Gas cylinders - Compatibility of cylinder and valve materials with gas contents - Part 2: Non-metallic materials (ISO 11114-2:2021)

This document gives guidance on the selection and evaluation of compatibility between non-metallic materials for gas cylinders and valves and the gas contents. It is also applicable to tubes, pressure drums and bundles of cylinders.
This document covers composite and laminated materials used for gas cylinders. It does not include ceramics, glasses and adhesives.
This document considers the influence of the gas in changing the material and mechanical properties (e.g. chemical reaction or change in physical state). The basic properties of the materials, such as mechanical properties required for design purposes (normally available from the materials supplier), are not considered. Other aspects, such as quality of delivered gas, are not considered.
The compatibility data given are related to single component gases but can be applicable to gas mixtures.
This document does not apply to cryogenic fluids (this is covered in ISO 21010).

Gasflaschen - Verträglichkeit von Werkstoffen für Gasflaschen und Ventile mit den in Berührung kommenden Gasen - Teil 2: Nichtmetallische Werkstoffe (ISO 11114-2:2021)

Dieses Dokument enthält eine Anleitung für die Auswahl und Bewertung der Verträglichkeit von nichtmetallischen Werkstoffen für Gasflaschen und Ventile mit den in Berührung kommenden Gasen. Es ist auch für Großflaschen, Druckfässer und Flaschenbündel anwendbar.
Dieses Dokument behandelt Verbund- und Schichtwerkstoffe, die für Gasflaschen verwendet werden. Es umfasst nicht Keramiken, Gläser und Klebstoffe.
Dieses Dokument berücksichtigt die Auswirkung des Gases auf Änderungen der Werkstoff- und mechanischen Eigenschaften (z. B. chemische Reaktion oder Änderungen des physikalischen Zustandes). Die für Auslegungszwecke notwendigen grundsätzlichen Werkstoffeigenschaften, wie z. B. mechanische Eigenschaften, werden nicht berücksichtigt (werden üblicherweise vom Werkstofflieferanten bereitgestellt). Andere Gesichtspunkte, wie z. B. die Qualität des gelieferten Gases, werden nicht berücksichtigt.
Die enthaltenen Verträglichkeitsdaten beziehen sich auf Einzelgase, können jedoch auch für Gasgemische anwendbar sein.
Dieses Dokument ist nicht anzuwenden für tiefkalte Fluide (dies ist von ISO 21010 abgedeckt).

Bouteilles à gaz - Compatibilité des matériaux des bouteilles et des robinets avec les contenus gazeux - Partie 2: Matériaux non métalliques (ISO 11114-2:2021)

Le présent document donne des recommandations pour la sélection et l’évaluation de la compatibilité entre les matériaux non métalliques des bouteilles à gaz/robinets avec le gaz. Il s’applique également aux tubes, aux fûts sous pression et aux cadres de bouteilles.
Le présent document couvre les matériaux composites et les matériaux stratifiés utilisés pour les bouteilles à gaz. Il n’inclut pas les céramiques, les verres ni les adhésifs.
Le présent document traite de l’influence du gaz sur la transformation du matériau ou sur la modification de ses propriétés mécaniques (par exemple une réaction chimique ou une modification de l’état physique). Les propriétés fondamentales des matériaux, telles que les propriétés mécaniques requises pour la conception d’un produit (en général fournies par le fabricant du matériau), ne sont donc pas abordées. D’autres aspects, tels que la qualité du gaz fourni, ne sont pas pris en compte.
Les données de compatibilité indiquées se rapportent à des gaz à un composant unique, mais elles peuvent être applicables aux mélanges gazeux.
Le présent document ne s’applique pas aux fluides cryogéniques (qui font l’objet de la norme ISO 21010).

Plinske jeklenke - Združljivost materialov za ventil in jeklenko s plinom - 2. del: Nekovinski materiali (ISO 11114-2:2021)

Ta dokument podaja smernice za izbiro in oceno združljivosti nekovinskih materialov za plinske jeklenke in ventile ter vsebnost plina. Uporablja se tudi za cevi, tlačne valje in sklope jeklenk.
Ta dokument zajema kompozitne in laminirane materiale, ki se uporabljajo za plinske jeklenke. Ne vključuje keramike, stekla in lepil.
Ta dokument obravnava vpliv plina na spreminjanje lastnosti materialov in mehanskih lastnosti (npr. kemijska reakcija ali sprememba fizikalnega stanja). Osnovne lastnosti materialov, kot so mehanske lastnosti, zahtevane za potrebe projektiranja (običajno jih predloži dobavitelj materialov), niso obravnavane. Drugi vidiki, kot je kakovost dobavljenega plina, niso obravnavani.
Navedeni podatki o združljivosti se navezujejo na enokomponentne pline, vendar jih je mogoče uporabiti za mešanice plinov.
Ta dokument se ne uporablja za kriogene tekočine (to je zajeto v standardu ISO 21010).

General Information

Status
Published
Publication Date
09-Nov-2021
Withdrawal Date
30-May-2022
Current Stage
6060 - Definitive text made available (DAV) - Publishing
Start Date
10-Nov-2021
Completion Date
10-Nov-2021

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SLOVENSKI STANDARD
01-januar-2022
Nadomešča:
SIST EN ISO 11114-2:2013
Plinske jeklenke - Združljivost materialov za ventil in jeklenko s plinom - 2. del:
Nekovinski materiali (ISO 11114-2:2021)
Gas cylinders - Compatibility of cylinder and valve materials with gas contents - Part 2:
Non-metallic materials (ISO 11114-2:2021)
Gasflaschen - Verträglichkeit von Werkstoffen für Gasflaschen und Ventile mit den in
Berührung kommenden Gasen - Teil 2: Nichtmetallische Werkstoffe (ISO 11114-2:2021)
Bouteilles à gaz - Compatibilité des matériaux des bouteilles et des robinets avec les
contenus gazeux - Partie 2: Matériaux non métalliques (ISO 11114-2:2021)
Ta slovenski standard je istoveten z: EN ISO 11114-2:2021
ICS:
23.020.35 Plinske jeklenke Gas cylinders
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 11114-2
EUROPEAN STANDARD
NORME EUROPÉENNE
November 2021
EUROPÄISCHE NORM
ICS 23.020.35 Supersedes EN ISO 11114-2:2013
English Version
Gas cylinders - Compatibility of cylinder and valve
materials with gas contents - Part 2: Non-metallic
materials (ISO 11114-2:2021)
Bouteilles à gaz - Compatibilité des matériaux des Gasflaschen - Verträglichkeit von Werkstoffen für
bouteilles et des robinets avec les contenus gazeux - Gasflaschen und Ventile mit den in Berührung
Partie 2: Matériaux non métalliques (ISO 11114- kommenden Gasen - Teil 2: Nichtmetallische
2:2021) Werkstoffe (ISO 11114-2:2021)
This European Standard was approved by CEN on 24 October 2021.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2021 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 11114-2:2021 E
worldwide for CEN national Members.

Contents Page
European foreword . 3

European foreword
This document (EN ISO 11114-2:2021) has been prepared by Technical Committee ISO/TC 58 "Gas
cylinders" in collaboration with Technical Committee CEN/TC 23 “Transportable gas cylinders” the
secretariat of which is held by BSI.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by May 2022, and conflicting national standards shall be
withdrawn at the latest by May 2022.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN ISO 11114-2:2013.
Any feedback and questions on this document should be directed to the users’ national standards
body/national committee. A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the
United Kingdom.
Endorsement notice
The text of ISO 11114-2:2021 has been approved by CEN as EN ISO 11114-2:2021 without any
modification.
INTERNATIONAL ISO
STANDARD 11114-2
Third edition
2021-10
Gas cylinders — Compatibility of
cylinder and valve materials with gas
contents —
Part 2:
Non-metallic materials
Bouteilles à gaz — Compatibilité des matériaux des bouteilles et des
robinets avec les contenus gazeux —
Partie 2: Matériaux non métalliques
Reference number
ISO 11114-2:2021(E)
ISO 11114-2:2021(E)
© ISO 2021
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on
the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below
or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii
ISO 11114-2:2021(E)
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Materials . 2
4.1 General . 2
4.2 Type of materials . 2
5 General consideration .3
6 Specific considerations . 4
6.1 General . 4
6.2 Non-compatibility risks . 4
6.2.1 Violent reaction (oxidation/burning) (F) . 4
6.2.2 Mass loss (W) . 6
6.2.3 Swelling of material (S) . 6
6.2.4 Change in mechanical properties (M) . 6
6.2.5 Other compatibility considerations . 6
7 Compatibility data . .7
7.1 Table of compatibility . 7
7.2 Symbols and abbreviated terms . 8
7.2.1 Symbols for compatibility . 8
7.2.2 Abbreviated terms for materials . 8
7.2.3 Symbols for compatibility risks . 9
7.2.4 Examples . 9
7.2.5 Tables 1 and 2 . 10
Bibliography .20
iii
ISO 11114-2:2021(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www.iso.org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO’s adherence to
the World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT), see
www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 58, Gas cylinders, in collaboration with
the European Committee for Standardization (CEN) Technical Committee CEN/TC 23, Transportable gas
cylinders, in accordance with the Agreement on technical cooperation between ISO and CEN (Vienna
Agreement).
This third edition cancels and replaces the second edition (ISO 11114-2:2013), which has been
technically revised. The main changes compared with the previous edition are as follows:
— new materials were added in Table 1;
— Table 2, dedicated to the compatibility for liners, was added.
A list of all parts in the ISO 11114 series can be found on the ISO website.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www.iso.org/members.html.
iv
ISO 11114-2:2021(E)
Introduction
This document provides guidance on the compatibility of non-metallic materials used for gas cylinders
and gas cylinder valves with the gas contents of the cylinder. Compatibility of met
...

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