ASTM D4304-99
(Specification)Standard Specification for Mineral Lubricating Oil Used in Steam or Gas Turbines
Standard Specification for Mineral Lubricating Oil Used in Steam or Gas Turbines
SCOPE
1.1 This specification covers mineral oils used in steam and gas turbine lubrication systems where the performance requirements demand a highly refined mineral base oil compounded with rust and oxidation inhibitors plus selected additives as needed to control foam, wear, demulsibility, and so forth.
1.2 This specification is intended to define the properties of mineral oil-based turbine lubricating oils that are functionally interchangeable with existing oils of this type, and are compatible with most existing machinery components and, with appropriate field maintenance, will maintain their functional characteristics.
1.3 This specification is intended to define only new lubricating oil before it is installed in the machinery.
1.4 This specification is intended to be used as a guide. It is possible that oils that do not meet this specification may perform satisfactorily in some turbines.
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Standards Content (Sample)
NOTICE: This standard has either been superseded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
Designation: D 4304 – 99 An American National Standard
Standard Specification for
Mineral Lubricating Oil Used in Steam or Gas Turbines
This standard is issued under the fixed designation D 4304; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope D 1947 Test Method for Load-Carrying Capacity of Fluid
Gear Lubricants
1.1 This specification covers mineral oils used in steam and
D 2272 Test Method for Oxidation Stability of Steam Tur-
gas turbine lubrication systems where the performance require-
bine Oils by Rotating Bomb
ments demand a highly refined mineral base oil compounded
D 2422 Classification of Industrial Fluid Lubricants by
with rust and oxidation inhibitors plus selected additives as
Viscosity System
needed to control foam, wear, demulsibility, and so forth.
D 3339 Test Method for Acid Number of Petroleum Prod-
1.2 This specification is intended to define the properties of
ucts by Semi-Micro Color Indicator Titration
mineral oil-based turbine lubricating oils that are functionally
D 3427 Test Method for Air Release Properties of Petro-
interchangeable with existing oils of this type, are compatible
leum Oils
with most existing machinery components, and with appropri-
D 4057 Practice for Manual Sampling of Petroleum and
ate field maintenance, will maintain their functional character-
Petroleum Products
istics.
D 4310 Test Method for Determination of the Sludging and
1.3 This specification is intended to define only new lubri-
Corrosion Tendencies of Inhibited Mineral Oils
cating oil before it is installed in the machinery.
D 5182 Test Method for Evaluating the Scuffing (Scoring)
1.4 This specification is intended to be used as a guide. It is
Load Capacity of Oils (FZG Visual Method)
possible that oils that do not meet this specification may
2.2 ISO Standard:
perform satisfactorily in some turbines.
ISO 4406 Method for Coding the Level of Contamination
2. Referenced Documents
by Solid Particles
2.1 ASTM Standards:
3. Terminology
D 92 Test Method for Flash and Fire Points by Cleveland
3.1 Definitions:
Open Cup
3.1.1 Type I mineral oils, n—oils for steam and gas turbine
D 97 Test Method for Pour Point of Petroleum Oils
lubricating systems where the machinery does not require
D 130 Test Method for Detection of Copper Corrosion from
lubricants with enhanced load carrying capacity. Such oils
Petroleum Products by the Copper Strip Tarnish Test
normally contain rust and oxidation inhibitors plus other
D 445 Test Method for Kinematic Viscosity of Transparent
additives as needed to meet the specified performance charac-
and Opaque Liquids (the Calculation of Dynamic Viscos-
teristics. Type I oils usually are available in ISO-VG 32, 46, 68,
ity)
and 100 (see Classification D 2422).
D 665 Test Method for Rust-Preventing Characteristics of
2 3.1.2 Type II mineral oils, n—oils for steam and gas turbine
Inhibited Mineral Oil in the Presence of Water
lubricating systems where the machinery requires enhanced
D 892 Test Method for Foaming Characteristics of Lubri-
2 load carrying capacity. These oils are similar to Type I and are
cating Oils
typically used in marine turbines. Such oils contain rust and
D 943 Test Method for Oxidation Characteristics of Inhib-
2 oxidation inhibitors, plus mild extreme pressure (EP) additives
ited Mineral Oils
and other additives as needed to meet the specified perfor-
D 974 Test Method for Acid and Base Number by Color-
2 mance characteristics. Type II oils usually are available in
Indicator Titration
ISO-VG 68, 100, and 150.
D 1401 Test Method for Water Separability of Petroleum
2 3.1.3 functional properties, n—those properties of the min-
Oils and Synthetic Fluids
eral lubricating oil that are required for satisfactory operation
of the machinery. These properties are listed in Section 5.
This specification is under the jurisdiction of ASTM Committee D-2 on
Petroleum Products and Lubricants and is the direct responsibility of Subcommittee Discontinued; see 1996 Annual Book of ASTM Standards, Vol 05.01.
D02.C on Turbine Oils. Annual Book of ASTM Standards, Vol 05.02.
Current edition approved Dec. 10, 1999. Published February 2000. Originally Annual Book of ASTM Standards, Vol 05.03.
6 nd th
published as D 4304 – 84. Last previous edition D 4304 – 93. Available from American National Standards Institute, 11 W 42 Street, 13
Annual Book of ASTM Standards, Vol 05.01. Floor, New York, NY 10036.
Copyright © ASTM, 100 Barr Harbor Drive, West Conshohocken, PA 19428-2959, United States.
D 4304
4. Sampling and Testing 5.3 and Table 1 and Table 2. The significance of these
properties is discussed in Appendix X1.
4.1 Sampling—Generally, take all oil samples in accordance
with Practice D 4057. 5.2 Requirements for Type I oils are shown in Table 1.
4.2 Use the ASTM and other test methods described in
5.3 Requirements for Type II oils are shown in Table 2.
Tables 1 and 2.
6. Keywords
5. Functional Property Requirements
5.1 Mineral lubricating oils conforming to the specification 6.1 gas turbine oil; mineral oil; R and O oils; steam turbine
shall meet the functional property limits specified in 5.2 and oil; turbine lubricating oils; turbine lubrication systems
TABLE 1 Requirements for Type I Turbine Oils
NOTE 1—The nature of some tests are such that they are not necessarily run on each batch. The values are representative.
Property ASTM Test Method Limits
Physical:
ISO—viscosity grade D 2422 32 46 68 100
Flash point, °C, min D 92 180 180 180 180
A
Pour point, °C, max D 97 −5 −5 −5 −5
Viscosity, cSt (mm /s) 40°C D 445 28.8–35.2 41.4–50.6 61.2–74.8 90–110
Visual examination at 20°C . clear and bright
Chemical:
B
Total Acid Number, mg KOH/g, max D 974 report report report report
Performance
Emulsion characteristics: D 1401
at 54°C, minutes to 3 mL emulsion, max 30 30 30 .
at 82°C, minutes to 3 mL emulsion, max . . . 30
Foaming characteristics: D 892
Sequence I, tendency/stability, mL, max 200/0 200/0 200/0 200/0
Air release, 50°C, minutes max D 3427 5 10 10 17
Rust preventing characteristics D 665A Pass Pass Pass Pass
Copper corrosion,3hat 100°C, max D 130 1111
C
Oxidation stability :
Hours to neut. No. 2.0, min D 943 2000 2000 1500 1000
Minutes to 175 kPa drop, min D 2272 200 200 175 150
D
Cleanliness :
A
Lower pour point may be required for some applications.
B
Test Method D 3339 may be used as an alternative test method.
C
Test Method D 943 is the accepted test method for oxidation stability of new steam turbine oils in the United States and Canada. It is recognized that Test Method D 943
is a lengthy procedure. Test Method D 2272 is a shorter test for quality control. See X1.3.6 for significance of Test Method D 2272.
D
Cleanliness of the oil may be described by either the microscopic particle count or the electronic particle count methods and may be reported in terms of ISO 4406.
Cleanliness applies only at the time of delivery and can be used to establish a baseline for periodic condition monitoring. The cleanliness limits are meant to be
representative of good workmanship in manufacture and handling and as a general practice, the oil must be filtered prior to its installation in the equipment in accordance
with the equipment manufacturer’s recommendations.
D 4304
TABLE 2 Requirements for Type II Turbine Oils
NOTE 1—The nature of some tests are such that they are not necessarily run on each batch.
Property ASTM Test Method Limits
Physical:
ISO—viscosity grade D 2422 68 100 150
Flash point, °C, min D 92 180 180 210
A
Pour point, °C, max D 97 −5 −5 −5
Viscosity, cSt, 40°C (mm /s) D 445 61.2–74.8 90–110 135–165
Visual examination at 20°C . clear and bright
Chemical:
B
Total Acid Number, mg KOH/g, max D 974 report report report
Performance
Emulsion characteristics: D 1401
at 54°C, minutes to 3 mL emulsion, max 30 . .
at 82°C, minutes to 3 mL emulsion, max . 30 60
Foaming characteristics: D 892
Sequence I, tendency/stability, mL, max 200/0 200/0 200/0
Air release, 50°C minutes max D 3427 10 17 25
Rust preventing characteristics D 665B pass pass pass
Copper corrosion,3hat 100°C, max D 130 1 1 1
C
Oxidation stability:
Hours to neut. No. 2.0, min D 943 1500 1000 1000
Minutes to 175 kPa drop, min D 2272 175 150 150
Load carrying capacity:
D
fail stage, min D 5182 888
E
Cleanliness
A
Lower pour point may be required for some applications.
B
Test Method D 3339 may be used as alternative method.
C
Test Method D 943 is the accepted test method for oxidation stability of new steam turbine oils in the United States and Canada. It is recognized that Test Method D 943
is a lengthy procedure. Thus, Test Method D 2272 is a suggested shorter test for quality control. See X1.3.6 for significance of Test Method D 2272.
D
Load carrying ability of the oil was formerly described by Test Method D 1947. This test method has been withdrawn by ASTM due to the unavailability of test machine
and test parts.
E
Cleanliness of the oil may be described by either the microscopic particle count or the electronic particle count methods and may be reported in terms of ISO 4406.
Cleanliness applies only at the time of delivery and can be used to establish a baseline for periodic condition monitoring. The cleanliness limits are meant to be
representative of good workmanship in manufacture and handling and as a general practice, the oil must be filtered prior to its installation
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