Standard Guide for NAPL Mobility and Migration in Sediments – Evaluation Metrics

SIGNIFICANCE AND USE
4.1 Hydrophobic organic liquids (for example, petroleum hydrocarbons, coal tars) may exist in the environment for long periods of time as NAPLs. Standardized guidance and test methods do not exist to assess NAPL movement (both pore-scale mobility and NAPL body-scale migration) in sediment. Literature searches have resulted in a limited body of available and applicable research. Current research has focused on site-specific sediment NAPL movement evaluation approaches.  
4.2 Standardized guidance and test methods currently exist for assessing NAPL mobility and migration at upland sites, from organizations such as ASTM International (Guides E2531 and E2856), Interstate Technology and Regulatory Council (2), and the American Petroleum Institute (3, 4). Approaches commonly used in upland sites may or may not be applicable for any given sediment site. This guide provides perspectives on the applicability of various methodologies for specific sediment conditions.  
4.3 This guide describes various methodologies that are useful in sediment NAPL movement evaluation, such as laboratory test methods, calculation approaches, and field observation analysis. The guide then provides frameworks to evaluate the data generated from these methodologies to determine if the NAPL observed in the sediments under in situ conditions exhibits movement of any kind.  
4.4 Important exposure pathways in upland sites are usually not applicable to sediment sites. The U.S. Environmental Protection Agency notes, “Contaminants in the biologically active layer of the surface sediment at a site often drive exposure” (5). In aquatic environments, benthic organisms live in the surface sediment to maintain access to oxygenated overlying water. These benthic organisms are at the base of the food chain. If NAPL in subsurface sediment is not migrating, the NAPL will not move into the surface sediment and result in exposure to benthic organisms. NAPL that is stable and only present in subsurface sediment...
SCOPE
1.1 This guide discusses methodologies that can be applied to evaluate the potential for the movement (that is, pore-scale mobility or NAPL body-scale migration) of non-aqueous phase liquid (NAPL) in sediments. NAPL movement assessment in sediments is significantly different than in upland soils. As such, the frameworks for evaluating NAPL movement in upland soils have limited applicability for sediments. In particular, because upland NAPL conceptual site models may not be applicable to many sediment sites, this guide provides a framework to evaluate whether NAPL is mobile (at the pore scale) or migrating (at the NAPL body scale) in sediments.  
1.2 Assessment of the potential for NAPL to move in sediment is important for several reasons, including (but not limited to) evaluation of risk to potential receptors, the need for potential remedial action, and potential remedial strategies. For example, if the NAPL is migrating, sensitive receptors may be impacted and this will influence the choice and timing of any remedy selected for an area of the sediment site. If the NAPL is not mobile or migrating, then remedial actions may not be warranted.  
1.3 This guide is applicable at sediment sites where NAPL has been identified in the sediment by various screening methods and the need for a NAPL movement evaluation is warranted (Guide E3248).  
1.4 Petroleum hydrocarbon, coal tar, and other tar NAPLs (including fuels, oils, and creosote) are the primary focus of this guide. These forms of contamination are commonly related to historical operations at refineries, petroleum distribution terminals, manufactured gas plants (MGPs), and various large industrial sites.  
1.5 Although certain technical aspects of this guide apply to other NAPLs (for example, dense NAPLs [DNAPLs] such as chlorinated hydrocarbon solvents), this guide does not completely address the additional complexities of those DNAPLs.  
1.6 The goal of this guide...

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Publication Date
31-Mar-2021
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ASTM E3282-21 - Standard Guide for NAPL Mobility and Migration in Sediments – Evaluation Metrics
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: E3282 − 21
Standard Guide for
NAPL Mobility and Migration in Sediments – Evaluation
1
Metrics
This standard is issued under the fixed designation E3282; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 1.6 The goal of this guide is to provide a sound technical
basistodetermineifNAPLatthesiteismobileorimmobileat
1.1 This guide discusses methodologies that can be applied
the pore scale, and if mobile, whether it is stable or migrating
to evaluate the potential for the movement (that is, pore-scale
at the NAPLbody scale.The potential for NAPLmovement in
mobilityorNAPLbody-scalemigration)ofnon-aqueousphase
the sediment is a key component in the development of the
liquid (NAPL) in sediments. NAPL movement assessment in
conceptual site model (CSM) and in deciding what remedial
sediments is significantly different than in upland soils. As
options should potentially be chosen for the site to reduce
such, the frameworks for evaluating NAPL movement in
potential risks to human health and ecological receptors.
upland soils have limited applicability for sediments. In
1.7 Thisguidecanbeusedtohelpdevelop,orrefine,aCSM
particular, because upland NAPL conceptual site models may
not be applicable to many sediment sites, this guide provides a for the sediment site. A robust CSM is typically needed to
optimize potential future work efforts at the site, which may
framework to evaluate whether NAPL is mobile (at the pore
scale) or migrating (at the NAPL body scale) in sediments. include various risk management and remedial strategies for
the site, as well as subsequent monitoring after any remedy
1.2 Assessment of the potential for NAPL to move in
implementation.
sediment is important for several reasons, including (but not
1.8 ThisguideconsidersthemobilityofNAPLinsediments
limitedto)evaluationofrisktopotentialreceptors,theneedfor
that originated from three broad categories of potential NAPL
potentialremedialaction,andpotentialremedialstrategies.For
emplacement mechanisms (Guide E3248).
example, if the NAPLis migrating, sensitive receptors may be
1.8.1 Migration of NAPL by advection (flow through the
impacted and this will influence the choice and timing of any
soilporenetwork)fromanuplandsiteintotheporenetworkof
remedy selected for an area of the sediment site. If the NAPL
sediments beneath an adjacent water body is one category of
is not mobile or migrating, then remedial actions may not be
warranted. NAPL emplacement mechanism. This most commonly occurs
within coarse-grained strata in the sediment.
1.3 This guide is applicable at sediment sites where NAPL
1.8.2 Direct discharge of light NAPL (LNAPL) into a
has been identified in the sediment by various screening
waterway, where it is broken down by mechanical energy to
methods and the need for a NAPL movement evaluation is
form LNAPL beads, is another category of NAPL emplace-
warranted (Guide E3248).
ment mechanism. Oil-particle aggregates (OPAs) are formed
1.4 Petroleum hydrocarbon, coal tar, and other tar NAPLs
when suspended particulates in surface water adhere to
(including fuels, oils, and creosote) are the primary focus of
LNAPL beads. Once enough particulates have adhered to an
thisguide.Theseformsofcontaminationarecommonlyrelated
LNAPL bead and the OPA becomes dense enough, it settles
to historical operations at refineries, petroleum distribution
through the water column onto a competent sediment surface,
terminals, manufactured gas plants (MGPs), and various large
where it forms an in situ deposited NAPL (IDN) and may be
industrial sites.
buried by future sedimentation.
1.8.3 The third category of NAPLemplacement mechanism
1.5 Althoughcertaintechnicalaspectsofthisguideapplyto
is DNAPL flow (that is, direct discharge of DNAPL into a
other NAPLs (for example, dense NAPLs [DNAPLs] such as
waterway), followed by settling through the water column and
chlorinated hydrocarbon solvents), this guide does not com-
depositiondirectlyontoacompetentsedimentsurface,whereit
pletely address the additional complexities of those DNAPLs.
may be buried by future sedimentation.
1.9 Ebullition-facilitated transport of NAPL from the sedi-
1
ThisguideisunderthejurisdictionofASTMCommitteeE50onEnvironmental
ment to the water column by gas bubbles is not within the
Assessment, Risk Management and CorrectiveAction and is the direct responsibil-
scope of this guide.Transport of NAPLdue to erosional forces
ity of Subcommittee E50.04 on Corrective Action.
(for example, propeller wash) is not within the scope of this
Current edition approved April 1, 2021. Published June 2021
...

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