ASTM D537-85(1997)
(Specification)Standard Specification for Sodium Metasilicate (Withdrawn 2001)
Standard Specification for Sodium Metasilicate (Withdrawn 2001)
SCOPE
1.1 This specification for sodium metasilicate covers material suitable for various washing, cleaning, and scouring processes, with or without soap as conditions demand, and where a moderately strong alkaline material is desired.
1.2 This material may be hazardous if not properly managed.
1.3 Precautionary information for the safe use, storage, and disposal of this material should be preliminarily obtained from suppliers and others.
1.4 In case of personal accident with this material, apply appropriate first aid; telephone the nearest Poison Control Center for assistance, and get medical attention immediately.
General Information
Standards Content (Sample)
NOTICE: This standard has either been superseded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
Designation: D 537 – 85 (Reapproved 1997)
Standard Specification for
Sodium Metasilicate
This standard is issued under the fixed designation D 537; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope Therefore, the calculation of net weight shall be based upon a
product containing 98 % of sodium metasilicate calculated as
1.1 This specification for sodium metasilicate covers mate-
Na SiO ·5H O for Type I or 91.5 % of sodium metasilicate
2 3 2
rial suitable for various washing, cleaning, and scouring
calculated as Na SiO for Type II. The net weight of the
2 3
processes, with or without soap as conditions demand, and
material to be paid for shall be calculated as follows:
where a moderately strong alkaline material is desired.
1.2 This material may be hazardous if not properly man- W 5 ~R 3 T!/98 for Type I (1)
aged.
W 5 ~R 3 T!/91.5 for Type II (2)
1.3 Precautionary information for the safe use, storage, and
where:
disposal of this material should be preliminarily obtained from
W 5 net weight of the material to be paid for,
suppliers and others.
R 5 net weight of the material as received,
1.4 In case of personal accident with this material, apply
T 5 total sodium metasilicate calculated as Na SiO ·
appropriate first aid; telephone the nearest Poison Control 2 3
5H O, and
Center for assistance, and get medical attention immediately.
T8 5 total sodium metasilicate calculated as Na SiO .
2 3
2. Referenced Documents 4.2 In the event that the calculation under 4.1 results in a
figure greater than 100 %, the seller waives the right to invoice
2.1 ASTM Standards:
the purchaser for any amount in excess of 100 %.
D 501 Test Methods of Sampling and Chemical Analysis of
Alkaline Detergents
5. Chemical Composition
3. Sodium Metasilicate 5.1 Sodium metasilicate, as received, shall conform to the
requirements as to chemical composition prescribed in Table 1.
3.1 Sodium metasilicate shall be a uniform product in one of
the following forms as specified by the purchaser:
6. Sampling and Analysis
3.1.1 Type I— White granular or crystalline material.
6.1 The material shall be sampled and analyzed in accor-
3.1.2 Type II— Granular anhydrous material.
dance with Test Methods
...
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1.1 These test methods cover procedures for the sampling and chemical analysis of inorganic alkaline detergents.
1.2 The procedures appear in the following order:
Sections
Caustic Soda:
Sampling
5
Total Alkalinity as Sodium Oxide (Na2O)
6 – 8
Sodium Hydroxide (NaOH)
9 – 11
Carbonate as Sodium Carbonate (Na2CO3)
12
Carbon Dioxide (CO2) by the Evolution Method
13 – 16
Soda Ash:
Sampling
17
Matter Volatile at 150 °C to 155 °C
18 and 19
Total Alkalinity as Sodium Carbonate (Na2CO3 )
20 – 22
Sodium Bicarbonate (NaHCO3)
23 – 25
Sodium Bicarbonate (NaHCO3) by Potentiometric Titration
26 – 28
Matter Insoluble in Water
29 and 30
Apparent Density
31 and 32
Modified Soda (Sequicarbonate Type):
Sampling
33
Total Alkalinity as Sodium Oxide (Na2O)
34 – 36
Sodium Bicarbonate (NaHCO3) and Sodium Carbonate (Na2CO3)
37 – 39
Matter Insoluble in Water
40
Sodium Bicarbonate:
Sampling
41
Sodium Bicarbonate, Sodium Carbonate, and Free Moisture
42 – 45
Matter Insoluble in Water
46
Sodium Metasilicate, Sodium Sesquisilicate and Sodium Orthosil- icate:
Sampling
47
Total Alkalinity as Sodium Oxide (Na2O)
48 – 50
Total Silica as SiO2
51 – 53
Sodium Metasilicate (Na2SiO3·5H2O)
54
Sodium Sesquisilicate (3Na2O·2SiO2·11H2O)
55
Matter Insoluble in Water
56 and 57
Loss on Ignition of Sodium Sesquisilicate (3Na2O·2SiO2 ·11H2O)
58 and 59
Sodium Orthosilicate (Na4SiO4)
60
Trisodium Phosphate:
Sampling
61
Trisodium Phosphate (Na3PO4) Content and Phosphorus Pentoxide (P2O5)
62 – 64
Trisodium Phosphate Calculated as Na3PO4·12H2O, Na3PO4· H2O, Na3PO4, and as P2O5
65 – 68
Total Alkalinity as Sodium Oxide (Na2O)
69 – 71
Matter Insoluble in Water
72 and 73
Tetrasodium Pyrophosphate:
Sampling
74
Tetrasodium Pyrophosphate
(Na4P2O7)
75 – 79
Matter Insoluble in Water
80 and 81
Loss on Ignition
82 and 83
Borax:
Sampling
84
Total Borate and Excess Alkalinity or Acidity
85 – 87
Matter Insoluble in Water
88 and 89
Sodium Triphosphate:
Sampling
90
Tritratable Na2O
91 – 94
Total P2O5:
Preferred Method
95 – 97
Alternative Method
98 – 101
pH Titration
102 – 107
Quantitative Separation and Measurement of Various Phosphates:
Reverse-Flow Ion-Exchange Chromatography (Preferred Method)
108 – 119
Paper Chromatographic Method
120 – 127
pH of 1 percent Solution
128
Turbidity
129
Temperature Rise
130 – 134
Sulfate
135 – 137
Ignition Loss
140 and 141
Matter Insoluble in Water
142 – 144
Particle Size
145
Orthophosphate
146 – 151
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1.1 These test methods cover the sampling and chemical analysis of paste, powder, or liquid detergent fatty alkyl sulfates.
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Sections
Sampling:
Powders and Flakes Packed in Cans or Cartons
4
Powders and Flakes in Bulk
5
Liquids
6
Pastes
7
Preparation of Sample
8
Moisture by the Distillation Test Method
11 – 14
pH
15
Alkalinity
16 – 19
Alcohol-Soluble Matter
20 – 22
Alcohol-Insoluble Matter
23 and 24
Unsulfated Material
25 – 28
Combined Alcohols
29 – 32
Ester SO3:
Method A. Titration Test Method
36 and 37
Sections
Ester SO3:
Method B. Gravimetric Test Method
38 and 39
Sodium Sulfate
40 – 43
Chlorides Calculated as Sodium Chloride (NaCl)
44 – 47
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1.2 The analytical procedures appear in the following order:
Sections
Moisture and Other Matter Volatile at 105°C (Oven Method)
5 and 6
Free Alkali or Free Acid
7 and 8
Anhydrous, Salt-Free, Soda Soap
9 – 12
Alcohol-Soluble Matter
13 and 14
Matter Insoluble in Water
15 and 15
Total Alkalinity of Matter Insoluble in Alcohol (Alkaline Salts)
16 and 17
Sodium Silicate
18 – 20
Phosphates
21 – 28
Phosphate (Colorimetric Method Using Molybdenum Blue)
29 – 34
Unsaponified and Unsaponifiable Matter
35 – 39
Free Fatty Matter
40
Chlorides in Alcohol-Soluble Matter
41 – 43
Rosin (McNicoll Method)
44 – 47
Synthetic Detergent (by Difference)
48
Neutral, Inorganic Salts
49
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1.1 These test methods cover the chemical analysis of sulfonated and sulfated oils. The analytical procedures appear in the following order:
Section
Moisture:
Test Method A. Water by Distillation with Volatile Solvent
4 – 9
Test Method B. Moisture and Volatile Matter by Hot-Plate Method
10 – 14
Organically Combined Sulfuric Anhydride:
Test Method A. Titration Test
15 – 19
Test Method B. Extraction-Titration Test
20 – 24
Test Method C. Ash-Gravimetric Test (in the Presence of True
Sulfonates)
25 – 28
Total Desulfated Fatty Matter
29 – 32
Total Active Ingredients
33 – 36
Unsaponifiable Nonvolatile Matter
37 – 41
Inorganic Salts
42 – 46
Total Alkalinity
47 – 49
Total Ammonia
50 – 52
Acidity as Free Fatty Acids or Acid Number:
Test Method A. In the Absence of Ammonium or Triethanolamine Soaps
53 – 56
Test Method B. In the Presence of Dark Colored Oils but in the
Absence of Ammonium or Triethanolamine Soaps (Brine Test)
57 – 60
Test Method C. In the Presence of Ammonium or Triethanolamine Soaps
61 – 63
Water-Immiscible Organic Solvents Volatile with Steam
64 – 70
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