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ASTM D4130-99

(Test Method)

Standard Test Method for Sulfate Ion in Brackish Water, Seawater, and Brines

Standard Test Method for Sulfate Ion in Brackish Water, Seawater, and Brines

SCOPE
1.1 This test method covers the turbidimetric determination of sulfate ion in brackish water, seawater, and brines. It has been used successfully with synthetic brine grade waters; however, it is the user's responsibility to ensure the validity of this test method to other matrices.  
1.2 This test method is applicable to waters having an ionic strength greater than 0.65 mol/L and a sulfate ion concentration greater than 25 mg/L. A concentration less than 25 mg/L sulfate can be determined by using a standard addition method.  
1.3 For brines having an ionic strength of less than 0.65 mol/L, refer to Test Methods D516.  
1.4 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
09-Jun-1999
ICS
13.060.50 - Examination of water for chemical substances
Technical Committee
D19 - Water
Drafting Committee
D19.05 - Inorganic Constituents in Water
Current Stage
Ref Project

Relations

Replaced By
ASTM D4130-03 - Standard Test Method for Sulfate Ion in Brackish Water, Seawater, and Brines
Effective Date
10-Jun-2003
Referred By
ASTM C1797-23 - Standard Specification for Ground Calcium Carbonate and Aggregate Mineral Fillers for use in Hydraulic Cement Concrete
Effective Date
10-Jun-1999
Referred By
ASTM D7684-11(2020) - Standard Guide for Microscopic Characterization of Particles from In-Service Lubricants
Effective Date
10-Jun-1999

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ASTM D4130-99 - Standard Test Method for Sulfate Ion in Brackish Water, Seawater, and BrinesASTM D4130-99 - Standard Test Method for Sulfate Ion in Brackish Water, Seawater, and Brines
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ASTM D4130-99 - Standard Test Method for Sulfate Ion in Brackish Water, Seawater, and Brines
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Standards Content (Sample)

NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
Designation: D 4130 – 99
Standard Test Method for
1
Sulfate Ion in Brackish Water, Seawater, and Brines
This standard is issued under the fixed designation D 4130; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope 4. Summary of Test Method
1.1 This test method covers the turbidimetric determination 4.1 A sulfate ion is converted to a barium sulfate suspended
of sulfate ion in brackish water, seawater, and brines. It has under controlled conditions. A glycerin-acid solution is added
been used successfully with synthetic brine grade waters; to acidify and stabilize the suspension. A calculated volume of
however, it is the user’s responsibility to ensure the validity of a NaCl solution is added to adjust the ionic strength to a set
this test method to other matrices. value of 2 mol/L (Note 1). The turbidity resulting upon
1.2 This test method is applicable to waters having an ionic addition of barium chloride is determined by a photoelectric
strength greater than 0.65 mol/L and a sulfate ion concentration colorimeter and compared to a curve prepared from standard
greater than 25 mg/L. A concentration less than 25 mg/L sulfate sulfate solutions.
can be determined by using a standard addition method.
NOTE 1—The ionic strength (IS) of the sample is calculated from the
1.3 For brines having an ionic strength of less than 0.65 + ++ ++ −
concentration of the major ion constituents (Na ,Ca ,Mg ,Cl ),
+ ++
mol/L, refer to Test Methods D 516.
(K and Sr if their concentration exceeds 2000 mg/L) as follows:
1.4 This standard does not purport to address all of the
where:
safety problems, if any, associated with its use. It is the
2
IS, mol/L = 1/2 ( C Z ,
i i
responsibility of the user of this standard to establish appro-
C = g/L ion i/molecular weight ion, i, and
i
priate safety and health practices and determine the applica-
Z = valence of ion i.
i
bility of regulatory limitations prior to use.
5. Significance and Use
2. Referenced Documents
5.1 The determination of sulfate and other dissolved con-
2.1 ASTM Standards:
stituents is important in identifying the source of brines
2
D 516 Test Methods for Sulfate Ion in Water
produced during the drilling and production phases of crude oil
2
D 1129 Terminology Relating to Water
or natural gas.
D 1192 Specification for Equipment for Sampling Water
2
and Steam
6. Interferences
2
D 1193 Specification for Reagent Water
6.1 Suspended matter in the sample must be removed. Dark
D 2777 Practice for Determination of Precision and Bias of
colors that cannot be compensated for in the procedure
2
Applicable Methods of Committee D-19 on Water
interfere with the measurement of suspended barium sulfate
D 3370 Practices for Sampling Water from Closed Con-
(BaSO ).
4
2
duits
E 275 Practice for Describing and Measuring Performances 7. Apparatus
of Ultraviolet, Visible, and Near Infrared Spectrophotom-
7.1 Photometer—A filter photometer or a spectrophotom-
3
eters
eter for measurements between 400 to 450 nm, the preferable
wavelength being 425 nm. The cell for the instrument must
3. Terminology
have a light path of 20 6 2 mm and hold a volume of 25 mL.
3.1 Definitions—For definitions of terms used in this test
Filter photometers, spectrophotometers, and photometric prac-
method, refer to Terminology D 1129.
tices prescribed in this test method shall conform to Practice
E 275.
1
This test method is under the jurisdiction of ASTM Committee D-19 on Water
8. Reagents
and is the direct responsibility of Subcommittee D19.05 on Inorganic Constituents
in Water.
8.1 Purity of Reagents—Reagent grade chemicals shall be
Current edition approved June 10, 1999. Published September 1999. Originally
used in all tests. Unless otherwise indicated, it is intended that
E1
published as D 4130–82. Last previous edition D 4130–82 (1992)
2 all reagents shall conform to the specifications of the commit-
Annual Book of ASTM Standards, Vol 11.01.
3
tee on Analytical Reagents of the American Chemical Society,
Annual Book of ASTM Standards, Vol 03.06.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
D 4130 – 99
4
where such specifications are available. Other grades may be The ionic strength (IS) of the sample when diluted to 100 must
used, providing it is first ascertained that the reagent is of not exceed 2.00 mol/L.
...

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5.1 This test method is useful for the analysis of total uranium in water following wet-ashing, as required, due to impurities or suspended materials in the water.
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5.1 This test method has been developed by U.S. EPA Region 5 Chicago Regional Laboratory (CRL).  
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5.1 The first reported synthesis of BPA was by the reaction of phenol with acetone by Zincke.4 BPA has become an important high volume industrial chemical used in the manufacture of polycarbonate plastic and epoxy resins. Polycarbonate plastic and resins are used in numerous products including electrical and electronic equipment, automobiles, sports and safety equipment, reusable food and drink containers, electrical laminates for printed circuit boards, composites, paints, adhesives, dental sealants, protective coatings and many other products.5  
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1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
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1.2 A full collaborative study to meet the requirements of Practice D2777 has not been completed. This standard contains single-operator precision and bias based on single-operator data. Publication of standards that have not been fully validated is done to make the current technology accessible to users of standards, and to solicit additional input from the user community.  
1.3 A reporting limit check sample (RLCS) is analyzed during every batch to ensure that if an analyte was present in a sample at or near the reporting limit it would be positively identified and accurately quantitated within set quality control limits. A method detection limit (MDL) study was not done for this method, the method detection limits would be much lower than the reporting limits in this method and would be irrelevant. A RLCS was determined to be more applicable for this standard. If this method is adapted to report much lower or near the MDL then a MDL study would be warranted.  
1.4 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 The Reporting Range for the target analytes are listed in Table 1.  
1.5.1 The reporting limit in this test method is the minimum value below which data are documented as non-detects. The reporting limit is calculated from the concentration of the Level 1 calibration standard as shown in Table 6 after taking into account an 8 mL water sample volume and a final diluted sample volume of 10 mL (80 % water/20 % methanol).  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
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Standard Test Method for Determination of Nonylphenol, p-tert-Octylphenol, Nonylphenol Monoethoxylate and Nonylphenol Diethoxylate in Environmental Waters by Liquid Chromatography/Tandem Mass Spectrometry

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SCOPE
1.1 This test method covers the determination of nonylphenol (NP), nonylphenol ethoxylate (NP1EO), nonylphenol diethoxylate (NP2EO), and octylphenol (OP), extracted from water utilizing solid phase extraction (SPE), separated using liquid chromatography (LC) and detected with tandem mass spectrometry (MS/MS). These compounds are qualitatively and quantitatively determined by this method. This method adheres to single reaction monitoring (SRM) mass spectrometry.  
1.2 The method detection limit (MDL) and reporting limit (RL) for NP, NP1EO, NP2EO, and OP are listed in Table 1.    
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
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    English language
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  • Standard
    10 pages
    English language
    sale 15% off