ASTM D4615-12

Standard Specification for n-Butyl Acetate (All Grades) (Withdrawn 2021)

ABSTRACT
This specification establishes the properties and requirements for various grades of n-butyl acetate suitable for use as solvents in paint and related coatings. Specimens shall be sampled and tested as appropriate, and shall adhere accordingly to specified values for purity, alcohol content, color (Pt-Co units), distillation range, nonvolatile matter content, odor, water content, acidity, and apparent specific gravity.
SCOPE
1.1 This specification covers the various grades of n-butyl acetate suitable for use as solvents in paint and related coatings.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For specific hazard information and guidance, see the supplier's Material Safety Data Sheet for material listed in this specification.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

• Status: Historical
• Publication Date: 31-Oct-2012
• ICS: 71.080.99 - Other organic chemicals
• Technical Committee: D01 - Paint and Related Coatings, Materials, and Applications
• Drafting Committee: D01.35 - Solvents, Plasticizers, and Chemical Intermediates

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D4615 −12
Standard Specification for
1
n-Butyl Acetate (All Grades)
This standard is issued under the fixed designation D4615; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope* D1209 Test Method for Color of Clear Liquids (Platinum-
Cobalt Scale)
1.1 This specification covers the various grades of n-butyl
D1296 Test Method for Odor of Volatile Solvents and
acetate suitable for use as solvents in paint and related
Diluents
coatings.
D1353 Test Method for Nonvolatile Matter in Volatile Sol-
1.2 The following applies to all specified limits in this
vents for Use in Paint, Varnish, Lacquer, and Related
standard; for purposes of determining conformance with this
Products
standard, an observed value or a calculated value shall be
D1364 Test Method for Water in Volatile Solvents (Karl
rounded off “to the nearest unit” in the last right-hand digit
Fischer Reagent Titration Method)
used in expressing the specification limit, in accordance with
D1613 Test Method for Acidity in Volatile Solvents and
the rounding-off method of Practice E29.
Chemical Intermediates Used in Paint, Varnish, Lacquer,
and Related Products
1.3 The values stated in SI units are to be regarded as
standard. No other units of measurement are included in this D3545 Test Method for Alcohol Content and Purity of
Acetate Esters by Gas Chromatography
standard.
D4052 Test Method for Density, Relative Density, and API
1.4 For specific hazard information and guidance, see the
Gravity of Liquids by Digital Density Meter
supplier’s Material Safety Data Sheet for material listed in this
D5386 Test Method for Color of Liquids Using Tristimulus
specification.
Colorimetry
1.5 This standard does not purport to address all of the
E1 Specification for ASTM Liquid-in-Glass Thermometers
safety concerns, if any, associated with its use. It is the
E29 Practice for Using Significant Digits in Test Data to
responsibility of the user of this standard to establish appro-
Determine Conformance with Specifications
priate safety and health practices and determine the applica-
E300 Practice for Sampling Industrial Chemicals
bility of regulatory limitations prior to use.
2.2 U.S. Federal Specification:
PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging
2. Referenced Documents
3
of
2
2.1 ASTM Standards:
D268 Guide for Sampling and Testing Volatile Solvents and
3. Properties
Chemical Intermediates for Use in Paint and Related
3.1 n-Butyl acetate shall conform to one of the requirements
Coatings and Material
of one of the grades in Table 1.
D891 TestMethodsforSpecificGravity,Apparent,ofLiquid
Industrial Chemicals
4. Sampling
D1078 Test Method for Distillation Range of Volatile Or-
4.1 The material shall be sampled in accordance with
ganic Liquids
Practice E300.
1 5. Test Methods
This specification is under the jurisdiction of ASTM Committee D01 on Paint
and Related Coatings, Materials, andApplications and is the direct responsibility of
5.1 The properties enumerated in this specification shall be
Subcommittee D01.35 on Solvents, Plasticizers, and Chemical Intermediates.
determined in accordance with the following ASTM methods:
Current edition approved Nov. 1, 2012. Published January 2013. Originally
approved in 1986. Last previous edition approved in 2006 as D4615 – 06. DOI:
5.1.1 Purity and Alcohol Content—Test Method D3545.
10.1520/D4615-12.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM
3
Standards volume information, refer to the standard’s Document Summary page on Available from Standardization Documents Order Desk, DODSSP, Bldg. 4,
the ASTM website. Section D, 700 Robbins Ave., Philadelphia, PA 19111-5098.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D4615−12
TABLE 1 Requirements for n-Butyl Acetate
Grades
Property
A
90–92 98 99.5 99.5U
Purity, wt %, min 90–92 98.0 99.5 99.5
Alcohol, wt %, max . . 0.5 0.5
B
Color, Pt-Co units, max 10 10 10 10
Distillation Range, °C 118–128 120–128 124–129 124–129
Nonvolatile Matter, mg/100 mL, max 5 5 5 5
C
Odor Non-residual Non-residual Non-residual Non-residual
D
Water, wt %, max 0.2 0.1 0.1 0.05
Acidity, wt %, max 0.01 0.01 0.01 0.01
E
Apparent Specific Gravity:
20/20°C 0.874–0.876 0.880–0.883 0.880–0.883 0.880–0.883
or
25/25°C 0.870–0.872
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D4615 − 06 D4615 − 12
Standard Specification for
1
n-Butyl Acetate (All Grades)
This standard is issued under the fixed designation D4615; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope*
1.1 This specification covers the various grades of n-butyl acetate suitable for use as solvents in paint and related coatings.
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard,
an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing
the specification limit, in accordance with the rounding-off method of Practice E29.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 For specific hazard information and guidance, see the supplier’s Material Safety Data Sheet for material listed in this
specification.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
2. Referenced Documents
2
2.1 ASTM Standards:
D268 Guide for Sampling and Testing Volatile Solvents and Chemical Intermediates for Use in Paint and Related Coatings and
Material
D891 Test Methods for Specific Gravity, Apparent, of Liquid Industrial Chemicals
D1078 Test Method for Distillation Range of Volatile Organic Liquids
D1209 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)
D1296 Test Method for Odor of Volatile Solvents and Diluents
D1353 Test Method for Nonvolatile Matter in Volatile Solvents for Use in Paint, Varnish, Lacquer, and Related Products
D1364 Test Method for Water in Volatile Solvents (Karl Fischer Reagent Titration Method)
D1613 Test Method for Acidity in Volatile Solvents and Chemical Intermediates Used in Paint, Varnish, Lacquer, and Related
Products
D3545 Test Method for Alcohol Content and Purity of Acetate Esters by Gas Chromatography
D4052 Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
D5386 Test Method for Color of Liquids Using Tristimulus Colorimetry
E1 Specification for ASTM Liquid-in-Glass Thermometers
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
E300 Practice for Sampling Industrial Chemicals
2.2 U.S. Federal Specification:
3
PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging of
3. Properties
3.1 n n-Butyl acetate shall conform to one of the requirements of one of the grades in Table 1.
1
This specification is under the jurisdiction of ASTM Committee D01 on Paint and Related Coatings, Materials, and Applications and is the direct responsibility of
Subcommittee D01.35 on Solvents, Plasticizers, and Chemical Intermediates.
Current edition approved June 1, 2006Nov. 1, 2012. Published June 2006January 2013. Originally approved in 1986. Last previous edition approved in 20012006 as
D4615 – 95 (2001).D4615 – 06. DOI: 10.1520/D4615-06.10.1520/D4615-12.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
3
Available from Standardization Documents Order Desk, DODSSP, Bldg. 4, Section D, 700 Robbins Ave., Philadelphia, PA 19111-5098.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D4615 − 12
TABLE 1 Requirements for n-Butyl Acetate
Grades
Property
A
90–92 90–92 98 98 99.5 99.5 99.5U 99.5U
Purity, wt %, min 90–92 98.0 99.5 99.5
Alcohol, wt %, max . . 0.5 0.5
B
Color, Pt-Co units, max 10 10 10 10
Distillation Range, °C 118–128 120–128 124–129 124–129
Nonvolatile Matter, mg/100 mL, max 5 5 5 5
C
Odor Non-residual Non-residual Non-residual Non-residual
D
Water, wt %, max 0.2 0.1 0.1 0.05
Acidity, wt %, max 0.01 0.01 0.01 0.
...