Conservation of cultural heritage - Determination of soluble salts in natural stone and related materials used in cultural heritage

EN 16455 provides a methodology for the qualitative and quantitative analysis of anions and cations obtained by dissolution of soluble salts present in either natural stone or other porous inorganic materials constituting cultural heritage and in materials and products used for their conservation. The methodology requires samples to have been taken from the cultural property. The main ions considered in this standard are: Cl-, NO2-, NO3-, SO42-, Na+, K+, NH4+, Ca2+, Mg2+.

Erhaltung des kulturellen Erbes - Bestimmung von löslichen Salzen in Naturstein und artverwandten Materialien des kulturellen Erbes

Diese Norm legt ein Verfahren für die qualitative und quantitative Bestimmung von Anionen und Kationen fest, die durch die Auflösung von löslichen Salzen – aus Naturstein oder anderen porösen anorganischen Materialien wie Mörtel, Stuck, Ziegel, und keramischem Material stammend – erhalten wurden.
Bei den in dieser Norm betrachteten Ionen handelt es sich um:
Cl-, NO2-, NO3-, PO43-, SO42-, C2O42-, CO32-, Na+, K+, NH4+, Ca2+, Mg2+

Conservation du patrimoine culturel - Détermination de la teneur en sels solubles de la pierre naturelle et des matériaux associés utilisés dans le patrimoine culturel

La présente norme fournit une méthodologie pour l’analyse qualitative et quantitative des anions et des cations obtenus par dissolution des sels solubles présents dans la pierre naturelle ou dans d’autres matériaux poreux inorganiques tels que les mortiers, le stuc, la brique et la céramique.
Les ions considérés dans la présente norme sont les suivants :
Cl-, NO2-, NO3-, PO4 3 - , SO42 -, C2O42 -, CO32-, Na+, K+, NH4+, Ca2+, Mg2+

Ohranjanje kulturne dediščine - Ugotavljanje topljivih soli v naravnem kamnu in sorodnih materialih, uporabljenih v kulturni dediščini

Standard EN 16455 določa metodologijo za kvalitativno in kvantitativno analizo anionov in kationov, pridobljenih z raztapljanjem topljivih soli, prisotnih v naravnem kamnu ali drugih poroznih anorganskih materialih, ki predstavljajo kulturno dediščino, ter v materialih in izdelkih, ki se uporabljajo za njihovo ohranjanje. Metodologija zahteva odvzem vzorcev iz kulturne dediščine. Glavni ioni, obravnavani v tem standardu, so: Cl-, NO2-, NO3-, SO42-, Na+, K+, NH4+, Ca2+, Mg2+.

General Information

Status
Published
Public Enquiry End Date
24-Oct-2012
Publication Date
16-Oct-2014
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
22-Sep-2014
Due Date
27-Nov-2014
Completion Date
17-Oct-2014

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2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Erhaltung des kulturellen Erbes - Bestimmung von löslichen Salzen in Naturstein und artverwandten Materialien des kulturellen ErbesConservation du patrimoine culturel - Détermination de la teneur en sels solubles de la pierre naturelle et des matériaux associés utilisés dans le patrimoine culturelConservation of cultural heritage - Determination of soluble salts in natural stone and related materials used in cultural heritage97.195Umetniški in obrtniški izdelkiItems of art and handicraftsICS:Ta slovenski standard je istoveten z:EN 16455:2014SIST EN 16455:2014en,fr,de01-november-2014SIST EN 16455:2014SLOVENSKI
STANDARD



SIST EN 16455:2014



EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 16455
September 2014 ICS 97.195 English Version
Conservation of cultural heritage - Extraction and determination of soluble salts in natural stone and related materials used in and from cultural heritage
Conservation du patrimoine culturel - Extraction et détermination des sels solubles dans la pierre naturelle et les matériaux associés utilisés dans le patrimoine culturel
Erhaltung des kulturellen Erbes - Auflösung und Bestimmung von löslichen Salzen in Naturstein und artverwandten Materialien des kulturellen Erbes This European Standard was approved by CEN on 25 July 2014.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre:
Avenue Marnix 17,
B-1000 Brussels © 2014 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 16455:2014 ESIST EN 16455:2014



EN 16455:2014 (E) 2 Contents Page Foreword .3 Introduction .4 1 Scope .5 2 Normative references .5 3 Terms and definitions .5 4 Principle .6 5 Reagents, materials and analytical equipment .6 6 Procedure .6 6.1 Sampling .6 6.2 Analysis procedure.6 6.2.1 General .6 6.2.2 Conductivity measurements .7 6.2.3 Ions measurement .7 7 Expression of results .7 7.1 Specific conductivity,
(S „ cm−1) .7 7.2 Individual ions .7 8 Test report .8 Bibliography .9
SIST EN 16455:2014



EN 16455:2014 (E) 3 Foreword This document (EN 16455:2014) has been prepared by Technical Committee CEN/TC 346 “Conservation of cultural heritage”, the secretariat of which is held by UNI. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by March 2015 and conflicting national standards shall be withdrawn at the latest by March 2015. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. SIST EN 16455:2014



EN 16455:2014 (E) 4 Introduction Soluble salts are often present in stones and other porous inorganic building materials as alteration products of chemical or biological origin. They can originate from surface deposition of environmental pollutants or from water capillary transport from other external sources and also from materials themselves or from conservation interventions. Soluble salts present in porous inorganic materials can, (depending on material properties, environmental conditions or possible treatments the surrounding conditions), initiate physical-chemical degradation processes. This standard describes a procedure to extract soluble salts present in porous inorganic materials to determine the ions and to estimate the content of soluble salts. There are several test methods for the analysis of salts, for example: a) recognition of salt crystals by microscopy; b) qualitative chemical reactions. These make it possible to identify the type of anions and cations present in a solution, after dissolution of salts in water (i.e. sulphates, nitrates, ch
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