Standard Test Method for Conducting Cyclic Galvanostaircase Polarization

SCOPE
1.1 This test method covers a procedure for conducting cyclic galvanostaircase polarization (GSCP) to determine relative susceptibility to localized corrosion (pitting and crevice corrosion) for aluminum alloy 3003-H14 (UNS A93003) (1). It may serve as guide for examination of other alloys (2-5). This test method also describes a procedure that can be used as a check for one's experimental technique and instrumentation.
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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Publication Date
31-Oct-2004
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ASTM G100-89(2004) - Standard Test Method for Conducting Cyclic Galvanostaircase Polarization
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information.
Designation:G100–89(Reapproved 2004)
Standard Test Method for
Conducting Cyclic Galvanostaircase Polarization
This standard is issued under the fixed designation G100; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope are not intended to correlate in a quantitative manner with the
rate of propagation of localized corrosion that one might
1.1 This test method covers a procedure for conducting
observe in service.
cyclic galvanostaircase polarization (GSCP) to determine rela-
3.2 The breakdown (E ), and protection potentials (E )
tive susceptibility to localized corrosion (pitting and crevice b prot
determined by the cyclic GSCP method correlate with the
corrosion) for aluminum alloy 3003-H14 (UNSA93003) (1).
constant potential corrosion test (immersion-glassware) result
It may serve as guide for examination of other alloys (2–5).
for aluminum (1, 6, 8). When the applied potential was more
Thistestmethodalsodescribesaprocedurethatcanbeusedas
negative than the GSCP E , no pit initiation was observed.
a check for one’s experimental technique and instrumentation. prot
When the applied potential was more positive than the GSCP
1.2 This standard does not purport to address all of the
E ,pittingoccurredevenwhentheappliedpotentialwasless
safety concerns, if any, associated with its use. It is the prot
negative than E .
b
responsibility of the user of this standard to establish appro-
3.2.1 Severecrevicecorrosionoccurredwhentheseparation
priate safety and health practices and determine the applica-
of E and E was 500 mV or greater and E was less
b prot prot
bility of regulatory limitations prior to use.
than−400 mV Vs. SCE (in 100 ppm NaCl) (1, 6, 7). For
2. Referenced Documents
aluminum, E determined by cyclic GSCP agrees with the
prot
repassivationpotentialdeterminedbythescratchpotentiostatic
2.1 ASTM Standards:
method (1, 10). Both the scratch potentiostatic method and the
D1193 Specification for Reagent Water
constant potential technique for determination of E require
prot
G1 Practice for Preparing, Cleaning, and Evaluating Corro-
much longer test times and are more involved techniques than
sion Test Specimens
the GSCP method.
G5 Reference Test Method for Making Potentiostatic and
3.3 DeBerry and Viebeck (3–5) found that the breakdown
Potentiodynamic Anodic Polarization Measurements
potentials (E ) (galvanodynamic polarization, similar to GSCP
G59 Test Method for Conducting Potentiodynamic Polar- b
but no kinetic information) had a good correlation with the
ization Resistance Measurements
inhibition of localized corrosion of 304L stainless steel by
G69 Test Method for Measurement of Corrosion Potentials
surface active compounds. They attained accuracy and preci-
of Aluminum Alloys
sion by avoiding the strong induction effect which they
3. Significance and Use
observed by the potentiodynamic technique.
3.4 If this test method is followed using the specific alloy
3.1 In this test method, susceptibility to localized corrosion
discussed it will provide (GSCP) measurements that will
of aluminum is indicated by a protection potential (E )
prot
reproduce data developed at other times in other laboratories.
determined by cyclic galvanostaircase polarization (1). The
3.5 E and E obtainedarebasedontheresultsfromeight
more noble this potential, the less susceptible is the alloy to
b prot
different laboratories that followed the standard procedure
initiationoflocalizedcorrosion.Theresultsofthistestmethod
using aluminum alloy 3003-H14 (UNS A93003). E and E
b prot
are included with statistical analysis to indicate the acceptable
This test method is under the jurisdiction of ASTM Committee G01 on
range.
Corrosion of Metals and is the direct responsibility of Subcommittee G1.11 on
Electrochemical Measurements in Corrosion Testing.
4. Apparatus
Current edition approved Nov 1, 2004. Published November 2004. Originally
approved in 1989. Last previous edition approved in 1999 as G100–1999). DOI:
4.1 Cell—The cell should be constructed of inert materials
10.1520/G0100-89R04.
such as borosilicate glass and PTFE fluorocarbon. It should
Theboldfacenumbersinparenthesesrefertothelistofreferencesattheendof
have ports for the insertion of a working electrode (1 cm flat
this test method.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or specimen holder (Note 1) is very convenient), two auxiliary
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
electrodes, salt bridge for reference electrode, and a thermom-
Standards volume information, refer to the standard’s Document Summary page on
eterorathermostatprobefortemperaturecontrol.Thefigurein
the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
G100–89 (2004)
NOTE 3—Coarse grades of graphite should be avoided because they
Test Method G5 would be satisfactory, but a flat bottom cell is
absorb solute impurities. Ultrafine grades are available from spectro-
also satisfactory provided that all of the essential ports are
graphic supply companies.
provided. (See Ref (9) for details.)
4.3.3 Reference Electrode—Saturated calomel (Note 1). It
NOTE 1—These specific recommendations and conditions were fol-
should be checked against another reference which has not
lowedtoimprovetheinter-laboratoryprecisionduringtheroundrobinfor
been exposed to test solutions and they should be within 3 mV
galvanostaircase polarization.
of each other. Practice G69 round robin test conducted by
4.2 Current Staircase Generator and Recorder—The sche-
G01.11 (unpublished results) indicate that potential difference
matic diagram of the apparatus is given in Fig. 1.The recorder
should not exceed 2 or 3 mV. The reference electrode is
may be replaced by a plotter if the current staircase signal is
connected to the test bridge solution which consists of 75%
generatedwiththeaidofacomputer.Thecurrentstaircasemay
saturated KCl, prepared by adding 1 part (by volume) of
be generated manually (Note 2) but this is not recommended.
distilled water to 3 parts saturated KCl. When the bridge is in
The most convenient current staircase generators are found in
active use, the bridge solution should be replaced once each
recent commercial potentiostats where the software is avail-
day and the bridge tip immersed in this solution when not in
able. The electrical equipment may be checked in accordance
use. Any test solution that does not deposit films may also be
with the procedure in Practice G59.
usedinthebridge.(TheVYCOR tip should notbeallowedto
NOTE 2—The current staircase signal was generated manually in the go to dryness.)
roundrobinbecauseautomatedsystemorsoftwarewasnotavailablewhen
4.4 Magnetic Stirrer.
this project was started.
4.3 Electrodes: 5. Procedure
4.3.1 Working Electrode—For generating data to be com-
5.1 Test solution, 3000 6 30 ppm (0.0513 M) NaCl. For
paredtothereferencedataincludedhere
...

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