iTeh StandardsiTeh Standards
EURUSD
Your shopping cart is empty.
ASTM

ASTM D6301-98

(Practice)

Standard Practice for the Collection of Samples of Filterable and Nonfilterable Matter in Water

Standard Practice for the Collection of Samples of Filterable and Nonfilterable Matter in Water

SCOPE
1.1 This practice is applicable for sampling condensed steam in water, such as boiler feedwater, for the collection of filterable and (optional) nonfilterable matter using 0.45-µm membrane filter (filterable matter) and ion exchange media (nonfilterable matter).
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
09-Jul-1998
ICS
13.060.45 - Examination of water in general
Technical Committee
D19 - Water
Drafting Committee
D19.03 - Sampling Water and Water-Formed Deposits, Analysis of Water for Power Generation and Process Use, On-Line Water Analysis, and Surveillance of Water
Current Stage
Ref Project

Relations

Replaced By
ASTM D6301-03 - Standard Practice for the Collection of Samples of Filterable and Nonfilterable Matter in Water
Effective Date
10-Aug-2003
Referred By
ASTM D6502-10(2022) - Standard Test Method for Measurement of On-line Integrated Samples of Low Level Suspended Solids and Ionic Solids in Process Water by X-Ray Fluorescence (XRF)
Effective Date
10-Jul-1998

Buy Standard

ASTM D6301-98 - Standard Practice for the Collection of Samples of Filterable and Nonfilterable Matter in WaterASTM D6301-98 - Standard Practice for the Collection of Samples of Filterable and Nonfilterable Matter in Water
PreviousNext
Standard
ASTM D6301-98 - Standard Practice for the Collection of Samples of Filterable and Nonfilterable Matter in Water
English language
4 pages
sale 15% off
Preview
sale 15% off
Preview

Standards Content (Sample)


NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
Designation: D 6301 – 98
Standard Practice for
the Collection of Samples of Filterable and Nonfilterable
Matter in Water
This standard is issued under the fixed designation D 6301; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope 3.2.3 nonfilterable matter, n—includes all matter that will
pass through a 0.45-μm pore size filter and may be captured on
1.1 This practice is applicable for sampling condensed
anion, or cation ion exchange membranes, or both.
steam or water, such as boiler feedwater, for the collection of
filterable and (optional) nonfilterable matter using 0.45-μm
4. Summary of Practice
membrane filter (filterable matter) and ion exchange media
4.1 A typical sampling apparatus, commonly called a cor-
(nonfilterable matter).
rosion product sampler, is used to obtain integrated, represen-
1.2 This standard does not purport to address all of the
tative samples of filterable and nonfilterable matter using a
safety concerns, if any, associated with its use. It is the
0.45-μm membrane filter and ion exchange membranes. The
responsibility of the user of this standard to establish appro-
sampling is accomplished at system operating pressure and
priate safety and health practices and determine the applica-
sample temperature of #50°C. The practice utilizes a modified
bility of regulatory limitations prior to use.
stainless steel high pressure filter housing to accommodate a
2. Referenced Documents 47-mm diameter filter (for filterable matter) and if desired, ion
exchange membranes (for nonfilterable matter). The sample
2.1 ASTM Standards:
collection system (corrosion product sampler) is designed and
D 1066 Practice for Sampling Steam
2 operated specifically for quantitative determination of filterable
D 1129 Terminology Relating to Water
and nonfilterable matter. An important feature of the sampler is
D 1192 Guide for Equipment for Sampling Water and
the flow totalizer, which accurately determines the total volume
Steam in Closed Conduits
of sample water which has passed through the sampler,
D 1193 Specification for Reagent Water
regardless of changes in flowrate or pressure during the
D 3370 Practice for Sampling Water from Closed Conduits
collection period. Control and pressure reducing valves and
D 3864 Guide for Continual On-Line Monitoring Systems
metering devices are downstream of the filter housing to
for Water Analysis
eliminate the possible contribution of filterable and nonfilter-
3. Terminology able matter from these components to the sample stream.
Additional flow may bypass the filter housing, so that flows
3.1 Definitions—For definitions of terms used in this prac-
within the sample lines are maintained within required range
tice, refer to Terminology D 1129.
(see Guide D 3864). If a single sampling point is not represen-
3.2 Definitions of Terms Specific to This Standard:
tative due to lack of homogeneity in the process fluid (the water
3.2.1 corrosion product sampler, n—a device used to col-
being sampled), multiple point sampling may be required.
lect integrated samples of filterable and (as an option) nonfil-
terable matter. It consists of a flow totalizer that accurately
5. Significance and Use
measures the amount of sample passing through the device and
5.1 The transport of suspended and corrosion products from
a 0.45-μm pore size membrane filter. Adding a second filter
the preboiler cycle has been shown to be detrimental to all
holder for ion exchange resin impregnated membranes allows
types of steam generating equipment. Corrosion product trans-
for collecting nonfilterable matter.
port as low as 10 ppb can have significant impact on steam
3.2.2 filterable matter, n—includes all matter that is re-
generators performance.
moved by a 0.45-μm pore size filter.
5.2 Deposited corrosion products on PWR steam generator
tubes can reduce heat transfer, and, if the deposit is sufficiently
This practice is under the jurisdiction of ASTM Committee D-19 on Water and
thick, can provide a local area for impurities in the bulk water
is the direct responsibility of Subcommittee D19.03 on Sampling of Water and
to concentrate, resulting in a corrosive environment. In BWR
Water-formed Deposits, Surveillance of Water, and Flow Measurement of Water
plants, the transport of corrosion products can cause fuel
Samples.
Current edition approved July 10, 1998. Published December 1998.
Annual Book of ASTM Standards, Vol 11.01.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
D6301–98
FIG. 1 Simplified Flow Diagram for Corrosion Product Sampler
NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
D6301–98
failure, out of core radiation problems from activation reac- 9. Calibration
tions, and other material related problems.
9.1 Calibrate the flow totalizer following the manufacturer’s
5.3 In fossil plants, the transport of corrosion products can
recommendation.
reduce heat transfer in the boilers leading to tube failures from
overheating. The removal of these corrosion products by
10. Procedure
chemical cleaning is expensive and potentially harmful to the
10.1 If subsequent chemical analysis of collected filterable/
boiler tubes.
nonfilterable material is desired, record the lot numbers of the
5.4 Normally, grab samples are not sensitive enough to
ion exchange membranes. Prepare sample blanks from same
detect changes in the level of corrosion product transport. Also,
lot.
system transients may be missed by only taking grab samples.
10.2 Install filter and optional ion exchange membranes in
An integrated sample over time will increase the sensitivity for
filter holder so that the sample goes through the filter first,
detecting the corrosion products and provide a better under-
taking care to ensure tha
...

Questions, Comments and Discussion

Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.

This May Also Interest You

ASTM
ASTM D5241-92(2024)(Practice)
Standard Practice for Micro-Extraction of Water for Analysis of Volatile and Semi-Volatile Organic Compounds in Water

SIGNIFICANCE AND USE
4.1 This practice provides a general procedure for the solvent extraction of volatile and semi-volatile organic compounds from a water matrix. Solvent extraction is used as the initial step in the solvent extraction of organic constituents for the purpose of quantifying extractable organic compounds.  
4.2 Typical detection limits that can be achieved using micro-extraction techniques with gas chromatography (GC) with flame ionization detector (FID), electron capture detector (ECD), or with a mass spectrometer (GC/MS) range from milligrams per litre (mg/L) to nanograms per litre (ng/L). The detection limit, linear concentration range, and sensitivity of the test method for a specific organic compound will depend upon the sample clean-up, injection volume, solvent to sample ratio, solvent concentration methods used, and the determinative technique employed.  
4.3 Micro-extraction has the advantage of speed, simple extraction devices, and the use of small amounts of sample and solvents.  
4.3.1 Selectivity can be improved by the choice of solvent (usually hexane or pentane) or mixed solvents, extraction time and temperature, and ionic strength of the solution.  
4.3.2 Extraction devices can vary from the sample container itself to commercial devices specifically designed for micro-extraction. See 7.1 and 7.2.  
4.3.3 A list of chlorinated organic compounds that can be determined by this practice includes both high and low boiling compounds or chemicals (see Table 1). (A) Based on the injection of chlorinated compounds in pentane solution, taking into consideration the 100:1 concentration of a water sample by the microextraction technique.
SCOPE
1.1 This practice covers standard procedures for extraction of volatile and semi-volatile organic compounds from water using small volumes of solvents.  
1.2 The compounds of interest must have a greater solubility in the organic solvent than the water phase.  
1.3 Not all of the solvents that can be used in micro extraction are addressed in this practice. The applicability of a solvent to extract the compound(s) of interest must be demonstrated before use.  
1.4 This practice provides sample extracts suitable for any technique amenable to solvent injection such as gas chromatography or high performance liquid chromatography (HPLC).  
1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 9.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    5 pages
    English language
    sale 15% off
ASTM
ASTM D7315-17(2023)(Test Method)
Standard Test Method for Determination of Turbidity Above 1 Turbidity Unit (TU) in Static Mode

SIGNIFICANCE AND USE
5.1 Turbidity at the levels defined in the scope of this test method are often monitored to help control processes, monitor the health and biology of water environments and determine the impact of changes in response to environmental events (weather events, floods, etc.). Turbidity is often undesirable in drinking water, plant effluent waters, water for food and beverage processing, and for a large number of other water-dependent manufacturing processes. Removal is often accomplished by coagulation, sedimentation, and various levels of filtration. Measurement of turbidity provides an indicator of contamination, and is a vital measurement for monitoring the characteristics and or quality within the sample’s source or process.  
5.2 This test method does overlap Test Method D6855 for the range of 1 to 5 TU. If the predominant measurement falls below 1.0 TU with occasional spikes above this value, Test Method D6855 may be more applicable. For measurements that are consistently above 1 TU, this test method is applicable.  
5.3 This test method is suitable to turbidity such as that found in all waters that measure above 1 NTU. Examples include environmental waters (streams, rivers, lakes, reservoirs, estuaries), processes associated with water pollution control plants (wastewater treatment plants), and various industrial processes involving water with noticeable turbidity. For measurement of cleaner waters, refer to Test Method D6855.  
5.4 The appropriate measurement range for a specific technology or instrument type that should be utilized is at or below 80 % of full-scale capability for the respective instrument or technology. Measurements above this level may not be dependable.  
5.4.1 Dilutions of waters are not recommended, especially in the case of samples with rapidly settling particles (that is, sediments). It is recommended that an appropriate instrument design that covers the expected range be selected to avoid the need to perform dilutions.  
5.5 Technol...
SCOPE
1.1 This test method covers the static determination of turbidity in water. Static refers to a sample that is removed from its source and tested in an isolated instrument. (See Section 4.)  
1.2 This test method is applicable to the measurement of turbidities greater than 1.0 turbidity unit (TU). The upper end of the measurement range was left undefined because different technologies described in this test method can cover very different ranges. The round robin study covered the range of 0 to 4000 turbidity units because instrument verification in this range can typically be covered by standards that can be consistently reproduced.  
1.3 Many of the turbidity units and instrument designs covered in this test method are numerically equivalent in calibration when a common calibration standard is applied across those designs listed in Table 1. Measurement of a common calibration standard of a defined value will also produce equivalent results across these technologies.  
1.3.1 In this test method calibration standards are often defined in NTU values, but the other assigned turbidity units, such as those in Table 1 are equivalent. For example, a 1 NTU formazin standard is also a 1 FNU, a 1 FAU, a 1 BU, and so forth.  
1.4 This test method does not purport to cover all available technologies for high-level turbidity measurement.  
1.5 This test method was tested on different natural waters and wastewater, and with standards that will serve as surrogates to samples. It is the user's responsibility to ensure the validity of this test method for waters of untested matrices.  
1.6 Depending on the constituents within a high-level sample, the proposed sample preparation and measurement methods may or may not be applicable. Those samples with the highest particle densities typically prove to be the most difficult to measure. In these cases, and alternative measurement method such as the process monitoring method can be consi...

  • Standard
    22 pages
    English language
    sale 15% off
ASTM
ASTM D3976-22(Practice)
Standard Practice for Preparation of Sediment Samples for Chemical Analysis

SIGNIFICANCE AND USE
5.1 The chemical analysis of sediments, collected from such locations as streams, rivers, ponds, lakes, and oceans can provide information of environmental significance.  
5.2 Sediment samples are inherently heterogeneous in that they contain occluded water in varying and unpredictable amounts and may contain foreign objects or material not ordinarily considered as sediment, the inclusion of which would result in inaccurate analysis.  
5.3 Standard methods for separating foreign objects to facilitate homogenization will minimize errors due to poor mixing and inclusion of extraneous material.  
5.4 Standardized procedures for drying provide a means for reporting analytical values to a common dry weight basis.
SCOPE
1.1 This practice describes standard procedures for preparation of test samples (including the removal of occluded water and moisture) of field samples collected from locations such as streams, rivers, ponds, lakes, and oceans.  
1.2 These procedures are applicable to the determination of volatile, semivolatile, and nonvolatile constituents of sediments.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For a specific precautionary statement, see Note 3.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    3 pages
    English language
    sale 15% off
  • Standard
    3 pages
    English language
    sale 15% off
ASTM
ASTM D5847-22(Practice)
Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis

SIGNIFICANCE AND USE
5.1 In order to be certain that the end user of analytical results obtained from using an ASTM Committee D19 test method can be confident that the values have been obtained through a competent application of the test method, a demonstration of the proficiency of the analytical system shall be performed. Appropriate proficiency is demonstrated by achievement of performance criteria derived from results of the test method collaborative study. The QC measures specified in this practice shall be included in each ASTM test method, as applicable, to ensure the quality of measurements.  
5.2 In order for users of D19 test methods to achieve consistently valid results, a minimum level of QC shall be performed. This minimum level of QC is stipulated in this practice and by the task groups developing D19 test methods. If the specific requirements outlined in this practice are not applicable to the test method, alternative QC shall be defined in the test method.
SCOPE
1.1 This practice provides specific, mandatory requirements for incorporating quality control (QC) procedures into all test methods under the jurisdiction of Committee D19.  
1.2 ASTM International has adopted the following:
Policy on implementation of requirements for a quality control section in standard test methods generated by Committee D19 on Water.  
GENERAL—By July 29, 1998, or at the next reapproval or revision, whichever is later, every D19 Standard Test Method shall contain a QC section that is in full compliance with the requirements of this practice.  
NEW COLLABORATIVE TESTING—As of July 29, 1998, each collaborative study design shall include a QC section as part of the method to be tested. Prior to approval of the study design, the Results Advisor or equivalent shall ascertain the appropriateness of the QC section in meeting the requirements of this practice and Practice D2777, and shall advise the designer of the study of any changes needed to fulfill the requirements of these practices. Before a collaborative study may be conducted, approval of the study design by the Results Advisor or equivalent shall be obtained.  
OLDER VALIDATED METHODS—Standard test methods that were validated using Practices D2777 – 77, D2777 – 86, or D2777 – 94, when balloted for reapproval or revision, shall contain a QC section based upon the best information from the historical record. Where appropriate, information derived from the record of the collaborative study shall be utilized for this purpose. The introduction of the QC section into these standard test methods shall not be construed as a requirement for a new collaborative study, though the Subcommittee may opt for such a study. Any information available regarding QC or precision/bias testing shall be included in the appropriate sections of the published test method.  
1.3 Required QC sections in all applicable test methods are intended to achieve two goals. First, users of Committee D19 test methods will be able to demonstrate a minimum competency in the performance of these test methods by comparison with collaborative study data. Second, all users of test methods will be required to perform a minimum level of QC as part of proper implementation of these test methods to ensure ongoing competency.  
1.4 This practice contains the primary requirements for QC of a specific test method. In many cases, it may be desirable to implement additional QC requirements to assure the desired quality of data.  
1.5 The specific requirements in this practice may not be applicable to all test methods. These requirements may vary depending on the type of test method used as well as the analyte being determined and the sample matrix being analyzed.  
1.5.1 If there are compelling reasons why any of the specific QC requirements listed in this practice are not applicable to a specific test method, these reaso...

  • Standard
    12 pages
    English language
    sale 15% off
  • Standard
    12 pages
    English language
    sale 15% off
ASTM
ASTM D6301-21(Practice)
Standard Practice for Collection of On-Line Composite Samples of Suspended Solids and Ionic Solids in Process Water

SIGNIFICANCE AND USE
5.1 The transport of any suspended solids or corrosion products from the preboiler cycle has been shown to be detrimental to all types of steam generating equipment. Corrosion product transport as low as 10 ppb can have significant impact on steam generators performance.  
5.2 Deposited corrosion products on pressurized water reactor (PWR) steam generator tubes can reduce heat transfer, and, if the deposit is sufficiently thick, can provide a local area for impurities in the bulk water to concentrate, resulting in a corrosive environment. In boiling water reactor (BWR) plants, the transport of corrosion products can cause fuel failure, out of core radiation problems from activation reactions, and other material related problems.  
5.3 In fossil plants, the transport of corrosion products can reduce heat transfer in the boilers leading to tube failures from overheating. The removal of these corrosion products by chemical cleaning is expensive and potentially harmful to the boiler tubes.  
5.4 Normally, grab samples are not sensitive enough to detect changes in the level of corrosion product transport. Also, system transients may be missed by only taking grab samples. An integrated sample over time will increase the sensitivity for detecting the corrosion products and provide a better understanding of the total corrosion product transport to steam generators.
SCOPE
1.1 This practice is applicable for sampling condensed steam or water, such as boiler feedwater, for the collection of suspended solids and (optional) ionic solids using a 0.45-μm membrane filter (suspended solids) and ion exchange media (ionic solids). As the major suspended component found in most boiler feedwaters is some form of corrosion product from the preboiler system, the device used for this practice is commonly called a corrosion product sampler.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    5 pages
    English language
    sale 15% off
  • Standard
    5 pages
    English language
    sale 15% off
ASTM
ASTM D8429-21(Test Method)
Standard Test Method for Legionella pneumophila in Water Samples Using Legiolert

SIGNIFICANCE AND USE
5.1 This test provides an easy and reliable method for the detection of L. pneumophila in potable and non-potable waters in 7 days.  
5.2 Routine monitoring for L. pneumophila determines whether implemented control measures are effective, such as those outlined in a water safety program (2).  
5.2.1 Water system management is necessary to maintain L. pneumophila concentrations below hazardous levels. Through routine measurement of L. pneumophila levels, a monitoring program can ensure that control measures are effective and implemented when necessary in response to increasing levels. Water samples may be examined for L. pneumophila during epidemiological investigations as part of local authority, industrial, or hospital programs, or in order to validate treatment control methods. Routine sampling could also be carried out based on risk assessments or on local, state, or federal requirements or guidelines.
SCOPE
1.1 This test method describes a simple procedure for the detection of Legionella pneumophila (L. pneumophila) in potable water and non-potable waters (cooling towers, for example). This procedure describes a liquid culture method based on a bacterial enzyme technology. The detection of L. pneumophila is signaled through the utilization of a substrate present in the Legiolert reagent. L. pneumophila cells grow rapidly and reproduce using the rich supply of amino acids, vitamins and other nutrients present in the Legiolert reagent. Actively growing strains of L. pneumophila use the added substrate to produce a brown color indicator or produce turbid growth with or without brown coloration. Legiolert can detect this bacterial species at the following minimum concentrations based on the protocol employed:  
1.1.1 Potable Water:  
1.1.1.1 ≥1 organism / 100 mL at 7 days for 100 mL potable protocol.
1.1.1.2 ≥1 organism / 10 mL at 7 days for 10 mL potable protocol.  
1.1.2 Non-potable Water:  
1.1.2.1 ≥1 organism / 1.0 mL at 7 days for 1.0 mL non-potable protocol.
1.1.2.2 ≥1 organism / 0.1 mL at 7 days for 0.1 mL non-potable protocol.  
1.1.3 This test method can be used for potable (drinking) waters and non-potable waters such as cooling tower waters (1).3 It is the user’s responsibility to ensure the validity of this test method for waters of untested matrices.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    7 pages
    English language
    sale 15% off
ASTM
ASTM D7366-08(2019)(Practice)
Standard Practice for Estimation of Measurement Uncertainty for Data from Regression-based Methods

SIGNIFICANCE AND USE
5.1 Appropriate application of this practice should result in an estimate of the test-method’s uncertainty (at any concentration within the working range), which can be compared with data-quality objectives to see if the uncertainty is acceptable.  
5.2 With data sets that compare recovered concentration with true concentration, the resulting regression plot allows the correction of the recovery data to true values. Reporting of such corrections is at the discretion of the user.  
5.3 This practice should be used to estimate the measurement uncertainty for any application of a test method where measurement uncertainty is important to data use.
SCOPE
1.1 This practice establishes a standard for computing the measurement uncertainty for applicable test methods in Committee D19 on Water. The practice does not provide a single-point estimate for the entire working range, but rather relates the uncertainty to concentration. The statistical technique of regression is employed during data analysis.  
1.2 Applicable test methods are those whose results come from regression-based methods and whose data are intra-laboratory (not inter-laboratory data, such as result from round-robin studies). For each analysis conducted using such a method, it is assumed that a fixed, reproducible amount of sample is introduced.  
1.3 Calculation of the measurement uncertainty involves the analysis of data collected to help characterize the analytical method over an appropriate concentration range. Example sources of data include: (1) calibration studies (which may or may not be conducted in pure solvent), (2) recovery studies (which typically are conducted in matrix and include all sample-preparation steps), and (3) collections of data obtained as part of the method’s ongoing Quality Control program. Use of multiple instruments, multiple operators, or both, and field-sampling protocols may or may not be reflected in the data.  
1.4 In any designed study whose data are to be used to calculate method uncertainty, the user should think carefully about what the study is trying to accomplish and much variation should be incorporated into the study. General guidance on designing studies (for example, calibration, recovery) is given in Appendix X1. Detailed guidelines on sources of variation are outside the scope of this practice, but general points to consider are included in Appendix X2, which is not intended to be exhaustive. With any study, the user must think carefully about the factors involved with conducting the analysis, and must realize that the computed measurement uncertainty will reflect the quality of the input data.  
1.5 Associated with the measurement uncertainty is a user-chosen level of statistical confidence.  
1.6 At any concentration in the working range, the measurement uncertainty is plus-or-minus the half-width of the prediction interval associated with the regression line.  
1.7 It is assumed that the user has access to a statistical software package for performing regression. A statistician should be consulted if assistance is needed in selecting such a program.  
1.8 A statistician also should be consulted if data transformations are being considered.  
1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.10 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    7 pages
    English language
    sale 15% off
ASTM
ASTM D3975-93(2019)(Practice)
Standard Practice for Development and Use (Preparation) of Samples for Collaborative Testing of Methods for Analysis of Sediments

SIGNIFICANCE AND USE
5.1 The objective of this practice is to provide guidelines for the preparation of samples for use in collaborative tests, to evaluate methods during their development, and for the evaluation of the precision and bias of proposed test methods.  
5.2 Statements of the precision and bias are a mandatory part of ASTM test methods. Such an evaluation is necessary to provide guidance to the user as to the reliability of measurements that can be expected by its use. The statements are developed on the basis of user experience (ordinarily collaborative tests) with the test method.  
5.3 The availability of test samples is a key requirement for collaborative evaluation of test methods.
SCOPE
1.1 This practice establishes uniform general procedures for the development (preparation) and use of samples in the collaborative testing of methods for chemical analysis of sediments and similar materials.  
1.2 The principles of this practice are applicable to aqueous samples with suitable technical modifications.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    5 pages
    English language
    sale 15% off
ASTM
ASTM D6362-98(2018)(Practice)
Standard Practice for Certificates of Reference Materials for Water Analysis

SIGNIFICANCE AND USE
4.1 This practice is designed to assist suppliers and users of reference materials by identifying the information necessary on the certificate of analysis of materials designated for use in ASTM test methods. This practice is specifically designed to ensure that materials suitable for use as either calibration or quality control standards are available. This practice does not define a specific certification protocol, but rather provides guidance in the development of adequate data to support the use of the material as either a calibration or quality control standard. Suppliers are referred to ISO Guide 35 for guidelines on acceptable certification protocols. End users are referred to ISO Guide 31 for a more complete description of the elements of typical certificates of analysis.
SCOPE
1.1 This practice covers the information that must be provided on certificates of analysis of reference materials designated to support ASTM methods. It provides end users of these materials with a defined set of data that is required to be on a certificate of analysis and provides information to assist the end user in evaluating the independence of the material. Similarly, it provides the suppliers of reference materials with a consistent format for the presentation of certification data.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    6 pages
    English language
    sale 15% off
ASTM
ASTM D596-01(2018)(Guide)
Standard Guide for Reporting Results of Analysis of Water

SIGNIFICANCE AND USE
4.1 The proper use of analytical data requires adequate documentation of all inputs, that is, the source and history of the sample, laboratory performing the analysis, method of analysis, date of analysis, precision and bias of the measurements, and related quality assurance information.  
4.2 In order to have defensible data, the report must be complete and accurate, providing adequate information to evaluate the quality of the data and contain supporting information that documents sampling and analysis procedures.  
4.3 This guide contains some of the common data qualifiers or “flags” commonly used by laboratories following the good laboratory practices, the government contract program, or found in the commercial laboratories. Examples of these qualifiers are the use of (E) for estimated value, (U) for analyzed for but not detected, and (B) for analyte was found in the blank (see 8.11). The qualifiers included in this guide should help the laboratory and its customers to better understand each other by using standardized qualifiers.  
4.4 Practice D933 is a comprehensive practice for reporting water-formed constituents such as metal oxides, acid anhydrides, and others.
SCOPE
1.1 This guide provides guidelines for reporting inorganic and organic results of analyses of drinking water, waste water, process water, ground water, and surface water, and so forth, to laboratory clients in a complete and systematic fashion.  
1.2 The reporting of bacterial and radiological data are not addressed in this guide.  
1.3 The commonly used data qualifiers for reviewing and reporting information are listed and defined. Client and laboratory specific requirements may make use of other qualifiers. This guide does not preclude the use of other data qualifiers.  
1.4 This guide discusses procedures for and specific problems in the reporting of low level data, potential errors (Type I and Type II), and reporting data that are below the calculated method detection limit and above the analyte.  
1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Guide
    6 pages
    English language
    sale 15% off