Standard Specification for Ketone Ethylene Ester Based Sheet Roofing

ABSTRACT
This specification covers flexible sheet made from ketone ethylene ester (KEE) as the primary polymer intended for use in single ply roofing membrane exposed to the weather. The sheet shall be reinforced with fabric. The sheet shall be formulated from the appropriate polymers and other compounding ingredients. To make seam and repairs, the sheet shall be capable of being bonded watertight to itself during the design service life of the sheets. Overall thickness; thickness, coating over reinforcement optical method; breaking strength; elongation at break; tearing strength; linear dimensional change; fabric adhesion; heat aging; after heat aging low temperature bend; low temperature bend; water absorption; factory seam strength; hydrostatic resistance; static puncture test; accelerated weathering test; fungi resistance; abrasion test; and dimension tests shall be performed to conform with the requirements specified.
SCOPE
1.1 This specification covers flexible sheet made from ketone ethylene ester (KEE) as the primary polymer intended for use in single ply roofing membrane exposed to the weather. The sheet shall be reinforced with fabric.
1.2 In-place roof system design criteria, such as fire resistance, field-seaming strength, material compatibility, uplift resistance, in-situ shrinkage, among others, are factors that must be considered, but are beyond the scope of this specification.
1.3 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in non-conformance with the standard.
1.4 The following precautionary caveat pertains to the test methods portion only, Section 8, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory requirements prior to use.

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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D6754/D6754M −10
StandardSpecification for
1
Ketone Ethylene Ester Based Sheet Roofing
This standard is issued under the fixed designation D6754/D6754M; the number immediately following the designation indicates the
year of original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last
reapproval. A superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope D3045Practice for Heat Aging of Plastics Without Load
D3389Test Method for Coated FabricsAbrasion Resistance
1.1 This specification covers flexible sheet made from
(Rotary Platform Abrader)
ketone ethylene ester (KEE) as the primary polymer intended
D5602Test Method for Static Puncture Resistance of Roof-
foruseinsingleplyroofingmembraneexposedtotheweather.
ing Membrane Specimens
The sheet shall be reinforced with fabric.
D5635Test Method for Dynamic Puncture Resistance of
1.2 In-place roof system design criteria, such as fire
Roofing Membrane Specimens
resistance,field-seamingstrength,materialcompatibility,uplift
G21Practice for Determining Resistance of Synthetic Poly-
resistance, in-situ shrinkage, among others, are factors that
meric Materials to Fungi
must be considered, but are beyond the scope of this specifi-
G151PracticeforExposingNonmetallicMaterialsinAccel-
cation.
erated Test Devices that Use Laboratory Light Sources
G154PracticeforOperatingFluorescentLightApparatusfor
1.3 The values stated in either SI units or inch-pound units
are to be regarded separately as standard. The values stated in UV Exposure of Nonmetallic Materials
G155Practice for Operating XenonArc LightApparatus for
each system may not be exact equivalents; therefore, each
system shall be used independently of the other. Combining Exposure of Non-Metallic Materials
values from the two systems may result in non-conformance
3. Terminology
with the standard.
3.1 Definitions—Terminology D1079 shall apply to this
1.4 The following precautionary caveat pertains to the test
specification.
methods portion only, Section 8, of this specification: This
standard does not purport to address all of the safety concerns,
3.2 ketone ethylene ester (KEE), n—a high molecular
if any, associated with its use. It is the responsibility of the user
weightthermoplasticcopolymerofethylene,containingcarbon
of this standard to establish appropriate safety and health
monoxide and either vinyl acetate or acrylate monomer which
practices and determine the applicability of regulatory require-
are incorporated to provide softness and polarity.
ments prior to use.
3.2.1 Discussion—Ester groups of the vinyl acetate or
acrylate are pendant from the ethylene backbone and reduce
2. Referenced Documents
crystallinity, which provides flexibility. Carbon monoxide
2
2.1 ASTM Standards:
groups within the polymer backbone provide polarity. The
D471Test Method for Rubber Property—Effect of Liquids
KEEpolymeristhereforeaflexiblepolymer,whichismiscible
D751Test Methods for Coated Fabrics
with other polymers of similar polarity.
D1079Terminology Relating to Roofing and Waterproofing
3.3 polymer content, n—in this specification, polymer con-
D1204Test Method for Linear Dimensional Changes of
tent shall be defined as polymeric materials which are in the
Nonrigid Thermoplastic Sheeting or Film at Elevated
solid state at room temperature, and are high (greater than
Temperature
50000 Mw) in molecular weight. Other ingredients, known to
D2136Test Method for Coated Fabrics—Low-Temperature
the art of polymer compounding, such as certain waxes,
Bend Test
stabilizers, and other additives, while polymeric in nature are
not considered to be part of the base polymer system.
1
This specification is under the jurisdiction of ASTM Committee D08 on
RoofingandWaterproofingandisthedirectresponsibilityofSubcommitteeD08.18
4. Materials and Manufacture
on Nonbituminous Organic Roof Coverings.
Current edition approved July 1, 2010. Published August 2010. Originally
4.1 The sheet shall be formulated from the appropriate
approved in 2002. Last previous edition approved in 2002 as D6754–02. DOI:
polymers and other compounding ingredients. The KEE poly-
10.1520/D6754_D6754M–10.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or mer shall be a minimum of 50% by weight of the polymer
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
content of the sheet.
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. 4.2 The sheet shall be reinforced internally with a fabric.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

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D6754/D6754M−10
4.3 To make seam and repairs, the sheet shall be capable
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:D6754–02 Designation: D6754/D6754M – 10
Standard Specification for
1
Ketone Ethylene Ester Based Sheet Roofing
This standard is issued under the fixed designation D6754/D6754M; the number immediately following the designation indicates the
year of original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last
reapproval. A superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This specification covers flexible sheet made from ketone ethylene ester (KEE) as the primary polymer intended for use in
single ply roofing membrane exposed to the weather. The sheet shall be reinforced with fabric.
1.2 In-place roof system design criteria, such as fire resistance, field-seaming strength, material compatibility, uplift resistance,
in-situ shrinkage, among others, are factors that must be considered, but are beyond the scope of this specification.
1.3
1.3 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each
system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the
two systems may result in non-conformance with the standard.
1.4 The following precautionary caveat pertains to the test methods portion only, Section 8, of this specification: This standard
does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this
standard to establish appropriate safety and health practices and determine the applicability of regulatory requirements prior to
use.
2. Referenced Documents
2
2.1 ASTM Standards:
D471 Test Method for Rubber PropertyEffect of Liquids
D751 Test Methods for Coated Fabrics
D1079 Terminology Relating to Roofing and Waterproofing
D1204 Test Method for Linear Dimensional Changes of Nonrigid Thermoplastic Sheeting or Film at Elevated Temperature
D2136 Test Method for Coated FabricsLow-Temperature Bend Test
D3045 Practice for Heat Aging of Plastics Without Load
D3389 Test Method for Coated Fabrics Abrasion Resistance (Rotary Platform Abrader)
D5602 Test Method for Static Puncture Resistance of Roofing Membrane Specimens
D5635 Test Method for Dynamic Puncture Resistance of Roofing Membrane Specimens
G21 Practice for Determining Resistance of Synthetic Polymeric Materials to Fungi
G151
G151 Practice for Exposing Nonmetallic Materials in Accelerated Test Devices that Use Laboratory Light Sources
G154 Practice for Operating Fluorescent Light Apparatus for UV Exposure of Nonmetallic Materials
G155 Practice for Operating Xenon Arc Light Apparatus for Exposure of Non-Metallic Materials
3. Terminology
3.1 Definitions—Terminology D1079 shall apply to this specification.
3.2 ketone ethylene ester (KEE), n—ahighmolecularweightthermoplasticcopolymerofethylene,containingcarbonmonoxide
and either vinyl acetate or acrylate monomer which are incorporated to provide softness and polarity.
3.2.1 Discussion—Ester groups of the vinyl acetate or acrylate are pendant from the ethylene backbone and reduce crystallinity,
which provides flexibility. Carbon monoxide groups within the polymer backbone provide polarity. The KEE polymer is therefore
a flexible polymer, which is miscible with other polymers of similar polarity.
3.3 polymercontent,n—inthisspecification,polymercontentshallbedefinedaspolymericmaterialswhichareinthesolidstate
1
This specification is under the jurisdiction of ASTM Committee D08 on Roofing, Waterproofing, Roofing and Bituminous Materials Waterproofing and is the direct
responsibility of Subcommittee D08.18 on Nonbituminous Organic Roof Coverings.
Current edition approved Jan. 10, 2002. Published March 2002. DOI: 10.1520/D6754-02.
Current edition approved July 1, 2010. Published August 2010. Originally approved in 2002. Last previous edition approved in 2002 as D6754 – 02. DOI:
10.1520/D6754_D6754M–10.
2
For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
D6754/D6754M – 10
at room temperature, and are high (greater than 50 000 Mw) in molecular weight. Other ingredients, known to the art of polymer
compounding, such as
...

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