (PAI) Molding and Extrusion Materials

ABSTRACT
This classification system covers polyamide-imide materials suitable for injection molding and extrusion. Polyamide-imide materials are classified into groups that are subdivided into classes and grades. These groups are: Group 01 which is suitable for injection molding, Group 02 which is suitable for extrusion, and Group 03 which is for other purposes. Each group is then subdivided into classes such as Class 1 used for general purpose, Class 2 used for wear resistance, Class 3 used for high strength conditions, and Class 0 for other conditions. Different tests shall be conducted in order to determine the following properties of polyamide-imide materials: tensile strength, elongation, flexural strength, flexural modulus, and Izod impact strength.
SCOPE
1.1 This classification system covers polyamide-imide materials suitable for injection molding and extrusion.  
1.2 The properties included in this classification system are those required to identify the compositions covered. It is possible that other requirements are necessary to identify particular characteristics important to specialized applications. The use of suffixes as shown in Section 5 is one way of specifying these requirements.  
1.3 This standard allows for the use of recycled materials provided that specification requirements based upon this classification system are met.  
1.4 This classification system and subsequent line call-out (specification) is intended to be a means of calling out plastics materials used in the fabrication of end items or parts. It is not intended for the selection of materials. Material selection needs to be made by those having expertise in the plastics field after careful consideration of the design and the performance required of the part, the environment to which it will be exposed, the fabrication process to be employed, the inherent properties of the material other than those covered by this classification, and the economics.  
1.5 The values stated in SI units are to be regarded as the standard. (Reporting in inch-pound units is acceptable.)  
1.6 The following precautionary caveat pertains only to the test methods portion, Section 11, of this classification system: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
Note 1: There is no known ISO equivalent to this standard.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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Publication Date
31-Oct-2022
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This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation:D5204 −22
Standard Classification System and Basis for Specification for
1
Polyamide-Imide (PAI) Molding and Extrusion Materials
This standard is issued under the fixed designation D5204; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope* ization established in the Decision on Principles for the
Development of International Standards, Guides and Recom-
1.1 This classification system covers polyamide-imide ma-
mendations issued by the World Trade Organization Technical
terials suitable for injection molding and extrusion.
Barriers to Trade (TBT) Committee.
1.2 The properties included in this classification system are
those required to identify the compositions covered. It is
2. Referenced Documents
possible that other requirements are necessary to identify
2
2.1 ASTM Standards:
particular characteristics important to specialized applications.
D149 Test Method for Dielectric Breakdown Voltage and
The use of suffixes as shown in Section 5 is one way of
DielectricStrengthofSolidElectricalInsulatingMaterials
specifying these requirements.
at Commercial Power Frequencies
1.3 This standard allows for the use of recycled materials
D150 Test Methods forAC Loss Characteristics and Permit-
provided that specification requirements based upon this clas-
tivity (Dielectric Constant) of Solid Electrical Insulation
sification system are met.
D256 Test Methods for Determining the Izod Pendulum
Impact Resistance of Plastics
1.4 This classification system and subsequent line call-out
(specification) is intended to be a means of calling out plastics D257 Test Methods for DC Resistance or Conductance of
Insulating Materials
materials used in the fabrication of end items or parts. It is not
intendedfortheselectionofmaterials.Materialselectionneeds D618 Practice for Conditioning Plastics for Testing
D790 Test Methods for Flexural Properties of Unreinforced
to be made by those having expertise in the plastics field after
careful consideration of the design and the performance and Reinforced Plastics and Electrical Insulating Materi-
als
required of the part, the environment to which it will be
exposed, the fabrication process to be employed, the inherent D792 Test Methods for Density and Specific Gravity (Rela-
properties of the material other than those covered by this tive Density) of Plastics by Displacement
classification, and the economics. D883 Terminology Relating to Plastics
D1525 Test Method for Vicat Softening Temperature of
1.5 The values stated in SI units are to be regarded as the
Plastics
standard. (Reporting in inch-pound units is acceptable.)
D1600 Terminology forAbbreviatedTerms Relating to Plas-
1.6 The following precautionary caveat pertains only to the
tics
test methods portion, Section 11, of this classification system:
D1708 Test Method forTensile Properties of Plastics by Use
This standard does not purport to address all of the safety
of Microtensile Specimens
concerns, if any, associated with its use. It is the responsibility
D2863 Test Method for Measuring the Minimum Oxygen
of the user of this standard to establish appropriate safety,
Concentration to Support Candle-Like Combustion of
health, and environmental practices and determine the appli-
Plastics (Oxygen Index)
cability of regulatory limitations prior to use.
D3641 Practice for Injection Molding Test Specimens of
Thermoplastic Molding and Extrusion Materials
NOTE 1—There is no known ISO equivalent to this standard.
D3892 Practice for Packaging/Packing of Plastics
1.7 This international standard was developed in accor-
D4000 Classification System for Specifying Plastic Materi-
dance with internationally recognized principles on standard-
als
1
ThisclassificationsystemisunderthejurisdictionofASTMCommitteeD20on
Plastics and is the direct responsibility of Subcommittee D20.15 on Thermoplastic
2
Materials. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved Nov. 1, 2022. Published November 2022. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
approved in 1991. Last previous edition approved in 2019 as D5204 - 19. DOI: Standards volume information, refer to the standard’s Document Summary page on
10.1520/D5204-22. the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM Intern
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D5204 − 19 D5204 − 22
Standard Classification System and Basis for Specification for
1
Polyamide-Imide (PAI) Molding and Extrusion Materials
This standard is issued under the fixed designation D5204; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope*
1.1 This classification system covers polyamide-imide materials suitable for injection molding and extrusion.
1.2 The properties included in this classification system are those required to identify the compositions covered. It is possible that
other requirements are necessary to identify particular characteristics important to specialized applications. The use of suffixes as
shown in Section 5 is one way of specifying these requirements.
1.3 This standard allows for the use of recycled materials provided that specification requirements based upon this classification
system are met.
1.4 This classification system and subsequent line call-out (specification) is intended to be a means of calling out plastics materials
used in the fabrication of end items or parts. It is not intended for the selection of materials. Material selection needs to be made
by those having expertise in the plastics field after careful consideration of the design and the performance required of the part,
the environment to which it will be exposed, the fabrication process to be employed, the inherent properties of the material other
than those covered by this classification, and the economics.
1.5 The values stated in SI units are to be regarded as the standard. (Reporting in inch-pound units is acceptable.)
1.6 The following precautionary caveat pertains only to the test methods portion, Section 11, of this classification system: This
standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user
of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory
limitations prior to use.
NOTE 1—There is no known ISO equivalent to this standard.
1.7 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
1
This classification system is under the jurisdiction of ASTM Committee D20 on Plastics and is the direct responsibility of Subcommittee D20.15 on Thermoplastic
Materials.
Current edition approved Aug. 1, 2019Nov. 1, 2022. Published August 2019November 2022. Originally approved in 1991. Last previous edition approved in 20172019
as D5204 - 17.D5204 - 19. DOI: 10.1520/D5204-19.10.1520/D5204-22.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D5204 − 22
D149 Test Method for Dielectric Breakdown Voltage and Dielectric Strength of Solid Electrical Insulating Materials at
Commercial Power Frequencies
D150 Test Methods for AC Loss Characteristics and Permittivity (Dielectric Constant) of Solid Electrical Insulation
D256 Test Methods for Determining the Izod Pendulum Impact Resistance of Plastics
D257 Test Methods for DC Resistance or Conductance of Insulating Materials
D618 Practice for Conditioning Plastics for Testing
D790 Test Methods for Flexural Properties of Unreinforced and Reinforced Plastics and Electrical Insulating Materials
D792 Test Methods for Density and Specific Gravity (Relative Density) of Plastics by Displacement
D883 Terminology Relating to Plastics
D1525 Test Method for Vicat Softening Temperature of Plastics
D1600 Terminology for Abbreviated Terms Relating to Plastics
D1708 Test Method for Tensile Properties of Plastics by Use o
...

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