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ASTM D3193-96(2003)

(Specification)

Standard Specification for Ethylbenzene

Standard Specification for Ethylbenzene

ABSTRACT
This specification covers ethylbenzene. Different tests shall be conducted in order to determine the following properties of ethylbenzene: purity, benzene content, toluene content, xylene content, cumene content, diethylbenzene content, chloride content, sulfur content, and color.
SCOPE
1.1 This specification covers ethylbenzene.
1.2 Consult current OSHA regulations, supplier's Material Safety Data Sheets for all materials, and local regulations used in this specification.
1.3 The following applies to all specified limits in this specification for purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off "to the nearest unit" in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.

General Information

Status
Historical
Publication Date
09-Jan-2003
ICS
71.080.15 - Aromatic hydrocarbons
Technical Committee
D16 - Aromatic, Industrial, Specialty and Related Chemicals
Drafting Committee
D16.07 - Styrene, Ethylbenzene and C9 and C10 Aromatic Hydrocarbons
Current Stage
Ref Project

Relations

Replaces
ASTM D3193-96 - Standard Specification for Ethylbenzene
Effective Date
10-Jan-2003
Replaced By
ASTM D3193-09 - Standard Specification for Ethylbenzene
Effective Date
15-Jan-2009

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ASTM D3193-96(2003) - Standard Specification for EthylbenzeneASTM D3193-96(2003) - Standard Specification for Ethylbenzene
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ASTM D3193-96(2003) - Standard Specification for Ethylbenzene
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D 3193 – 96 (Reapproved 2003)
Standard Specification for
Ethylbenzene
This standard is issued under the fixed designation D 3193; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope D 5386 Test Method for Color of Liquids UsingTristimulus
Colorimetry
1.1 This specification covers ethylbenzene.
D 5808 Test Method for Determining Organic Chloride in
1.2 Consult current OSHA regulations, supplier’s Material
Aromatic Hydrocarbons and Related Chemicals by Micro-
Safety Data Sheets for all materials, and local regulations used
coulemetry
in this specification.
E29 Practice for Using Significant Digits in Test Data to
1.3 The following applies to all specified limits in this
Determine Conformance with Specifications
specification for purposes of determining conformance with
2.2 Other Document:
this specification, an observed value or a calculated value shall
OSHA Regulations, 29 CFR, paragraphs 1910.1000 and
be rounded off “to the nearest unit” in the last right-hand digit
1910.1200
used in expressing the specification limit, in accordance with
the rounding-off method of PracticeE29.
3. Properties
2. Referenced Documents 3.1 Ethylbenzene shall conform to the following require-
ments:
2.1 ASTM Standards:
Property Specification ASTM Test
D 1209 Test Method for Color of Clear Liquids (Platinum-
Method
Cobalt Scale)
D 3437 Practice for Sampling and Handling Liquid Cyclic
Purity, min, weight % 99.00 D 5060
Benzene, max, weight % 0.1 D 5060
Products
Toluene, max, weight % 0.4 D 5060
D 3961 Test Method for Trace Quantities of Sulfur in
Xylenes, max, weight % 0.4 D 5060
Liquid Aromatic Hydrocarbons by Oxidative Microcou- Cumene, max, weight % 0.03 D 5060
Diethylbenzene, max, weight % 0.003 D 5060
lometry
Chlorides, max, mg/kg 3 D 5194 or D 5808
D 4045 Test Method for Sulfur in Petroleum Products by
Sulfur, max, mg/kg 1 D 3961 or D 4045
Hydrogenolysis and Rateometric Colorimetry Color, max, Pt-Co 10 D 1209 or D 5386
D 5060 Test Method for Determining Impurities in High-
4. Sam
...

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Standard Specification for Ethylbenzene

ABSTRACT
This specification covers ethylbenzene. Different tests shall be conducted in order to determine the following properties of ethylbenzene: purity, benzene content, toluene content, xylene content, cumene content, diethylbenzene content, chloride content, sulfur content, and color.
SCOPE
1.1 This specification covers ethylbenzene.  
1.2 The following applies to all specified limits in this specification for purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measure are included in this specification.  
1.4 Consult current OSHA regulations, supplier’s Safety Data Sheet for all materials, and local regulations used in this specification.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
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4.1 Organic and inorganic chlorine compounds can have a deleterious effect on equipment and reactions in processes involving aromatic hydrocarbons.  
4.2 Maximum chloride levels are often specified for process streams and for aromatic hydrocarbon products.
SCOPE
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1.5 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
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1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.  
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SCOPE
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This specification covers a grade of o-xylene identified as ortho-Xylene 980. O-xylene 980 shall be tested and sampled in accordance with standard test methods and practices and shall conform to the following requirements: purity; non-aromatic hydrocarbons; p-xylene plus m-xylene; C9 and heavier aromatics; cumene; bromine index; appearance which shall be a clear liquid, free of sediment and haze; color in the platinum-cobalt scale; and distillation range.
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ABSTRACT
This specification covers cumene (isopropylbenzene) manufactured via a zeolite catalyst process. Cumene shall conform to the following requirements: purity weight percent, alpha-methylstrene, benzene, cumene hydroperoxide, diisopropylbenzenes, ethylbenzene, i-butylbenzene, n-butylbenzene, s- butylbenzene, t- butylbenzene, phenols, n-propylbenzene, sulfur, toluene, total butylbenzenes, total cymenes, total non-aromatics, total GC unknowns, bromine index, appearance, and color.
SCOPE
1.1 This specification covers cumene (isopropylbenzene) manufactured using a zeolite catalyst process.  
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1.3 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
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1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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