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ASTM D7124-16

(Specification)

Standard Specification for Benzene for Use with Zeolite Based Catalysts

Standard Specification for Benzene for Use with Zeolite Based Catalysts

ABSTRACT
This specification covers benzene for use with zeolite based catalysts. Tests shall be performed to determine the property requirements of benzene in accordance to the following test methods: benzene weight percentage; sulfur mass; thiophene mass; toluene mass; nonaromatic hydrocarbons weight percentage; nitrogen mass; acid wash color; bromine index, water, and appearance.
SCOPE
1.1 This specification covers benzene for use with zeolite based catalysts.  
1.2 The following applies to all specified limits in this specification: for purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 Consult current OSHA regulations, supplier’s Safety Data Sheets, and local regulations for all materials used in this specification.

General Information

Status
Historical
Publication Date
31-May-2016
ICS
71.080.15 - Aromatic hydrocarbons
Technical Committee
D16 - Aromatic, Industrial, Specialty and Related Chemicals
Drafting Committee
D16.01 - Benzene, Toluene, Xylenes, Cyclohexane and Their Derivatives
Current Stage
Ref Project

Relations

Replaces
ASTM D7124-12 - Standard Specification for Benzene for Use with Zeolite Based Catalysts
Effective Date
01-Jun-2016
Replaced By
ASTM D7124-17 - Standard Specification for Benzene for Use with Zeolite Based Catalysts
Effective Date
01-Jun-2017

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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D7124 −16
Standard Specification for
1
Benzene for Use with Zeolite Based Catalysts
This standard is issued under the fixed designation D7124; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* in Refined Benzene by Gas Chromatography
D5386 Test Method for Color of Liquids Using Tristimulus
1.1 This specification covers benzene for use with zeolite
Colorimetry
based catalysts.
D5776 Test Method for Bromine Index of Aromatic Hydro-
1.2 The following applies to all specified limits in this
carbons by Electrometric Titration
specification: for purposes of determining conformance with
D6304 Test Method for Determination of Water in Petro-
this specification, an observed value or a calculated value shall
leum Products, Lubricating Oils, and Additives by Cou-
be rounded off “to the nearest unit” in the last right-hand digit
lometric Karl Fischer Titration
used in expressing the specification limit, in accordance with
D7011 Test Method for Determination of Trace Thiophene
the rounding-off method of Practice E29.
in Refined Benzene by Gas Chromatography and Sulfur
1.3 The values stated in SI units are to be regarded as the
Selective Detection
standard. The values given in parentheses are for information
D7183 Test Method for Determination of Total Sulfur in
only.
Aromatic Hydrocarbons and Related Chemicals by Ultra-
violet Fluorescence
1.4 Consult current OSHA regulations, supplier’s Safety
Data Sheets, and local regulations for all materials used in this D7184 Test Method for Ultra Low Nitrogen in Aromatic
specification. Hydrocarbons by Oxidative Combustion and Reduced
Pressure Chemiluminescence Detection
2. Referenced Documents
D7359 Test Method for Total Fluorine, Chlorine and Sulfur
2
in Aromatic Hydrocarbons and Their Mixtures by Oxida-
2.1 ASTM Standards:
tive Pyrohydrolytic Combustion followed by Ion Chroma-
D848 Test Method for Acid Wash Color of Industrial Aro-
tography Detection (Combustion Ion Chromatography-
matic Hydrocarbons
CIC)
D1492 Test Method for Bromine Index of Aromatic Hydro-
D7360 Test Method for Analysis of Benzene by Gas Chro-
carbons by Coulometric Titration
D1685 Test Method for Traces of Thiophene in Benzene by matography with External Calibration
3
Spectrophotometry (Withdrawn 2009) D7375 Test Method for Trace Quantities of Water in Aro-
D3437 Practice for Sampling and Handling Liquid Cyclic matic Hydrocarbons and Their Mixtures by Coulometric
Products Karl Fischer Titration
D4492 Test Method for Analysis of Benzene by Gas Chro-
D7457 Test Method for Determining Chloride in Aromatic
matography
Hydrocarbons and Related Chemicals by Microcoulom-
D4735 Test Method for Determination of Trace Thiophene
etry
D7504 Test Method for Trace Impurities in Monocyclic
Aromatic Hydrocarbons by Gas Chromatography and
1
This specification is under the jurisdiction of ASTM Committee D16 on
Effective Carbon Number
Aromatic Hydrocarbons and Related Chemicals and is the direct responsibility of
D7536 Test Method for Chlorine in Aromatics by Mono-
Subcommittee D16.01 on Benzene, Toluene, Xylenes, Cyclohexane and Their
chromatic Wavelength Dispersive X-ray Fluorescence
Derivatives.
CurrenteditionapprovedJune1,2016.PublishedJuly2016.Originallyapproved
Spectrometry
in 2005. Last previous edition approved in 2012 as D7124 – 12. DOI: 10.1520/
D8005 Test Method for Color of Clear Liquids (Platinum-
D7124-16.
2
Cobalt Scale)
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
E29 Practice for Using Significant Digits in Test Data to
Standards volume information, refer to the standard’s Document Summary page on
Determine Conformance with Specifications
the ASTM website.
3 E1064 Test Method for Water in Organic Liquids by Coulo-
The last approved version of this historical standard is referenced on
www.astm.org. metric Karl Fischer Titration
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D7124−16
2.2 Other Document: 4. Sampling
OSHA Regulations, 29 CFR paragraphs 1910.1000 and
4.1 The material shall be sampled in accordance with
4
1910.1200
Practice D3437.
3. Properties
5. Supplementary Requirements (Non-mandatory)
3.1 Benzene for use with zeolite based catalysts shall
conform to the following requirements:
5.1 The following supplementary requirements shall apply
ASTM Test
when agreed upon by the supplier and purchas
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D7124 − 12 D7124 − 16
Standard Specification for
1
Benzene for Use with Zeolite Based Catalysts
This standard is issued under the fixed designation D7124; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This specification covers benzene for use with zeolite based catalysts.
1.2 The following applies to all specified limits in this specification: for purposes of determining conformance with this
specification, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used
in expressing the specification limit, in accordance with the rounding-off method of Practice E29.
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.4 Consult current OSHA regulations, supplier’s Material supplier’s Safety Data Sheets, and local regulations for all materials
used in this specification.
2. Referenced Documents
2
2.1 ASTM Standards:
D848 Test Method for Acid Wash Color of Industrial Aromatic Hydrocarbons
D1209 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)
D1492 Test Method for Bromine Index of Aromatic Hydrocarbons by Coulometric Titration
3
D1685 Test Method for Traces of Thiophene in Benzene by Spectrophotometry (Withdrawn 2009)
D3437 Practice for Sampling and Handling Liquid Cyclic Products
D4492 Test Method for Analysis of Benzene by Gas Chromatography
D4735 Test Method for Determination of Trace Thiophene in Refined Benzene by Gas Chromatography
D5386 Test Method for Color of Liquids Using Tristimulus Colorimetry
D5776 Test Method for Bromine Index of Aromatic Hydrocarbons by Electrometric Titration
D6069 Test Method for Trace Nitrogen in Aromatic Hydrocarbons by Oxidative Combustion and Reduced Pressure
3
Chemiluminescence Detection (Withdrawn 2015)
D6304 Test Method for Determination of Water in Petroleum Products, Lubricating Oils, and Additives by Coulometric Karl
Fischer Titration
D7011 Test Method for Determination of Trace Thiophene in Refined Benzene by Gas Chromatography and Sulfur Selective
Detection
D7183 Test Method for Determination of Total Sulfur in Aromatic Hydrocarbons and Related Chemicals by Ultraviolet
Fluorescence
D7184 Test Method for Ultra Low Nitrogen in Aromatic Hydrocarbons by Oxidative Combustion and Reduced Pressure
Chemiluminescence Detection
D7359 Test Method for Total Fluorine, Chlorine and Sulfur in Aromatic Hydrocarbons and Their Mixtures by Oxidative
Pyrohydrolytic Combustion followed by Ion Chromatography Detection (Combustion Ion Chromatography-CIC)
D7360 Test Method for Analysis of Benzene by Gas Chromatography with External Calibration
D7375 Test Method for Trace Quantities of Water in Aromatic Hydrocarbons and Their Mixtures by Coulometric Karl Fischer
Titration
D7457 Test Method for Determining Chloride in Aromatic Hydrocarbons and Related Chemicals by Microcoulometry
1
This specification is under the jurisdiction of ASTM Committee D16 on Aromatic Hydrocarbons and Related Chemicals and is the direct responsibility of Subcommittee
D16.01 on Benzene, Toluene, Xylenes, Cyclohexane and Their Derivatives.
Current edition approved Nov. 1, 2012June 1, 2016. Published December 2012July 2016. Originally approved in 2005. Last previous edition approved in 20112012 as
D7124 – 11.D7124 – 12. DOI: 10.1520/D7124-12.10.1520/D7124-16.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’sstandard’s Document Summary page on the ASTM website.
3
The last approved version of this historical standard is referenced on www.astm.org.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D7124 − 16
D7504 Test Method for Trace Impurities in Monocyclic Aromatic Hydrocarbons by Gas Chromatography and Effective Carbon
Number
D7536 Test Method for Chlorine in Aromatics by Monochromatic Wavelength Dispersive X-ray Fluorescence Spectrometry
D8005 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)
E29 Practice for Using Signi
...

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