iTeh StandardsiTeh Standards
EURUSD
Your shopping cart is empty.
ASTM

ASTM D5194-04

(Test Method)

Standard Test Method for Trace Chloride in Liquid Aromatic Hydrocarbons

Standard Test Method for Trace Chloride in Liquid Aromatic Hydrocarbons

SCOPE
1.1 This test method covers the determination of total chloride (organic and inorganic) in liquid aromatic hydrocarbons and cyclohexane.
1.2 The test method is applicable to samples with chloride concentrations of 1 to 25 mg/kg.
1.3 Bromides and iodides, if present, will be calculated as chlorides.
1.4 Materials, such as styrene, that are polymerized by sodium biphenyl reagent cannot be analyzed by this test method.
1.5 The following applies to all specified limits in this test method: for purposes of determining conformance with this test method, an observed value or a calculated value shall be rounded off "to the nearest unit" in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E 29.
1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For a specific hazard statement, see Section .

General Information

Status
Historical
Publication Date
30-Nov-2004
ICS
71.080.15 - Aromatic hydrocarbons
Technical Committee
D16 - Aromatic, Industrial, Specialty and Related Chemicals
Drafting Committee
D16.04 - Instrumental Analysis
Current Stage
Ref Project

Relations

Replaces
ASTM D5194-96(2000) - Standard Test Method for Trace Chloride in Liquid Aromatic Hydrocarbons
Effective Date
01-Dec-2004
Replaced By
ASTM D5194-06 - Standard Test Method for Trace Chloride in Liquid Aromatic Hydrocarbons
Effective Date
01-Mar-2006
Referred By
ASTM D7185-19 - Standard Specification for Low Toluene Low Dioxane (LTLD) Benzene
Effective Date
01-Dec-2004
Referred By
ASTM D5808-20 - Standard Test Method for Determining Chloride in Aromatic Hydrocarbons and Related Chemicals by Microcoulometry
Effective Date
01-Dec-2004
Referred By
ASTM D3193-19 - Standard Specification for Ethylbenzene
Effective Date
01-Dec-2004
Referred By
ASTM D2359-19 - Standard Specification for Refined Benzene-535
Effective Date
01-Dec-2004
Referred By
ASTM D5211-19 - Standard Specification for Xylenes for <emph type="ital">p</emph>-Xylene Feedstock
Effective Date
01-Dec-2004
Referred By
ASTM D7124-19 - Standard Specification for Benzene for Use with Zeolite Based Catalysts
Effective Date
01-Dec-2004

Buy Standard

ASTM D5194-04 - Standard Test Method for Trace Chloride in Liquid Aromatic HydrocarbonsASTM D5194-04 - Standard Test Method for Trace Chloride in Liquid Aromatic Hydrocarbons
PreviousNext
Standard
ASTM D5194-04 - Standard Test Method for Trace Chloride in Liquid Aromatic Hydrocarbons
English language
4 pages
sale 15% off
Preview
sale 15% off
Preview

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D5194–04
Standard Test Method for
1
Trace Chloride in Liquid Aromatic Hydrocarbons
This standard is issued under the fixed designation D 5194; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope* D 3437 Practice for Sampling and Handling Liquid Cyclic
Products
1.1 This test method covers the determination of total
D 3505 Test Method for Density or Relative Density of
chloride (organic and inorganic) in liquid aromatic hydrocar-
Pure Liquid Chemicals
bons and cyclohexane.
D 4052 Test Method for Density and Relative Density of
1.2 The test method is applicable to samples with chloride
Liquids by Digital Density Meter
concentrations of 1 to 25 mg/kg.
E29 Practice for Using Significant Digits in Test Data to
1.3 Bromides and iodides, if present, will be calculated as
Determine Conformance with Specifications
chlorides.
2.2 Other Documents:
1.4 Materials, such as styrene, that are polymerized by
OSHA Regulations, 29 CFR, paragraphs 1910.1000 and
sodium biphenyl reagent cannot be analyzed by this test
3
1910.1200
method.
1.5 The following applies to all specified limits in this test
3. Summary of Test Method
method: for purposes of determining conformance with this
3.1 A known amount of hydrocarbon sample is transferred
test method, an observed value or a calculated value shall be
into a separatory funnel containing toluene. Sodium biphenyl
rounded off “to the nearest unit” in the last right-hand digit
reagent is added to convert organic halogens into inorganic
used in expressing the specification limit, in accordance with
halides. The excess reagent is decomposed with water and the
the rounding-off method of PracticeE29.
phases are separated. The aqueous phase is acidified, washed,
1.6 The values stated in SI units are to be regarded as
and concentrated. Acetone is added and the solution is titrated
standard. No other units of measurement are included in this
with silver nitrate solution.
standard.
1.7 This standard does not purport to address all of the
4. Significance and Use
safety concerns, if any, associated with its use. It is the
4.1 Organic and inorganic chlorine compounds can have a
responsibility of the user of this standard to establish appro-
deleterious effect on equipment and reactions in processes
priate safety and health practices and determine the applica-
involving aromatic hydrocarbons.
bility of regulatory limitations prior to use. For a specific
4.2 Maximum chloride levels are often specified for process
hazard statement, see Section 7.
streams and for aromatic hydrocarbon products.
2. Referenced Documents
5. Apparatus
2.1 ASTM Standards:
5.1 Titrator, potentiometric, recording, + 2000 mV range, 1
D 891 Test Methods for Specific Gravity, Apparent, of
2 mV resolution with dispenser having a volume readout of 0.00
Liquid Industrial Chemicals
to 9.99 mL or 0.00 to 99.99 mL and 0.01 % resolution.
D 1193 Specification for Reagent Water
5.2 Electrode, glass, reference.
5.3 Electrode, silver, billet type.
1
This test method is under the jurisdiction of ASTM Committee D16 on
6. Reagents and Materials
Aromatic Hydrocarbons and Related Chemicals and is the direct responsibility of
Subcommittee D16.04 on Instrumental Analysis.
6.1 Purity of Reagents—Reagent grade chemicals shall be
Current edition approved Dec. 1, 2004. Published January 2005. Originally
used in all tests. Unless otherwise indicated, it is intended that
approved in 1991. Last previous edition approved in 2000 as D 5194 – 96 (2000).
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
3
Standards volume information, refer to the standard’s Document Summary page on AvailablefromU.S.GovernmentPrintingOfficeSuperintendentofDocuments,
the ASTM website. 732 N. Capitol St., NW, Mail Stop: SDE, Washington, DC 20401.
*A Summary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
D5194–04
all reagents conform to the specifications of the Committee on 8. Sampling
Analytical Reagents of theAmerican Chemical Society, where
8.1 Refer to Practice D 3437 for proper sampling and
4
such specifications are available. Other grades may be used,
handling of liquid hydrocarbons analyzed by this test method.
provided it is first ascertained that the reagent is of sufficiently
high purity to permit its use without lessening the accuracy of
9. Electrode Preparation
the determi
...

Questions, Comments and Discussion

Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.

This May Also Interest You

ASTM
ASTM D2121-23(Test Method)
Standard Test Methods for Polymer Content of Styrene Monomer

SIGNIFICANCE AND USE
5.1 This test method can be used for determining polymer concentrations in styrene monomer.  
5.2 This test method will not detect dimers and trimers.  
5.3 This test method can be used for plant control and for specification analysis.
SCOPE
1.1 These test methods cover the determination of the polymer content of styrene monomer. It should be noted, however, that dimers and trimers are not measured by these test methods.  
1.2 Test Method A, which is based on the use of a spectrophotometer or photometer, is intended for the quantitative determination of the polymer content of styrene monomer in concentrations up to 15 mg/kg. Samples containing more than 15 mg/kg of polymer must be suitably diluted before measurement. The limit of detection (LOD) is 1.2 mg/kg and the limit of quantitation (LOQ) is 4.0 mg/kg. LOD and LOQ were calculated using the last sample in Table 1.  
1.3 Test Method B is a rapid visual procedure that is intended for the approximate evaluation of polymer to a maximum concentration of 1.0 mass %. Samples having a polymer content of 1.0 mass % or greater should be suitably diluted prior to measurement.  
1.4 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 9.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    4 pages
    English language
    sale 15% off
  • Standard
    4 pages
    English language
    sale 15% off
ASTM
ASTM D7504-23(Test Method)
Standard Test Method for Trace Impurities in Monocyclic Aromatic Hydrocarbons by Gas Chromatography and Effective Carbon Number

SIGNIFICANCE AND USE
5.1 Determining the type and amount of hydrocarbon impurities remaining from the manufacture of toluene, mixed xylenes, p-xylene, o-xylene, ethylbenzene, benzene, and styrene used as chemical intermediates and solvents is often required. This test method is suitable for setting specifications and for use as an internal quality control tool where these products are produced or are used. Typical impurities are: alkanes containing 1 to 10 carbons atoms, benzene, toluene, ethylbenzene (EB), xylenes, and aromatic hydrocarbons containing nine carbon atoms or more.  
5.2 This method may not detect all components and there may be unknown components that would be assigned inappropriate correction factors and thus, the results may not be absolute.
SCOPE
1.1 This test method covers the determination of total nonaromatic hydrocarbons and monocyclic aromatic hydrocarbons in benzene, toluene, ethylbenzene, p-xylene, o-xylene, styrene and mixed xylenes by gas chromatography. The purity of benzene, toluene, ethylbenzene, p-xylene, o-xylene, styrene and mixed xylenes is also calculated. Similar test methods, using the internal standard calibration technique and the external standard calibration technique, are Test Methods D2360, D5060, D5135, and D5917 respectively.  
1.2 The limit of detection (LOD) is 0.0002 mass % and limit of quantitation (LOQ) is 0.0006 mass % for impurities in toluene, mixed xylenes, p-xylene, o-xylene, ethylbenzene, benzene, and styrene.  
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    14 pages
    English language
    sale 15% off
  • Standard
    14 pages
    English language
    sale 15% off
ASTM
ASTM D5471-23(Specification)
Standard Specification for O-Xylene 980

ABSTRACT
This specification covers a grade of o-xylene identified as ortho-Xylene 980. O-xylene 980 shall be tested and sampled in accordance with standard test methods and practices and shall conform to the following requirements: purity; non-aromatic hydrocarbons; p-xylene plus m-xylene; C9 and heavier aromatics; cumene; bromine index; appearance which shall be a clear liquid, free of sediment and haze; color in the platinum-cobalt scale; and distillation range.
SCOPE
1.1 This specification covers a grade of o-xylene identified as ortho-Xylene 980.  
1.2 The following applies to all specified limits in this specification: for purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off to the nearest unit in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 Consult current OSHA regulations and supplier’s Safety Data Sheets, and local regulations for all materials used in this specification.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Technical specification
    2 pages
    English language
    sale 15% off
  • Technical specification
    2 pages
    English language
    sale 15% off
ASTM
ASTM D5713-23(Test Method)
Standard Test Method for Analysis of High Purity Benzene for Cyclohexane Feedstock by Capillary Gas Chromatography

SIGNIFICANCE AND USE
5.1 This test method is useful for benzene purity on the basis of impurities normally present in benzene and may be used for final product inspections and process control.  
5.2 This test method will detect the following impurities: toluene, methylcyclopentane, n-hexane, 2-methylhexane, cyclohexane, cyclopentane, 2-methylpentane, 2,3-dimethylpentane, 3-methylhexane, n-heptane, methylcyclohexane, ethylcyclopentane, 2,4-dimethylhexane, trimethylpentane, and others where specific impurity standards are available. Absolute purity cannot be accurately determined if unknown impurities are present.
SCOPE
1.1 This test method covers the determination of specific impurities in, and the purity of benzene for cyclohexane feedstock by gas chromatography.  
1.2 This test method has been found applicable to benzene in the range from 99 % to 100 % purity and to impurities at concentrations of 2 mg/kg to 10 000 mg/kg. The limit of detection (LOD) is 2 mg/kg for an impurity and the limit of quantitation (LOQ) is 6 mg/kg for an impurity.  
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see 7.2 and Section 8.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    4 pages
    English language
    sale 15% off
  • Standard
    4 pages
    English language
    sale 15% off
ASTM
ASTM D7057-23(Test Method)
Standard Test Method for Analysis of Isopropylbenzene (Cumene) by Gas Chromatography (External Standard)

SIGNIFICANCE AND USE
5.1 This test method is suitable for setting specifications on the materials referenced in 1.2 and for use as an internal quality control tool where isopropylbenzene is produced or is used in a manufacturing process. It may also be used in development or research work involving isopropylbenzene.  
5.2 This test method is useful in determining the purity of isopropylbenzene with normal impurities present. If extremely high boiling or unusual impurities are present in the isopropylbenzene, this test method would not necessarily detect them and the purity calculation would be erroneous.  
5.3 Cumene hydroperoxide, if present, will yield thermal decomposition products, primarily AP and DMPC as stated in 4.1, that will elute in the chromatogram thereby giving incorrect results unless they are excluded as indicated in 4.1. It is also possible to get erroneous results for trace alpha-methylstyrene present in isopropylbenzene if the inlet has become unduly contaminated with non-volatile foreign substances.  
5.4 The nonaromatic hydrocarbons commonly present from the isopropylbenzene manufacturing process, particularly a non-zeolitic one, will interfere with the determination of xylenes (if present).
SCOPE
1.1 This test method covers the determination of the purity of isopropylbenzene (cumene) by gas chromatography. Calibration of the gas chromatography system is done by the external standard calibration technique.  
1.2 This test method has been found applicable to the measurement of impurities such as nonaromatic hydrocarbons, benzene, toluene, ethylbenzene, phenol, cymenes, t-butylbenzene, n-butylbenzene, n-propylbenzene, alpha-methylstyrene, sec-butylbenzene, and diisopropylbenzenes, which are impurities that can be found in isopropylbenzene. The latter impurities can be analyzed over a range of 1 mg/kg to 500 mg/kg by this method (see Table 1). The limit of quantitation averages 3.8 mg/kg while the limit of detection for these impurities averages 1.1 mg/kg based on the data in Table 1.  
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 9.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    5 pages
    English language
    sale 15% off
  • Standard
    5 pages
    English language
    sale 15% off
ASTM
ASTM D4790-23(Terminology)
Standard Terminology of Aromatic Hydrocarbons and Related Chemicals
  • Standard
    6 pages
    English language
    sale 15% off
  • Standard
    6 pages
    English language
    sale 15% off
ASTM
ASTM D848-23(Test Method)
Standard Test Method for Acid Wash Color of Industrial Aromatic Hydrocarbons

SIGNIFICANCE AND USE
5.1 This test method is suitable for setting specifications on the materials referenced in 1.1. It may also be used as an internal quality control tool and in development or research work.  
5.2 The color developed in the acid layer gives an indication of impurities which if sulfonated would cause the material to be discolored.
SCOPE
1.1 This test method covers the determination of the acid wash color of benzene, toluene, xylenes, refined solvent naphthas, and similar industrial aromatic hydrocarbons.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8 and 12.1.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    4 pages
    English language
    sale 15% off
  • Standard
    4 pages
    English language
    sale 15% off
ASTM
ASTM D4077-23(Specification)
Standard Specification for Cumene (Isopropylbenzene)

ABSTRACT
This specification covers cumene (isopropylbenzene). Tests shall be performed to determine the requirements of cumene in accordance to the following test methods: purity; alpha-methylstrene, benzene, butylbenzenes, diisopropylbenzenes, ethylbenzene, phenols, n-propylbenzene, sulfur, bromine index, and appearance.
SCOPE
1.1 This specification covers cumene (isopropylbenzene).  
1.2 The following applies to all specified limits in this specification: for purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 Consult current OSHA Regulations and Supplier’s Safety Data Sheets, and local regulations for all materials used in this specification.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Technical specification
    2 pages
    English language
    sale 15% off
  • Technical specification
    2 pages
    English language
    sale 15% off
ASTM
ASTM D7977-23(Test Method)
Standard Test Methods for Polymer Content of AMS (α-Methylstyrene)

SIGNIFICANCE AND USE
4.1 This test method can be used for determining polymer concentrations in AMS monomer.  
4.2 This test method will not detect dimers and trimers.  
4.3 This test method can be used for plant control and for specification analysis. Information regarding plant control and specification analysis can be found in test method D6367.
SCOPE
1.1 This test method covers the determination of the polymer content of AMS (α-Methylstyrene). Dimers and trimers are not measured by these test methods.  
1.2 This test method has been found applicable to determining the polymer content of AMS in concentrations up to 15 mg/kg with an LOQ of 0.6 mg/kg and an LOD of 0.2 mg/kg based on the data in Table 1. Samples containing more than 15 mg/kg of polymer must be suitably diluted before measurement.  
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    4 pages
    English language
    sale 15% off
  • Standard
    4 pages
    English language
    sale 15% off
ASTM
ASTM D847-23(Test Method)
Standard Test Method for Acidity of Benzene, Toluene, Xylenes, Solvent Naphthas, and Similar Industrial Aromatic Hydrocarbons

SIGNIFICANCE AND USE
5.1 This test method is suitable for setting specifications, for use as an internal quality control tool, and for use in development or research work on industrial aromatic hydrocarbons and related materials. This test method gives an indication of residual acidity and is a measure of the quality of the finished product. It is an indication of the tendency of the product to corrode equipment.
SCOPE
1.1 This test method is intended for the detection of acidity of benzene, toluene, xylenes, solvent naphthas, and similar industrial aromatic hydrocarbons.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements see Section 9.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    3 pages
    English language
    sale 15% off
  • Standard
    3 pages
    English language
    sale 15% off