Standard Specification for Titanium and Titanium Alloy Seamless Pipe

ABSTRACT
This specification covers the requirements for 34 grades of titanium and titanium alloy seamless pipe intended for general corrosion resisting and elevated temperature service. Alloys may be supplied in the following conditions: Grades 5, 23, 24, 25, 29, 35, or 36 annealed or aged; Grades 9, 18, 28, or 38 cold-worked and stress-relieved or annealed; Grades 9, 18, 23, 28, or 29 transformed-beta condition; and Grades 19, 20, or 21 solution-treated or solution-treated and aged. The grades shall conform to the required chemical composition for nitrogen, carbon, hydrogen, iron, oxygen, aluminum, vanadium, tin, ruthenium, palladium, chromium, nickel, niobium, zirconium, silicon, and titanium. Chemical analysis and product analysis shall be performed. Mechanical requirements shall conform to the required room temperature values for tensile strength, yield strength, and elongation. The following shall also be performed: tension, flattening, bend, and hydrostatic tests.
SCOPE
1.1 This specification covers the requirements for 34 grades of titanium and titanium alloy seamless pipe intended for general corrosion resisting and elevated temperature service as follows:
1.1.1 Grade 1—Unalloyed titanium, low oxygen,
1.1.2 Grade 2—Unalloyed titanium, standard oxygen,
1.1.2.1 Grade 2H—Unalloyed titanium (Grade 2 with 58 ksi minimum UTS),
1.1.3 Grade 3—Unalloyed titanium, medium oxygen,
1.1.4 Grade 5—Titanium alloy (6 % aluminum, 4 % vanadium),
1.1.5 Grade 7—Unalloyed titanium plus 0.12 to 0.25 % palladium, standard oxygen,
1.1.5.1 Grade 7H—Unalloyed titanium plus 0.12 to 0.25 % palladium (Grade 7 with 58 ksi minimum UTS),
1.1.6 Grade 9—Titanium alloy (3 % aluminum, 2.5 % vanadium),
1.1.7 Grade 11—Unalloyed titanium plus 0.12 to 0.25 % palladium, low oxygen,
1.1.8 Grade 12—Titanium alloy (0.3 % molybdenum, 0.8 % nickel),
1.1.9 Grade 13—Titanium alloy (0.5 % nickel, 0.05 % ruthenium), low oxygen,
1.1.10 Grade 14—Titanium alloy (0.5 % nickel, 0.05 % ruthenium), standard oxygen,
1.1.11 Grade 15—Titanium alloy (0.5 % nickel, 0.05 % ruthenium), medium oxygen,
1.1.12 Grade 16—Unalloyed titanium plus 0.04 to 0.08 % palladium, standard oxygen,
1.1.12.1 Grade 16H—Unalloyed titanium plus 0.04 to 0.08 % palladium (Grade 16 with 58 ksi minimum UTS),
1.1.13 Grade 17—Unalloyed titanium plus 0.04 to 0.08 % palladium, low oxygen,
1.1.14 Grade 18—Titanium alloy (3 % aluminum, 2.5 % vanadium plus 0.04 to 0.08 % palladium),
1.1.15 Grade 19—Titanium alloy (3 % aluminum, 8 % vanadium, 6 % chromium, 4 % zirconium, 4 % molybdenum),
1.1.16 Grade 20—Titanium alloy (3 % aluminum, 8 % vanadium, 6 % chromium, 4 % zirconium, 4 % molybdenum) plus 0.04 to 0.08 % palladium,  
1.1.17 Grade 21—Titanium alloy (15 % molybdenum, 3 % aluminum, 2.7 % niobium, 0.25 % silicon),
1.1.18 Grade 23—Titanium alloy (6 % aluminum, 4 % vanadium, extra low interstitial, ELI),  
1.1.19 Grade 24—Titanium alloy (6 % aluminum, 4 % vanadium) plus 0.04 to 0.08 % palladium,
1.1.20 Grade 25—Titanium alloy (6 % aluminum, 4 % vanadium) plus 0.3 to 0.8 % nickel and 0.04 to 0.08 % palladium,
1.1.21 Grade 26—Unalloyed titanium plus 0.08 to 0.14 % ruthenium,
1.1.21.1 Grade 26H—Unalloyed titanium plus 0.08 to 0.14 % ruthenium (Grade 26 with 58 ksi minimum UTS),
1.1.22 Grade 27—Unalloyed titanium plus 0.08 to 0.14 % ruthenium,
1.1.23 Grade 28—Titanium alloy (3 % aluminum, 2.5 % vanadium plus 0.08 to 0.14 % ruthenium),
1.1.24 Grade 29—Titanium alloy (6 % aluminum, 4 % vanadium, extra low interstitial, ELI plus 0.08 to 0.14 % ruthenium),
1.1.25 Grade 33—Titanium alloy (0.4 % nickel, 0.015 % palladium, 0.025 % ruthenium, 0.15 % chromium),
1.1.26 Grade 34—Titanium alloy (0.4 % nickel, 0.015 % palladium, 0.025 % ruthenium, 0.15 % chromium),
1.1.27 Grade 35—Titanium alloy (4.5 % aluminum, 2 % molybdenum, 1.6 % vanadium, 0.5 % iron, 0.3 % silicon),
1.1.28 Grade 36—Titanium alloy (45 % niobium),
1.1.29 Grade 37—Titanium alloy (1.5 %...

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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:B861 −10
StandardSpecification for
1
Titanium and Titanium Alloy Seamless Pipe
This standard is issued under the fixed designation B861; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope* 1.1.15 Grade 19—Titanium alloy (3 % aluminum, 8 %
vanadium, 6 % chromium, 4 % zirconium, 4 % molybdenum),
1.1 This specification covers the requirements for 34 grades
1.1.16 Grade 20—Titanium alloy (3 % aluminum, 8 %
of titanium and titanium alloy seamless pipe intended for
vanadium, 6 % chromium, 4 % zirconium, 4 % molybdenum)
general corrosion resisting and elevated temperature service as
plus 0.04 to 0.08 % palladium,
follows:
1.1.17 Grade 21—Titanium alloy (15 % molybdenum, 3 %
1.1.1 Grade 1—Unalloyed titanium, low oxygen,
aluminum, 2.7 % niobium, 0.25 % silicon),
1.1.2 Grade 2—Unalloyed titanium, standard oxygen,
1.1.18 Grade 23—Titanium alloy (6 % aluminum, 4 %
1.1.2.1 Grade 2H—Unalloyedtitanium(Grade2with58ksi
vanadium, extra low interstitial, ELI),
minimum UTS),
1.1.19 Grade 24—Titanium alloy (6 % aluminum, 4 % va-
1.1.3 Grade 3—Unalloyed titanium, medium oxygen,
nadium) plus 0.04 to 0.08 % palladium,
1.1.4 Grade 5—Titanium alloy (6 % aluminum, 4 %
1.1.20 Grade 25—Titanium alloy (6 % aluminum, 4 % va-
vanadium),
nadium)plus0.3to0.8 %nickeland0.04to0.08 %palladium,
1.1.5 Grade 7—Unalloyed titanium plus 0.12 to 0.25 %
1.1.21 Grade 26—Unalloyed titanium plus 0.08 to 0.14 %
palladium, standard oxygen,
ruthenium,
1.1.5.1 Grade 7H—Unalloyed titanium plus 0.12 to 0.25 %
1.1.21.1 Grade 26H—Unalloyed titanium plus 0.08 to
palladium (Grade 7 with 58 ksi minimum UTS),
0.14 % ruthenium (Grade 26 with 58 ksi minimum UTS),
1.1.6 Grade 9—Titanium alloy (3 % aluminum, 2.5 %
1.1.22 Grade 27—Unalloyed titanium plus 0.08 to 0.14 %
vanadium),
ruthenium,
1.1.7 Grade 11—Unalloyed titanium plus 0.12 to 0.25 %
1.1.23 Grade 28—Titanium alloy (3 % aluminum, 2.5 %
palladium, low oxygen,
vanadium plus 0.08 to 0.14 % ruthenium),
1.1.8 Grade 12—Titaniumalloy(0.3 %molybdenum,0.8 %
1.1.24 Grade 29—Titanium alloy (6 % aluminum, 4 %
nickel),
vanadium, extra low interstitial, ELI plus 0.08 to 0.14 %
1.1.9 Grade 13—Titanium alloy (0.5 % nickel, 0.05 %
ruthenium),
ruthenium), low oxygen,
1.1.25 Grade 33—Titanium alloy (0.4 % nickel, 0.015 %
1.1.10 Grade 14—Titanium alloy (0.5 % nickel, 0.05 %
palladium, 0.025 % ruthenium, 0.15 % chromium),
ruthenium), standard oxygen,
1.1.26 Grade 34—Titanium alloy (0.4 % nickel, 0.015 %
1.1.11 Grade 15—Titanium alloy (0.5 % nickel, 0.05 %
palladium, 0.025 % ruthenium, 0.15 % chromium),
ruthenium), medium oxygen,
1.1.27 Grade 35—Titanium alloy (4.5 % aluminum, 2 %
1.1.12 Grade 16—Unalloyed titanium plus 0.04 to 0.08 %
molybdenum, 1.6 % vanadium, 0.5 % iron, 0.3 % silicon),
palladium, standard oxygen,
1.1.28 Grade 36—Titanium alloy (45 % niobium),
1.1.12.1 Grade 16H—Unalloyed titanium plus 0.04 to
1.1.29 Grade 37—Titanium alloy (1.5 % aluminum), and
0.08 % palladium (Grade 16 with 58 ksi minimum UTS),
1.1.30 Grade 38—Titanium alloy (4 % aluminum, 2.5 %
1.1.13 Grade 17—Unalloyed titanium plus 0.04 to 0.08 %
vanadium, 1.5 % iron).
palladium, low oxygen,
NOTE 1—H grade material is identical to the corresponding numeric
1.1.14 Grade 18—Titanium alloy (3 % aluminum, 2.5 %
grade (that is, Grade 2H = Grade 2) except for the higher guaranteed
vanadium plus 0.04 to 0.08 % palladium),
minimum UTS, and may always be certified as meeting the requirements
of its corresponding numeric grade. Grades 2H, 7H, 16H, and 26H are
intended primarily for pressure vessel use.
1
This specification is under the jurisdiction of ASTM Committee B10 on The H grades were added in response to a user association request
Reactive and Refractory Metals and Alloys and is the direct responsibility of
based on its study of over 5200 commercial Grade 2, 7, 16, and 26 test
Subcommittee B10.01 on Titanium.
reports, where over 99 % met the 58 ksi minimum UTS.
Current edition approved May 1, 2010. Published May 2010. Originally
1.2 The values stated in inch-pound units are to be regarded
approved in 1995. Last previous edition approved in 2009 as B861 – 09. DOI:
10.1520/B0861-10. as standard. The values given in parentheses are mathematical
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
B861−10
conversions to SI units that are provided for information only 4.1.10 In
...

This document is not anASTM standard and is intended only to provide the user of anASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:B861–09 Designation: B861 – 10
Standard Specification for
1
Titanium and Titanium Alloy Seamless Pipe
This standard is issued under the fixed designation B861; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope*
1.1 This specification covers the requirements for 34 grades of titanium and titanium alloy seamless pipe intended for general
corrosion resisting and elevated temperature service as follows:
1.1.1 Grade 1—Unalloyed titanium, low oxygen,
1.1.2 Grade 2—Unalloyed titanium, standard oxygen,
1.1.2.1 Grade 2H—Unalloyed titanium (Grade 2 with 58 ksi minimum UTS),
1.1.3 Grade 3—Unalloyed titanium, medium oxygen,
1.1.4 Grade 5—Titanium alloy (6 % aluminum, 4 % vanadium),
1.1.5 Grade 7—Unalloyed titanium plus 0.12 to 0.25 % palladium, standard oxygen,
1.1.5.1 Grade 7H—Unalloyed titanium plus 0.12 to 0.25 % palladium (Grade 7 with 58 ksi minimum UTS),
1.1.6 Grade 9—Titanium alloy (3 % aluminum, 2.5 % vanadium),
1.1.7 Grade 11—Unalloyed titanium plus 0.12 to 0.25 % palladium, low oxygen,
1.1.8 Grade 12—Titanium alloy (0.3 % molybdenum, 0.8 % nickel),
1.1.9 Grade 13—Titanium alloy (0.5 % nickel, 0.05 % ruthenium), low oxygen,
1.1.10 Grade 14—Titanium alloy (0.5 % nickel, 0.05 % ruthenium), standard oxygen,
1.1.11 Grade 15—Titanium alloy (0.5 % nickel, 0.05 % ruthenium), medium oxygen,
1.1.12 Grade 16—Unalloyed titanium plus 0.04 to 0.08 % palladium, standard oxygen,
1.1.12.1 Grade 16H—Unalloyed titanium plus 0.04 to 0.08 % palladium (Grade 16 with 58 ksi minimum UTS),
1.1.13 Grade 17—Unalloyed titanium plus 0.04 to 0.08 % palladium, low oxygen,
1.1.14 Grade 18—Titanium alloy (3 % aluminum, 2.5 % vanadium plus 0.04 to 0.08 % palladium),
1.1.15 Grade 19—Titanium alloy (3 % aluminum, 8 % vanadium, 6 % chromium, 4 % zirconium, 4 % molybdenum),
1.1.16 Grade 20—Titanium alloy (3 % aluminum, 8 % vanadium, 6 % chromium, 4 % zirconium, 4 % molybdenum) plus 0.04
to 0.08 % palladium,
1.1.17 Grade 21—Titanium alloy (15 % molybdenum, 3 % aluminum, 2.7 % niobium, 0.25 % silicon),
1.1.18 Grade 23—Titanium alloy (6 % aluminum, 4 % vanadium, extra low interstitial, ELI),
1.1.19 Grade 24—Titanium alloy (6 % aluminum, 4 % vanadium) plus 0.04 to 0.08 % palladium,
1.1.20 Grade 25—Titanium alloy (6 % aluminum, 4 % vanadium) plus 0.3 to 0.8 % nickel and 0.04 to 0.08 % palladium,
1.1.21 Grade 26—Unalloyed titanium plus 0.08 to 0.14 % ruthenium,
1.1.21.1 Grade 26H—Unalloyed titanium plus 0.08 to 0.14 % ruthenium (Grade 26 with 58 ksi minimum UTS),
1.1.22 Grade 27—Unalloyed titanium plus 0.08 to 0.14 % ruthenium,
1.1.23 Grade 28—Titanium alloy (3 % aluminum, 2.5 % vanadium plus 0.08 to 0.14 % ruthenium),
1.1.24 Grade 29—Titanium alloy (6 % aluminum, 4 % vanadium, extra low interstitial, ELI plus 0.08 to 0.14 % ruthenium),
1.1.25 Grade 33—Titanium alloy (0.4 % nickel, 0.015 % palladium, 0.025 % ruthenium, 0.15 % chromium),
1.1.26 Grade 34—Titanium alloy (0.4 % nickel, 0.015 % palladium, 0.025 % ruthenium, 0.15 % chromium),
1.1.27 Grade 35—Titanium alloy (4.5 % aluminum, 2 % molybdenum, 1.6 % vanadium, 0.5 % iron, 0.3 % silicon),
1.1.28 Grade 36—Titanium alloy (45 % niobium),
1.1.29 Grade 37—Titanium alloy (1.5 % aluminum), and
1.1.30 Grade 38—Titanium alloy (4 % aluminum, 2.5 % vanadium, 1.5 % iron).
NOTE 1—H grade material is identical to the corresponding numeric grade (that is, Grade 2H = Grade 2) except for the higher guaranteed minimum
1
This specification is under the jurisdiction of ASTM Committee B10 on Reactive and Refractory Metals and Alloys and is the direct responsibility of Subcommittee
B10.01 on Titanium.
Current edition approved Aug.May 1, 2009.2010. Published August 2009.May 2010. Originally approved in 1995. Last previous edition approved in 20082009 as
B861–08a.B861 – 09. DOI: 10.1520/B0861-109.
*A Summary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
B861 – 10
UTS, and may always be certified as meeting the requirements of its corresponding numeric grade. Grades 2H, 7H, 16H, and 26H are intended primarily
for pressure vessel use.
TheHgradeswereaddedinresponset
...

This document is not anASTM standard and is intended only to provide the user of anASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:B861–09 Designation: B861 – 10
Standard Specification for
1
Titanium and Titanium Alloy Seamless Pipe
This standard is issued under the fixed designation B861; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope*
1.1 This specification covers the requirements for 34 grades of titanium and titanium alloy seamless pipe intended for general
corrosion resisting and elevated temperature service as follows:
1.1.1 Grade 1—Unalloyed titanium, low oxygen,
1.1.2 Grade 2—Unalloyed titanium, standard oxygen,
1.1.2.1 Grade 2H—Unalloyed titanium (Grade 2 with 58 ksi minimum UTS),
1.1.3 Grade 3—Unalloyed titanium, medium oxygen,
1.1.4 Grade 5—Titanium alloy (6 % aluminum, 4 % vanadium),
1.1.5 Grade 7—Unalloyed titanium plus 0.12 to 0.25 % palladium, standard oxygen,
1.1.5.1 Grade 7H—Unalloyed titanium plus 0.12 to 0.25 % palladium (Grade 7 with 58 ksi minimum UTS),
1.1.6 Grade 9—Titanium alloy (3 % aluminum, 2.5 % vanadium),
1.1.7 Grade 11—Unalloyed titanium plus 0.12 to 0.25 % palladium, low oxygen,
1.1.8 Grade 12—Titanium alloy (0.3 % molybdenum, 0.8 % nickel),
1.1.9 Grade 13—Titanium alloy (0.5 % nickel, 0.05 % ruthenium), low oxygen,
1.1.10 Grade 14—Titanium alloy (0.5 % nickel, 0.05 % ruthenium), standard oxygen,
1.1.11 Grade 15—Titanium alloy (0.5 % nickel, 0.05 % ruthenium), medium oxygen,
1.1.12 Grade 16—Unalloyed titanium plus 0.04 to 0.08 % palladium, standard oxygen,
1.1.12.1 Grade 16H—Unalloyed titanium plus 0.04 to 0.08 % palladium (Grade 16 with 58 ksi minimum UTS),
1.1.13 Grade 17—Unalloyed titanium plus 0.04 to 0.08 % palladium, low oxygen,
1.1.14 Grade 18—Titanium alloy (3 % aluminum, 2.5 % vanadium plus 0.04 to 0.08 % palladium),
1.1.15 Grade 19—Titanium alloy (3 % aluminum, 8 % vanadium, 6 % chromium, 4 % zirconium, 4 % molybdenum),
1.1.16 Grade 20—Titanium alloy (3 % aluminum, 8 % vanadium, 6 % chromium, 4 % zirconium, 4 % molybdenum) plus 0.04
to 0.08 % palladium,
1.1.17 Grade 21—Titanium alloy (15 % molybdenum, 3 % aluminum, 2.7 % niobium, 0.25 % silicon),
1.1.18 Grade 23—Titanium alloy (6 % aluminum, 4 % vanadium, extra low interstitial, ELI),
1.1.19 Grade 24—Titanium alloy (6 % aluminum, 4 % vanadium) plus 0.04 to 0.08 % palladium,
1.1.20 Grade 25—Titanium alloy (6 % aluminum, 4 % vanadium) plus 0.3 to 0.8 % nickel and 0.04 to 0.08 % palladium,
1.1.21 Grade 26—Unalloyed titanium plus 0.08 to 0.14 % ruthenium,
1.1.21.1 Grade 26H—Unalloyed titanium plus 0.08 to 0.14 % ruthenium (Grade 26 with 58 ksi minimum UTS),
1.1.22 Grade 27—Unalloyed titanium plus 0.08 to 0.14 % ruthenium,
1.1.23 Grade 28—Titanium alloy (3 % aluminum, 2.5 % vanadium plus 0.08 to 0.14 % ruthenium),
1.1.24 Grade 29—Titanium alloy (6 % aluminum, 4 % vanadium, extra low interstitial, ELI plus 0.08 to 0.14 % ruthenium),
1.1.25 Grade 33—Titanium alloy (0.4 % nickel, 0.015 % palladium, 0.025 % ruthenium, 0.15 % chromium),
1.1.26 Grade 34—Titanium alloy (0.4 % nickel, 0.015 % palladium, 0.025 % ruthenium, 0.15 % chromium),
1.1.27 Grade 35—Titanium alloy (4.5 % aluminum, 2 % molybdenum, 1.6 % vanadium, 0.5 % iron, 0.3 % silicon),
1.1.28 Grade 36—Titanium alloy (45 % niobium),
1.1.29 Grade 37—Titanium alloy (1.5 % aluminum), and
1.1.30 Grade 38—Titanium alloy (4 % aluminum, 2.5 % vanadium, 1.5 % iron).
NOTE 1—H grade material is identical to the corresponding numeric grade (that is, Grade 2H = Grade 2) except for the higher guaranteed minimum
1
This specification is under the jurisdiction of ASTM Committee B10 on Reactive and Refractory Metals and Alloys and is the direct responsibility of Subcommittee
B10.01 on Titanium.
Current edition approved Aug.May 1, 2009.2010. Published August 2009.May 2010. Originally approved in 1995. Last previous edition approved in 20082009 as
B861–08a.B861 – 09. DOI: 10.1520/B0861-109.
*A Summary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
B861 – 10
UTS, and may always be certified as meeting the requirements of its corresponding numeric grade. Grades 2H, 7H, 16H, and 26H are intended primarily
for pressure vessel use.
TheHgradeswereaddedinresponset
...

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