Standard Guide for Assessing Biodegradability of Hydraulic Fluids

SIGNIFICANCE AND USE
5.1 This guide discusses ways to assess the likelihood that a hydraulic fluid will undergo biodegradation if it enters an environment that is known to support biodegradation of some substances, for example the material used as the positive control in the test. The information can be used in making or assessing claims of biodegradability of a fluid formula.  
5.2 Biodegradation occurs when a fluid interacts with the environment, and so the extent of biodegradation is a function of both the chemical composition of the hydraulic fluid and the physical, chemical, and biological status of the environment at the time the fluid enters it. This guide cannot assist in judging the status of a particular environment, so it is not meant to provide standards for judging the persistence of a hydraulic fluid in any specific environment either natural or man-made.  
5.3 If any of the tests discussed in this guide gives a high result, it implies that the hydraulic fluid will biodegrade and will not persist in the environmental compartment being considered. If a low result is obtained, it does not mean necessarily that the substance will not biodegrade in the environment, but does mean that further testing is required if a claim of biodegradability is to be made. Such testing may include, but is not limited to, other tests mentioned in this guide or simulation tests for a particular environmental compartment.
SCOPE
1.1 This guide covers and provides information to assist in planning a laboratory test or series of tests from which may be inferred information about the biodegradability of an unused fully formulated hydraulic fluid in its original form. Biodegradability is one of three characteristics which are assessed when judging the environmental impact of a hydraulic fluid. The other two characteristics are ecotoxicity and bioaccumulation.  
1.2 Biodegradability may be considered by type of environmental compartment: aerobic fresh water, aerobic marine, aerobic soil, and anaerobic media. Test methods for aerobic fresh water, aerobic soil and anaerobic media have been developed that are appropriate for the concerns and needs of testing in each compartment.  
1.3 This guide addresses releases to the environment that are incidental to the use of a hydraulic fluid but is not intended to cover situations of major, accidental release. The tests discussed in this guide take a minimum of three to four weeks. Therefore, issues relating to the biodegradability of hydraulic fluid are more effectively addressed before the fluid is used, and thus before incidental release may occur. Nothing in this guide should be taken to relieve the user of the responsibility to properly use and dispose of hydraulic fluids.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

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Published
Publication Date
30-Jun-2023
Current Stage
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Standards Content (Sample)

This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D6006 − 23
Standard Guide for
1
Assessing Biodegradability of Hydraulic Fluids
This standard is issued under the fixed designation D6006; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* mendations issued by the World Trade Organization Technical
Barriers to Trade (TBT) Committee.
1.1 This guide covers and provides information to assist in
planning a laboratory test or series of tests from which may be
2. Referenced Documents
inferred information about the biodegradability of an unused
2
fully formulated hydraulic fluid in its original form. Biode-
2.1 ASTM Standards:
gradability is one of three characteristics which are assessed
D4175 Terminology Relating to Petroleum Products, Liquid
when judging the environmental impact of a hydraulic fluid.
Fuels, and Lubricants
The other two characteristics are ecotoxicity and bioaccumu-
D5210 Test Method for Determining the Anaerobic Biodeg-
lation.
radation of Plastic Materials in the Presence of Municipal
3
Sewage Sludge (Withdrawn 2016)
1.2 Biodegradability may be considered by type of environ-
D5291 Test Methods for Instrumental Determination of
mental compartment: aerobic fresh water, aerobic marine,
Carbon, Hydrogen, and Nitrogen in Petroleum Products
aerobic soil, and anaerobic media. Test methods for aerobic
and Lubricants
fresh water, aerobic soil and anaerobic media have been
D5480 Test Method for Engine Oil Volatility by Gas Chro-
developed that are appropriate for the concerns and needs of
3
matography (Withdrawn 2003)
testing in each compartment.
D5864 Test Method for Determining Aerobic Aquatic Bio-
1.3 This guide addresses releases to the environment that
degradation of Lubricants or Their Components
are incidental to the use of a hydraulic fluid but is not intended
E1196 Test Method for Determining the Anaerobic Biodeg-
to cover situations of major, accidental release. The tests
radation Potential of Organic Chemicals (Withdrawn
discussed in this guide take a minimum of three to four weeks. 3
1998)
Therefore, issues relating to the biodegradability of hydraulic
4
2.2 ISO Standards:
fluid are more effectively addressed before the fluid is used,
ISO 9439:1990 Technical Corrigendum I, Water Quali-
and thus before incidental release may occur. Nothing in this
ty–Evaluation in an Aqueous Medium of the Ultimate
guide should be taken to relieve the user of the responsibility
Biodegradability of Organic Compounds
to properly use and dispose of hydraulic fluids.
ISO 4259:1992(E) Petroleum Products–Determination and
1.4 The values stated in SI units are to be regarded as
Application of Precision Data in Relation to Methods of
standard. No other units of measurement are included in this
Test
standard.
2.3 OECD Standards:
1.5 This standard does not purport to address all of the
OECD 301B (the Modified Sturm Test) Guidelines for
safety concerns, if any, associated with its use. It is the
5
Testing Chemicals
responsibility of the user of this standard to establish appro-
OECD 301F (the Manometric Respirometry Test) Guide-
priate safety, health, and environmental practices and deter-
5
lines for Testing of Chemicals
mine the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accor-
dance with internationally recognized principles on standard-
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
ization established in the Decision on Principles for the
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Development of International Standards, Guides and Recom-
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website.
3
The last approved version of this historical standard is referenced on
1
This guide is under the jurisdiction of ASTM Committee D02 on Petroleum www.astm.org.
4
Products, Liquid Fuels, and Lubricants and is the direct responsibility of Subcom- Available from International Organization for Standardization (ISO), ISO
mittee D02.12 on Environmental Standards for Lubricants. Central Secretariat, Chemin de Blandonnet 8, CP 401, 1214 Vernier, Geneva,
Current edition approved July 1, 2023. Published August 2023. Originally Switzerland, https://www.iso.org.
5
approved in 1996. Last previous edition approved in 2017 as D6006 – 17. DOI: Available from Organisation for Economic Co-Operation and Development
10.1520/D6006-23. (OECD), 2, rue André Pascal, F
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D6006 − 17 D6006 − 23
Standard Guide for
1
Assessing Biodegradability of Hydraulic Fluids
This standard is issued under the fixed designation D6006; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This guide covers and provides information to assist in planning a laboratory test or series of tests from which may be inferred
information about the biodegradability of an unused fully formulated hydraulic fluid in its original form. Biodegradability is one
of three characteristics which are assessed when judging the environmental impact of a hydraulic fluid. The other two
characteristics are ecotoxicity and bioaccumulation.
1.2 Biodegradability may be considered by type of environmental compartment: aerobic fresh water, aerobic marine, aerobic soil,
and anaerobic media. Test methods for aerobic fresh water, aerobic soil and anaerobic media have been developed that are
appropriate for the concerns and needs of testing in each compartment.
1.3 This guide addresses releases to the environment that are incidental to the use of a hydraulic fluid but is not intended to cover
situations of major, accidental release. The tests discussed in this guide take a minimum of three to four weeks. Therefore, issues
relating to the biodegradability of hydraulic fluid are more effectively addressed before the fluid is used, and thus before incidental
release may occur. Nothing in this guide should be taken to relieve the user of the responsibility to properly use and dispose of
hydraulic fluids.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and healthsafety, health, and environmental practices and determine
the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
D4175 Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
D5210 Test Method for Determining the Anaerobic Biodegradation of Plastic Materials in the Presence of Municipal Sewage
3
Sludge (Withdrawn 2016)
1
This guide is under the jurisdiction of ASTM Committee D02 on Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of Subcommittee
D02.12 on Environmental Standards for Lubricants.
Current edition approved Jan. 1, 2017July 1, 2023. Published February 2017August 2023. Originally approved in 1996. Last previous edition approved in 20112017 as
D6006 – 11.D6006 – 17. DOI: 10.1520/D6006-17.10.1520/D6006-23.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
3
The last approved version of this historical standard is referenced on www.astm.org.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D6006 − 23
D5291 Test Methods for Instrumental Determination of Carbon, Hydrogen, and Nitrogen in Petroleum Products and Lubricants
3
D5480 Test Method for Engine Oil Volatility by Gas Chromatography (Withdrawn 2003)
D5864 Test Method for Determining Aerobic Aquatic Biodegradation of Lubricants or Their Components
3
E1196 Test Method for Determining the Anaerobic Biodegradation Potential of Organic Chemicals (Withdrawn 1998)
4
2.2 ISO Standards:
ISO 9439:1990 Technical Corrigendum I, Water Quality–Evaluation in an Aqueous Medium of the Ultimate Biodegradability
of Organic Compounds
ISO 4259:1992(E) Petroleum Products–Determination and Application of Precision Data in Relation to Methods of Test
2.3 OECD Standards:
5
OECD 30
...

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