Standard Test Method for Measurement of Corrosion Potentials of Aluminum Alloys

SIGNIFICANCE AND USE
The corrosion potential of an aluminum alloy depends upon the amounts of certain alloying elements that the alloy contains in solid solution. Copper and zinc, which are two of the major alloying elements for aluminum, have the greatest effect with copper shifting the potential in the noble or positive direction, and zinc in the active or negative direction. For example, commercially unalloyed aluminum (1100 alloy)3 has a potential of −750 mV when measured in accordance with this practice, 2024–T3 alloy with nearly all of its nominal 4.3 % copper in solid solution, a potential of −600 to −620 mV (Note 2), and 7072 alloy with nearly all of its nominal 1.0 % zinc in solid solution, a potential of − 885 mV (SCE) (1-3).4  
Note 2—The potential depends upon the rate of quenching.
Because it reflects the amount of certain alloying elements in solid solution, the corrosion potential is a useful tool for characterizing the metallurgical condition of aluminum alloys, especially those of the 2XXX and 7XXX types, which contain copper and zinc as major alloying elements. Its uses include the determination of the effectiveness of solution heat treatment and annealing (1), of the extent of precipitation during artificial aging (4) and welding (5), and of the extent of diffusion of alloying elements from the core into the cladding of alclad products (2).
SCOPE
1.1 This test method is a procedure for measurement of the corrosion potential (see Note 1) of an aluminum alloy in an aqueous solution of sodium chloride with enough hydrogen peroxide added to provide an ample supply of cathodic reactant.Note 1—The corrosion potential is sometimes referred to as the open-circuit solution or rest potential.
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
09-Oct-1997
Current Stage
Ref Project

Relations

Buy Standard

Standard
ASTM G69-97(2003) - Standard Test Method for Measurement of Corrosion Potentials of Aluminum Alloys
English language
4 pages
sale 15% off
Preview
sale 15% off
Preview

Standards Content (Sample)


NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:G69–97 (Reapproved 2003)
Standard Test Method for
Measurement of Corrosion Potentials of Aluminum Alloys
ThisstandardisissuedunderthefixeddesignationG69;thenumberimmediatelyfollowingthedesignationindicatestheyearoforiginal
adoptionor,inthecaseofrevision,theyearoflastrevision.Anumberinparenthesesindicatestheyearoflastreapproval.Asuperscript
epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope for characterizing the metallurgical condition of aluminum
alloys, especially those of the 2XXX and 7XXX types, which
1.1 This test method is a procedure for measurement of the
contain copper and zinc as major alloying elements. Its uses
corrosion potential (see Note 1) of an aluminum alloy in an
include the determination of the effectiveness of solution heat
aqueous solution of sodium chloride with enough hydrogen
treatment and annealing (1), of the extent of precipitation
peroxide added to provide an ample supply of cathodic
during artificial aging (4) and welding (5), and of the extent of
reactant.
diffusion of alloying elements from the core into the cladding
NOTE 1—The corrosion potential is sometimes referred to as the
of alclad products (2).
open-circuit solution or rest potential.
4. Apparatus
1.2 This standard does not purport to address all of the
safety concerns, if any, associated with its use. It is the
4.1 The apparatus consists of an inert container for the test
responsibility of the user of this standard to establish appro-
solution, a mechanical support for the test specimens that
priate safety and health practices and determine the applica-
insulates them electrically from each other and from ground,
bility of regulatory limitations prior to use.
saturated calomel electrode (SCE) (see Note 3), wires and
accessories for electrical connections, and equipment for the
2. Referenced Documents
measurement of potential.
2.1 ASTM Standards:
NOTE 3—Saturated calomel electrodes are available from several
D1193 Specification for Reagent Water
manufacturers.Itisagoodpracticetoensuretheproperfunctioningofthe
reference electrode by measuring its potential against one or more
3. Significance and Use
reference electrodes. The potential difference should not exceed 2 or 3
3.1 The corrosion potential of an aluminum alloy depends
mV.
upon the amounts of certain alloying elements that the alloy 12
4.2 A high-impedence (>10 V) voltmeter is suitable for
contains in solid solution. Copper and zinc, which are two of
measurement of the potential. Measurement of this potential
the major alloying elements for aluminum, have the greatest
should be carried out to within 6 1 mV. Automatic data
effectwithcoppershiftingthepotentialinthenobleorpositive
recording systems may be used to permit the simultaneous
direction, and zinc in the active or negative direction. For
measurementofmanyspecimensandthecontinuousrecording
example, commercially unalloyed aluminum (1100 alloy) has
of corrosion potentials.
apotentialof−750mVwhenmeasuredinaccordancewiththis
practice, 2024–T3 alloy with nearly all of its nominal 4.3%
5. Reagents
copperinsolidsolution,apotentialof−600to−620mV(Note
5.1 Purity of Reagents—Reagent grade chemicals shall be
2), and 7072 alloy with nearly all of its nominal 1.0% zinc in
used in all tests. Unless otherwise indicated, it is intended that
solid solution, a potential of−885 mV (SCE) (1-3).
all reagents shall conform to the specifications of the Commit-
tee onAnalytical Reagents of theAmerican Chemical Society,
NOTE 2—The potential depends upon the rate of quenching.
where such specifications are available. Other grades may be
3.2 Because it reflects the amount of certain alloying ele-
used, provided it is first ascertained that the reagent is of
ments in solid solution, the corrosion potential is a useful tool
sufficiently high purity to permit its use without lessening the
accuracy of the determination.
This practice is under the jurisdiction of Committee G01 on Corrosion of
Metals and is the direct responsibility of Subcommittee G01.11 on Electrochemical
Measurements in Corrosion Testing. Round-robin test conducted by G01.11 (unpublished results).
Current edition approved Oct. 10, 1997. Published December 1997. Originally Reagent Chemicals, American Chemical Society Specifications, American
e1
approved in 1981. Last previous edition approved in 1994 as G69–81(1994) . Chemical Society, Washington, DC. For suggestions on the testing of reagents not
Annual Book of ASTM Standards, Vol 11.01. listed by the American Chemical Society, see Analar Standards for Laboratory
All alloy designations are those of the Aluminum Association. Chemicals, BDH Ltd., Poole, Dorset, U.K., and the United States Pharmacopeia
The boldface numbers in parentheses refer to the references at the end of this and National Formulary,U.S.PharmaceuticalConvention,Inc.(USPC),Rockville,
standard. MD.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
G69–97 (2003)
NOTE 4—Caution:Clad products with thin claddings should only be
5.2 Purity of Water—The water shall be distilled or deion-
abraded lightly except to remove the cladding for measurement of the
ized conforming to the purity requirements of Specification
core.
D1193, Type IV reagent water.
5.3 Sodium Chloride (NaCl).
8.5 Following mechanical preparation, the specimen is
5.4 Hydrogen Peroxide (H O ) (30%)—In case of uncer-
2 2
cleaned,ordegreased,inaninertsolvent(forexample,acetone
tainty (for example, whenever freshly opened reagent is not
or perchloroethylene).
used), the concentration of hydrogen peroxide in the reagent
8.6 All parts of a specimen and its electrical connection to
shall be confirmed by chemical analysis as described inAnnex
be exposed in the test solution, except for the area of the
A1. In no case shall reagent containing less than 20%
specimen prepared for measurement, are masked off. Any
hydrogen peroxide be used.
material that masks a surface physically and electrically and
that is inert in the test solution may be used (see Annex A2).
6. Solution Conditions
6.1 The test solution shall consist of 58.5 6 0.1 g of NaCl
9. Procedure
and 9 6 1 mL of 30% hydrogen peroxide reagent per 1 L of
9.1 For corrosion potential measurements, the test speci-
aqueous solution. (This solution is 1 M with respect to
mens and the reference electrode are immersed in the appro-
concentration of sodium chloride.)
6.2 The hydrogen peroxide reagent shall be added just priate quantity of test solution; the test specimens are con-
before measurements are made because it decomposes upon nected to the positive terminal of the equipment for measuring
standing.
potential, and the reference electrode to the negative terminal.
6.3 Freshly prepared solution shall be used for each set of
9.2 Care should be taken to ensure that all the unmasked
measurements.
area of each test specimen prepared for measurement is
6.4 Not less than 500 mLof solution shall be used for each
exposed to the test solution and that any other unmasked area
set of measurements.
is not exposed. Care should also be taken to ensure that any
6.5 The total exposed area of all the specimens of the same
unmaskedportionoftheelectricalconnectionisoutsidethetest
composition in each set of measurements shall not exceed 100
solution.
mm per 100 mL of solution.
9.3 The potential of each specimen shall be measured at
6.6 The temperature of the test solution shall be maintained
5-min intervals for a period of1hor recorded continuously
at 25 6 2°C.
using the output of a high-impedance voltmeter.
9.4 The potential of each specimen shall be reported as the
7. Test Specimen
average of the values for the last 30 min of measurement (that
7.1 For measurement alone, specimen size is unimportant
is, for the last 7 measurem
...

Questions, Comments and Discussion

Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.