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ASTM D4139-04(2014)

(Guide)

Standard Guide for Determining Volatile and Nonvolatile Content of Pigments

Standard Guide for Determining Volatile and Nonvolatile Content of Pigments

SIGNIFICANCE AND USE
3.1 The nonvolatile content of raw materials may be used to determine the total nonvolatile content (solids) of paint and related coatings. Such information may be useful to coatings producers and users for the determination of the total solids available for film formation and for the estimation of the volatile organic content.
SCOPE
1.1 This guide is intended to aid in the selection of the proper ASTM test method for determining the volatile and nonvolatile content of pigments.  
Note 1: Test methods for determining the composition of the volatile fraction are not covered by this guide.  
1.2 The standards included are as follows:    
Standard  
Section  
ASTM Designation  
Inert or low hiding pigments  
4.1  
D280  
White pigments  
4.2  
D280    
Black pigments  
4.3  
D280  
D1509  
Aluminum and zinc pigments  
4.4  
D280    
D480  
Blue pigments  
4.5  
D280    
D1135  
Green pigments  
4.6  
D280    
Yellow, orange, brown pigments  
4.7  
D280  
D3724    
Red pigments  
4.8  
D280  
Miscellaneous  
4.9  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

General Information

Status
Historical
Publication Date
30-Nov-2014
ICS
87.060.10 - Pigments and extenders
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.31 - Pigment Specifications
Current Stage
Ref Project

Relations

Replaces
ASTM D4139-04(2009) - Standard Guide for Determining Volatile and Nonvolatile Content of Pigments
Effective Date
01-Dec-2014
Replaced By
ASTM D4139-04(2020) - Standard Guide for Determining Volatile and Nonvolatile Content of Pigments
Effective Date
01-Jun-2020

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REDLINE ASTM D4139-04(2014) - Standard Guide for Determining Volatile and Nonvolatile Content of PigmentsREDLINE ASTM D4139-04(2014) - Standard Guide for Determining Volatile and Nonvolatile Content of Pigments
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REDLINE ASTM D4139-04(2014) - Standard Guide for Determining Volatile and Nonvolatile Content of Pigments
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Standards Content (Sample)


NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D4139 − 04 (Reapproved 2014)
Standard Guide for
Determining Volatile and Nonvolatile Content of Pigments
This standard is issued under the fixed designation D4139; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 3. Significance and Use
1.1 This guide is intended to aid in the selection of the 3.1 The nonvolatile content of raw materials may be used to
proper ASTM test method for determining the volatile and determine the total nonvolatile content (solids) of paint and
nonvolatile content of pigments. related coatings. Such information may be useful to coatings
producers and users for the determination of the total solids
NOTE 1—Test methods for determining the composition of the volatile
available for film formation and for the estimation of the
fraction are not covered by this guide.
volatile organic content.
1.2 The standards included are as follows:
4. Procedure
Standard Section ASTM Designation
Inert or low hiding pigments 4.1 D280
4.1 Inert or Low Hiding Pigments:
White pigments 4.2 D280
Black pigments 4.3 D280 4.1.1 Test Methods D280 contain Method A for pigments
D1509
that do not decompose at 110°C, using a time of2hat105to
Aluminum and zinc pigments 4.4 D280
110°C, and Method B for pigments that decompose at 110°C,
D480
Blue pigments 4.5 D280 using vacuum to remove the volatile material.
D1135
4.1.1.1 Test Methods D280 are applicable to anhydrous and
Green pigments 4.6 D280
hydrous aluminum silicate, barium sulfate, calcium,
Yellow, orange, brown pigments 4.7 D280
borosilicate, calcium carbonate, diatomaceous silica, magne-
D3724
Red pigments 4.8 D280
sium silicate, pumice, and wet ground mica pigments for
Miscellaneous 4.9
determination of hygroscopic moisture and other matter vola-
1.3 The values stated in SI units are to be regarded as
tile under the test conditions.
standard. No other units of measurement are included in this
4.2 White Pigments—Test Methods D280 are applicable to
standard.
titanium dioxide, white lead, and zinc sulfide pigments.
2. Referenced Documents
4.3 Black Pigments:
4.3.1 Test Methods D280 are applicable to synthetic black
2.1 ASTM Standards:
iron oxide pigment.
D280 Test Methods for Hygroscopic Moisture (and Other
4.3.2 Test Methods D1509 is used to determine heating loss
Matter Volatile Under the Test Conditions) in Pigments
in carbon black pigment.
D480 Test Methods for Sampling and Testing of Flaked
Aluminum Powders and Pastes
4.4 Aluminum and Zinc Pigments:
D1135 Test Methods for Chemical Analysis of Blue Pig-
4.4.1 Test Methods D480 include the determination of
ments
nonvolatile matter in aluminum paste.
D1509 Test Methods for Carbon Black—Heating Loss
4.4.2 Test Methods D280 are applicable to zinc dust (me-
D3724 Specification for Synthetic Brown Iron Oxide Pig-
tallic zinc powder).
ment
4.5 Blue Pigments:
4.5.1 Test Methods D280 are applicable to copper phthalo-
cyanine blue and ultramarine blue pigments.
This guide is under the jurisdiction of ASTM Committee D01 on Paint and
4.5.2 Test Methods D1135 include the determination of
Related Coatings, Materials, and Applications and is the direct responsibility of
moisture in i
...


This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D4139 − 04 (Reapproved 2009) D4139 − 04 (Reapproved 2014)
Standard Guide for
Determining Volatile and Nonvolatile Content of Pigments
This standard is issued under the fixed designation D4139; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This guide is intended to aid in the selection of the proper ASTM test method for determining the volatile and nonvolatile
content of pigments.
NOTE 1—Test methods for determining the composition of the volatile fraction are not covered by this guide.
1.2 The standards included are as follows:
Standard Section ASTM Designation
Inert or low hiding pigments 4.1 D280
White pigments 4.2 D280
Black pigments 4.3 D280
D1509
Aluminum and zinc pigments 4.4 D280
D480
Blue pigments 4.5 D280
D1135
Green pigments 4.6 D280
Yellow, orange, brown pigments 4.7 D280
D3724
Red pigments 4.8 D280
Miscellaneous 4.9
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
2. Referenced Documents
2.1 ASTM Standards:
D280 Test Methods for Hygroscopic Moisture (and Other Matter Volatile Under the Test Conditions) in Pigments
D480 Test Methods for Sampling and Testing of Flaked Aluminum Powders and Pastes
D1135 Test Methods for Chemical Analysis of Blue Pigments
D1509 Test Methods for Carbon Black—Heating Loss
D3724 Specification for Synthetic Brown Iron Oxide Pigment
3. Significance and Use
3.1 The nonvolatile content of raw materials may be used to determine the total nonvolatile content (solids) of paint and related
coatings. Such information may be useful to coatings producers and users for the determination of the total solids available for film
formation and for the estimation of the volatile organic content.
4. Procedure
4.1 Inert or Low Hiding Pigments:
4.1.1 Test Methods D280 contain Method A for pigments that do not decompose at 110°C, using a time of 2 h at 105 to 110°C,
and Method B for pigments that decompose at 110°C, using vacuum to remove the volatile material.
4.1.1.1 Test Methods D280 are applicable to anhydrous and hydrous aluminum silicate, barium sulfate, calcium, borosilicate,
calcium carbonate, diatomaceous silica, magnesium silicate, pumice, and wet ground mica pigments for determination of
hygroscopic moisture and other matter volatile under the test conditions.
This guide is under the jurisdiction of ASTM Committee D01 on Paint and Related Coatings, Materials, and Applications and is the direct responsibility of Subcommittee
D01.31 on Pigment Specifications.
Current edition approved June 1, 2009Dec. 1, 2014. Published June 2009December 2014. Originally approved in 1982. Last previous edition approved in 20042009 as
D4139 – 04.D4139 – 04 (2009). DOI: 10.1520/D4139-04R09.10.1520/D4139-04R14.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’sstandard’s Document Summary page on the ASTM website.
Copyright © ASTM International, 100 Barr Ha
...

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D562  
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