ASTM D858-02

Standard Test Methods for Manganese in Water

SCOPE
1.1 These test methods cover the atomic absorption determination of dissolved and total recoverable manganese in water and certain wastewaters. Three test methods are given as follows: Concentration Range SectionsTest Method A-Atomic Absorption, Direct  0.1 to 5 mg/L7 to 15Test Method B-Atomic Absorption, Chelation-Extraction  10 to 500 μg/L 16 to 24Test Method C-Atomic Absorption, Graphite Furnace 5 to 50 μg/L25 to 33
1.2 Test Methods A, B, and C were used successfully on reagent grade and natural waters. Other matrices used in the study were brine (Test Method B), effluent from a wood treatment plant, and condensate from a medium Btu coal gasification process (Test Method C). It is the user's responsibility to ensure the validity of a test method for waters of untested matrices.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see 11.7.1, 20.2, 20.9 and 22.10.
1.4 Former Test Method A (Colorimetric) was discontinued. For historical information, see Appendix X1.

General Information

• Status: Historical
• Publication Date: 09-Mar-2002
• ICS: 13.060.50 - Examination of water for chemical substances
• Technical Committee: D19 - Water
• Drafting Committee: D19.05 - Inorganic Constituents in Water

Relations

• Replaces: ASTM D858-95 - Standard Test Methods for Manganese in Water
• Effective Date: 10-Mar-2002
• Replaced By: ASTM D858-07 - Standard Test Methods for Manganese in Water
• Effective Date: 01-Aug-2007
• Referred By: ASTM D1068-15 - Standard Test Methods for Iron in Water
• Effective Date: 10-Mar-2002
• Referred By: ASTM D1691-17 - Standard Test Methods for Zinc in Water
• Effective Date: 10-Mar-2002
• Referred By: ASTM D1688-17 - Standard Test Methods for Copper in Water
• Effective Date: 10-Mar-2002
• Referred By: ASTM D1687-17 - Standard Test Methods for Chromium in Water
• Effective Date: 10-Mar-2002
• Referred By: ASTM D4382-18 - Standard Test Method for Barium in Water, Atomic Absorption Spectrophotometry, Graphite Furnace
• Effective Date: 10-Mar-2002
• Referred By: ASTM D3559-15 - Standard Test Methods for Lead in Water
• Effective Date: 10-Mar-2002
• Referred By: ASTM D8006-16 - Standard Guide for Sampling and Analysis of Residential and Commercial Water Supply Wells in Areas of Exploration and Production (E&P) Operations
• Effective Date: 10-Mar-2002
• Referred By: ASTM C375-22 - Standard Classification of Water Used in Milling of Porcelain Enamel
• Effective Date: 10-Mar-2002
• Referred By: ASTM D4309-18 - Standard Practice for Sample Digestion Using Closed Vessel Microwave Heating Technique for the Determination of Total Metals in Water
• Effective Date: 10-Mar-2002
• Referred By: ASTM D1886-14(2021)e1 - Standard Test Methods for Nickel in Water
• Effective Date: 10-Mar-2002
• Referred By: ASTM D3558-15 - Standard Test Methods for Cobalt in Water
• Effective Date: 10-Mar-2002
• Referred By: ASTM D3645-15 - Standard Test Methods for Beryllium in Water
• Effective Date: 10-Mar-2002
• Referred By: ASTM D1971-16(2021)e1 - Standard Practices for Digestion of Water Samples for Determination of Metals by Flame Atomic Absorption, Graphite Furnace Atomic Absorption, Plasma Emission Spectroscopy, or Plasma Mass Spectrometry
• Effective Date: 10-Mar-2002

Standards Content (Sample)

NOTICE: NOTICE: This standardThis standard has either been superseded has either been superseded andand replaced replacedby a new version or withdrawn by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Contact ASTM International (www.astm.org) for the lastest information

Designation:D 858–02
Standard Test Methods for
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Manganese in Water
This standard is issued under the fixed designation D 858; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope D1192 Specification for Equipment for SamplingWater and
3
Steam in Closed Conduits
1.1 These test methods cover the atomic absorption deter-
3
D 1193 Specification for Reagent Water
mination of dissolved and total recoverable manganese in
3
D 1687 Test Methods for Chromium in Water
water and certain wastewaters. Three test methods are given as
3
D 1688 Test Methods for Copper in Water
follows:
3
D 1691 Test Methods for Zinc in Water
Concentration
3
D 1886 Test Methods for Nickel in Water
Range Sections
Test Method A—Atomic Absorption, Di- 0.1 to 5 mg/L 7 to 15
D 2777 Practice for Determination of Precision and Bias of
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rect
3
Applicable Methods of Committee D19 on Water
Test Method B—Atomic Absorption, 10 to 500 µg/L 16 to 24
2
D 3370 Practices for Sampling Water from Closed Con-
Chelation-Extraction
3
Test Method C—Atomic Absorption, 5to50µg/L 25to33
duits
Graphite Furnace
3
D 3557 Test Methods for Cadmium in Water
3
1.2 Test Methods A, B, and C were used successfully on
D 3558 Test Methods for Cobalt in Water
3
reagent grade and natural waters. Other matrices used in the
D 3559 Test Method for Lead in Water
study were brine (Test Method B), effluent from a wood
D 3919 Practice for Measuring Trace Elements in Water by
3
treatment plant, and condensate from a medium Btu coal
Graphite Furnace Atomic Absorption Spectrophotometry
gasification process (Test Method C). It is the user’s responsi-
D 4841 Practice for Estimation of Holding Time for Water
3
bility to ensure the validity of a test method for waters of
Samples Containing Organic and Inorganic Constituents
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untested matrices.
D 5810 Guide for Spiking into Aqueous Samples
1.3 This standard does not purport to address all of the
D 5847 Practice for Writing Quality Control Specifications
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safety concerns, if any, associated with its use. It is the
for Standard Test Methods for Water Analysis
responsibility of the user of this standard to establish appro-
3. Terminology
priate safety and health practices and determine the applica-
bility of regulatory limitations prior to use. For specific hazard 3.1 Definitions of Terms Specific to This Standard:
statements, see 11.7.1, 20.2, 20.9, and 22.10.
3.1.1 total recoverable manganese—an arbitrary analytical
1.4 FormerTest MethodA(Colorimetric) was discontinued. term relating to the recoverable forms of manganese that are
For historical information, see Appendix X1.
determinable by the digestion method which is included in the
procedure.
2. Referenced Documents
3.2 Definitions:
2.1 ASTM Standards:
3.2.1 For definitions of terms used in these test methods,
3
D 1066 Practice for Sampling Steam
refer to Terminology D 1129.
3
D 1068 Test Methods for Iron in Water
3
4. Significance and Use
D 1129 Terminology Relating to Water
4.1 Elementalconstituentsinpotablewater,receivingwater,
and wastewater need to be identified for support of effective
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These test methods are under the jurisdiction of ASTM Committee D19 on
pollution control programs. Test MethodsA, B, and C provide
Water and are the direct responsibility of Subcommittee D19.05 on Inorganic
the techniques necessary to make such measurements.
Constituents in Water.
4.2 Although inhaled manganese dusts have been reported
Current edition approved March 10, 2002. Published June 2002. Originally
published as D 858 – 45 T. Last previous edition D 858 – 95. to be toxic to humans, manganese normally is ingested as a
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Platte, J.A., and Marcy,V. M., “ANewTool for theWater Chemist,” Industrial
trace nutrient in both food and water. Because it is considered
Water Engineering, May 1965. Brown, E., Skougstad, M. W., and Fishman, M. J.,
to be relatively nontoxic to man, as well as aquatic life, a limit
“Methods for Collection andAnalysis ofWater Samples for Dissolved Minerals and
Gases,” Techniques of Water-Resources Investigations of the U.S. Geological
Survey, Book 5, Chapter A1, 1970, p. 115.
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Annual Book of ASTM Standards, Vol 11.01. Annual Book of ASTM Standards, Vol 11.02.
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