Standard Test Method for Unsteady-State Heat Transfer Evaluation of Flame Resistant Materials for Clothing with Burn Injury Prediction

SIGNIFICANCE AND USE
5.1 This test method is intended for the determination of a thermal performance estimate value of a material, a combination of materials, or a comparison of different materials used in flame resistant clothing for workers exposed to combined convective and radiant thermal hazards.  
5.2 This test method evaluates a material’s heat transfer properties when exposed to a heat exposure at a constant value and specific duration. Air movement at the face of the specimen and around the calorimeter can affect the measured heat transferred due to forced convective heat losses. Minimizing air movement around the specimen and test apparatus will aid in the repeatability of the results.  
5.3 This test method accounts for the thermal energy stored in the exposed test specimen after the heat exposure has ceased. Higher values of Thermal Performance Estimate ratings determined in this test associate to higher values of thermal (convective and radiative) energy protection against a predicted skin burn injury.  
5.4 This test method maintains the specimen in a static, horizontal position and does not involve movement except that resulting from the exposure.  
5.5 This test method specifies a standardized 84 ± 2 kW/m2 (2 ± 0.05 cal/cm2s) exposure condition. Different exposure conditions have the potential to produce different results. Other exposure conditions representative of the expected hazard are allowed but shall be reported with the results along with a determination of the exposure energy level stability.  
5.6 This test method contains optional provisions for conducting certification testing against a prescribed Thermal Performance Estimate value.
SCOPE
1.1 This test method measures the non-steady state heat transfer through flame resistant materials for clothing subjected to a combined convective and radiant heat exposure.  
1.1.1 This test method is not applicable to materials that are not flame resistant.Note 1—The determination of a material’s flame resistance shall be made prior to testing and done in accordance with the applicable performance or specification standard, or both, for the material’s end-use.  
1.1.2 This test method accounts for the thermal energy contained in an exposed test specimen after the standardized combined convective and radiant heat exposure has ceased and is used to estimate performance to a predicted second-degree skin burn injury.  
1.2 This test method is used to measure and describe the response of materials, products, or assemblies to heat under controlled conditions, but does not by itself incorporate all factors required for fire hazard or fire risk assessment of the materials, products, or assemblies under actual fire conditions.  
1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound or other units that are commonly used for thermal testing.  
1.4 This standard does not purport to address the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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ASTM F2703-08(2013) - Standard Test Method for Unsteady-State Heat Transfer Evaluation of Flame Resistant Materials for Clothing with Burn Injury Prediction
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: F2703 − 08 (Reapproved 2013)
Standard Test Method for
Unsteady-State Heat Transfer Evaluation of Flame Resistant
Materials for Clothing with Burn Injury Prediction
This standard is issued under the fixed designation F2703; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 2. Referenced Documents
1.1 This test method measures the non-steady state heat 2.1 ASTM Standards:
transferthroughflameresistantmaterialsforclothingsubjected D123Terminology Relating to Textiles
to a combined convective and radiant heat exposure. D1776Practice for Conditioning and Testing Textiles
1.1.1 This test method is not applicable to materials that are D1777Test Method for Thickness of Textile Materials
not flame resistant. D3776Test Methods for Mass Per Unit Area (Weight) of
Fabric
NOTE 1—The determination of a material’s flame resistance shall be
E457Test Method for Measuring Heat-Transfer Rate Using
made prior to testing and done in accordance with the applicable
a Thermal Capacitance (Slug) Calorimeter
performance or specification standard, or both, for the material’s end-use.
F1494Terminology Relating to Protective Clothing
1.1.2 This test method accounts for the thermal energy
contained in an exposed test specimen after the standardized
3. Terminology
combinedconvectiveandradiantheatexposurehasceasedand
is used to estimate performance to a predicted second-degree 3.1 Definitions:
skin burn injury. 3.1.1 breakopen, n—in testing thermal protective materials,
amaterialresponseevidencedbytheformationofaholeinthe
1.2 This test method is used to measure and describe the
test specimen during the thermal exposure that may result in
response of materials, products, or assemblies to heat under
the exposure energy in direct contact with the heat sensor.
controlled conditions, but does not by itself incorporate all
3.1.1.1 Discussion—The specimen is considered to exhibit
factors required for fire hazard or fire risk assessment of the
breakopen when a hole is produced as a result of the thermal
materials, products, or assemblies under actual fire conditions.
2 2
exposure that is at least 3.2 cm (0.5 in. ) in area or at least 2.5
1.3 The values stated in SI units are to be regarded as
cm (1.0 in.) in any dimension. Single threads across the
standard. The values given in parentheses are mathematical
opening or hole do not reduce the size of the hole for the
conversions to inch-pound or other units that are commonly
purposes of this test method.
used for thermal testing.
3.1.2 charring, n—the formation of a carbonaceous residue
1.4 This standard does not purport to address the safety
as the result of pyrolysis or incomplete combustion.
concerns, if any, associated with its use. It is the responsibility
3.1.3 dripping,n—amaterialresponseevidencedbyflowing
of the user of this standard to establish appropriate safety and
of the polymer.
health practices and determine the applicability of regulatory
3.1.4 embrittlement, n—the formation of a brittle residue as
limitations prior to use.
a result of pyrolysis or incomplete combustion.
1.5 This international standard was developed in accor-
dance with internationally recognized principles on standard-
3.1.5 heat flux, n—the thermal intensity indicated by the
ization established in the Decision on Principles for the
amountofenergytransmitteddividedbyareaandtime;kW/m
Development of International Standards, Guides and Recom-
(cal/cm ·s).
mendations issued by the World Trade Organization Technical
3.1.6 ignition, n—the initiation of combustion.
Barriers to Trade (TBT) Committee.
3.1.7 melting, n—a material response evidenced by soften-
ing of the polymer.
ThistestmethodisunderthejurisdictionofASTMCommitteeF23onPersonal
ProtectiveClothingandEquipmentandisthedirectresponsibilityofSubcommittee
F23.80 on Flame and Thermal. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved June 1, 2013. Published June 2013. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
approved in 2008. Last previous edition approved in 2008 as F2703-08. DOI: Standards volume information, refer to the standard’s Document Summary page on
10.1520/F2703-08R13. the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
F2703 − 08 (2013)
3.1.8 unsteady state heat transfer value, n—in testing of 4.3 A Thermal Performance Estimate value of the test
thermal protective materials, a quantity expressed as the specimen is determined iteratively as the intersection of the
time-dependent difference between the incident and exiting time-dependent cumulative heat response as measured by the
thermal energy values normal to and across two defined calorimeter to a time-dependent, empirical predicted second-
parallel surfaces of an exposed thermal insulative material. degree skin burn injury performance curve identified in
10.4.1.5, Eq 1).
3.1.9 thermal performance estimate (TPE), n—in testing of
thermal protective materials, the cumulative amount of energy
4.4 Observations of the thermal response of the specimen
identified by the intersection of a measured time-dependent
resulting from the exposure are optionally reported.
heat transfer response through a subject material to a time-
5. Significance and Use
dependent, empirical predicted second-degree skin burn injury
3 2
performance curve, expressed as a rating or value; J/cm
5.1 This test method is intended for the determination of a
(cal/cm ).
thermal performance estimate value of a material, a combina-
tionofmaterials,oracomparisonofdifferentmaterialsusedin
3.1.10 response to heat exposure, n—in testing the resis-
flame resistant clothing for workers exposed to combined
tance to heat transfer of thermal protective materials, the
convective and radiant thermal hazards.
observable response of the material to the energy exposure as
indicated by break-open, melting, dripping, charring,
5.2 This test method evaluates a material’s heat transfer
embrittlement, shrinkage, sticking, and ignition.
properties when exposed to a heat exposure at a constant value
3.1.11 second-degree burn injury, n—in testing of thermal and specific duration. Air movement at the face of the
specimen and around the calorimeter can affect the measured
protective materials, reversible burn damage at the epidermis/
dermis interface in human tissue. heattransferredduetoforcedconvectiveheatlosses.Minimiz-
ing air movement around the specimen and test apparatus will
3.1.12 shrinkage, n—a decrease in one or more dimensions
aid in the repeatability of the results.
of an object or material.
5.3 This test method accounts for the thermal energy stored
3.1.13 sticking, n—a material response evidenced by soft-
in the exposed test specimen after the heat exposure has
ening and adherence of the material to the surface of itself or
ceased. Higher values of Thermal Performance Estimate rat-
another material.
ings determined in this test associate to higher values of
3.1.14 sample test suite, n—any number of test specimens
thermal (convective and radiative) energy protection against a
used to derive a single thermal performance estimate value.
predicted skin burn injury.
3.1.14.1 Discussion—the determination of a single thermal
5.4 This test method maintains the specimen in a static,
performance estimate value requires exposing a number of
horizontalpositionanddoesnotinvolvemovementexceptthat
specimens under varying exposure conditions so that the
resulting from the exposure.
thermal energy stored in the sample after the heat source is
removed is considered and accounted for when determining
5.5 Thistestmethodspecifiesastandardized84 62kW/m
performance against a burn injury prediction.
(2 6 0.05 cal/cm s) exposure condition. Different exposure
conditionshavethepotentialtoproducedifferentresults.Other
3.1.15 For the definitions of protective clothing terms used
exposure conditions representative of the expected hazard are
in this method, refer to Terminology F1494, and for other
allowed but shall be reported with the results along with a
textile terms used in this method, refer to Terminology D123.
determination of the exposure energy level stability.
4. Summary of Test Method
5.6 This test method contains optional provisions for con-
4.1 Ahorizontally positioned test specimen is exposed to a
ducting certification testing against a prescribed Thermal
combined convective and radiant heat source with an exposure
Performance Estimate value.
2 2
heat flux of 84 62kW/m (2 6 0.05 cal/cm s).
6. Apparatus and Materials
NOTE 2—Other exposure heat flux values are allowed, however
6.1 General Arrangement—The measurement apparatus
different exposure conditions have the potential to produce different
results. The test facility shall verify the stability of other exposure levels configuration consists of a combined convective and radiant
over the material’s exposure time interval (used to determine the thermal
energyheatsource,awatercooledshutterforexposurecontrol,
performance estimate value) and include this in the test results report.
a specimen and sensor support structure, a specimen holder
4.2 The unsteady-state transfer of heat through the test
assembly, a copper calorimeter sensor assembly, and a data
specimen is measured using a copper slug calorimeter. The
acquisition/analysis system. Automation of the apparatus for
change in temperature versus time is used, along with the
execution of the measurement procedure is allowed. The
known thermo-physical properties of copper, to determine the
general arrangement of the test apparatus configuration is
respective thermal energy passed through the test specimen.
shown in Fig. 1.
6.2 Gas Supply—Propane (commercial grade or better) or
Methane (technical grade or better).
Derivedfrom:Stoll,A.M.andChianta,M.A.,“MethodandRatingSystemfor
Evaluations of Thermal Protection,” Aerospace Medicine, Vol 40, 1969, pp.
6.3 Gas Flowmeter—Any gas flowmeter or rotometer with
1232–1238 and Stoll,A. M. and Chianta, M.A., “Heat Transfer through Fabrics as
rangetogiveaflowequivalentofatleast6L(0.21ft )/minair
Related to Thermal Injury,” Transactions – New York Academy of Sciences, Vol 33,
No. 7, Nov. 1971, pp. 649–670. at standard conditions.
F2703 − 08 (2013)
NOTE 1—Note the exposure heat source incorporates two Meker burners and nine quartz infrared lamps.
FIG. 1 Apparatus Used to Measure Heat Transfer Performance of Textile Materials
6.4 Thermal Energy Source: sensor must be dried and cured, in accordance with the
6.4.1 Two each, Meker or Fisher burners jetted for the manufacturers instructions, before use and present a uniformly
selected fuel gas (propane or methane) with a 38 mm (1.5 in.) applied coating (no visual thick spots or surface irregularities).
diameter top arranged so that the bodies (top section) do not In the absence of manufacturer’s instructions, an external heat
obstruct the quartz lamps and their flame profiles overlap. source, for example, an external heat lamp, shall be used to
Dimension tolerances are 65%. completelydriveoffanyremainingorganiccarriersinafreshly
6.4.2 Nine 500W T3 translucent quartz infrared lamps, painted surface before use.
connected to a variable electrical power controller, arranged as
NOTE 3—Emissivity of painted calorimeters is discussed in theASTM
a linear array with 13 6 0.5 mm center-to-center spacing set
Report, “ASTM Research Program on Electric Arc Test Method Devel-
125 6 10 mm from the specimen surface.
opment to Evaluate Protective Clothing Fabric;ASTM F18.65.01 Testing
Group Report on Arc Testing Analysis of the F1959 Standard Test
6.4.2.1 Use of a water-cooled housing for the quartz infra-
Method—Phase 1.”
red lamp bank is recommended. This helps to avoid heating
adjacent mechanical components and to shield the operator 6.5.2 The thermocouple wire bead is installed in the calo-
from the radiant energy. rimeter as shown in Fig. 2.
6.5.2.1 The thermocouple wire bead shall be bonded to the
6.5 Thermal Sensor:
copperdiskeithermechanicallyorbyusinghighmeltingpoint
6.5.1 Thetransmittedheatsensorisa4 60.05cmdiameter
5 (HMP) solder.
circular copper slug calorimeter constructed from electrical
(1)Amechanical bond shall be produced by mechanically
gradecopperwithamassof18 60.05g(priortodrilling)with
deforming the copper disk material (utilizing a copper filling
asingleANSItypeJ(Fe/Cu-Ni)orANSItypeK(Ni-Cr/Ni-Al)
slug as shown in Fig. 2) around the thermocouple bead.
thermocouple wire bead (0.254 mm wire diameter or finer—
(2)A solder bond shall be produced by using a suitable
equivalent to 30 AWG) installed as identified in 6.5.2 and
HMP solder with a melting temperature >280°C.
shown in Fig. 2. The sensor holder shall be constructed from
non-conductive heat resistant material with a thermal conduc-
NOTE 4—HMP solders consisting of 5%Sb-95%Pb (~307°C melting
point) and 5%Sb-93.5%Pb-1.5%Ag (;300°C melting point) have been
tivity value of ≤ 0.15 W/m·K, high temperature stability, and
found to be suitable. The 280°C temperature minimum identified above
resistance to thermal shock. The board shall be nominally 1.3
corresponds to the point where melting of the solder bond would be
cm (0.5 in.) or greater in thickness. The sensor is held into the
experienced with an ~17 second exposure of an 84 kW/m heat flux to a
recess of the board using three straight pins, trimmed to a
prepared copper calorimeter with a surface area of 12.57 cm and a mass
nominal length of 5 mm, by placing them equidistant around of 18.0 g.Acareful soldering technique is required to avoid “cold” solder
joints (where the solder has not formed a suitable bond of the thermo-
the edge of the sensor so that the heads of the pins hold the
couple to the copper disk).
sensor flush to the surface.
6.5.1.1 Paint the exposed surface of the copper slug calo- 6.5.3 Weight the sensor board assembly so that the total
massis1.0 60.01kgandthedownwardforceexhibitedbythe
rimeter with a thin coating of a flat black high temperature
spray paint with an absorptivity of 0.9 or greater. The painted copper slug sensor surface is uniform.
NOTE 5—Any system of weighting that provides a uniformly weighted
A500 Watt T3 120VAC quartz infrared heat lamp, product number 21651-1
from Philips Lighting Company has been used successfully in this application.
5 7
See Test Method E457 for information regarding slug calorimeters. Supporting data have been filed atASTM Inte
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