ASTM D6262-98(2003)
(Specification)Standard Specification for Extruded, Compression Molded, and Injection Molded Basic Shapes of Poly(aryl ether ketone) (PAEK)
Standard Specification for Extruded, Compression Molded, and Injection Molded Basic Shapes of Poly(aryl ether ketone) (PAEK)
SCOPE
1.1 This specification covers requirements and methods of test for the material, dimensions, and workmanship, and the properties of extruded, compression molded, and injection molded PAEK sheet, plate, rod, and tubular bar manufactured from PAEK.
1.2 The properties included in this specification are those required for the compositions covered. Requirements necessary to identify particular characteristics important to specialized applications may be described by using the classification system given in Section 4.
1.3 This specification allows the use of key clad plastics² (see Section 4).
1.4 The values are stated in inch-pound units and are regarded as the standard in all property and dimensional tables. For reference purposes, SI units are also included in Table 1.
1.5 The following precautionary caveat pertains only to the test method portion Section 11, of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
Note 1—There is no similar or equivalent ISO standard.
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Designation: D 6262 – 98 (Reapproved 2003)
Standard Specification for
Extruded, Compression Molded, and Injection Molded Basic
Shapes of Poly(aryl ether ketone) (PAEK)
This standard is issued under the fixed designation D 6262; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
INTRODUCTION
This specification in intended to be a means of calling out plastic product used in the fabrication of
end items or parts.
1. Scope D 618 Practice for Conditioning Plastics for Testing
D 638 Test Method for Tensile Properties of Plastics
1.1 This specification covers requirements and methods of
D 790 TestMethodsforFlexuralPropertiesofUnreinforced
test for the material, dimensions, and workmanship, and the
and Reinforced Plastics and Electrical Materials
properties of extruded, compression molded, and injection
D 883 Terminology Relating to Plastics
molded PAEK sheet, plate, rod, and tubular bar manufactured
D 3892 Practice for Packaging/Packing of Plastics
from PAEK.
D 4000 Classification System for Specifying Plastics Mate-
1.2 The properties included in this specification are those
rials
required for the compositions covered. Requirements neces-
D 5033 GuidefortheDevelopmentofStandardsRelatingto
sary to identify particular characteristics important to special-
the Proper Use of Recycled Plastics
ized applications may be described by using the classification
2.2 ANSI Standards:
system given in Section 4.
Z1.4-1993 Sampling Procedures and Tables for Inspection
1.3 This specification allows the use of key clad plastics
by Attributes
(see Section 4).
1.4 The values are stated in inch-pound units and are
3. Terminology
regarded as the standard in all property and dimensional tables.
3.1 Definitions:
For reference purposes, SI units are also included in Table 1.
3.1.1 plate, n—flat stock ⁄4 in. [6.4 mm], or greater.
1.5 The following precautionary caveat pertains only to the
3.1.2 recycled plastic shape, n—a product made from up to
test method portion Section 11, of this specification. This
100 % recycled plastic.
standard does not purport to address all of the safety concerns,
3.1.3 rod, n—solid cylindrical shape with a minimum di-
if any, associated with its use. It is the responsibility of the user
ameter of ⁄8 in. [3.2 mm].
of this standard to establish appropriate safety and health
3.1.4 sheet, n—flat stock less than and including ⁄4 in. [6.4
practices and determine the applicability of regulatory limita-
mm] thickness.
tions prior to use.
3.1.5 tubular bar, n—annular shapes with minimum inside
NOTE 1—There is no similar or equivalent ISO standard. 3 1
diameterof ⁄8 in.[3.5mm]andminimumwallthicknessof ⁄16
in. [1.6 mm].
2. Referenced Documents
3.1.6 virgin plastic shape, n—product that is produced from
2.1 ASTM Standards:
100 % plastic resin that has not been subjected to subsequent
D 256 Test Method for Determining the Pendulum Impact
melt processing.
Resistance of Notched Specimens of Plastics
3.2 Definitions of Terms Specific to This Standard:
3.2.1 For definitions of other technical terms pertaining to
plastics used in this specification, see Terminology D 883 or
This specification is under the jurisdiction of ASTM Committee D20 on
Guide D 5033.
Plastics and is the direct responsibility of Subcommittee D20.20 on Plastic Products
(Section D20.20.02).
Current edition approved March 10, 2003. Published May 2003. Originally
approved in 1998. Last previous edition approved in 1998 as D 6262 - 98. Annual Book of ASTM Standards, Vol 08.03.
2 5
As defined in Guide D 5033. Available from American National Standards Institute (ANSI), 25 W. 43rd St.,
Annual Book of ASTM Standards, Vol 08.02. 4th Floor, New York, NY 10036.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
D 6262 – 98 (2003)
4. Classification and Material
1 = Unfilled class
1 = General purpose grade product
4.1 Product shape and size as defined in the applicable
purchase order. 4.5.1.2 Example 2—Compression molded natural PAEK
plate.
4.2 This specification covers product extruded as listed in
Table S-PAEK. Products included in the designations reference CELL CALLOUT: S-PAEK0211
Classification D 4000 callout where applicable.
S-PAEK02 = Product made from PAEK in accordance with Table
4.2.1 ThetypeofPAEKextruded,compressionmolded,and
S-PAEK
injection molded product may be categorized by type, grade 1 = Unfilled class
1 = General purpose grade product
and class depending on resin and filler compositions as defined
in Table S-PAEK.
4.5.2 The two examples illustrate how a one-line, alpha-
4.2.2 Every type of PAEK shape may be categorized into numeric sequence can identify the product composition, com-
one of several grades as follows: mercial parameters and physical characteristics of extruded or
4.2.2.1 Grade 1 — General Purpose—Extruded, compres- compression molded product. A space must be used as a
sion molded or injection molded product made using only separator between the specification number and the type
100 % virgin PAEK resin. designation. No separators are needed between type, class and
4.2.2.2 Grade 2 — Recycle Grade—Extruded, compression grade. When special notes are to be included, such information
should be preceded by a comma. Special tolerances must be
moldedorinjectionmoldedproductmadeusinganyamountup
to 100 % of recycled thermoplastic PAEK. noted at time of order and are inserted after the grade in
parenthesis and preceded by a comma.
4.3 The type, class and grade is further differentiated based
on dimensional stability (elevated temperature excursion test),
5. Physical Property Requirements
Table S-PAEK and dimensional requirements, TablesAand B.
5.1 The physical property values listed within this specifi-
4.4 Property Tables:
cation’s tables are to be considered minimum specification
4.4.1 Table S-PAEK may be used to describe extruded,
values. Any requirement for specific test data for a given
compression molded, and injection molded products.
production lot should be specified at the time of order. Physical
4.4.2 Table 1 may also be used to describe extruded,
properties for products not yet included in Table S-PAEK may
compression molded, and injection molded products not in-
be specified using Table 1 for extruded, compression molded,
cluded in Table S-PAEK via a cell callout which includes the
and injection molded products.
applicable Table S-PAEK PAEK type and specific properties
(Designations 1 through 7).
6. Dimensional Requirements
4.4.3 To facilitate the incorporation of future or special
6.1 The type, class, and grade is further differentiated based
materials not covered by the Table S-PAEK, the “as specified”
on dimensional stability (elevated temperature excursion test),
category (OO) for type, class and grade is shown on the table
Table S-PAEK, and dimensional requirements,TablesAand B.
with the basic properties to be obtained from Table 1, as they
Products shall be produced within commercial tolerances and
apply.
withtheloweststresslevelsformachinedpartsasdelineatedin
4.4.4 Reinforcements and additive materials. A symbol
TablesAandBforextrudedproducts.Themannerinwhichthe
(single-letter) will be used for the major reinforcement or
tolerances are obtained is not relevant.
combination, or both, along with two numbers which indicate
6.2 Tubular bar and compression molded dimensions shall
the percentage of addition by mass with the tolerances as
be supplied in the unfinished condition, unless otherwise
tabulated below. This must be included in all Table 1 callouts.
specified at time of order, sufficient to finish to the nominal
Tolerance
dimension ordered.
Symbol Material (Based on the Total
6.3 The maximum allowable camber or bow, or both, shall
Mass);
be within the limits referenced in Tables A and B.
C Carbon and graphite fiber 62%
G Glass 62%
7. Workmanship, Finish, and Appearance
L Lubricants (for example, PTFE, graphite, 62%
silicone and molybdenum disulfide) 7.1 Appearance—The color of products shall be as pub-
M Mineral 62%
lished by the shapes manufacturer. They shall be uniform in
R Combinations of reinforcements by agree- 63%
color throughout the thickness. Specific colors and color
ment between supplier a and the user for
the total reinforcement or fillers, or both matching only as agreed to by order. Physical properties may
be affected by colors.
4.5 Callout Designation—A one-line system shall be used
7.2 Finish—All products shall be free of blisters, wrinkles,
to specify PAEK materials covered by this specification. The
cracks, gouges and defects that restrict commercial use of the
system uses predefined cells to refer to specific aspects of this
product. Special surface finish shall be supplied only when
specification, as illustrated below:
specified in the purchase order or contract.
4.5.1 Description:
7.3 Defects—All products shall be free of voids, dirt,
4.5.1.1 Example 1—Extruded natural PAEK extruded rod:
foreign material and embedded particles exceeding ⁄32 in. [0.8
CELL CALLOUT: S-PAEK0111
mm] maximum diameter as defined below.
S-PAEK01 = Product made from PAEK resin in accordance with 7.3.1 The criteria for determining the internal cleanliness
Table S-PAEK
shall be external visual inspection.Amaximum number of two
D 6262 – 98 (2003)
internal defects per square foot of plate/sheet and one foot 11.2.2 Testing Procedure—Placethespecimeninanoilbath
length of rod and tubular bar. Clusters of defects less than ⁄32 consisting of polyalkylene glycol or an air circulating oven and
in. [0.8 mm] diameter are to be counted as a single defect. heated to the applicable temperature for PAEK type as noted
below. Measure the outside diameter and thickness or length of
8. Sampling
the specimen as applicable at 73.4 6 1.8°F [23 6 1°C] to the
8.1 Sampling shall be statistically adequate to satisfy the
nearest 0.0001 in. [0.0025 mm]. See 11.2.2.1. After 6 h, the
requirements of this specification as applicable (see 2.2). specimen shall be allowed to slowly cool to room temperature
8.2 For purposes of sampling, an inspection lot for exami-
at a rate not to exceed 40°F [22°C] per hour. Then measure the
nation and tests shall consist of all material of the same type, specimen at 73.46 1.8°F [23 6 1°C] and calculate the percent
class, and grade and nominal size submitted for inspection at
change in each dimension.
one time. 11.2.2.1 Test temperatures:
PAEK 5 400 6 5.4°F @204 6 3°C# (1)
9. Number of Tests
11.2.3 Reproducibility—Inter-laboratory reproducibility is
9.1 Routine lot inspection shall consist of all the criteria
being determined and will be added within one year. Precision
specified in the applicable product tables.
statement will be finalized and included within two years.
9.2 The criteria listed in these product tables and definitions
11.3 Lengthwise Camber and Widthwise Bow:
are sufficient to establish conformity of the sheet, plate, rod or
11.3.1 Make all measurements for camber and bow using
tubular bars to this specification. When the number of test
the maximum distance rod, sheet, or plate deviates from the
specimens is not stated in the test method, a single determina-
straight line extended from edge to edge when measured in
tion may be made. If more than single determinations and
accordance with 11.3.2. The shape shall be oriented such that
separateportionsofthesamesamplearemade,theresultsshall
the weight of the product doesn’t influence the results.
be averaged. The final result shall conform to the requirements
11.3.2 Rod, Sheet and Plate.
prescribed in this specification.
11.3.2.1 Rod—Rod will be laid on side and measured with
10. Test Conditions
concave side facing the straight edge. Camber is measured
from the straight edge to the maximum concave point on rod.
10.1 Conditioning of Specimens—The specification values
Camber may not exceed the values of Table A for extruded or
and dimensions are based on conditioning techniques outlined
compression molded product.
in Procedure A of Practice D 618.
⁄8 in. [16 mm]
11.3.2.2 Sheet and Plate up to and Including
10.2 Standard Temperature—Thetestsshallbeconductedat
Thick—Plate up to and including ⁄8 in. [16 mm] in thickness
the standard laboratory temperature of 73.4 6 3.6°F [23 6
shall meet the requirements of Table B for extruded or
2°C] and 50 6 5 % RH.
compression molded products with a straight edge, positioned
11. Test Methods
in a lengthwise and widthwise direction, with the plate stand-
ing on its edge.
11.1 Tensile stress at break, elongation at break, and tensile
11.3.2.3 Sheet and Plate Greater than ⁄8 in. [16 mm]
modulus (tangent) in accordance with Test Method D 638, at
Thick—Plate above ⁄8 in. [16 mm] thick shall not exceed the
the rate of 0.2 in. [5 mm]/min.
requirements of Table B for extruded or compression product
11.1.1 All plate and sheet specimens are in accordance with
on the lengthwise ends and widthwise edges when laid on a flat
Type I of Test Method D 638.
surface (crown side down).
11.1.2 All rod specimens are in accordance with Type I of
11.3.3 Reproducibility—Inter-laboratory reproducibility is
Test Method D 638.
being determined and will be added within one year. The
11.1.3 All tubular bar specimens are in accordance with
precision statement will be finalized and included within two
Type I of Test Method D 638.
11.2 Dimensional Stability: years.
11.4 Squareness (Based ona4ft [120 cm] Nominal Length:
11.2.1 Specimen Preparation (a Minimum of Three Test
Samples Required): 11.4.1 Measure and compare diagonal lengths (corner to
corner).Accept the product if the difference is ⁄16 in. [1.6 mm]
11.2.1.1 Rods and Tubular Bar—Prepare each specimen by
cutting a 1.5 in. [35 mm] long slice from the shape to be tested. or less and the measured minimums diagonal meets the
following requirements: 1 ft wide is 49- ⁄2 in. [125.5 cm]
The slice shall then be machined, using a coolant and good
machining practices to a length of 1.000 6 0.005 in. [25 6 minimum; 2 ft wide is 53- ⁄4 in. [136.5 cm] minimum; and 4 ft
wide is 68 in. [1463.0 cm] minimum.
0.13 mm]. Each end of the specimen shall have a machined
surface. 11.4.2 If the diagonal difference exceeds ⁄16 in. [1.6 mm]
proceedtomeasurethegap(thatisthedeviationfroma2ft[60
11.2.1.2 Plate and Sheer—Thetestisnotapplicabletosheet
under ⁄16 in. [4.8 mm] thick. Each specimen shall consist of a cm] framing square). The maximum allowable gap shall not
exceed ⁄8 in. [3.2 mm] except for the 1 ft [30 cm] wide sizes
2 in. [25 mm] diameter disc m
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