ASTM G36-94(2018)
(Practice)Standard Practice for Evaluating Stress-Corrosion-Cracking Resistance of Metals and Alloys in a Boiling Magnesium Chloride Solution
Standard Practice for Evaluating Stress-Corrosion-Cracking Resistance of Metals and Alloys in a Boiling Magnesium Chloride Solution
SIGNIFICANCE AND USE
5.1 For most applications, this environment provides an accelerated method of ranking the relative degree of stress-corrosion cracking susceptibility for stainless steels and related alloys in aqueous chloride-containing environments. Materials that normally provide acceptable resistance in hot chloride service may crack in this test. The test may not be relevant to stress-corrosion cracking in polythionic acid or caustic environments.
5.2 Resistance to stress-corrosion cracking in boiling magnesium chloride (155.0°C (311.0°F)) should, where possible, be correlated to resistance in service for the materials of interest. However, such correlations may not always be possible.
5.3 Boiling magnesium chloride may also cause pitting of many stainless alloys. This leads to the possibility of confusing stress-corrosion failures with mechanical failures induced by corrosion-reduced net cross sections. This danger is particularly great when small cross section samples, high applied stress levels, long exposure periods, stress-corrosion resistant alloys, or a combination thereof are being used. Careful examination is recommended for correct diagnosis of the cause of failure.
SCOPE
1.1 This practice describes a procedure for conducting stress-corrosion cracking tests in a boiling magnesium chloride solution. Although this test may be performed using various concentrations of magnesium chloride, this procedure covers a test solution held at a constant boiling temperature of 155.0 ± 1.0°C (311.0 ± 1.8°F). The boiling points of aqueous magnesium chloride solutions at one atmosphere pressure as a function of concentration are shown graphically in Fig. 1.2 A suggested test apparatus capable of maintaining solution concentration and temperature within the prescribed limits for extended periods of time is also described herein.3
FIG. 1 Boiling Points of Aqueous Magnesium Chloride Solutions at One Atmosphere as a Function of Concentration2
1.2 The boiling magnesium chloride test is applicable to wrought, cast, and welded stainless steels and related alloys. It is a method for detecting the effects of composition, heat treatment, surface finish, microstructure, and stress on the susceptibility of these materials to chloride stress corrosion cracking.4
1.3 This practice is concerned primarily with the test solution, which may be used with a variety of stress corrosion test specimens, surface finishes, and methods of applying stress.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. See Section 7 for specific safety precautions.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
General Information
Relations
Standards Content (Sample)
This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: G36 − 94 (Reapproved 2018)
Standard Practice for
Evaluating Stress-Corrosion-Cracking Resistance of Metals
1
and Alloys in a Boiling Magnesium Chloride Solution
ThisstandardisissuedunderthefixeddesignationG36;thenumberimmediatelyfollowingthedesignationindicatestheyearoforiginal
adoptionor,inthecaseofrevision,theyearoflastrevision.Anumberinparenthesesindicatestheyearoflastreapproval.Asuperscript
epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope priate safety, health, and environmental practices and deter-
mine the applicability of regulatory limitations prior to use.
1.1 This practice describes a procedure for conducting
See Section 7 for specific safety precautions.
stress-corrosioncrackingtestsinaboilingmagnesiumchloride
1.5 This international standard was developed in accor-
solution. Although this test may be performed using various
dance with internationally recognized principles on standard-
concentrations of magnesium chloride, this procedure covers a
ization established in the Decision on Principles for the
test solution held at a constant boiling temperature of 155.0 6
Development of International Standards, Guides and Recom-
1.0°C (311.0 6 1.8°F). The boiling points of aqueous magne-
mendations issued by the World Trade Organization Technical
sium chloride solutions at one atmosphere pressure as a
2 Barriers to Trade (TBT) Committee.
function of concentration are shown graphically in Fig. 1. A
suggested test apparatus capable of maintaining solution con-
2. Referenced Documents
centration and temperature within the prescribed limits for
5
3
2.1 ASTM Standards:
extended periods of time is also described herein.
D1193Specification for Reagent Water
1.2 The boiling magnesium chloride test is applicable to
G1Practice for Preparing, Cleaning, and Evaluating Corro-
wrought, cast, and welded stainless steels and related alloys. It
sion Test Specimens
is a method for detecting the effects of composition, heat
G15Terminology Relating to Corrosion and CorrosionTest-
treatment, surface finish, microstructure, and stress on the
6
ing (Withdrawn 2010)
susceptibility of these materials to chloride stress corrosion
G30 Practice for Making and Using U-Bend Stress-
4
cracking.
Corrosion Test Specimens
1.3 This practice is concerned primarily with the test
solution, which may be used with a variety of stress corrosion
3. Terminology
test specimens, surface finishes, and methods of applying
3.1 Definitions—For definitions of terms used in this prac-
stress.
tice see Terminology G15.
1.4 This standard does not purport to address all of the
safety concerns, if any, associated with its use. It is the
4. Summary of Practice
responsibility of the user of this standard to establish appro-
4.1 A predetermined quantity of reagent grade magnesium
chloride and some distilled water are added to a container.The
1
container and contents, with thermometer and condenser
This practice is under the jurisdiction ofASTM Committee G01 on Corrosion
of Metals and is the direct responsibility of Subcommittee G01.06 on Environmen-
affixed, are placed on a source of heat. When the magnesium
tally Assisted Cracking.
chloride solution boils, it is adjusted to maintain the desired
Current edition approved Oct. 1, 2018. Published November 2018. Originally
concentration and boiling point through the addition of small
approvedin1973.Lastpreviouseditionapprovedin2013asG36–94(2013).DOI:
10.1520/G0036-94R18. quantities of either water or salt.
2
Available data on the relationship of concentrations and boiling points of
4.2 After the solution has stabilized at the desired boiling
magnesium chloride solutions are critically reviewed and supplemented by I. B.
Casale in “Boiling Points of Magnesium Chloride Solutions—TheirApplication in pointforthetest,thestressedspecimensareadded.Depending
Stress Corrosion Studies,” Corrosion, Vol 23, 1967, pp. 314–17.
upon the intent of the test, the specimens should be given
3
The apparatus and test procedures for maintaining constant boiling tempera-
tures of magnesium chloride solutions for stress corrosion tests are described by M.
A. Streicher and A. J. Sweet in Corrosion, Vol 25, 1969, pp. 1–6.
4 5
The use of concentrated magnesium chloride solutions for determining the For referenced ASTM standards, visit the ASTM website, www.astm.org, or
susceptibility to stress corrosion cracking of austenitic and ferritic stainless steels contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
and related nickel-base alloys was first described by M. A. Scheil, Symposium on Standards volume information, refer to the standard’s Document Summary page
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