ASTM D7044-04
(Specification)Standard Specification for Biodegradable Fire Resistant Hydraulic Fluids
Standard Specification for Biodegradable Fire Resistant Hydraulic Fluids
SCOPE
1.1 This specification covers performance classifications for biodegradable fire resistant hydraulic fluids that are used in the industrial/mobile and mining industries.
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use.
General Information
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Standards Content (Sample)
NOTICE: This standard has either been superseded and replaced by a new version or withdrawn. Contact ASTM
International (www.astm.org) for the latest information.
An American National Standard
Designation: D 7044 – 04
Standard Specification for
Biodegradable Fire Resistant Hydraulic Fluids
This standard is issued under the fixed designation D 7044; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope Properties of Lubricating Fluids (Four-Ball Method)
D 2882 Test Method for Indicating theWear Characteristics
1.1 This specification covers performance classifications for
of Petroleum and Non-Petroleum Hydraulic Fluids in a
biodegradable fire resistant hydraulic fluids that are used in the
Constant Volume Vane Pump
industrial/mobile and mining industries.
D 3427 Test Method for Gas Bubble Separation Time of
1.2 This standard does not purport to address all of the
Petroleum Oils
safety concerns, if any, associated with its use. It is the
D 4052 Test Method for Density and Relative Density of
responsibility of the user of this standard to establish appro-
Liquids by Digital Density Meter
priate safety and health practices and to determine the
D 5182 Test Method for Evaluating the Scuffing (Scoring)
applicability of regulatory limitations prior to use.
Load Capacity of Oils (FZG Visual Method)
2. Referenced Documents
D 5306 Test Method for Linear Flame Propagation Rate of
Lubricating Oils and Hydraulic Fluids
2.1 ASTM Standards:
D 6046 Classification of Hydraulic Fluids for Environmen-
D 92 Test Method for Flash and Fire Points by Cleveland
tal Impact
Open Cup
D 6304 Test Method for Determination of Water in Petro-
D 95 Test Method for Water in Petroleum Products and
leum Products, Lubricating Oils, andAdditives by Coulo-
Bituminous Materials by Distillation
metric Karl Fischer Titration
D 240 Test Method for Heat of Combustion of Liquid
D 6546 Test Methods for and Suggested Limits for Deter-
Hydrocarbon Fuels by Bomb Calorimeter
mining Compatibility of Elastomer Seals for Industrial
D 664 TestMethodforAcidNumberofPetroleumProducts
Hydraulic Fluid Applications
by Potentiometric Titration
E 70 Test Method for pH of Aqueous Solutions with Glass
D 892 Test Method for Foaming Characteristics of Lubri-
Electrode
cating Oils
E 659 Test Method for Autoignition Temperature of Liquid
D 943 Test Method for Oxidation Characteristics of Inhib-
Chemicals
ited Mineral Oils
2.2 DIN Standards:
D 974 Test Method for Acid and Base Number by Color-
DIN 51348 Testing of fire resistant governor fluids; deter-
Indicator Titration
mination of hydrolytic stability
D 1298 Practice for Density, Relative Density (Specific
DIN 51354-2 Testing of Lubricants; FZG Gear Test Rig –
Gravity), or API Gravity of Crude Petroleum and Liquid
Part 1: Method A/8,3/90 for Lubricating Oils
Petroleum Products by Hydrometer Method
DIN 51373 Testing of Fire Resistant Heat Transfer Fluids;
D 1401 Test Method for Water Separability of Petroleum
Determination of Resistance to Oxidation Including an
Oils and Synthetic Fluids
Assessment of the Catalyst Plates
D 2422 Classification of Industrial Fluid Lubricants by
DIN 51389-2 Determination of lubricants; mechanical test-
Viscosity Grade
ing of hydraulic fluids in the vane-cell-pump; method A
D 2532 Test Method for Viscosity and Viscosity Change
foranhydrous hydraulic fluids
after Standing at Low Temperature of Aircraft Turbine
DIN 51777-2 Testing of Mineral Oil Hydrocarbons and
Lubricants
Solvents; Determination of Water Content according to
D 2783 Test Method for Measurement of Extreme-Pressure
Karl Fischer; Indirect Method
2.3 ISO Standards:
This specification is under the jurisdiction ofASTM Committee D02 and is the
direct responsibility of Subcommittee D02.N0 on Hydraulic Fluids.
Current edition approved May 1, 2004. Published July 2004.
2 3
For referenced ASTM standards, visit the ASTM website, www.astm.org, or Available from Deutsches Institut für Normung e. V. (DIN), 10772, Berlin,
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Germany.
Standards volume information, refer to the standard’s Document Summary page on Available fromAmerican National Standards Institute (ANSI), 25 W. 43rd St.,
the ASTM website. 4th Floor, New York, NY 10036.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
NOTICE: This standard has either been superseded and replaced by a new version or withdrawn. Contact ASTM
International (www.astm.org) for the latest information.
D7044–04
ISO 2049 Petroleum Products - Determination of Color ISO 14935 Petroleum and Related Products – Determina-
(ASTM Scale) tion of Wick Flame Persistence of Fire Resistant Fluids
ISO 15029-1 Petroleum and Related Products – Determina-
ISO 2160 Petroleum Products - Corrosiveness to Copper –
Copper Strip Test tion of Spray Ignition Characteristics of Fire Resistant
Fluids – Part 1: Spray Flame Persistence – Hollow-Cone
ISO 2592 Determination of Flash and Fire Points – Cleve-
Nozzle Method
land Open Cup Method
ISO/FDIS 15380 Lubricants, Industrial Oils and Related
ISO 3104 Petroleum Products - Transparent and Opaque
Products (Class L)—Family H (Hydraulic Systems)—
Liquids - Determination of Kinematic Viscosity and
Specifications for Categories HETG, HEPG, HEES, and
Calculation of Dynamic Viscosity
HEPR
ISO 3105 Glass Capillary Kinematic Viscometers—
2.4 Lux Standards:
Specifications and Operating Instructions
Lux 3.1.3 Stabilized Flame Heat Release – Spray Test
ISO 3448 Industrial Liquid Lubricants - ISO Viscosity
Lux 5.2.3 Determination of the Emulsion Stability of HFB
Classification
Fluids at Medium Temperature
ISO 3675 Crude Petroleum and Liquid Petroleum Products
Lux 5.2.4 Determination of the Emulsion Stability of
- Laboratory Determination of Density - Hydrometer
HFB…LT Fluids at Low Temperature
Method
Lux 5.3.1 Determination of aging Properties of HFC Fluids
ISO 3733 Petroleum Products and Bituminous Materials –
Lux 5.8 Determination of the Shear Stability of Hydraulic
Determination of Water - Distillation Method
Fluids
ISO 4263-1 Petroleum and Related Products - Determina-
Lux 5.9.1 Determination of the Corrosion Inhibiting Prop-
tion of the Aging Behavior of Inhibited Oils and Fluids –
erties of HFA, HFC, and HFD Fluids
TOST Test – Part 1: Procedure for Mineral Oils
MSHASchedule 30, 43 FR 12317 (WickTest) Part 35: Fire
ISO 4404-1 Petroleum and Related Products - Determina-
Resistant Hydraulic Fluids
tion of the Corrosion Resistance of Fire-Resistant Fluids –
NBSIR 81-2312: MSHAWick Test for Hydraulic Fluids: A
Part 1: Water-Containing Fluids
Preliminary Evaluation
ISO 5884 Aerospace—Fluid Systems and Components—
2.5 Other Standards:
Methods for System Sampling and Measuring the Solid
CETOP RP 65H Manifold Ignition Test
Particle Contamination of Hydraulic Fluids
CETOP RP 67H Antiwear Vane Pump Test for Hydraulic
ISO 6072 Compatibility between Fluids and Standard Elas-
Fluids
tomeric Materials
IP 281
ISO 6245 Petroleum Products - Determination of Ash
ISO 6247 Petroleum Products - Determination of Foaming
3. Terminology
Characteristics of Lubricating Oils
3.1 Definitions:
ISO 6296 Petroleum Products - Determination of Water –
3.1.1 bioaccumulation, n—the net accumulation of a sub-
Potentiometric Karl Fischer Titration Method
stance by an organism as a result of uptake from all environ-
ISO 6618 Petroleum Products and Lubricants - Determina-
mental sources.
tion of Acid or Base Number – Color Indicator Titration
3.1.2 biodegradable, n—any substance containing <10 %
Method
wt. O content which undergoes $60 % biodegradation as
ISO 6619 Petroleum Products and Lubricants—
theoretical CO in 28 days and $67 % biodegradation as
Neutralization Number—Potentiometric Titration Method
theoretical O uptake in 28 days, or any hydraulic fluid
ISO 6743-4 Lubricants, Industrial Oils and Related Prod-
containing $10 % wt. O content which undergoes $60 %
ucts (class L) – Classification – Part 4: Family H (Hy-
biodegradation as theoretical CO or as theoretical O uptake
2 2
draulic Systems)
in 28 days.
ISO 7120 Petroleum Products and Lubricants – Petroleum
3.1.3 biodegradation, n—the process of chemical break-
Oils and Other Fluids - Determination of Rust Preventing
down or transformation of a material caused by organisms or
Characteristics in the Presence of Water
their enzymes.
ISO 7745 Hydraulic Fluid Power—Fire-resistant (FR)
3.1.3.1 Discussion—Biodegradation is only one mechanism
Fluids—Guidelines for Use
by which materials are transformed in the environment.
ISO 9120 Petroleum and Related Products - Determination
ofAirReleasePropertiesofSteamTurbineandOtherOils
– Impinger Method 5
European Commission, Safety and Health Commission for the Mining and
ISO 12185 Crude Petroleum and Petroleum Products – Other Extractive Industries, “Requirements and Tests Applicable to Fire-Resistant
Hydraulic Fluids Used for Power Transmission and Control (Hydrostatic and
Determination of Density - Oscillating U-Tube Method
Hydrokinetic),” Seventh Edition, Doc. N4746/10/91 EN, Luxembourg, April 1994.
ISO 12922 Lubricants, Industrial Oils and Related Products
The Bureau of Mines, Federal Register, vol. 24, No. 245, December 17, 1959,
(classL)–FamilyH(HydraulicSystems)–Specifications
revised March 24, 1978.
National Bureau of Standards, Washington, DC, July 1981.
for Categories HFAE, HFAS, HFB, HFC, HFDR, and
Available from the Comité Européen des Transmissions Oléohydrauliques et
HFDU
Pneumatiques (CETOP), Lyoner Straße 18, 60528, Frankfurt am Main, Germany.
ISO 12937 Petroleum Products - Determination of Water –
Available from Energy Institute, 61 New Cavendish St., London, WIG 7AR,
Coulometric Karl Fischer Titration Method U.K.
NOTICE: This standard has either been superseded and replaced by a new version or withdrawn. Contact ASTM
International (www.astm.org) for the latest information.
D7044–04
TABLE 1 Specifications for Categories HFAE and HFAS Fluids According to ISO 12922
Composition Type HFAE: These are oil-in-water emulsions, typically with more than 80 % water content (+5 °C to + 50 °C,
ISO 7745)
Type HFAS: These are chemical solutions in water, typically more than 80 % water content (+ 5 °C to + 50 °C,
ISO 7745)
Specification
Characteristic or Test Unit Standard or Test Method
Finished Emulsion Finished Solution
A A
Category HFAE Category HFAS
BC
Apperance
Water content, min. % (V/V) 80 80 D95, D 6304
D
Foam at: + 25 °C max. ml/ml 300/10 300/10 D 892
+ 50 °C max. ml/ml 300/10 300/10
+ 25 °C max. ml/ml 300/10 300/10
pH at 20 °C 6,7 to 11,0 6.7 to 11,0 E70
B
Emulsion stability (50 °C/600 h), max. Rating 2A-2R D 1401
B
—free oil % (v/V) Trace
B
cream, max.% (v/V) % (v/V) 0.5
EE
Corrosion protection Rating (ISO 4404)
EE
Elastomer compatibility NBR1, EPDM1 and FPM1 D 6546
elastomer, 60 °C/168 h
relative volume change, max. % 7 7
relative hardness change: min. IRHD –7 –7
max. IRHD +2 +2
EE
change in tensile strength %
EE
elongation at break
A
These products are normally supplied as concentrates, and should be used with the correct water quantity as specified by the supplier (viscosity of concentrate to be
350 mm /s maximum at 20 °C).
B
The requirement is not relevant to this fluid type.
C
The appearance of the delivered fluid shall be clear and bright and free of any visible particulate matter, under normal visible light at ambient temperature, using a
clear container of approximately 10 cm diameter.
D 2
For fluids with a viscosity greater than 10 mm /s at 20 °C.
E
Report only on request.
3.1.4 fire resistant fluid, n—any liquid that is able to 5. Classification Requirements
withstand fire or give protection from fire.
5.1 Type HFA Hydraulic Fluids—The requirements for this
3.1.5 hydraulic fluid, n—a liquid used in hydraulic systems
type of fluid are presented in Table 1.
for lubrication and transmission of power.
5.2 Type HFB Hydraulic Fluids—The requirements for this
type of fluid are presented in Table 2and include ISO viscosity
4. Classification
grades from 46 to 100, in accordance with Classification
D 2422 (ISO 3448).
4.1 The following classifications of fire-resistant hydraulic
5.3 Type HFC Hydraulic Fluids—The requirements for this
fluids, except for HEPG, were taken from ISO 6743-4.
type of fluid are presented inTable 2 and include ISO viscosity
4.1.1 HFA—Fire resistant hydraulic fluids that may be
gradesfrom22to68,inaccordancewithClassificationD 2422
further classified as:
(ISO 3448).
4.1.1.1 HFAE—Oil-in-water emulsions containing more
5.4 Type HFD Hydraulic Fluids—The requirements for this
than 80 % by weight water and typically in the range 95 to
type of fluid are presented inTable 2 and include ISO viscosity
99 % by weight water.
grades from 15 to 100, in accordance with Classification
4.1.1.2 HFAS—Chemical solutions. Not containing emul-
D 2422 (ISO 3448).
sions and typically contains more than 80 % by weight water.
5.5 Type HEPG Hydraulic Fluids—The requirements for
4.1.2 HFB—Water-in-oil emulsions containing approxi-
this type of fluid are presented in Table 3 and include ISO
mately 60 % by weight oil.
viscosity grades from 22 to 68, in accordance with Classifica-
4.1.3 HFC—Aqueous monomer and polymer polyglycol tion D 2422 (ISO 3448).
solutions. Water content not less than 35 % by weight.
6. Inspection
4.1.4 HFD—Phosphate ester or polyolester-based, water
insoluble fire resistant fluids.
6.1 Inspection of the material shall be agreed upon between
4.1.5 HFDR—Phosphate ester based fluids. the purchaser and the supplier.
4.1.6 HFDU—Water-free fluids based on chemical com-
7. Packaging and Package Marking
pounds other than phosphate esters and chlorinated hydrocar-
bons.
7.1 The fluid shall be suitably packaged to permit accep-
4.1.7 HEPG—Anhydrous “environmentally friendly” poly- tance by the carrier and to afford adequate protection from
alkylene glycol derived hydraulic fluids that may be water normal hazards of handling and shipping. Packaging shall
soluble or insoluble. conform to applicable carrier rules and regulations.
NOTICE: This standard has either been superseded and replaced by a new version or withdrawn. Contact ASTM
International (www.astm.org) for the latest information.
D7044–04
TABLE 2 Specifications for Categories HFB, HFC and HFD Fluids According to ISO 12922
Type HFB: These are water-in-oil emulsions (+5 °C to + 50 °C, ISO 7745)
Type HFC: These are water polymer solutions, typically with more than 35 % water content
(−20 °C to +50 °C, ISO 7745)
Composition
Type HFDR: These are synthetic fluids free of water consisting of phosphate esters
A
(−2
...
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